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热压工艺参数对n型和p型Bi_2Te_3基赝三元热电材料电学性能的影响 被引量:14

Influence of process parameters on the electrical properties of n-type and p-type Bi_2Te_3-based pseudo-ternary thermoelectric materials by the hot-pressing method
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摘要 通过熔炼研磨热压方法制备了n型和p型赝三元Bi2Te3基的热压合金样品,测量了由不同工艺参数(热压温度、热压压力)制备的样品Seebeck系数和电导率.分析了热压参数对热电性能产生的影响.特别是发现了增加热压压力和热压温度会使n型和p型热压样品的Seebeck系数和电导率都有所提高,这与单晶和取向晶体材料的Seebeck系数和电导率变化趋势相反的规律显然不同,其结果对热压样品的电学性能提高有积极的影响. Seebeck coefficient and electrical conductivity of the N-type and beta-type Bi2Te3-based alloys prepared by melting/grinding/hot-pressing method for different process parameters (temperature and pressure of hot-pressing) were measured, and the effects of process parameters were analyzed. It has been found that the temperature and pressure of hot-pressing play very important roles in enhancing both Seebeck coefficient and electrical conductivity of the Bi-2 Te-3-based alloys. The phenomena are different from those of Bi-2 Te-3 single crystal and its oriented crystal in the electrical properties. Better electrical properties may be obtained.
出处 《物理学报》 SCIE EI CAS CSCD 北大核心 2005年第7期3321-3326,共6页 Acta Physica Sinica
基金 教育部科学技术研究重点项目(批准号:00163) 哈尔滨市重点科技攻关计划项目(批准号:0111210024) 黑龙江省教育厅科学技术计划项目(批准号:10541091)资助的课题.~~
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