In order to investigate the feasibility of sequential removal NO and SO2 using non-thermal plasma and adsorbent simultaneously, the removal of NO and SO2 from dry gas stream (NO/SO2/N2/O2) with very little O2 using ...In order to investigate the feasibility of sequential removal NO and SO2 using non-thermal plasma and adsorbent simultaneously, the removal of NO and SO2 from dry gas stream (NO/SO2/N2/O2) with very little O2 using non-thermal plasma was investigated using a coaxial dielectric barrier discharge. Comparative experiments were carried out in the dry gas stream with and without Ar respectively at O2 concentration of 0.1%. The results showed that NO could be removed remarkably and it would be enhanced in the presence of Ar in the dry gas stream. It seems that SO2 could not be removed unless there is Ar in the dry gas stream. The mechanism of removal of NO and SO2 in the dry gas stream was discussed.展开更多
An experimental system of De-NO with plasma-catalyst(Cu zeolite) was established to investigate the differences between De- NO with plasma-catalyst and De-NO only with plasma, to provide the instruction for selectin...An experimental system of De-NO with plasma-catalyst(Cu zeolite) was established to investigate the differences between De- NO with plasma-catalyst and De-NO only with plasma, to provide the instruction for selecting appropriate catalyst and operating condition, The characteristics of De-NO with plasma and De-NO with plasma-catalyst were investigated comparatively by experiments. The experimental results show that De-NO with plasma-catalyst has high NO removal rate; Cu zeolite is an effective catalyst which can promote NO removal rate in plasma remarkably; De-NO with plasma-catalyst should be operated at low temperature and the temperature has opposite effects on the function of catalvst and plasma; water vapor and O2 can increase the NO removal rate.展开更多
Studies on the effect of the chlorine content of chlorophenols (CPs) on their adsorption from aqueous solution by mesoporous SBA-15 are important in understanding the mechanisms of CP adsorption. In this study, thre...Studies on the effect of the chlorine content of chlorophenols (CPs) on their adsorption from aqueous solution by mesoporous SBA-15 are important in understanding the mechanisms of CP adsorption. In this study, three CPs with different degrees of chlorine content (i.e., 2-chlorophenol, 2,6-dichlorophenol and 2,4,6-trichlorophenol) were investigated. The effects of parameters such as temperature and solution pH were studied. The results showed that CP adsorption by SBA- 15 increased with increasing number of chlorine substituents and depended strongly on the temperature and solution pH. Thermodynamic parameters such as Gibbs free energy change (AGO), enthalpy change (△H^0) and entropy change (△S^0) were also calculated. By comparison of the adsorption coefficient of CPs with varying physical-chemical properties (size, hydrophobicity and electron density), we propose that hydrophobic interactions between CPs and the SBA-15 surface, as well as electron donor-acceptor (EDA) complexes between oxygen of the siloxane surface of SBA-15 (e--donor) and the n-system of the CPs (e--acceptor), were dominant adsorption mechanisms.展开更多
Carbon nanotube yarns(CNTY)possess good specific strength and specific conductivity.As such,their potential for commercial applications is significant.Fatigue performance is a significant consideration in yarn/wire ap...Carbon nanotube yarns(CNTY)possess good specific strength and specific conductivity.As such,their potential for commercial applications is significant.Fatigue performance is a significant consideration in yarn/wire applications.In this study,the flexural fatigue performance of CNTY spun from super-aligned carbon nanotube arrays was investigated using a reversed bending test.The results showed that CNTY exhibited excellent resistance to pure flexural fatigue,significantly outperforming stainless steel wire;CNTY failed where a combination of flexural fatigue and tension–tension fatigue had special hollow fracture morphology,and CNTY resistance remained fundamentally unchanged in the combination fatigue process.展开更多
Long-term preservation of human platelets will greatly reduce the risk of their shortage. Lyophilization has been proved feasible for this purpose. For the recovery of lyophilized platelets,rehydration is an important...Long-term preservation of human platelets will greatly reduce the risk of their shortage. Lyophilization has been proved feasible for this purpose. For the recovery of lyophilized platelets,rehydration is an important process. In this paper,the rehydration proc-esses for 1 mL and 2 mL samples were studied. The effects of prehydration duration(15,30,60,90,120 and 150 min) in 37°C water vapor and the concentration of rehydration solution(25%,50%,75%,100% platelet-poor plasma) on the recovery rate,MPV(mean platelet volume) and PDW(platelet distribution width) were investigated. The mass changes during the prehydration process were weighed. The optimized rehydration conditions are as follows:(1) for 1 mL sample,the prehydration duration was 15 min and for 2 mL sample the prehydration duration was 90 min;(2) the rehydration solution was 75% platelet-poor plasma. Under optimized conditions,the morphology of the rehydrated platelets kept normal and their ultrastructures kept intact,their aggregation capacity to thrombin(1 U/mL) was 82.8% of the fresh ones. These results will be helpful for designing the freeze-drying protocols for human platelets.展开更多
基金Project supported by the National Natural Sciences Foundation of China(No.50576037)Natural Science Foundation of Jiangsu Province(No.BK2006198)
文摘In order to investigate the feasibility of sequential removal NO and SO2 using non-thermal plasma and adsorbent simultaneously, the removal of NO and SO2 from dry gas stream (NO/SO2/N2/O2) with very little O2 using non-thermal plasma was investigated using a coaxial dielectric barrier discharge. Comparative experiments were carried out in the dry gas stream with and without Ar respectively at O2 concentration of 0.1%. The results showed that NO could be removed remarkably and it would be enhanced in the presence of Ar in the dry gas stream. It seems that SO2 could not be removed unless there is Ar in the dry gas stream. The mechanism of removal of NO and SO2 in the dry gas stream was discussed.
基金The National Basic Research Program(973) of China(G1999022209)
文摘An experimental system of De-NO with plasma-catalyst(Cu zeolite) was established to investigate the differences between De- NO with plasma-catalyst and De-NO only with plasma, to provide the instruction for selecting appropriate catalyst and operating condition, The characteristics of De-NO with plasma and De-NO with plasma-catalyst were investigated comparatively by experiments. The experimental results show that De-NO with plasma-catalyst has high NO removal rate; Cu zeolite is an effective catalyst which can promote NO removal rate in plasma remarkably; De-NO with plasma-catalyst should be operated at low temperature and the temperature has opposite effects on the function of catalvst and plasma; water vapor and O2 can increase the NO removal rate.
基金Project supported by the National Natural Science Foundation of China(No.51106071)the Priority Academic Program Development of Jiangsu Higher Education Institutions,China
基金supported by the Postdoctoral Fund of Southeast Universitythe Natural Science Foundation of Jiangsu Province (No. BK2009294)
文摘Studies on the effect of the chlorine content of chlorophenols (CPs) on their adsorption from aqueous solution by mesoporous SBA-15 are important in understanding the mechanisms of CP adsorption. In this study, three CPs with different degrees of chlorine content (i.e., 2-chlorophenol, 2,6-dichlorophenol and 2,4,6-trichlorophenol) were investigated. The effects of parameters such as temperature and solution pH were studied. The results showed that CP adsorption by SBA- 15 increased with increasing number of chlorine substituents and depended strongly on the temperature and solution pH. Thermodynamic parameters such as Gibbs free energy change (AGO), enthalpy change (△H^0) and entropy change (△S^0) were also calculated. By comparison of the adsorption coefficient of CPs with varying physical-chemical properties (size, hydrophobicity and electron density), we propose that hydrophobic interactions between CPs and the SBA-15 surface, as well as electron donor-acceptor (EDA) complexes between oxygen of the siloxane surface of SBA-15 (e--donor) and the n-system of the CPs (e--acceptor), were dominant adsorption mechanisms.
基金supported by the National Natural Science Foundation for Distinguished Young Scholars (51125028)Key Technologies R&D Program of China (2011BAI12B07 and 2012BAI16B01)
文摘Carbon nanotube yarns(CNTY)possess good specific strength and specific conductivity.As such,their potential for commercial applications is significant.Fatigue performance is a significant consideration in yarn/wire applications.In this study,the flexural fatigue performance of CNTY spun from super-aligned carbon nanotube arrays was investigated using a reversed bending test.The results showed that CNTY exhibited excellent resistance to pure flexural fatigue,significantly outperforming stainless steel wire;CNTY failed where a combination of flexural fatigue and tension–tension fatigue had special hollow fracture morphology,and CNTY resistance remained fundamentally unchanged in the combination fatigue process.
基金supported by the National Natural Science Foundation of China (50606032)Specialized Research Fund for the Doctoral Program of Higher Education (20070335145)Scientific Research Foundation for Advanced Talents,Nanjing University of Aeronautics and Astronautics,China (1001-909382)
文摘Long-term preservation of human platelets will greatly reduce the risk of their shortage. Lyophilization has been proved feasible for this purpose. For the recovery of lyophilized platelets,rehydration is an important process. In this paper,the rehydration proc-esses for 1 mL and 2 mL samples were studied. The effects of prehydration duration(15,30,60,90,120 and 150 min) in 37°C water vapor and the concentration of rehydration solution(25%,50%,75%,100% platelet-poor plasma) on the recovery rate,MPV(mean platelet volume) and PDW(platelet distribution width) were investigated. The mass changes during the prehydration process were weighed. The optimized rehydration conditions are as follows:(1) for 1 mL sample,the prehydration duration was 15 min and for 2 mL sample the prehydration duration was 90 min;(2) the rehydration solution was 75% platelet-poor plasma. Under optimized conditions,the morphology of the rehydrated platelets kept normal and their ultrastructures kept intact,their aggregation capacity to thrombin(1 U/mL) was 82.8% of the fresh ones. These results will be helpful for designing the freeze-drying protocols for human platelets.