摘要
用分光光度法研究了ＯＰ对Ｎｉ在盐水中的缓蚀作用，应用吸附理论和Ｓｅｋｉｎｅ方法处理实验数据，发现ＯＰ在Ｎｉ表面发生了吸附并服从Ｌａｎｇｍｕｉｒ吸附等温式．求得吸附热为５２．２９ｋＪ·ｍｏｌ－１，可以认为这种吸附是产生缓蚀作用的主要原因．
The inhibitory effect of nickl caused by OP (p-octyl polyethylene glycol phenyl ether) in sodium chlorid solution has been studed by spectrophotometric method. The experimental results are explained with adsorption theroy and Sekine's method. It is sugestide that OP is adsorpted by the surface of nickl in acidic sodium chloride solution. The adsorption obeys Langmuir's isotherm and is the main cause of inhibition. The experimental adsorption heat is 52. 29 kJ/mol.
出处
《陕西师大学报（自然科学版）》
CSCD
1994年第2期41-44,共4页
Journal of Shaanxi Normal University(Natural Science Edition)
关键词
镍
吸附
缓蚀
非离子型
表面活性剂
inhibition
nickl
adsorption heat
spectrophotometry
