This letter demonstrates an experimental approach to measuring the angular-momentum-resolved population of excited states in laser-produced argon ions.By measuring the spectra of free induction decay emissions corresp...This letter demonstrates an experimental approach to measuring the angular-momentum-resolved population of excited states in laser-produced argon ions.By measuring the spectra of free induction decay emissions corresponding to the resonant transitions between Rydberg states,the relative population of the Rydberg states is obtained with known Einstein A-coefficients.This study deepens the mechanistic understanding of coherent dynamics in laser-driven ionic excited states,and establishes experimental benchmarks essential for validating and refining advanced quantum kinetic models in strong-field physics.展开更多
With the widespread adoption of lithium-ion batteries(LIBs),safety concerns associated with flammable organic elec-trolytes have become increasingly critical.Solid-state lithium batteries(SSLBs),with enhanced safety a...With the widespread adoption of lithium-ion batteries(LIBs),safety concerns associated with flammable organic elec-trolytes have become increasingly critical.Solid-state lithium batteries(SSLBs),with enhanced safety and higher energy density potential,are regarded as a promising next-generation energy storage technology.However,the practical appli-cation of solid-state electrolytes(SSEs)remains hindered by several challenges,including low Li+ion conductivity,poor interfacial compatibility with electrodes,unfavorable mechanical properties and difficulties in scalable manufacturing.This review systematically examines recent progress in SSEs,including inorganic types(oxides,sulfides,halides),organic types(polymers,plastic crystals,poly(ionic liquids)(PILs)),and the emerging class of soft solid-state electrolytes(S3Es),especially those based on“rigid-flexible synergy”composites and“Li+-desolvation”mechanism using porous frameworks.Critical assessment reveals that single-component SSEs face inherent limitations that are difficult to be fully overcome through compositional and structural modification alone.In contrast,S3Es integrate the strength of complementary components to achieve a balanced and synergic enhancement in electrochemical properties(e.g.,ionic conductivity and stability window),mechanical integrity,and processability,showing great promise as next-generation SSEs.Furthermore,the application-ori-ented challenges and emerging trends in S3E research are outlined,aiming to provide strategic insights into future develop-ment of high-performance SSEs.展开更多
BACKGROUND Vitamin D deficiency has been associated with prostate cancer,particularly in ethnic minorities.Patients with prostate cancer may still be deficient even in areas of high sun exposure.Although androgen depr...BACKGROUND Vitamin D deficiency has been associated with prostate cancer,particularly in ethnic minorities.Patients with prostate cancer may still be deficient even in areas of high sun exposure.Although androgen deprivation therapy(ADT)is well documented to affect bone health,its impact on vitamin D levels is still uncertain.This study investigates the subgroups of prostate cancer patients most associated with vitamin D deficiency and ADT’s relation to this.AIM To examine how prevalent vitamin D deficiency is among prostate cancer patients in a sun-rich environment,with focus on differences by race and disease stage.It also assessed whether ADT is associated with changes in vitamin D levels.METHODS Prostate cancer patients treated at Chao Family Comprehensive Cancer Center between 2014-2024 were retrospectively studied with regards to vitamin D levels across racial groups,disease stages,and ADT exposure.Changes in vitamin D levels pre-and post-ADT over 24 months were assessed by statistical methods including paired t-tests.RESULTS Among 120 patients(mean age:74 years,mean body mass index:27.6 kg/m^(2)),African American(33.3%)and Hispanic(31.8%)patients had the greatest prevalence of vitamin D deficiency(<20 ng/mL).With a 28.6%deficit rate,metastatic castration-resistant prostate cancer had the highest prevalence rates of deficiency.There was no significant difference between pre-and post-ADT vitamin D levels(P=0.45).CONCLUSION Vitamin D deficiency is common in prostate cancer patients,especially racial minorities and those with advanced disease,despite residing in an area with high sun exposure.ADT does not significantly impact vitamin D levels in the short term.Routine screening and supplementation should be considered in these high-risk groups.展开更多
Higher-order topological insulators,which host topologically protected states at boundaries that are at least two dimensions lower than the bulk,are an emerging class of topological materials.They provide great opport...Higher-order topological insulators,which host topologically protected states at boundaries that are at least two dimensions lower than the bulk,are an emerging class of topological materials.They provide great opportunities for exploring novel topological phenomena and fascinating applications.Utilizing a low-temperature scanning tunneling microscope,we construct breathing-kagome lattices with Fe adatoms on Ag(111)and investigate their electronic properties.We observe the higher-order topological boundary states in the topological phase but not in the trivial one,which is consistent with the theory.These states are found to be robust against the removal of bulk or edge adatoms.Further,we show the arbitrary positioning of these states either at corner,edge,or bulk sites by slightly modifying their neighbors.Our study not only demonstrates the formation and robustness of the electronic higher-order topological boundary states in real atomic systems but also provides a route for controlling their positions.展开更多
Composite polymer electrolytes(CPEs)are considered as promising electrolytes for next-generation lithium batteries due to their superior advantages in safety,mechanical stability/flexibility,cathode compatibility,etc....Composite polymer electrolytes(CPEs)are considered as promising electrolytes for next-generation lithium batteries due to their superior advantages in safety,mechanical stability/flexibility,cathode compatibility,etc.However,achieving high Li+conductivity remains a major challenge,particularly at low temperatures.A key obstacle lies in the limited understanding of the complex interplay among amorphous components,including fillers,plasticizers,and residual solvents,which significantly hampers the rational design of high-performing CPEs.In this contribution,a polyvinylidene fluoride(PVDF)-based composite electrolyte has been developed,exhibiting high room-temperature ionic conductivity/mobility(>1 mS cm^(-1)/0.95×10^(-11)m^(2)s^(-1)),along with excellent electrochemical performances,including a wide stability window(4.8 V vs.Li/Li^(+)),superior charge/discharge capacity,and reversibility.By performing advanced solid-state nuclear magnetic resonance(ssNMR)techniques,in combination with systematic investigations into solid polymer electrolytes(SPEs),gel polymer electrolytes(GPEs),and CPEs,we establish an efficient NMR-based strategy for deconvoluting the structural and dynamic features of complex electrolyte systems.Notably,the simple1H magic-angle spinning(MAS)NMR spectroscopy enables the identification and monitoring of nearly all components in the composite matrix.Motion-sensitive1H-13C and1H-7Li correlation experiments further reveal that the rigidity of PVDF polymer chain segments and the presence of residual solvents are two critical factors governing Li+mobility.Moreover,we demonstrate that the order of the filler and plasticizer addition during the CPE fabrication significantly influences the performance of the electrolyte by regulating the retention of residual solvents.This work not only provides molecular-level insights into the structure-ion mobility relationships in the PVDF-based CPEs but also establishes a general NMR-based characterization approach for investigating other complex composite electrolyte materials.展开更多
The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned...The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned only for pure states,has limited applicability in realistic scenarios where mixed states are common.To address this limitation,we generalize the defnition of the QGT to mixed states using the purifcation bundle and the covariant derivative.Notably,our proposed defnition reduces to the traditional QGT when mixed states approach pure states.In our framework,the real and imaginary parts of this generalized QGT correspond to the Bures metric and the mean gauge curvature,respectively,endowing it with a broad range of potential applications.Additionally,using our proposed mixed-state QGT,we derive the geodesic equation applicable to mixed states.This work establishes a unifed framework for the geometric analysis of both pure and mixed states,thereby deepening our understanding of the geometric properties of quantum states.展开更多
A commentary on an anode-free cell design with electrochemically stable sodium borohydride solid electrolyte and pelletized aluminium current collector for sodium all-solid-state batteries is presented.First,the viabl...A commentary on an anode-free cell design with electrochemically stable sodium borohydride solid electrolyte and pelletized aluminium current collector for sodium all-solid-state batteries is presented.First,the viable strategies for implementing anode-free configuration utilizing solid-state electrolytes are briefly reviewed.Then,the remarkable work of Meng et al.on designing an anode-free sodium all-solid-state battery is elucidated.Finally,the significance of Meng’s work is discussed.展开更多
Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched wi...Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte,which is expected to be commercialized in the future.However,in high voltage conditions(>4.3 V),the decomposition of electrolyte components,structural degradation,and interface side reactions significantly reduce battery performance and hinder its further development.This review summarizes the latest research progress of inorganic electrolytes,polymer electrolytes,and composite electrolytes in high-voltage solid-state lithium batteries.At the same time,the designs of high-voltage polymer gel electrolyte and high-voltage quasi solid-state electrolyte are introduced in detail.In addition,interface engineering is crucial for improving the overall performance of high-voltage solid-state batteries.Finally,we highlight the challenges faced by high-voltage solid-state lithium batteries and put forward our own views on future research directions.This review offers instructive insights into the advancement of high-voltage solid-state lithium batteries for large-scale energy storage applications.展开更多
In quantum optics, unitary transformations of arbitrary states are evaluated by using the Taylor series expansion. However, this traditional approach can become cumbersome for the transformations involving non-commuti...In quantum optics, unitary transformations of arbitrary states are evaluated by using the Taylor series expansion. However, this traditional approach can become cumbersome for the transformations involving non-commuting operators. Addressing this issue, a nonstandard unitary transformation technique is highlighted here with new perspective. In a spirit of “quantum” series expansions, the transition probabilities between initial and final states, such as displaced, squeezed and other nonlinearly transformed coherent states are obtained both numerically and analytically. This paper concludes that, although this technique is novel, its implementations for more extended systems are needed.展开更多
Halide electrolytes,renowned for their excellent electrochemical stability and wide voltage window,exhibit significant potential in the development of high energy density solid-state batteries featuring high voltage c...Halide electrolytes,renowned for their excellent electrochemical stability and wide voltage window,exhibit significant potential in the development of high energy density solid-state batteries featuring high voltage cathode materials.In this study,we present the development and synthesis of a 0.6Li_(2)S-ZrCl_(4)solid electrolyte,demonstrating an ion conductivity of 1.9×10^(–3)S/cm at 25°C.Under a pressure of 500 MPa,the relative density of the electrolyte can reach 97.37%,showcasing its commendable compressibility.0.6Li_(2)S-ZrCl_(4)served as the electrolyte,and we assembled batteries utilizing a LiCoO_(2)(LCO)positive electrode,Li_(9.54)Si_(1.74)P_(1.44)S_(11.7)Cl_(0.3)(LSPSCl)coating,and Li-In negative electrode for laboratory testing.At 25°C,this all-solid-state battery demonstrated an impressive discharge capacity retention rate of86.99%(with a final discharge specific capacity of 110.5 m Ah/g)after 250 cycles at 24 m A/g and 100 MPa stack pressure.Upon substituting the positive electrode material with LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NMC811)and assembling an all-solid-state battery,it demonstrated a discharge capacity retention rate of 74.17%after200 cycles at 3.6 m A/g and 100 MPa stack pressure in an environment at 25°C(with a final discharge specific capacity of 103.3 m A/g).Our findings hold significant implications for the design of novel superionic conductors,thereby contributing to the advancement of all-solid-state battery technology.展开更多
The ultrafast excitation dynamics of atoms and molecules exposed to circularly polarized two-color(CPTC)laser fields constitute a fascinating topic in attosecond science. Although extensive research has established th...The ultrafast excitation dynamics of atoms and molecules exposed to circularly polarized two-color(CPTC)laser fields constitute a fascinating topic in attosecond science. Although extensive research has established the relationship between the Rydberg state excitation(RSE) yields and the CPTC field parameters, such as field amplitude ratios and helicity of two components, the role of the relative phase(φ) in modulating RSE efficiency remains unclear. In this work, we theoretically investigate the φ dependence of RSE and ionization yields in the co-rotating and counter-rotating circularly polarized two-color(CPTC) few-cycle laser fields by a semiclassical model. We find that, in co-rotating CPTC fields, both RSE and ionization yields display pronounced oscillations as a function of φ and these oscillations are significantly suppressed in the counter-rotating configuration, particularly for ionization yields. Moreover, the ratio of RSE to ionization yields exhibits an out-of-phase oscillatory pattern between low-and high-intensity regimes. These results can be comprehended by the unique feature of φ dependence of CPTC few-cycle fields, based on our semiclassical analysis. Our results demonstrate that phase-controlled CPTC fields offer a versatile tool for steering ultrafast ionization and RSE dynamics of atoms and molecules.展开更多
Solid-state lithium batteries(SSLBs)are regarded as an essential growth path in energy storage systems due to their excellent safety and high energy density.In particular,SSLBs using conversion-type cathode materials ...Solid-state lithium batteries(SSLBs)are regarded as an essential growth path in energy storage systems due to their excellent safety and high energy density.In particular,SSLBs using conversion-type cathode materials have received widespread attention because of their high theoretical energy densities,low cost,and sustainability.Despite the great progress in research and development of SSLBs based on conversiontype cathodes,their practical applications still face challenges such as blocked ionic-electronic migration pathways,huge volume change,interfacial incompatibility,and expensive processing costs.This review focuses on the advantages and critical issues of coupling conversion-type cathodes with solid-state electrolytes(SSEs),as well as state-of-the-art progress in various promising cathodes(e.g.,FeS_(2),CuS,FeF_(3),FeF_(2),and S)in SSLBs.Furthermore,representative research on conversion-type solid-state full cells is discussed to offer enlightenment for their practical application.Significantly,the energy density exhibited by the S cathode stands out impressively,while sulfide SSEs and halide SSEs have demonstrated immense potential for coupling with conversion-type cathodes.Finally,perspectives on conversion-type cathodes are provided at the material,interface,composite electrode,and battery levels,with a view to accelerating the development of conversion-type cathodes for high-energy–density SSLBs.展开更多
We propose a novel approach to generate and manipulate topological Floquet bound states in the continuum(BICs)via a class of systems constructed by coupling two identical periodically driven one-dimensional Su-Schrief...We propose a novel approach to generate and manipulate topological Floquet bound states in the continuum(BICs)via a class of systems constructed by coupling two identical periodically driven one-dimensional Su-Schrieffer-Heeger chains.The formation of topological Floquet BICs can be adjusted only by tuning the driving amplitude or frequency,regardless of whether the static system has BICs or not.The interchain bias can only change the localization property of topological Floquet BICs,and a bigger bias can lead to transforming topological Floquet BICs into bound states out of the continuum(BOCs).But it does not change the topological properties of these topological Floquet states.Based on the repulsion effect of edge states,we propose to detect occurrence of topological Floquet BICs and transition point between topological Floquet BICs and BOCs using quantum walk.Our work provided a convenient and realistic approach for the experimental realization and manipulation of BICs in a single-particle quantum system.展开更多
We present a concise review of the vector charmonium state ψ(4230), which was originally labelled as Y(4260)in the literature. As one of the earliest candidates for a quantum chromodynamics exotic states, its interpr...We present a concise review of the vector charmonium state ψ(4230), which was originally labelled as Y(4260)in the literature. As one of the earliest candidates for a quantum chromodynamics exotic states, its interpretation has initiated various ideas about possible manifestations of non-perturbative mechanisms in the charmonium mass regime. In this short article we briefly review the experimental status of ψ(4230) and discuss possible theoretical interpretations. We will focus on four broadly investigated scenarios, i.e., tetraquark, hybrid, hadro-quarkonium,and hadronic molecule, and highlight the key issues based on these approaches. Crucial experimental observables,e.g., mass position, lineshapes, di-lepton decay width Γ_(ee), production rates in B meson decays, dominant hadronic decay patterns, and the potential 1^(-+)and 0^(--)exotic partners, are assessed, which can provide crucial structure information for understanding this mysterious state.展开更多
Solid-state electrolytes(SSEs),as the core component within the next generation of key energy storage technologies-solid-state lithium batteries(SSLBs)-are significantly leading the development of future energy storag...Solid-state electrolytes(SSEs),as the core component within the next generation of key energy storage technologies-solid-state lithium batteries(SSLBs)-are significantly leading the development of future energy storage systems.Among the numerous types of SSEs,inorganic oxide garnet-structured superionic conductors Li7La3Zr2O12(LLZO)crystallized with the cubic Iaˉ3d space group have received considerable attention owing to their highly advantageous intrinsic properties encompassing reasonable lithium-ion conductivity,wide electrochemical voltage window,high shear modulus,and excellent chemical stability with electrodes.However,no SSEs possess all the properties necessary for SSLBs,thus both the ionic conductivity at room temperature and stability in ambient air regarding cubic garnet-based electrolytes are still subject to further improvement.Hence,this review comprehensively covers the nine key structural factors affecting the ion conductivity of garnet-based electrolytes comprising Li concentration,Li vacancy concentration,Li carrier concentration and mobility,Li occupancy at available sites,lattice constant,triangle bottleneck size,oxygen vacancy defects,and Li-O bonding interactions.Furthermore,the general illustration of structures and fundamental features being crucial to chemical stability is examined,including Li concentration,Li-site occupation behavior,and Li-O bonding interactions.Insights into the composition-structure-property relations among cubic garnet-based oxide ionic conductors from the perspective of their crystal structures,revealing the potential compatibility conflicts between ionic transportation and chemical stability resulting from Li-O bonding interactions.We believe that this review will lay the foundation for future reasonable structural design of oxide-based or even other types of superionic conductors,thus assisting in promoting the rapid development of alternative green and sustainable technologies.展开更多
This paper presents an advanced control strategy for DC-DC buck converters utilizing Non-Minimal State Space (NMSS) representation combined with Proportional-Integral-Plus (PIP) control, optimized through Linear Quadr...This paper presents an advanced control strategy for DC-DC buck converters utilizing Non-Minimal State Space (NMSS) representation combined with Proportional-Integral-Plus (PIP) control, optimized through Linear Quadratic Regulator (LQR) design. The proposed approach leverages NMSS to eliminate the need for state observers, enhancing robustness against model mismatch and improving overall system performance. The PIP controller extends traditional PI control by incorporating additional dynamic feedback. Experimental results demonstrate that the NMSS-PIP-LQR controlled buck converter achieves excellent dynamic performance. The design procedure is fully documented, and microcontroller implementation issues are discussed.展开更多
Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular st...Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.展开更多
The burgeoning market for lithium-ion batteries has stimulated a growing need for more reliable battery performance monitoring. Accurate state-of-health(SOH) estimation is critical for ensuring battery operational per...The burgeoning market for lithium-ion batteries has stimulated a growing need for more reliable battery performance monitoring. Accurate state-of-health(SOH) estimation is critical for ensuring battery operational performance. Despite numerous data-driven methods reported in existing research for battery SOH estimation, these methods often exhibit inconsistent performance across different application scenarios. To address this issue and overcome the performance limitations of individual data-driven models,integrating multiple models for SOH estimation has received considerable attention. Ensemble learning(EL) typically leverages the strengths of multiple base models to achieve more robust and accurate outputs. However, the lack of a clear review of current research hinders the further development of ensemble methods in SOH estimation. Therefore, this paper comprehensively reviews multi-model ensemble learning methods for battery SOH estimation. First, existing ensemble methods are systematically categorized into 6 classes based on their combination strategies. Different realizations and underlying connections are meticulously analyzed for each category of EL methods, highlighting distinctions, innovations, and typical applications. Subsequently, these ensemble methods are comprehensively compared in terms of base models, combination strategies, and publication trends. Evaluations across 6 dimensions underscore the outstanding performance of stacking-based ensemble methods. Following this, these ensemble methods are further inspected from the perspectives of weighted ensemble and diversity, aiming to inspire potential approaches for enhancing ensemble performance. Moreover, addressing challenges such as base model selection, measuring model robustness and uncertainty, and interpretability of ensemble models in practical applications is emphasized. Finally, future research prospects are outlined, specifically noting that deep learning ensemble is poised to advance ensemble methods for battery SOH estimation. The convergence of advanced machine learning with ensemble learning is anticipated to yield valuable avenues for research. Accelerated research in ensemble learning holds promising prospects for achieving more accurate and reliable battery SOH estimation under real-world conditions.展开更多
With the continuous expansion of the power system scale and the increasing complexity of operational mode,the interaction between transmission and distribution systems is becoming more and more significant,placing hig...With the continuous expansion of the power system scale and the increasing complexity of operational mode,the interaction between transmission and distribution systems is becoming more and more significant,placing higher requirements on the accuracy and efficiency of the power system state estimation to address the challenge of balancing computational efficiency and estimation accuracy in traditional coupled transmission and distribution state estimation methods,this paper proposes a collaborative state estimation method based on distribution systems state clustering and load model parameter identification.To resolve the scalability issue of coupled transmission and distribution power systems,clustering is first carried out based on the distribution system states.As the data and models of the transmission system and distribution systems are not shared.For the transmission system,equating the power transmitted from the transmission system to the distribution system is the same as equating the distribution system.Further,the power transmitted from the transmission system to different types of distribution systems is equivalent to different polynomial equivalent load models.Then,a parameter identification method is proposed to obtain the parameters of the equivalent load model.Finally,a transmission and distribution collaborative state estimation model is constructed based on the equivalent load model.The results of the numerical analysis show that compared with the traditional master-slave splitting method,the proposed method significantly enhances computational efficiency while maintaining high estimation accuracy.展开更多
Poly(ethylene oxide)(PEO)solid electrolytes hold great promise in all-solid-state lithium batteries(ASSLBs)with high-energy and safety capabilities.However,the PEO electrolyte is hardly resistant to degrade electroche...Poly(ethylene oxide)(PEO)solid electrolytes hold great promise in all-solid-state lithium batteries(ASSLBs)with high-energy and safety capabilities.However,the PEO electrolyte is hardly resistant to degrade electrochemically at high voltages(>4 V)in ASSLBs.Herein,we design and prepare a highly efficient and stable PEO-based solid electrolyte(denoted as PEO-L/DTPEO)applied to high-voltage ASSLBs,in which the Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)-containing PEO(PEO-L)serves as a bulk of the electrolyte and the PEO with dualsalts(LiDFOB and high-concentration LiTFSI)forms an ultrathin coating layer(DT-PEO)covering on PEO-L.With 3%coating layer,the PEO-L/DT-PEO electrolyte exhibits an enhanced decomposition potential(>4.9 V vs.Li/Li^(+))originating from the high concentration of LiTFSI as well as renders Al foil current collector high anticorrosion by the introduction of LiDFOB.Upon coupling with highvoltage NCM811 cathode,the DT-PEO efficiently suppresses the interfacial degradation kinetics between electrolyte and cathode,and slows down the irreversible phase change of NCM811.The assembled PEO-L/DT-PEObased Li/NCM811 battery exhibits an excellent cycling stability of remaining 63.0%after 400 cycles at a cutoff voltage of 4.2 V as well as an initial discharge specific capacity of 164.5 mAh g^(-1)at a rate of 0.4C.This work offers a facile and feasible strategy to overcoming interface decomposition of the PEO electrolyte matching perfectly with high-voltage cathode for high-performance ASSLBs.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.12234020,12474281,12450403,and 12274461)the Science and Technology Innovation Program of Hunan Province(Grant No.2022RC1193)。
文摘This letter demonstrates an experimental approach to measuring the angular-momentum-resolved population of excited states in laser-produced argon ions.By measuring the spectra of free induction decay emissions corresponding to the resonant transitions between Rydberg states,the relative population of the Rydberg states is obtained with known Einstein A-coefficients.This study deepens the mechanistic understanding of coherent dynamics in laser-driven ionic excited states,and establishes experimental benchmarks essential for validating and refining advanced quantum kinetic models in strong-field physics.
基金the financial support from the National Key R&D Program of China (Grant No. 2021YFB3800300)the supports from National Key R&D Program of China (Grant No. 2022YFB3807700)+6 种基金the National Natural Science Foundation of China (Grant No. U20A20248)the supports from the National Natural Science Foundation of China (Grant Nos. W2441017, 22409103)the “Innovation Yongjiang 2035” Key R&D Program (Grant Nos. 2024Z040, 2025Z063)the National Key R&D Program of China (Grant No. 2023YFC2812700)the Natural Science Foundation of Shandong Province (Grant No. ZR2024YQ008)funding supports from the National Key R&D Program of China (Grant No. 2021YFB3800300)science and technology innovation fund for emission peak and carbon neutrality of Jiangsu province (Grant Nos. BK20220034, BK20231512)。
文摘With the widespread adoption of lithium-ion batteries(LIBs),safety concerns associated with flammable organic elec-trolytes have become increasingly critical.Solid-state lithium batteries(SSLBs),with enhanced safety and higher energy density potential,are regarded as a promising next-generation energy storage technology.However,the practical appli-cation of solid-state electrolytes(SSEs)remains hindered by several challenges,including low Li+ion conductivity,poor interfacial compatibility with electrodes,unfavorable mechanical properties and difficulties in scalable manufacturing.This review systematically examines recent progress in SSEs,including inorganic types(oxides,sulfides,halides),organic types(polymers,plastic crystals,poly(ionic liquids)(PILs)),and the emerging class of soft solid-state electrolytes(S3Es),especially those based on“rigid-flexible synergy”composites and“Li+-desolvation”mechanism using porous frameworks.Critical assessment reveals that single-component SSEs face inherent limitations that are difficult to be fully overcome through compositional and structural modification alone.In contrast,S3Es integrate the strength of complementary components to achieve a balanced and synergic enhancement in electrochemical properties(e.g.,ionic conductivity and stability window),mechanical integrity,and processability,showing great promise as next-generation SSEs.Furthermore,the application-ori-ented challenges and emerging trends in S3E research are outlined,aiming to provide strategic insights into future develop-ment of high-performance SSEs.
文摘BACKGROUND Vitamin D deficiency has been associated with prostate cancer,particularly in ethnic minorities.Patients with prostate cancer may still be deficient even in areas of high sun exposure.Although androgen deprivation therapy(ADT)is well documented to affect bone health,its impact on vitamin D levels is still uncertain.This study investigates the subgroups of prostate cancer patients most associated with vitamin D deficiency and ADT’s relation to this.AIM To examine how prevalent vitamin D deficiency is among prostate cancer patients in a sun-rich environment,with focus on differences by race and disease stage.It also assessed whether ADT is associated with changes in vitamin D levels.METHODS Prostate cancer patients treated at Chao Family Comprehensive Cancer Center between 2014-2024 were retrospectively studied with regards to vitamin D levels across racial groups,disease stages,and ADT exposure.Changes in vitamin D levels pre-and post-ADT over 24 months were assessed by statistical methods including paired t-tests.RESULTS Among 120 patients(mean age:74 years,mean body mass index:27.6 kg/m^(2)),African American(33.3%)and Hispanic(31.8%)patients had the greatest prevalence of vitamin D deficiency(<20 ng/mL).With a 28.6%deficit rate,metastatic castration-resistant prostate cancer had the highest prevalence rates of deficiency.There was no significant difference between pre-and post-ADT vitamin D levels(P=0.45).CONCLUSION Vitamin D deficiency is common in prostate cancer patients,especially racial minorities and those with advanced disease,despite residing in an area with high sun exposure.ADT does not significantly impact vitamin D levels in the short term.Routine screening and supplementation should be considered in these high-risk groups.
基金supported by the National Key R&D Program of China(Grant Nos.2024YFA140850,2022YFA1403601,and 2023YFC2410501)the National Natural Science Foundation of China(Grants Nos.12241402,12474059,12274203,12374113,and 12274204)。
文摘Higher-order topological insulators,which host topologically protected states at boundaries that are at least two dimensions lower than the bulk,are an emerging class of topological materials.They provide great opportunities for exploring novel topological phenomena and fascinating applications.Utilizing a low-temperature scanning tunneling microscope,we construct breathing-kagome lattices with Fe adatoms on Ag(111)and investigate their electronic properties.We observe the higher-order topological boundary states in the topological phase but not in the trivial one,which is consistent with the theory.These states are found to be robust against the removal of bulk or edge adatoms.Further,we show the arbitrary positioning of these states either at corner,edge,or bulk sites by slightly modifying their neighbors.Our study not only demonstrates the formation and robustness of the electronic higher-order topological boundary states in real atomic systems but also provides a route for controlling their positions.
基金financially supported by the National Natural Science Foundation of China(Grant No.22325405,22432005,22321002,and 22404159)the Dalian Science and Technology Talent Innovation Program(Grant No.2024RG009)+2 种基金the China Postdoctoral Science Foundation(Grant Number 2024M753120)the LiaoNing Revitalization Talents Program(XLYC2203134)the ANSO Scholarship for Young Talents for financial support。
文摘Composite polymer electrolytes(CPEs)are considered as promising electrolytes for next-generation lithium batteries due to their superior advantages in safety,mechanical stability/flexibility,cathode compatibility,etc.However,achieving high Li+conductivity remains a major challenge,particularly at low temperatures.A key obstacle lies in the limited understanding of the complex interplay among amorphous components,including fillers,plasticizers,and residual solvents,which significantly hampers the rational design of high-performing CPEs.In this contribution,a polyvinylidene fluoride(PVDF)-based composite electrolyte has been developed,exhibiting high room-temperature ionic conductivity/mobility(>1 mS cm^(-1)/0.95×10^(-11)m^(2)s^(-1)),along with excellent electrochemical performances,including a wide stability window(4.8 V vs.Li/Li^(+)),superior charge/discharge capacity,and reversibility.By performing advanced solid-state nuclear magnetic resonance(ssNMR)techniques,in combination with systematic investigations into solid polymer electrolytes(SPEs),gel polymer electrolytes(GPEs),and CPEs,we establish an efficient NMR-based strategy for deconvoluting the structural and dynamic features of complex electrolyte systems.Notably,the simple1H magic-angle spinning(MAS)NMR spectroscopy enables the identification and monitoring of nearly all components in the composite matrix.Motion-sensitive1H-13C and1H-7Li correlation experiments further reveal that the rigidity of PVDF polymer chain segments and the presence of residual solvents are two critical factors governing Li+mobility.Moreover,we demonstrate that the order of the filler and plasticizer addition during the CPE fabrication significantly influences the performance of the electrolyte by regulating the retention of residual solvents.This work not only provides molecular-level insights into the structure-ion mobility relationships in the PVDF-based CPEs but also establishes a general NMR-based characterization approach for investigating other complex composite electrolyte materials.
基金supported by the National Natural Science Foundation of China(Grant Nos.12347104,U24A2017,12461160276,and 12175075)the National Key Research and Development Program of China(Grant No.2023YFC2205802)+1 种基金the Natural Science Foundation of Jiangsu Province(Grant Nos.BK20243060 and BK20233001)in part by the State Key Laboratory of Advanced Optical Communication Systems and Networks,China。
文摘The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned only for pure states,has limited applicability in realistic scenarios where mixed states are common.To address this limitation,we generalize the defnition of the QGT to mixed states using the purifcation bundle and the covariant derivative.Notably,our proposed defnition reduces to the traditional QGT when mixed states approach pure states.In our framework,the real and imaginary parts of this generalized QGT correspond to the Bures metric and the mean gauge curvature,respectively,endowing it with a broad range of potential applications.Additionally,using our proposed mixed-state QGT,we derive the geodesic equation applicable to mixed states.This work establishes a unifed framework for the geometric analysis of both pure and mixed states,thereby deepening our understanding of the geometric properties of quantum states.
基金grateful for support from the National Natural Science Foundation of China(Nos.52472247,52172229,21401145)Fundamental Research Funds for the Central Universities(No.104972024KFYjc0079).
文摘A commentary on an anode-free cell design with electrochemically stable sodium borohydride solid electrolyte and pelletized aluminium current collector for sodium all-solid-state batteries is presented.First,the viable strategies for implementing anode-free configuration utilizing solid-state electrolytes are briefly reviewed.Then,the remarkable work of Meng et al.on designing an anode-free sodium all-solid-state battery is elucidated.Finally,the significance of Meng’s work is discussed.
基金supported by the National Key R&D Program of China(2024YFA1211100)the National Natural Science Foundation of China(52301278,22479080,52202254,92372001,22393900,and 92372203)+2 种基金the Natural Science Foundation of Jiangsu Province(BK20230937,BK20220966)the Science and Technology Plans of Tianjin(23JCYBJC00170,24JCJQJC00220,and 24ZXZSSS00390)the Fundamental Research Funds for the Central Universities(02063253167,30922010708)。
文摘Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte,which is expected to be commercialized in the future.However,in high voltage conditions(>4.3 V),the decomposition of electrolyte components,structural degradation,and interface side reactions significantly reduce battery performance and hinder its further development.This review summarizes the latest research progress of inorganic electrolytes,polymer electrolytes,and composite electrolytes in high-voltage solid-state lithium batteries.At the same time,the designs of high-voltage polymer gel electrolyte and high-voltage quasi solid-state electrolyte are introduced in detail.In addition,interface engineering is crucial for improving the overall performance of high-voltage solid-state batteries.Finally,we highlight the challenges faced by high-voltage solid-state lithium batteries and put forward our own views on future research directions.This review offers instructive insights into the advancement of high-voltage solid-state lithium batteries for large-scale energy storage applications.
文摘In quantum optics, unitary transformations of arbitrary states are evaluated by using the Taylor series expansion. However, this traditional approach can become cumbersome for the transformations involving non-commuting operators. Addressing this issue, a nonstandard unitary transformation technique is highlighted here with new perspective. In a spirit of “quantum” series expansions, the transition probabilities between initial and final states, such as displaced, squeezed and other nonlinearly transformed coherent states are obtained both numerically and analytically. This paper concludes that, although this technique is novel, its implementations for more extended systems are needed.
基金financially supported by Natural Science Foundation of Hebei Province(Nos.B2020203037,F2021203097)Science Research Project of Hebei Education Department(No.JZX2024022)National Natural Science Foundation of China(Nos.52022088,51971245)。
文摘Halide electrolytes,renowned for their excellent electrochemical stability and wide voltage window,exhibit significant potential in the development of high energy density solid-state batteries featuring high voltage cathode materials.In this study,we present the development and synthesis of a 0.6Li_(2)S-ZrCl_(4)solid electrolyte,demonstrating an ion conductivity of 1.9×10^(–3)S/cm at 25°C.Under a pressure of 500 MPa,the relative density of the electrolyte can reach 97.37%,showcasing its commendable compressibility.0.6Li_(2)S-ZrCl_(4)served as the electrolyte,and we assembled batteries utilizing a LiCoO_(2)(LCO)positive electrode,Li_(9.54)Si_(1.74)P_(1.44)S_(11.7)Cl_(0.3)(LSPSCl)coating,and Li-In negative electrode for laboratory testing.At 25°C,this all-solid-state battery demonstrated an impressive discharge capacity retention rate of86.99%(with a final discharge specific capacity of 110.5 m Ah/g)after 250 cycles at 24 m A/g and 100 MPa stack pressure.Upon substituting the positive electrode material with LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NMC811)and assembling an all-solid-state battery,it demonstrated a discharge capacity retention rate of 74.17%after200 cycles at 3.6 m A/g and 100 MPa stack pressure in an environment at 25°C(with a final discharge specific capacity of 103.3 m A/g).Our findings hold significant implications for the design of novel superionic conductors,thereby contributing to the advancement of all-solid-state battery technology.
基金supported by the National Natural Science Foundation of China (Nos. 12121004, 12274273, and 12450402)the Science and Technology Department of Hubei Province (No. 2020CFA029)+1 种基金CAS Project for Young Scientists in Basic Research (No. YSBR-091)the Youth Innovation Promotion Association CAS (No. 2021328)。
文摘The ultrafast excitation dynamics of atoms and molecules exposed to circularly polarized two-color(CPTC)laser fields constitute a fascinating topic in attosecond science. Although extensive research has established the relationship between the Rydberg state excitation(RSE) yields and the CPTC field parameters, such as field amplitude ratios and helicity of two components, the role of the relative phase(φ) in modulating RSE efficiency remains unclear. In this work, we theoretically investigate the φ dependence of RSE and ionization yields in the co-rotating and counter-rotating circularly polarized two-color(CPTC) few-cycle laser fields by a semiclassical model. We find that, in co-rotating CPTC fields, both RSE and ionization yields display pronounced oscillations as a function of φ and these oscillations are significantly suppressed in the counter-rotating configuration, particularly for ionization yields. Moreover, the ratio of RSE to ionization yields exhibits an out-of-phase oscillatory pattern between low-and high-intensity regimes. These results can be comprehended by the unique feature of φ dependence of CPTC few-cycle fields, based on our semiclassical analysis. Our results demonstrate that phase-controlled CPTC fields offer a versatile tool for steering ultrafast ionization and RSE dynamics of atoms and molecules.
基金National Natural Science Foundation of China(22322903,52072061)Natural Science Foundation of Sichuan,China(2023NSFSC1914)Beijing National Laboratory for Condensed Matter Physics(2023BNLCMPKF015)。
文摘Solid-state lithium batteries(SSLBs)are regarded as an essential growth path in energy storage systems due to their excellent safety and high energy density.In particular,SSLBs using conversion-type cathode materials have received widespread attention because of their high theoretical energy densities,low cost,and sustainability.Despite the great progress in research and development of SSLBs based on conversiontype cathodes,their practical applications still face challenges such as blocked ionic-electronic migration pathways,huge volume change,interfacial incompatibility,and expensive processing costs.This review focuses on the advantages and critical issues of coupling conversion-type cathodes with solid-state electrolytes(SSEs),as well as state-of-the-art progress in various promising cathodes(e.g.,FeS_(2),CuS,FeF_(3),FeF_(2),and S)in SSLBs.Furthermore,representative research on conversion-type solid-state full cells is discussed to offer enlightenment for their practical application.Significantly,the energy density exhibited by the S cathode stands out impressively,while sulfide SSEs and halide SSEs have demonstrated immense potential for coupling with conversion-type cathodes.Finally,perspectives on conversion-type cathodes are provided at the material,interface,composite electrode,and battery levels,with a view to accelerating the development of conversion-type cathodes for high-energy–density SSLBs.
基金supported by the National Natural Science Foundation of China(Grant Nos.12175315 and 12205385)。
文摘We propose a novel approach to generate and manipulate topological Floquet bound states in the continuum(BICs)via a class of systems constructed by coupling two identical periodically driven one-dimensional Su-Schrieffer-Heeger chains.The formation of topological Floquet BICs can be adjusted only by tuning the driving amplitude or frequency,regardless of whether the static system has BICs or not.The interchain bias can only change the localization property of topological Floquet BICs,and a bigger bias can lead to transforming topological Floquet BICs into bound states out of the continuum(BOCs).But it does not change the topological properties of these topological Floquet states.Based on the repulsion effect of edge states,we propose to detect occurrence of topological Floquet BICs and transition point between topological Floquet BICs and BOCs using quantum walk.Our work provided a convenient and realistic approach for the experimental realization and manipulation of BICs in a single-particle quantum system.
基金supported in part by the National Natural Science Foundation of China (Grant Nos.12375073 and 12235018)。
文摘We present a concise review of the vector charmonium state ψ(4230), which was originally labelled as Y(4260)in the literature. As one of the earliest candidates for a quantum chromodynamics exotic states, its interpretation has initiated various ideas about possible manifestations of non-perturbative mechanisms in the charmonium mass regime. In this short article we briefly review the experimental status of ψ(4230) and discuss possible theoretical interpretations. We will focus on four broadly investigated scenarios, i.e., tetraquark, hybrid, hadro-quarkonium,and hadronic molecule, and highlight the key issues based on these approaches. Crucial experimental observables,e.g., mass position, lineshapes, di-lepton decay width Γ_(ee), production rates in B meson decays, dominant hadronic decay patterns, and the potential 1^(-+)and 0^(--)exotic partners, are assessed, which can provide crucial structure information for understanding this mysterious state.
基金supported by the National Natural Science Foundation of China(Nos.22171102 and 22090044)the National Key R&D Program of China(Nos.2021YFF0500502 and 2023YFA1506304)+2 种基金the Jilin Province Science and Technology Development Plan(No.20230101024JC)the"Medicine+X"crossinnovation team of Bethune Medical Department of Jilin University"Leading the Charge with Open Competition"construction project(No.2022JBGS04)the Jilin University Graduate Training Office(Nos.2021JGZ08 and 2022YJSJIP20).
文摘Solid-state electrolytes(SSEs),as the core component within the next generation of key energy storage technologies-solid-state lithium batteries(SSLBs)-are significantly leading the development of future energy storage systems.Among the numerous types of SSEs,inorganic oxide garnet-structured superionic conductors Li7La3Zr2O12(LLZO)crystallized with the cubic Iaˉ3d space group have received considerable attention owing to their highly advantageous intrinsic properties encompassing reasonable lithium-ion conductivity,wide electrochemical voltage window,high shear modulus,and excellent chemical stability with electrodes.However,no SSEs possess all the properties necessary for SSLBs,thus both the ionic conductivity at room temperature and stability in ambient air regarding cubic garnet-based electrolytes are still subject to further improvement.Hence,this review comprehensively covers the nine key structural factors affecting the ion conductivity of garnet-based electrolytes comprising Li concentration,Li vacancy concentration,Li carrier concentration and mobility,Li occupancy at available sites,lattice constant,triangle bottleneck size,oxygen vacancy defects,and Li-O bonding interactions.Furthermore,the general illustration of structures and fundamental features being crucial to chemical stability is examined,including Li concentration,Li-site occupation behavior,and Li-O bonding interactions.Insights into the composition-structure-property relations among cubic garnet-based oxide ionic conductors from the perspective of their crystal structures,revealing the potential compatibility conflicts between ionic transportation and chemical stability resulting from Li-O bonding interactions.We believe that this review will lay the foundation for future reasonable structural design of oxide-based or even other types of superionic conductors,thus assisting in promoting the rapid development of alternative green and sustainable technologies.
文摘This paper presents an advanced control strategy for DC-DC buck converters utilizing Non-Minimal State Space (NMSS) representation combined with Proportional-Integral-Plus (PIP) control, optimized through Linear Quadratic Regulator (LQR) design. The proposed approach leverages NMSS to eliminate the need for state observers, enhancing robustness against model mismatch and improving overall system performance. The PIP controller extends traditional PI control by incorporating additional dynamic feedback. Experimental results demonstrate that the NMSS-PIP-LQR controlled buck converter achieves excellent dynamic performance. The design procedure is fully documented, and microcontroller implementation issues are discussed.
文摘Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.
基金National Natural Science Foundation of China (52075420)Fundamental Research Funds for the Central Universities (xzy022023049)National Key Research and Development Program of China (2023YFB3408600)。
文摘The burgeoning market for lithium-ion batteries has stimulated a growing need for more reliable battery performance monitoring. Accurate state-of-health(SOH) estimation is critical for ensuring battery operational performance. Despite numerous data-driven methods reported in existing research for battery SOH estimation, these methods often exhibit inconsistent performance across different application scenarios. To address this issue and overcome the performance limitations of individual data-driven models,integrating multiple models for SOH estimation has received considerable attention. Ensemble learning(EL) typically leverages the strengths of multiple base models to achieve more robust and accurate outputs. However, the lack of a clear review of current research hinders the further development of ensemble methods in SOH estimation. Therefore, this paper comprehensively reviews multi-model ensemble learning methods for battery SOH estimation. First, existing ensemble methods are systematically categorized into 6 classes based on their combination strategies. Different realizations and underlying connections are meticulously analyzed for each category of EL methods, highlighting distinctions, innovations, and typical applications. Subsequently, these ensemble methods are comprehensively compared in terms of base models, combination strategies, and publication trends. Evaluations across 6 dimensions underscore the outstanding performance of stacking-based ensemble methods. Following this, these ensemble methods are further inspected from the perspectives of weighted ensemble and diversity, aiming to inspire potential approaches for enhancing ensemble performance. Moreover, addressing challenges such as base model selection, measuring model robustness and uncertainty, and interpretability of ensemble models in practical applications is emphasized. Finally, future research prospects are outlined, specifically noting that deep learning ensemble is poised to advance ensemble methods for battery SOH estimation. The convergence of advanced machine learning with ensemble learning is anticipated to yield valuable avenues for research. Accelerated research in ensemble learning holds promising prospects for achieving more accurate and reliable battery SOH estimation under real-world conditions.
基金State Grid Jiangsu Electric Power Co.,Ltd.Technology Project(J2023121).
文摘With the continuous expansion of the power system scale and the increasing complexity of operational mode,the interaction between transmission and distribution systems is becoming more and more significant,placing higher requirements on the accuracy and efficiency of the power system state estimation to address the challenge of balancing computational efficiency and estimation accuracy in traditional coupled transmission and distribution state estimation methods,this paper proposes a collaborative state estimation method based on distribution systems state clustering and load model parameter identification.To resolve the scalability issue of coupled transmission and distribution power systems,clustering is first carried out based on the distribution system states.As the data and models of the transmission system and distribution systems are not shared.For the transmission system,equating the power transmitted from the transmission system to the distribution system is the same as equating the distribution system.Further,the power transmitted from the transmission system to different types of distribution systems is equivalent to different polynomial equivalent load models.Then,a parameter identification method is proposed to obtain the parameters of the equivalent load model.Finally,a transmission and distribution collaborative state estimation model is constructed based on the equivalent load model.The results of the numerical analysis show that compared with the traditional master-slave splitting method,the proposed method significantly enhances computational efficiency while maintaining high estimation accuracy.
基金financially supported by the National Natural Science Foundation of China(Nos.22176011 and 22378019)the Opening Project of State Key Laboratory of Organic-Inorganic Composites
文摘Poly(ethylene oxide)(PEO)solid electrolytes hold great promise in all-solid-state lithium batteries(ASSLBs)with high-energy and safety capabilities.However,the PEO electrolyte is hardly resistant to degrade electrochemically at high voltages(>4 V)in ASSLBs.Herein,we design and prepare a highly efficient and stable PEO-based solid electrolyte(denoted as PEO-L/DTPEO)applied to high-voltage ASSLBs,in which the Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)-containing PEO(PEO-L)serves as a bulk of the electrolyte and the PEO with dualsalts(LiDFOB and high-concentration LiTFSI)forms an ultrathin coating layer(DT-PEO)covering on PEO-L.With 3%coating layer,the PEO-L/DT-PEO electrolyte exhibits an enhanced decomposition potential(>4.9 V vs.Li/Li^(+))originating from the high concentration of LiTFSI as well as renders Al foil current collector high anticorrosion by the introduction of LiDFOB.Upon coupling with highvoltage NCM811 cathode,the DT-PEO efficiently suppresses the interfacial degradation kinetics between electrolyte and cathode,and slows down the irreversible phase change of NCM811.The assembled PEO-L/DT-PEObased Li/NCM811 battery exhibits an excellent cycling stability of remaining 63.0%after 400 cycles at a cutoff voltage of 4.2 V as well as an initial discharge specific capacity of 164.5 mAh g^(-1)at a rate of 0.4C.This work offers a facile and feasible strategy to overcoming interface decomposition of the PEO electrolyte matching perfectly with high-voltage cathode for high-performance ASSLBs.
