摘要
1-羟乙基-2-长链烷基-2-咪唑啉的水解反应是碱催化而酸抑制的,水解动力学方程符合拟一级反应,水解反应速率常数和盐效应则随溶液pH而变化。并随过实验提出一个水解反应机理。
The hydrolytic reactions of l-hydroxyethyl-2-long chain alkyl-2-imidazolines are catalyzed by bases and inhibited by acids. The Kinetic equations of its hydrolysis correspond to pseudo first order.Effect of rH on the variation of rate constants and salt-effect were obser-ved. A hydrolytic mechanism is an initial attack ty hydrcxide en the C2 atcm of the imidaz-oline-ring and amides are then formed by reaction of water with the intermediate comple.x
出处
《日用化学工业》
CAS
CSCD
北大核心
1989年第3期1-4,共4页
China Surfactant Detergent & Cosmetics