摘要
让过氧化来甲酰和五氯化钼与氯苯反应，生成一个新的双核钼配合物［（Ｃ＿６Ｈ＿４Ｃｌ）＿２Ｃ（ｐｈ）］＿２［Ｍｏ＿２（μ－Ｃｌ）＿３Ｃｌ＿４Ｏ＿２］［Ｍｏ＿２（μ－Ｃｌ）＿２Ｃｌ＿４Ｏ＿２（μ－ＯＣＯＰｈ）］。用Ｘ－射线单晶衍射的方法测定了它的晶体结构。同时还研究了该化合物的谱学性质，并用ＡＳＥ—ＭＯ方法计算了它的电子结构。
A new dimolybdenum(V)complex[(C_6H_4Cl )_2C(Ph)]_2[Mo_2(μ-Cl)_3Cl_4O_2][Mo_2(μ-Cl)_2Cl_4O_2(μ-OCOPh)] has been obtained in the reaction of phcl withbenzoyl peroxltie(PhCO_2)_2 and MoCl_5. Its crystal structure has been determined by X-raydiffraction method. Spectroscopic characterization of the compound and ASED-MO calculation of the trityl cation are reported.
出处
《合成化学》
CAS
CSCD
1994年第1期75-78,共4页
Chinese Journal of Synthetic Chemistry
关键词
晶体
苯环
缩合反应
双核
钼络合物
Benzoyl peroxides,Molybeenum pentachlorltie,Dimolybdenum complex,Crystal structure,ASED-MO.
