摘要
测定了两个含羟基中环二胺Ni( )配合物的变温磁化率,研究了Ni( )配合物的自旋特征和磁性.结果表明配合物分子间均存在反铁磁相互作用,配合物中Ni( )是高自旋,配合物的结构为八面体构型.
The magnetic susceptibilities of the Ni (Ⅱ) complexes with the hydroxyl mesocyclic diamines were measured at various temperatures, and the spin fashion and the magnetic property of the Ni (Ⅱ) complexes were studied. The results indicate there is an antiferromagnetic intermolecular interaction in the Ni (Ⅱ) complexes, which are octahedral coordination compounds and in which Ni (Ⅱ) is high spin.
出处
《华中师范大学学报（自然科学版）》
CAS
CSCD
北大核心
2004年第4期452-454,共3页
Journal of Central China Normal University：Natural Sciences
关键词
羟基中环二胺
Ni(Ⅱ)配合物
磁化率
自旋特征
hydroxyl mesocyclic diamine
Ni (Ⅱ) complex
magnetic susceptibility
spin fashion
