摘要
合成了丙烯酸三苯基锡酯及其聚合物，通过ＩＲ、￣１ＨＮＭＲ、￣（１３）ＣＮＭＲ对其结构进行了表征，推断单体中的锡原子与羰基氧原子间存在分子间的配键，锡原子的配位数是５，而聚合物没有形成锡氧配键。
Triplienyltin acrylate and its polymer have been syntliesized and characterized by IR,￣1H NMR and￣(13)C NMR. The spectral data shows that triphenyltin acrylate has,an intermolecular O→Sn coordination and a pentacoordinated tin atom, while its polymer has,no O→Sn coordination becausethe bulk of molecular chain prevents it from the formation of intermolecular coOrdination through oxy-sen atom.
出处
《合成化学》
CAS
CSCD
1994年第3期263-267,共5页
Chinese Journal of Synthetic Chemistry
关键词
丙烯酸
苯基锡酯
聚合物
合成表征
Triphenyltin acrylate, Polytriphenyltin acrylate,Synthesis , Characterication.
