摘要
根据热动力学的基础理论，本文建立了等浓度三级反应的无量纲参数法．计算了２０℃时环氧氯丙烷与氢溴酸反应，１５和２０℃时甲醛与氮反应的速率常数．在误差范围内与文献值相符合．证明了等浓度三级反应的正确性。
On the basic theory of thermokinet,iCS proposed in pyevions articlethe methodof dimensionless parameter for third order reactions with equalconcentraction in this paper. The rate constant of the reactions f o repichlorohydrin with hydrobromicacid and formaldehydewith ammonia is calcataledat 15 and 20 (:. The rate constant of this reactioms calculated. is in agreementwith the vaules in literature.Thus the ratidity of this methodshould be proved,and the applied regin of this methodis extended.
出处
《成都大学学报（自然科学版）》
1994年第3期8-12,共5页
Journal of Chengdu University（Natural Science Edition）
关键词
热动力学
无量纲参数
三级反应
thermokinetics equal concentraction
dimensionless parameter rate constant.
