摘要
合成了N-萘甲酰基二茂铁乙酮腙与Cu(Ⅱ)、Ni(Ⅱ)和Co(Ⅱ)的配合物,通过元素分析、IR、 ̄1HNMR、UV、热分析和摩尔电导对配体和配合物进行了表征,研究了配体与金属离子的键合方式及配合物的组成和性质。研究结果表明,配合物的热稳定性都比配体的高。配体和配合物都是弱电解质。
The complexes of acetylferrocenyl naphthoyl hydrazone with Cu(Ⅱ)、Ni(Ⅱ)andCo(Ⅱ)have been synthesized.The characterization of the ligand and complexes have been madeby the elemental analyses、IR、 ̄1HNMR、UV、TG-DTA and molar conductance。The nature of ligandto metal ion bonding in its coordination compound and composition and proporties of the complexeshave been researched. The results show that the thermal stability of the complexes is much higherthan that of the ligand,and that they are attributed to weak electrolytes.
出处
《郑州大学学报(自然科学版)》
CAS
1995年第2期85-89,共5页
Journal of Zhengzhou University (Natural Science)
基金
河南省自然科学基金资助项目