摘要
以定标粒子理论为基础，通过对溶质、溶剂分子间的相互作用加以系统研究，得到了描述溶质、溶剂分子参量及色谱条件对气相色谱过程中溶质容量因子的影响规律。通过实验证实了溶质容量因子在一定范围内与柱压近似呈线性关系，并验证了容量因子与柱温及加和性物性参量的关系。
y making a study of the interaction between solute and solvents,based on the scaled particle theory,the relation equation between solute's physical factor and k'and the relation equation between chromatography condition and k 'are obtained.These equations have been tested in experiments.
出处
《色谱》
CAS
CSCD
北大核心
1995年第5期334-336,共3页
Chinese Journal of Chromatography
关键词
气相色谱
定标粒子理论
保留值方程
gas chromatography theory,the scaled particle theory,retention value equation
