摘要
双电解池正反馈示波计时电位法研究郑建斌，高鸿，朱俊杰，胡娟（西北大学电分析化学研究所，西安，７１００６９）（南京大学化学系）关键词正反馈示波计时电位法，双电解池，切口由于在经典示波计时电位法中所施加的交流极化电流的频率很高，充电电流就构成了影响去极剂...
A new method named double electrolytic cell positive feedback oscillographic chronopotentiometry was presented in this paper, and its repeatability was studied. The minimum concentration yielding a measurable incision was determined. The major factors affecting the results of positive feedback were also discussed. The experimental results show that the sensitivity of the new method is 1-5times as high as that of classical method.Therefore, the new method is very useful in microtitration, and it has an important significance to enhance sensitivity of reprocal oscillographic chronopotentiometry as well as other methods based on (dE/dt)-E curves.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1994年第4期509-511,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
正反馈
示波计时电位
双电解池
Positive feedback oscillographic chronopotentiometry,Double electrolytic cell,Incision
