摘要
Eight Complexes were synthesized with propane diamine and cobalt with four different ions under the reaction of liquid-solid and solid-gas, respectively. After reacted with O2, they are characterized with elemental analysis, IR, XRD, thermogravimetric analysis. Their ability to bind O2 was studied with gas volume try. As a result, it is found that the ability to bind O2 was related to cobalt salt with different ions, and the types of synthesize methods due to different r eaction mechanism.
Eight Complexes were synthesized with propane diamine and cobalt with four different ions under the reaction of liquid-solid and solid-gas, respectively. After reacted with O2, they are characterized with elemental analysis, IR, XRD, thermogravimetric analysis. Their ability to bind O2 was studied with gas volume try. As a result, it is found that the ability to bind O2 was related to cobalt salt with different ions, and the types of synthesize methods due to different r eaction mechanism.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2004年第12期1421-1425,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.29962003)