摘要
在EG的沸点下,PET在EG中的醇解速度较慢.若在醇解体系中添加适量BHET,由于BHET与PET良好的相容性,会加速醇解反应;若再同时添加Zn(OAc)2等催化剂,会进一步加速醇解反应;若在醇解体系中EG,适量BHET,Zn(OAc)2及微量H2O同时并存,则会获得最佳醇解效果.这一研究不仅具有理论意义,也可供聚酯类生产厂家借鉴.
The alcoholysis speed of polyethylene terephthalate (PET) in ethylene glycol (EG) will be greatly accelerated when definite amount of bis-hydroxyethyl terephthalate (BHET) is added because of the good compatibility between PET and BHET.The optimal alcoholysis results can be obtained when BHET, Zn(OAc)2 and a little H,O are added together into the alcoholysis system.
出处
《北京服装学院学报(自然科学版)》
CAS
北大核心
1994年第1期29-33,共5页
Journal of Beijing Institute of Fashion Technology:Natural Science Edition
关键词
乙二醇
醇解
相容性
聚酯纤维
olyethviene terephthalate
ethanediol
alcoholvsis
compatibility