摘要
本文综述了研制多功能ZN催化剂用于乙烯、丙烯、1-丁烯、苯乙烯、1,4-丁二烯进行液相均聚反应和二元、三元共聚反应,以及对制得的产物的结构和性能进行表征。研究了采用ZN多功能催化剂进行气相乙烯均聚和乙烯、1-丁烯共聚反应,并对上述液相聚合反应和气相聚合反应规律、聚合反应动力学进行了详细的研究和比较。
Slurry or bulk homopolymerizations of ethylene, propylene, 1-butene, 1, 4-butadiene and styrene with various modified supported ZN catalysts have been studied in detail. The copolymerization and terpolymerizations of above monomers have also been studied and the structure-properties of products were charaterized, Gaseous phase polymerization of ethylene and its copolymerization with 1-butene with supported ZN catalysts have been investigated. The results were compared with that of slurry polymerization.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1993年第5期1-6,共6页
Polymer Materials Science & Engineering
关键词
ZN催化剂
烯烃
聚合反应
动力学
ZN catalyst, olefin, polymerization, kinetics, gaseous phase polymerization, slurry polymerization.
