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固相反应合成丙二胺合钴氧合性能的研究 被引量:4

Oxygenation of Propane Diamine Cobalt(II) Complexes Synthesized via Solid State Reaction
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摘要 Eight Complexes were synthesized with propane diamine and cobalt with four different ions under the reaction of liquid-solid and solid-gas, respectively. After reacted with O2, they are characterized with elemental analysis, IR, XRD, thermogravimetric analysis. Their ability to bind O2 was studied with gas volume try. As a result, it is found that the ability to bind O2 was related to cobalt salt with different ions, and the types of synthesize methods due to different r eaction mechanism. Eight Complexes were synthesized with propane diamine and cobalt with four different ions under the reaction of liquid-solid and solid-gas, respectively. After reacted with O2, they are characterized with elemental analysis, IR, XRD, thermogravimetric analysis. Their ability to bind O2 was studied with gas volume try. As a result, it is found that the ability to bind O2 was related to cobalt salt with different ions, and the types of synthesize methods due to different r eaction mechanism.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2004年第12期1421-1425,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.29962003)
关键词 固相反应合成 丙二胺 钴配合物 氧合性能 氧载体 solid-state synthesis oxygen carrier propane diamine cob alt
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