摘要
气相色谱过程中同系物组分的比保留体积V_g的对数与柱温T_c的倒数在一定条件下满足线性关系已为实验和理论所证实,被称之为交点规律。对交点、线性方程的斜率与其它物性参数量之间的关系以及线性关系的适用范围的研究,前人已做过大量的工作。
The extrapolated curves of Inl-g versus \/T for homologues often intersect at one point in GLC but not in all cases . This paper applies the scaled particle theory to study this case. and gains the intersecting point equation which is explained theoretically-
出处
《色谱》
CAS
CSCD
北大核心
1993年第4期219-221,共3页
Chinese Journal of Chromatography
