摘要
本文使用一种根据实验测定的动力学数据推求活化能与温度关系的作图方法,用这种方法求出的速度常数比用阿累尼乌斯公式得到的结果更好地符合实验值。这种方法可以在原则上解决求与温度无关的活化能Eo的问题。
A method of obtaining temperature dependence of the activation energy from the experimental kinetic datum is presented in this article. The rate constant derived from this method is better fitted to experimental value than that of Arrhenius equation. The temperature-indenpendence activation energy Eo could be calculated by this method principally.
关键词
活化能
温度
activation energy, temperature
