期刊文献+

热历史对聚丙烯β-晶热熔转变的影响 被引量:1

The Influence of Thermal History on the Melting Transformation of β-form Crystals of IPP
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摘要 用X-射线衍射和DSC,研究了用成核剂制得主含β-晶的的聚丙烯试样,在油浴及DSC样品池内等温结晶及不同条件热处理的各种样品的结晶度、β-晶相对含量及热熔行为;讨论了它们的变化情况及原因,阅明了伴随有重结晶现象的热熔过程的热历史影响。 Samples of Ipp with major β-form crystals obtained by using nucleating agents, crystallized isothermally either in oil bath or in sample cells of DSC, of them some were further thermally treated under different conditions. Their crystallinity, relative contents of β-form crystals, and DSC melting behaviors were studied. It was found that the melting process and the occurrence of recrystallization during melting depend on the thermal history of the samples.
出处 《中山大学学报(自然科学版)》 CAS CSCD 1989年第1期55-62,共8页 Acta Scientiarum Naturalium Universitatis Sunyatseni
关键词 聚丙烯 Β-晶型 热熔行为 IPP, β-form IPP, melting behavior
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参考文献3

  • 1潘鉴元,中山大学学报,1987年,2期,21页
  • 2史观一,科学通报,1981年,12卷,731页
  • 3李泮通,高分子通讯,1980年,3期,129页

同被引文献9

  • 1Li Jiangxiong,Cheung Wai Lam. Conversion of growth and recrystallisation of β-phase in doped iPP[J]. Polymer,1999,40 (8):2085-2088.
  • 2Varga J, Karger-Kocsis J. Rules of supermolecular structureformation in sheared isotactic polypropylene mehs[J]. Journal of Polymer Science:Part B, Polymer Physics, 1996, 34(4): 657-670.
  • 3Fujiyama M. Structure and properties of injection moldings of 13-crystal nucleator-added PP:Part 6, Addition of β-crystal nucleator to particulate-filled polyprupylenes[J]. Intern Polymer Processing, 1998,13(4): 411-416.
  • 4Tjong S C, Xu S A. Non-isothermal crystallization kinetics of calcium carbonate-filled B-crystalline phase polypropylene composites[J]. Polymer International,1997, 44(1): 95-103.
  • 5Li Jiangxiong, Cheung Wai Lain, Jia Demin. A study on the heat of fusion of β-polypropylene[J]. Polymer, 1999, 40(5): 1219-1222.
  • 6Varga J. β-Modification of isotactic polypropylene: Prearation, structure, processing, properties and application[J]. Journal of Macromolecu]ar Science:Part B,Physics, 2002, 41 (4/5/6): 1121-1171.
  • 7MenyhOrd A, Faludi G, Varga J. β-Crystallisation tendency and structure of polypropylene grafted by maleic anhydide and its blends with isotactic polypropylene[J].Journal of Thermal Analysis and Calorimetry, 2008, 93(3): 937-945.
  • 8李素云 刘长维 陈炎 等.聚丙烯注射模塑工艺条件与结构形态和性能的研究.塑料工业,:19-24.
  • 9陆瞿亮,窦强.N,N′-二苯基丁二酰胺诱导生成β晶型等规聚丙烯[J].高分子材料科学与工程,2009,25(1):98-100. 被引量:5

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