摘要
Functionalized cyclopentenes could be prepared through Sm/TMSCl/t-BuOH mediated hydrodimerization cyclization of gem-diactivated alkene in one-pot at room temperature. The trans- or trans, transform isomer is in the majority and the major product was isolated from its stereoisomers through the fractional crystallization method.
Functionalized cyclopentenes could be prepared through Sm/TMSCl/t-BuOH mediated hydrodimerization cyclization of gem-diactivated alkene in one-pot at room temperature. The trans- or trans, transform isomer is in the majority and the major product was isolated from its stereoisomers through the fractional crystallization method.
基金
Project (No. 29872010) supported by the National Natural Science Foundation of China, the NSF of Zhejiang Province, China
the laboratory of Organometallic chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.
