Doping is essential for modulating semiconductor conductivity,forming p-n junctions,and reducing contact resistance[1].Notably,as organic semiconductors(OSCs)advance toward high performance,flexibility,and miniaturiza...Doping is essential for modulating semiconductor conductivity,forming p-n junctions,and reducing contact resistance[1].Notably,as organic semiconductors(OSCs)advance toward high performance,flexibility,and miniaturization,achieving precise regionally selective doping becomes critical for building complex,highly integrated devices[2].In inorganic semiconductors(e.g.,silicon),sub-100-nanometer regional doping is achievable through photolithography and ion implantation—techniques foundational to modern complementary metaloxide-semiconductor(CMOS)technology[3].展开更多
China is the country most seriously affected by coal and gas outburst accidents, which not only has the largest number of outburst mines, but also has a large number of outburst times and intensity. China's annual...China is the country most seriously affected by coal and gas outburst accidents, which not only has the largest number of outburst mines, but also has a large number of outburst times and intensity. China's annual total number of outburst and average intensity of outburst are far higher than the average level of major coal-producing countries in the world. In order to prevent coal and gas outburst accidents, China actively adopts coal mine outburst prevention measures, but the coal mine outburst prevention cost in China is as high as 50-60 yuan /t, which brings great economic pressure to coal mines. During coal seam mining and roadway excavation, on the one hand, when the mining work destroys or disturbs the original gas balance state in the stratum, the high gas in the coal seam will desorb and drift to the space with lower air pressure, and enter the goaf;On the other hand, mining causes the stress redistribution of surrounding rock in stope and changes the structure of coal and rock mass, and then changes the accumulation mode and migration form of gas in coal and rock mass, forming a certain width of outburst elimination area. In order to reduce the cost of outburst prevention and make rational use of outburst elimination belt, many coal and gas outburst mines in China adopt gob-side entry driving. However, the protection effect and scope of mined-out areas to surrounding solid coal are still unclear, and the Detailed Rules for Prevention and Control of Coal and Gas Outburst requires that mining activities in coal seams must take measures to eliminate outburst danger. Therefore, it is urgent to scientifically investigate and study the scope of pressure relief protection in solid coal along the gob side, so as to provide scientific basis and technical support for driving along the gob side, improve the utilization rate of resources, ensure safety in production, and have good economic and social benefits.展开更多
Organic-inorganic metal halides(OIMHs)have emerged as highly promising novel multifunctional optoelectronic materials,owing to their easily adjustable properties from a variety of combinations of different components....Organic-inorganic metal halides(OIMHs)have emerged as highly promising novel multifunctional optoelectronic materials,owing to their easily adjustable properties from a variety of combinations of different components.But it is still difficult and rare to realize highly tunable multicolor luminescence within the same material.In this work,we successfully incorporated three adjustable emission centers in OIMHs to synthesize a novel OIMH(NEA)_(2)MnBr_(4),with each emission center capable of emitting one of the primary colors—red,green,and blue.The green and red emissions originate from the tetrahedron and octahedron structures in the Mn-based frame,while the blue can be attributed to the contribution of organic components.Additionally,to achieve comparable emission intensity among the three primary colors,we enhanced the blue emission performance by optimizing the ratio of organic structure components and incorporating chirality in the OIMHs.The resulting high-quality films can be obtained by spin-coating method with a photoluminescence quantum yields of up to 96%.More interestingly,by the dual manipulation of excitation wavelength and temperature,the sample can be emitted at least seven distinct colors including a standard white luminescence at(0.33,0.33),opening up promising prospects for multicolor luminescence applications such as high-end anti-counterfeiting technology,light-emitting diodes,X-ray imaging,latent fingerprints,humidity detection,and so on.Therefore,based on application scenarios and requirements,our research on this highly tunable luminescent OIMH material lays a solid foundation for further development of various functional properties of related materials.展开更多
Microwave absorption(MA)materials often face poor synergy between impedance matching and attenuation in the low-frequency range.Balancing permittivity and permeability through magnetic-dielectric synergy is a promisin...Microwave absorption(MA)materials often face poor synergy between impedance matching and attenuation in the low-frequency range.Balancing permittivity and permeability through magnetic-dielectric synergy is a promising strategy to address this issue.To realize the synergy,herein,Sn whiskers with an in situ oxide layer served as substrates for magnetic-loss-active CoNi nanosheet growth,forming a hierarchical CoNi@SnO_(2)@Sn(CNS)heterostructure.The CNS absorber achieves a minimum reflection loss(RL_(min))value of-62.29 dB with an effective absorption bandwidth(EAB)of 2.2 GHz,covering the entire C-band with 70%absorption at only 2.61 mm thickness.The nanosheet design of CoNi enhances magnetic anisotropy to promote natural resonance,while the conductive Sn core and abundant Sn/SnO_(2) and CoNi/SnO_(2) heterointerfaces facilitate conduction loss and dielectric polarization.When composited into a thermoplastic polyurethane(TPU)matrix,the resulting CNS/TPU-2 film(20 wt%CNS)exhibits an RL_(min) value of-61.04 dB and a 2.5 GHz EAB.Its in-plane and through-plane thermal conductivities reach 2.41 and 0.51 W m^(-1) K^(-1),representing 4.1 and 2.6 times those of pure TPU films,respectively,facilitating heat dissipation from protected devices.This work provides valuable insights into magnetic-dielectric synergy for low-frequency MA of 1D metal-based materials,offering promising potential for 5G communications and flexible electronics.展开更多
文摘Doping is essential for modulating semiconductor conductivity,forming p-n junctions,and reducing contact resistance[1].Notably,as organic semiconductors(OSCs)advance toward high performance,flexibility,and miniaturization,achieving precise regionally selective doping becomes critical for building complex,highly integrated devices[2].In inorganic semiconductors(e.g.,silicon),sub-100-nanometer regional doping is achievable through photolithography and ion implantation—techniques foundational to modern complementary metaloxide-semiconductor(CMOS)technology[3].
文摘China is the country most seriously affected by coal and gas outburst accidents, which not only has the largest number of outburst mines, but also has a large number of outburst times and intensity. China's annual total number of outburst and average intensity of outburst are far higher than the average level of major coal-producing countries in the world. In order to prevent coal and gas outburst accidents, China actively adopts coal mine outburst prevention measures, but the coal mine outburst prevention cost in China is as high as 50-60 yuan /t, which brings great economic pressure to coal mines. During coal seam mining and roadway excavation, on the one hand, when the mining work destroys or disturbs the original gas balance state in the stratum, the high gas in the coal seam will desorb and drift to the space with lower air pressure, and enter the goaf;On the other hand, mining causes the stress redistribution of surrounding rock in stope and changes the structure of coal and rock mass, and then changes the accumulation mode and migration form of gas in coal and rock mass, forming a certain width of outburst elimination area. In order to reduce the cost of outburst prevention and make rational use of outburst elimination belt, many coal and gas outburst mines in China adopt gob-side entry driving. However, the protection effect and scope of mined-out areas to surrounding solid coal are still unclear, and the Detailed Rules for Prevention and Control of Coal and Gas Outburst requires that mining activities in coal seams must take measures to eliminate outburst danger. Therefore, it is urgent to scientifically investigate and study the scope of pressure relief protection in solid coal along the gob side, so as to provide scientific basis and technical support for driving along the gob side, improve the utilization rate of resources, ensure safety in production, and have good economic and social benefits.
基金supported by supported by the Basic Research Project of State Key Laboratory of Photovoltaic Science and Technology(No.202401020302)funding support from the National Natural Science Foundation of China(No.62274040 and No.62304046)Shanghai science and technology innovation action plan(No.24DZ3001200)。
文摘Organic-inorganic metal halides(OIMHs)have emerged as highly promising novel multifunctional optoelectronic materials,owing to their easily adjustable properties from a variety of combinations of different components.But it is still difficult and rare to realize highly tunable multicolor luminescence within the same material.In this work,we successfully incorporated three adjustable emission centers in OIMHs to synthesize a novel OIMH(NEA)_(2)MnBr_(4),with each emission center capable of emitting one of the primary colors—red,green,and blue.The green and red emissions originate from the tetrahedron and octahedron structures in the Mn-based frame,while the blue can be attributed to the contribution of organic components.Additionally,to achieve comparable emission intensity among the three primary colors,we enhanced the blue emission performance by optimizing the ratio of organic structure components and incorporating chirality in the OIMHs.The resulting high-quality films can be obtained by spin-coating method with a photoluminescence quantum yields of up to 96%.More interestingly,by the dual manipulation of excitation wavelength and temperature,the sample can be emitted at least seven distinct colors including a standard white luminescence at(0.33,0.33),opening up promising prospects for multicolor luminescence applications such as high-end anti-counterfeiting technology,light-emitting diodes,X-ray imaging,latent fingerprints,humidity detection,and so on.Therefore,based on application scenarios and requirements,our research on this highly tunable luminescent OIMH material lays a solid foundation for further development of various functional properties of related materials.
基金supported by the National Natural Science Foundation of China(52171033,52431003,U23A20574)the Fundamental Research Funds for the Central Universities(2242025K20004)the SEU Innovation Capability Enhancement Plan for Doctoral Students(CXJH_SEU 24148,CXJH_SEU 25036).
文摘Microwave absorption(MA)materials often face poor synergy between impedance matching and attenuation in the low-frequency range.Balancing permittivity and permeability through magnetic-dielectric synergy is a promising strategy to address this issue.To realize the synergy,herein,Sn whiskers with an in situ oxide layer served as substrates for magnetic-loss-active CoNi nanosheet growth,forming a hierarchical CoNi@SnO_(2)@Sn(CNS)heterostructure.The CNS absorber achieves a minimum reflection loss(RL_(min))value of-62.29 dB with an effective absorption bandwidth(EAB)of 2.2 GHz,covering the entire C-band with 70%absorption at only 2.61 mm thickness.The nanosheet design of CoNi enhances magnetic anisotropy to promote natural resonance,while the conductive Sn core and abundant Sn/SnO_(2) and CoNi/SnO_(2) heterointerfaces facilitate conduction loss and dielectric polarization.When composited into a thermoplastic polyurethane(TPU)matrix,the resulting CNS/TPU-2 film(20 wt%CNS)exhibits an RL_(min) value of-61.04 dB and a 2.5 GHz EAB.Its in-plane and through-plane thermal conductivities reach 2.41 and 0.51 W m^(-1) K^(-1),representing 4.1 and 2.6 times those of pure TPU films,respectively,facilitating heat dissipation from protected devices.This work provides valuable insights into magnetic-dielectric synergy for low-frequency MA of 1D metal-based materials,offering promising potential for 5G communications and flexible electronics.
