摘要
推导了适用于由单电解池和双电解池所获得的微分示波伏安曲线方程,从理论上描述了i'_f和i″_f的示波图象。
Equations describing various differential oscillographic voltammetric curves if,if (single cell)and(Δif),(Δif)'(double cells)were developed in this paper. Some valuable conclusions were obtained:(1)curves of the type(ΔAif)',(Δif)=f(E) having the same shapes as those of i'f,i'f=f(E), are more sensitive than the latter ones;(2)the peak-peak values can be enhanced by adjusting suitable electric parameters i_0 and f, which is beneficial to the observation of oscillogram changes at the end-point in titrations.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1995年第10期1532-1534,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
微分示波
伏安法
单电解池
双电解池
示波图象
Differential oscillographic voltammetric curves, Single cell, Double cells