Although the impact of road transport on urban air quality has achieved a high profile in China,still greater attention is required as it has not yet been considered fully even in relation to the road network linking ...Although the impact of road transport on urban air quality has achieved a high profile in China,still greater attention is required as it has not yet been considered fully even in relation to the road network linking cities and urban areas. Strategic environmental assessment (SEA) is a systematic and comprehensive process for evaluating the environmental impacts of a policy,plan or program in publicly accountable decision-making. Air pollution has been recognized as a significant issue in most transport SEA practices. The Strategic Environmental Assessment of the Hubei Road Network Plan (2002-2020) (HRNP) was introduced as one of the World Bank's pilot SEA projects. An effective framework was developed to investigate the functional relationship between the road network and its potential air pollutant emissions. In this study,two indicators were identified:emission intensity/ inventory of pollutants and the spatial distribution of the most polluted areas. Because strategic actions are inherently nebulous and data quality is often disappointing,three alternative scenarios were employed to address uncertainties and data/scale issues. Calculations were made using emission models and results were analyzed with the help of statistical tools and the geographic information system (GIS). The results from the project implementation and the feedback from the World Bank have both shown that the proposed framework is effective in the transport SEA process.展开更多
Taking a polystyrene production project as an example, according to Technical Guidelines for Environmental Risk Assessment of Con- struction Projects （HJ/T169-2004）, we firstly identity the risk of substances and pr...Taking a polystyrene production project as an example, according to Technical Guidelines for Environmental Risk Assessment of Con- struction Projects （HJ/T169-2004）, we firstly identity the risk of substances and production process to determine the major source of danger, and then conduct source analysis and consequence prediction of the maximum credible accident, finally assess the environmental risk of the project and propose main risk management measures. The results reveal that the environmental risk of the project is acceptable, and it is suggested that some dsk prevention and mitigation measures as well as contingency plans should be established.展开更多
Accurately revealing the spatial heterogeneity in the trade-offs and synergies of land use functions(LUFs)and their driving factors is imperative for advancing sustainable land utilization and optimizing land use plan...Accurately revealing the spatial heterogeneity in the trade-offs and synergies of land use functions(LUFs)and their driving factors is imperative for advancing sustainable land utilization and optimizing land use planning.This is especially critical for ecologically vulnerable inland river basins in arid regions.However,existing methods struggle to effectively capture complex nonlinear interactions among environmental factors and their multifaceted relationships with trade-offs and synergies of LUFs,especially for the inland river basins in arid regions.Consequently,this study focused on the middle reaches of the Heihe River Basin(MHRB),an arid inland river basin in northwestern China.Using land use,socioeconomic,meteorological,and hydrological data from 2000 to 2020,we analyzed the spatiotemporal patterns of LUFs and their trade-off and synergy relationships from the perspective of production,living,ecological functions.Additionally,we employed an integrated Extreme Gradient Boosting(XGBoost)-SHapley Additive exPlanations(SHAP)framework to investigate the environmental factors influencing the spatial heterogeneity in the trade-offs and synergies of LUFs.Our findings reveal that from 2000 to 2020,the production,living,and ecological functions of land use within the MHRB exhibited an increasing trend,demonstrating a distinct spatial pattern of''high in the southwest and low in the northeast''.Significant spatial heterogeneity defined the trade-off and synergistic relationships,with trade-offs dominating human activity-intensive oasis areas,while synergies prevailed in other areas.During the study period,synergistic relationships between production and living functions and between production and ecological functions were relatively robust,whereas synergies in living-ecological functions remained weaker.Natural factors(digital elevation model(DEM),annual mean temperature,Normalized Difference Vegetation Index(NDVI),and annual precipitation)emerged as the primary factors driving the trade-offs and synergies of LUFs,followed by socioeconomic factors(population density,Gross Domestic Product(GDP),and land use intensity),while distance factors(distance to water bodies,distance to residential areas,and distance to roads)exerted minimal influence.Notably,the interactions among NDVI,annual mean temperature,DEM,and land use intensity exerted the most substantial impacts on the relationships among LUFs.This study provides novel perspectives and methodologies for unraveling the mechanisms underlying the spatial heterogeneity in the trade-offs and synergies of LUFs,offering scientific insights to inform regional land use planning and sustainable natural resource management in inland river basins in arid regions.展开更多
To identify the root causes of heavy metal contamination in soils as well as prevent and control such contamination from its sources,this study explored the accumulation patterns and ecological risks of heavy metals l...To identify the root causes of heavy metal contamination in soils as well as prevent and control such contamination from its sources,this study explored the accumulation patterns and ecological risks of heavy metals like Cd and Pb in solid waste in mining areas and across the water body,sediment,soil and agricultural product ecosystem surrounding the mining areas.Focusing on the residual solid waste samples in lead-zinc deposits in a certain area of Guizhou Province,along with samples of topsoils,irrigation water,river sediments,and crops from surrounding areas.This study analyzed the distributions of eight heavy metals,i.e.,Cd,As,Cr,Hg,Pb,Zn,Cu,and Ni,in the samples through field surveys and sample tests.Furthermore,this study assessed the contamination levels and ecological risks of heavy metals in soils,sediments,and agricultural products using methods such as the single-factor index,Nemerow composite index,and potential ecological risk assessment.The results indicate that heavy metals in the solid waste samples all exhibited concentrations exceeding their risk screening values,with 60%greater than their risk intervention values.The soils and sediments demonstrate slight and moderate comprehensive ecological risks of heavy metals.The single-factor potential ecological risks of heavy metals in both the soil and sediment samples decreased in the order of Hg,Cd,Pb,As,Cu,Zn,Cr,and Ni,suggesting the same sources of heavy metals in the soils and sediments.Most of the agricultural product samples exhibited over-limit concentrations of heavy metals dominated by Cd,Pb,Ni,and Cr,excluding Hg and As.The agricultural product assessment using the Nemerow composite index reveals that 35%of the agricultural product samples reached the heavy metal contamination level,implying that the agricultural products from farmland around the solid waste dumps have been contaminated with heavy metals.The eight heavy metals in the soil,sediment,and agricultural product samples manifested high coefficients of variation(CVs),indicating pronounced spatial variability.This suggests that their concentrations in soils,sediments,and agricultural products are significantly influenced by human mining activities.Additionally,the agricultural products exhibit strong transport and accumulation capacities for Cd,Cu,and Zn.展开更多
As the main component of electronic products,plastics contain complex and diverse metal additives.Recycling process is not conducive to stable existence of metal additives in electronic plastics.Once the e-waste plast...As the main component of electronic products,plastics contain complex and diverse metal additives.Recycling process is not conducive to stable existence of metal additives in electronic plastics.Once the e-waste plastics enter the environment,they will continue to release harmful metals into environment after aging,causing serious hazards.This study delved into the analysis and comparison of metal content of e-waste plastics,elucidating aging process and metal leaching behavior over a 112-day natural light exposure period.The findings underscored that metal content in recycled plastics surpassed that in their new counterparts.Specifically,Ti content in new plastics remained below 100 mg/kg,while recycled plastics exhibited Ti content surpassing 100 mg/kg threshold.Throughout prolonged natural light exposure,metals such as Zn,Ba and Sb demonstrated a heightened likelihood of release from electronic plastics in comparison to other metals.The aging process during light exposure led to fragmentation of electronic plastics,accompanied by a reduction in particle size.Notably,the particle size reduction was more pronounced in poly acrylonitrile butadiene styrene(ABS)and recycled ABS,experiencing reductions of 40µm and 85µm,respectively.This phenomenon was attributed to the presence of polybutadiene structural units,which proved more susceptible to aging.Along with the breaking of plastics,the ABS plastics released metal species such as Pb,Cd,Ni,Al that had not been detected in other plastics solutions.The collective evidence from this study suggested that ABS and recycled ABS electronic plastics might pose a heightened potential environmental risk compared to other electronic plastics.展开更多
Heavy metal contamination of soils through anthropogenic activities is a widespread and serious problem confronting scientists and regulators throughout the world. In this study we investigated the distribution, chemi...Heavy metal contamination of soils through anthropogenic activities is a widespread and serious problem confronting scientists and regulators throughout the world. In this study we investigated the distribution, chemical species and availability of lead, zinc, cadmium and copper in nine surface（0 to 20 cm） soils from near an abandoned lead/zinc mine tailings located in Shaoxing, Zhejiang, China. Total heavy metal contents ranged from 5271 to 16369 mg/kg for Pb, 387 to 1221 mg/kg for Zn, 3.0 to 9.3 mg/kg for Cd and 65 to 206 mg/kg for Cu. In general, all heavy metals exceeded China National Standards for Soil Environmental Quality of Heavy Metals by a factor of 3-65 times. Comparison of the heavy metal concentrations（Pb, Zn, Cd and Cu） with clay content revealed a strongly significant relationship while significant relationship（ P 〈 0.001 ） was also obtained between Cd ＋ Zn and Pb ＋ Cu. Solid phase speciation of the soils using Tessier procedure showed that the heavy metals were distributed in the order： residual 〉〉 organically complexed-Fe-Mn oxides occluded 〉 carbonate bound 〉 exchangeable 〉 water soluble. In the organic matter fraction, the ratio of Pb（29.1% ） to its total concentration in the soils was higher than those of Zn（4.70% ）, Cd（3.16% ） and Cu（9.50% ）. The percentages of the water soluble and the exchangeable fractions of Pb（1.80% ） and Cd（2.74% ） were markedly greater than those of Zn（0.10% ） and Cu（0.15% ）, suggesting that Pb and Cd are relatively more mobile and hence more toxic in the contaminated soils. Strongly significant relationships between H20-Pb, H20-Zn and H20-Cu, strong positive correlations between H20-Pb, H20-Zn, H20-Cu and organic matter in soil were found. The content of H20-Pb, H20-Zn, H20-Cu was negatively correlated with pH values. The similar negative relationships between pH values and exchangeable heavy metals were also recorded. It is suggested that increasing soil pH or liming the soil could decrease bioavailability of heavy metals in the soil.展开更多
Food consumption is one of the key exposure routes of humans to contaminants. This article evaluated the residue levels of 51 pesticides and 16 polychlorinated biphenyls （PCBs） in selected fish and food items which ...Food consumption is one of the key exposure routes of humans to contaminants. This article evaluated the residue levels of 51 pesticides and 16 polychlorinated biphenyls （PCBs） in selected fish and food items which were commonly consumed in the Nantong area of Jiangsu Province, Southeast China. The 51 pesticides and 16 PCBs were analyzed by highly sensitive gas chromatography- tandem mass spectrometry （GC-MS/MS）. The results showed that organochlorine pesticides such as dichlorodiphenyltrichloroethanes （DDTs）, hexachlorocyclohexanes （I-ICHs）, hexachlorobenzene （HCB） and mirex and other pesticides including chlorpyrifos, pyrethroid pesticides, metolachlor, pyridaben and trifluralin were frequently detected in the samples, which was consistent with the accumulation level and characteristics of these toxic chemicals in human adipose tissue of people living in Nantong. Meanwhile, correlation of the residue level of toxic chemicals with their physical chemical properties and historic use pattern in Nantong area was observed. Combined with dietary survey results at the same sampling locations, human health risk assessment of ingestion through the dietary route was performed. The results suggested that the non-cancer risks of the chemicals investigated can be considered negligible in the Nantong area, however, the cancer risks from lifetime dietary exposure to DDTs and HCB have exceeded the acceptable levels.展开更多
The contamination and environmental risk assessment of the toxic elements in sediments from the middle-downstream (Zhuzhou-Changsha section) of the Xiangjiang River in Hunan Province of China were studied. The results...The contamination and environmental risk assessment of the toxic elements in sediments from the middle-downstream (Zhuzhou-Changsha section) of the Xiangjiang River in Hunan Province of China were studied. The results show that As, Cd, Pb and Zn are major contaminants in sediments, and average concentrations of these elements significantly exceed both the Control Standards for Pollutants in Sludge of China (GB4284-84) for agricultural use in acidic soils and the effect range median (ERM) values. The average concentrations of As, Cd and Pb in the river water slightly exceed the limit of Surface Water Environment Quality Standard (GB3838-2002). The concentrations of As and Cr in depth profiles extensively change, but slight changes are observed in Pb and Zn. Cd and Zn in most sediment samples can easily enter the food-chain and bring possible ecotoxicological risk to organisms living in sediments according to the risk assessment code.展开更多
Toxicity studies considering both the bare and stabilized forms of zero valent iron nanoparticles（nZVI） could be timely, given that ecological risks identified are minimized through modification or with substitution...Toxicity studies considering both the bare and stabilized forms of zero valent iron nanoparticles（nZVI） could be timely, given that ecological risks identified are minimized through modification or with substitution of approaches in the synthesis, development and environmental application of the nanoparticles before succeeding to volume production.This review is focused on the fate, transport and toxicological implications of the bare nZVI and surface modified particles used for environmental applications.展开更多
The groundwater level has been continuously decreasing due to climate change and long-time overexploitation in the Xiong’an New Area,North China,which caused the enhanced mixing of groundwater in different aquifers a...The groundwater level has been continuously decreasing due to climate change and long-time overexploitation in the Xiong’an New Area,North China,which caused the enhanced mixing of groundwater in different aquifers and significant changes in regional groundwater chemistry characteristics.In this study,groundwater and sediment pore-water in drilling cores obtained from a 600 m borehole were investigated to evaluate hydrogeochemical processes in shallow and deep aquifers and paleo-environmental evolution in the past ca.3.10 Ma.Results showed that there was no obvious change overall in chemical composition along the direction of groundwater runoff,but different hydrochemical processes occurred in shallow and deep groundwater in the vertical direction.Shallow groundwater(<150 m)in the Xiong’an New Area was characterized by high salinity(TDS>1000 mg/L)and high concentrations of Mn and Fe,while deep groundwater had better water quality with lower salinity.The high TDS values mostly occurred in aquifers with depth<70 m and>500 m below land surface.Water isotopes showed that aquifer pore-water mostly originated from meteoric water under the influence of evaporation,and aquitard pore-water belonged to Paleo meteoric water.In addition,the evolution of the paleoclimate since 3.10 Ma BP was reconstructed,and four climate periods were determined by theδ18O profiles of pore-water and sporopollen records from sediments at different depths.It can be inferred that the Quaternary Pleistocene(0.78‒2.58 Ma BP)was dominated by the cold and dry climate of the glacial period,with three interglacial intervals of warm and humid climate.What’s more,this study demonstrates the possibilities of the applications of pore-water on the hydrogeochemical study and further supports the finding that pore-water could retain the feature of paleo-sedimentary water.展开更多
[Objeetive] We aimed to calculate the flow of controlling units in a small watershed based on GIS technology. [Method] Hydrologic analysis on Qingyi River was conducted by using ArcGIS9.0, and the controlling units wi...[Objeetive] We aimed to calculate the flow of controlling units in a small watershed based on GIS technology. [Method] Hydrologic analysis on Qingyi River was conducted by using ArcGIS9.0, and the controlling units with response of water-land were divided according to the riv- er monitoring sections of Xuchang City; considering the wastewater entering the river and the water from its upper reach, the runoff of controlling sections in the driest month （ with guarantee rate of 90% ） was calculated by means of isoline, runoff coefficient and hydrologic analogy method, and the calculated value of Gaocun Bridge section in Linying was contrasted with the measured value in 2010. [Result] The results showed that the cal- culated value and measured value of Gaecun Bridge section in Linying in the driest month of 2010 were 6.03 and 5.93 m^3/s respectively, with relative error of 1.69%, which revealed that the result of calculated runoff was reasonable. [ Conclusion] The way to divide controlling units was reason- able, and the calculation result of runoff was accurate and can meet the precision of water environment capacity calculation.展开更多
Sediments are complex environments, with varying physicochemical characteristics, such as composition and type of organic matter, particle size distribution, and pH. Contaminated sediment is a significant environmenta...Sediments are complex environments, with varying physicochemical characteristics, such as composition and type of organic matter, particle size distribution, and pH. Contaminated sediment is a significant environmental problem affecting many marine, estuarine and freshwater environments throughout the world. Most assessments of water quality have historically focused on water-soluble compounds, with relatively little attention paid to sediment. The aim of this research is to assess the physical and chemical parameters of sediments from Nwaja Creek, Niger Delta, Nigeria. Monitoring of this sediment quality is an important part of preserving and restoring the biological integrity of water bodies as well as protecting aquatic life, wild life and human health. Sediment samples from Nwaja Creek were sampled from seven sampling stations along the creek for over three months May to July, 2015, rainfall peak period, for assessment of their physical and chemical characteristics, such as grain size, organic carbon, pH, conductivity, nitrate and phosphate. These parameters are known to influence the interactions and dynamics of pollutants within sediment matrix. Sediment particle size distribution indicates that they have higher proportion of clay (clay > silt > sand), the mean percentage composition of clay, silt and sand ranged between 64.28% ± 22.04% - 72.36% ± 14.00%, 18.71% ± 12.03% - 27.32% ± 22.17% and 8.40% ± 6.28% - 9.76% ± 4.59% respectively. TOC in the study area is generally above 1% across all stations during the study period with a range between 0.98% and 4.58%. Minimal monthly and spatial variations are observed in particle distribution, pH (3.9 - 8.5) and phosphate (5.5 - 15.5 kg/mg) while significant variations are observed in conductivity (23.0 - 567.0 uS/cm), total organic carbon (0.98% - 4.58%) and nitrate (0.45 - 11.9 mg/kg) concentration. It is concluded that physicochemical characteristics of the sediments from Nwaja Creek are influenced by anthropogenic sources rather than natural as shown by the elevated phosphate and nitrate levels because the Niger Delta geology is not essentially rich in nitrate and its excess in surface or groundwater is considered as pollutant.展开更多
With the implementation of the Official Mexican Standard NOM-011-CONAGUA-2000 [1], the water balance of 730 basins has been calculated and its water availability agreement is published. This rule points out to allocat...With the implementation of the Official Mexican Standard NOM-011-CONAGUA-2000 [1], the water balance of 730 basins has been calculated and its water availability agreement is published. This rule points out to allocate water for the environment only as an annual volume since methods for estimating environmental flows were not standardized in the country. For this reason, The Water Agency (CONAGUA) issued the standard NMX-AA-159-SCFI-2012 [2], to assess environmental flows needed both, at the strategic level in Integrated Water Resources Management (IWRM), or as part of the Environmental Impact Assessment (EIA) of large hydraulic projects. For over ten years, this standard was developed and finally published in September 2012 [3]. It explains different methods from hydrological to holistic approaches, with examples for the country. Its application will cover the urgent need to preserve water for ecosystems in watersheds with high ecological importance and low stress for water use. In this paper, an analysis of the environmental flow standard and examples of the suggested hydrological methods are presented. For its implementation, some steps are taking place, mainly establishing environmental water reserves and building capacities. In addition, environmental allocations are becoming a common practice for all water projects, as well as setting limits to hydrological alterations by hydroelectric dams. The standard promotes the use of technical integration tools to analyze the responses of ecosystems to changes in the flow regime and adaptive management under different scenarios of water use. Although the main steps have been taken, its implementation as mandatory rule will take time.展开更多
During the Environmental Impact Assessment procedure (EIA) for hydropower projects, apart from the compliance with environmental standards and regulations, important environmental and ecosystem changes are foreseen fr...During the Environmental Impact Assessment procedure (EIA) for hydropower projects, apart from the compliance with environmental standards and regulations, important environmental and ecosystem changes are foreseen from planning and construction stages. In Mexico, the EIA and environmental standards are being systematically applied and fulfilled at planning and construction stages for hydropower projects. These are mainly related to control air emissions, solid and hazardous wastes, water discharges and deal with protected species. In addition, due to land use changes, forestry compensation procedures have already been established. To comply with project approval conditions, an Environmental Management Plan (EMP) is carried out during construction;it includes mitigation measures, standards, regulations and approval conditions resulting of project review and in some cases requests from the public audience. Monitoring is carried out in the area of influence that is in the works and where it is expected that natural processes are modified. However, indicators to track these changes are minimal. This paper analyzes the regulatory and organizational frameworks to address environmental management during the planning and construction of hydropower facilities in Mexico and gives recommendations to expand the scope of the supervision and management of ecosystem changes.展开更多
The present study aims at measuring the activity concentrations of ^210Po and ^210Pb in the potable water of Eloor, a major industrial belt in the Ernakulam district of Kerala, India with an aim of evaluating resultan...The present study aims at measuring the activity concentrations of ^210Po and ^210Pb in the potable water of Eloor, a major industrial belt in the Ernakulam district of Kerala, India with an aim of evaluating resultant ingestion dose to critical population. The industrial units located in Eloor discharge their treated effluents into the river Periyar and the surrounding environs. The two major industries of interest with respect to NORMs are the fertilizer plant, processing rock phosphate and the monazite processing plant, which had been in operation for the last 50 years. For sampling, Eloor region was divided into four zones and a total of 55 water samples from different locations were collected and analysed as per standard analytical procedure manual of BARC. The ^210Po concentration ranged between 0.3 to 4.7 mBq.L^-1 and ^210Pb ranged from 0.6 to 4.3 mBq.L^-1. All values are well below the limit of 0.1 Bq.Ll recommended by World Health Organization. Statistical analysis shows a good co-relation between ^210Po and ^210Pb in the water samples analyzed and the mean activity concentration is found to be relatively high in the western region of Eloor compared to other regions. The annual effective dose equivalent to man from ^210Po and ^210Pb through drinking water intake were estimated and found to be 1.13 μSv.y^-1 and 0.99 μSv.y^-1 respectively, which is well below the reference level of committed effective dose （100 μSv.y^-1） recommended by WHO.展开更多
In this study, eleven soil samples and twenty-twoplants samples were collected in the vicinity of eleven industries and a thermal station was analyzed for zinc, copper, iron, lead and cadmium. Soil sample from Egbin t...In this study, eleven soil samples and twenty-twoplants samples were collected in the vicinity of eleven industries and a thermal station was analyzed for zinc, copper, iron, lead and cadmium. Soil sample from Egbin thermal station had the highest concentration of Zn (141.06 mg/kg) and Cu (131.70 mg/kg). Soil from international textile had the highest level of Fe and the soil from Ni-chemtex had the highest concentration Pb and Cd was the highest in soil from Guinness (28.91 mg/kg, 59.80 mg/kg and 1.72 mg/kg respectively). The highest concentrations of the heavy metals were observed from different plants species. Analyses of variance (p < 0.05) showed that heavy metal variation in plant and soil samples were not significant (p > 0.5). There were positive correlations between the heavy metals in the soils and the plant samples indicated that the plants obtained the heavy metals from the soil. Plants having BCF values less than one had limited ability to accumulate, translocate and phytoextract heavy metals. These plants in this study with higher Bioconcentration Factor value especially those greater than one (Croton lobatus, Borreria sp., Cy-athula prostrata, Lantana camara, Ficus sp., Mimosa pudica, Eclipta prostrata, Commelina sp. etc.) were suggested for further research and assessment on their bioaccumulation abilities and phy-toremediation potential.展开更多
基金Project supported by the Environment Department of the World Bank, and the National Project 985: Circular Economy Innovational Platform in Nankai University, China
文摘Although the impact of road transport on urban air quality has achieved a high profile in China,still greater attention is required as it has not yet been considered fully even in relation to the road network linking cities and urban areas. Strategic environmental assessment (SEA) is a systematic and comprehensive process for evaluating the environmental impacts of a policy,plan or program in publicly accountable decision-making. Air pollution has been recognized as a significant issue in most transport SEA practices. The Strategic Environmental Assessment of the Hubei Road Network Plan (2002-2020) (HRNP) was introduced as one of the World Bank's pilot SEA projects. An effective framework was developed to investigate the functional relationship between the road network and its potential air pollutant emissions. In this study,two indicators were identified:emission intensity/ inventory of pollutants and the spatial distribution of the most polluted areas. Because strategic actions are inherently nebulous and data quality is often disappointing,three alternative scenarios were employed to address uncertainties and data/scale issues. Calculations were made using emission models and results were analyzed with the help of statistical tools and the geographic information system (GIS). The results from the project implementation and the feedback from the World Bank have both shown that the proposed framework is effective in the transport SEA process.
文摘Taking a polystyrene production project as an example, according to Technical Guidelines for Environmental Risk Assessment of Con- struction Projects （HJ/T169-2004）, we firstly identity the risk of substances and production process to determine the major source of danger, and then conduct source analysis and consequence prediction of the maximum credible accident, finally assess the environmental risk of the project and propose main risk management measures. The results reveal that the environmental risk of the project is acceptable, and it is suggested that some dsk prevention and mitigation measures as well as contingency plans should be established.
基金funded by the University Teachers Innovation Fund Project of Gansu Province(2025A-001)the Northwest Normal University Young Teachers'Scientific Research Ability Improvement Plan(NWNULKQN2024-20).
文摘Accurately revealing the spatial heterogeneity in the trade-offs and synergies of land use functions(LUFs)and their driving factors is imperative for advancing sustainable land utilization and optimizing land use planning.This is especially critical for ecologically vulnerable inland river basins in arid regions.However,existing methods struggle to effectively capture complex nonlinear interactions among environmental factors and their multifaceted relationships with trade-offs and synergies of LUFs,especially for the inland river basins in arid regions.Consequently,this study focused on the middle reaches of the Heihe River Basin(MHRB),an arid inland river basin in northwestern China.Using land use,socioeconomic,meteorological,and hydrological data from 2000 to 2020,we analyzed the spatiotemporal patterns of LUFs and their trade-off and synergy relationships from the perspective of production,living,ecological functions.Additionally,we employed an integrated Extreme Gradient Boosting(XGBoost)-SHapley Additive exPlanations(SHAP)framework to investigate the environmental factors influencing the spatial heterogeneity in the trade-offs and synergies of LUFs.Our findings reveal that from 2000 to 2020,the production,living,and ecological functions of land use within the MHRB exhibited an increasing trend,demonstrating a distinct spatial pattern of''high in the southwest and low in the northeast''.Significant spatial heterogeneity defined the trade-off and synergistic relationships,with trade-offs dominating human activity-intensive oasis areas,while synergies prevailed in other areas.During the study period,synergistic relationships between production and living functions and between production and ecological functions were relatively robust,whereas synergies in living-ecological functions remained weaker.Natural factors(digital elevation model(DEM),annual mean temperature,Normalized Difference Vegetation Index(NDVI),and annual precipitation)emerged as the primary factors driving the trade-offs and synergies of LUFs,followed by socioeconomic factors(population density,Gross Domestic Product(GDP),and land use intensity),while distance factors(distance to water bodies,distance to residential areas,and distance to roads)exerted minimal influence.Notably,the interactions among NDVI,annual mean temperature,DEM,and land use intensity exerted the most substantial impacts on the relationships among LUFs.This study provides novel perspectives and methodologies for unraveling the mechanisms underlying the spatial heterogeneity in the trade-offs and synergies of LUFs,offering scientific insights to inform regional land use planning and sustainable natural resource management in inland river basins in arid regions.
文摘To identify the root causes of heavy metal contamination in soils as well as prevent and control such contamination from its sources,this study explored the accumulation patterns and ecological risks of heavy metals like Cd and Pb in solid waste in mining areas and across the water body,sediment,soil and agricultural product ecosystem surrounding the mining areas.Focusing on the residual solid waste samples in lead-zinc deposits in a certain area of Guizhou Province,along with samples of topsoils,irrigation water,river sediments,and crops from surrounding areas.This study analyzed the distributions of eight heavy metals,i.e.,Cd,As,Cr,Hg,Pb,Zn,Cu,and Ni,in the samples through field surveys and sample tests.Furthermore,this study assessed the contamination levels and ecological risks of heavy metals in soils,sediments,and agricultural products using methods such as the single-factor index,Nemerow composite index,and potential ecological risk assessment.The results indicate that heavy metals in the solid waste samples all exhibited concentrations exceeding their risk screening values,with 60%greater than their risk intervention values.The soils and sediments demonstrate slight and moderate comprehensive ecological risks of heavy metals.The single-factor potential ecological risks of heavy metals in both the soil and sediment samples decreased in the order of Hg,Cd,Pb,As,Cu,Zn,Cr,and Ni,suggesting the same sources of heavy metals in the soils and sediments.Most of the agricultural product samples exhibited over-limit concentrations of heavy metals dominated by Cd,Pb,Ni,and Cr,excluding Hg and As.The agricultural product assessment using the Nemerow composite index reveals that 35%of the agricultural product samples reached the heavy metal contamination level,implying that the agricultural products from farmland around the solid waste dumps have been contaminated with heavy metals.The eight heavy metals in the soil,sediment,and agricultural product samples manifested high coefficients of variation(CVs),indicating pronounced spatial variability.This suggests that their concentrations in soils,sediments,and agricultural products are significantly influenced by human mining activities.Additionally,the agricultural products exhibit strong transport and accumulation capacities for Cd,Cu,and Zn.
基金the Natural Science Foundation of Guangdong Province(No.2021B1515020041)the National Natural Science Foundation of China(No.42277403)+4 种基金the Projects of International Cooperation and Exchange of the National Natural Science Foundation of China(NSFC-UNEP)(No:32261143459)the Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control(No.2023B1212060002)the Guangdong Major Project of Basic and Applied Basic Research(No.2023B0303000024)the High-level University Special Fund(No.G03050K001)the Research Projects of the General Administration of Customs(No.2022HK060)for financial support.
文摘As the main component of electronic products,plastics contain complex and diverse metal additives.Recycling process is not conducive to stable existence of metal additives in electronic plastics.Once the e-waste plastics enter the environment,they will continue to release harmful metals into environment after aging,causing serious hazards.This study delved into the analysis and comparison of metal content of e-waste plastics,elucidating aging process and metal leaching behavior over a 112-day natural light exposure period.The findings underscored that metal content in recycled plastics surpassed that in their new counterparts.Specifically,Ti content in new plastics remained below 100 mg/kg,while recycled plastics exhibited Ti content surpassing 100 mg/kg threshold.Throughout prolonged natural light exposure,metals such as Zn,Ba and Sb demonstrated a heightened likelihood of release from electronic plastics in comparison to other metals.The aging process during light exposure led to fragmentation of electronic plastics,accompanied by a reduction in particle size.Notably,the particle size reduction was more pronounced in poly acrylonitrile butadiene styrene(ABS)and recycled ABS,experiencing reductions of 40µm and 85µm,respectively.This phenomenon was attributed to the presence of polybutadiene structural units,which proved more susceptible to aging.Along with the breaking of plastics,the ABS plastics released metal species such as Pb,Cd,Ni,Al that had not been detected in other plastics solutions.The collective evidence from this study suggested that ABS and recycled ABS electronic plastics might pose a heightened potential environmental risk compared to other electronic plastics.
文摘Heavy metal contamination of soils through anthropogenic activities is a widespread and serious problem confronting scientists and regulators throughout the world. In this study we investigated the distribution, chemical species and availability of lead, zinc, cadmium and copper in nine surface（0 to 20 cm） soils from near an abandoned lead/zinc mine tailings located in Shaoxing, Zhejiang, China. Total heavy metal contents ranged from 5271 to 16369 mg/kg for Pb, 387 to 1221 mg/kg for Zn, 3.0 to 9.3 mg/kg for Cd and 65 to 206 mg/kg for Cu. In general, all heavy metals exceeded China National Standards for Soil Environmental Quality of Heavy Metals by a factor of 3-65 times. Comparison of the heavy metal concentrations（Pb, Zn, Cd and Cu） with clay content revealed a strongly significant relationship while significant relationship（ P 〈 0.001 ） was also obtained between Cd ＋ Zn and Pb ＋ Cu. Solid phase speciation of the soils using Tessier procedure showed that the heavy metals were distributed in the order： residual 〉〉 organically complexed-Fe-Mn oxides occluded 〉 carbonate bound 〉 exchangeable 〉 water soluble. In the organic matter fraction, the ratio of Pb（29.1% ） to its total concentration in the soils was higher than those of Zn（4.70% ）, Cd（3.16% ） and Cu（9.50% ）. The percentages of the water soluble and the exchangeable fractions of Pb（1.80% ） and Cd（2.74% ） were markedly greater than those of Zn（0.10% ） and Cu（0.15% ）, suggesting that Pb and Cd are relatively more mobile and hence more toxic in the contaminated soils. Strongly significant relationships between H20-Pb, H20-Zn and H20-Cu, strong positive correlations between H20-Pb, H20-Zn, H20-Cu and organic matter in soil were found. The content of H20-Pb, H20-Zn, H20-Cu was negatively correlated with pH values. The similar negative relationships between pH values and exchangeable heavy metals were also recorded. It is suggested that increasing soil pH or liming the soil could decrease bioavailability of heavy metals in the soil.
基金supported by the 2008 Commonwealand Environmental protection Project of the Ministry of Environmental Protection of the People’s Republic of China (MEP) (No. 200809102)"333 High-level Talent Cultivation Project" research funding of Jiangsu Province-"Research on human health risk assessment of pesticides"
文摘Food consumption is one of the key exposure routes of humans to contaminants. This article evaluated the residue levels of 51 pesticides and 16 polychlorinated biphenyls （PCBs） in selected fish and food items which were commonly consumed in the Nantong area of Jiangsu Province, Southeast China. The 51 pesticides and 16 PCBs were analyzed by highly sensitive gas chromatography- tandem mass spectrometry （GC-MS/MS）. The results showed that organochlorine pesticides such as dichlorodiphenyltrichloroethanes （DDTs）, hexachlorocyclohexanes （I-ICHs）, hexachlorobenzene （HCB） and mirex and other pesticides including chlorpyrifos, pyrethroid pesticides, metolachlor, pyridaben and trifluralin were frequently detected in the samples, which was consistent with the accumulation level and characteristics of these toxic chemicals in human adipose tissue of people living in Nantong. Meanwhile, correlation of the residue level of toxic chemicals with their physical chemical properties and historic use pattern in Nantong area was observed. Combined with dietary survey results at the same sampling locations, human health risk assessment of ingestion through the dietary route was performed. The results suggested that the non-cancer risks of the chemicals investigated can be considered negligible in the Nantong area, however, the cancer risks from lifetime dietary exposure to DDTs and HCB have exceeded the acceptable levels.
基金Project (20507022) supported by the National Natural Science Foundation of ChinaProject (EREH050303) supported by the Foundation of Ministry of Education Key Laboratory of Environmental Remediation and Ecosystem Health
文摘The contamination and environmental risk assessment of the toxic elements in sediments from the middle-downstream (Zhuzhou-Changsha section) of the Xiangjiang River in Hunan Province of China were studied. The results show that As, Cd, Pb and Zn are major contaminants in sediments, and average concentrations of these elements significantly exceed both the Control Standards for Pollutants in Sludge of China (GB4284-84) for agricultural use in acidic soils and the effect range median (ERM) values. The average concentrations of As, Cd and Pb in the river water slightly exceed the limit of Surface Water Environment Quality Standard (GB3838-2002). The concentrations of As and Cr in depth profiles extensively change, but slight changes are observed in Pb and Zn. Cd and Zn in most sediment samples can easily enter the food-chain and bring possible ecotoxicological risk to organisms living in sediments according to the risk assessment code.
文摘Toxicity studies considering both the bare and stabilized forms of zero valent iron nanoparticles（nZVI） could be timely, given that ecological risks identified are minimized through modification or with substitution of approaches in the synthesis, development and environmental application of the nanoparticles before succeeding to volume production.This review is focused on the fate, transport and toxicological implications of the bare nZVI and surface modified particles used for environmental applications.
基金The study was financially supported by the National Natural Science Foundation of China(41807220)the Open Fund Project of Hebei Key Laboratory of Geological Resources and Environment Monitoring and Protection(JCYKT201903)the projects of the China Geological Survey(DD20160239 and DD20189142).
文摘The groundwater level has been continuously decreasing due to climate change and long-time overexploitation in the Xiong’an New Area,North China,which caused the enhanced mixing of groundwater in different aquifers and significant changes in regional groundwater chemistry characteristics.In this study,groundwater and sediment pore-water in drilling cores obtained from a 600 m borehole were investigated to evaluate hydrogeochemical processes in shallow and deep aquifers and paleo-environmental evolution in the past ca.3.10 Ma.Results showed that there was no obvious change overall in chemical composition along the direction of groundwater runoff,but different hydrochemical processes occurred in shallow and deep groundwater in the vertical direction.Shallow groundwater(<150 m)in the Xiong’an New Area was characterized by high salinity(TDS>1000 mg/L)and high concentrations of Mn and Fe,while deep groundwater had better water quality with lower salinity.The high TDS values mostly occurred in aquifers with depth<70 m and>500 m below land surface.Water isotopes showed that aquifer pore-water mostly originated from meteoric water under the influence of evaporation,and aquitard pore-water belonged to Paleo meteoric water.In addition,the evolution of the paleoclimate since 3.10 Ma BP was reconstructed,and four climate periods were determined by theδ18O profiles of pore-water and sporopollen records from sediments at different depths.It can be inferred that the Quaternary Pleistocene(0.78‒2.58 Ma BP)was dominated by the cold and dry climate of the glacial period,with three interglacial intervals of warm and humid climate.What’s more,this study demonstrates the possibilities of the applications of pore-water on the hydrogeochemical study and further supports the finding that pore-water could retain the feature of paleo-sedimentary water.
文摘[Objeetive] We aimed to calculate the flow of controlling units in a small watershed based on GIS technology. [Method] Hydrologic analysis on Qingyi River was conducted by using ArcGIS9.0, and the controlling units with response of water-land were divided according to the riv- er monitoring sections of Xuchang City; considering the wastewater entering the river and the water from its upper reach, the runoff of controlling sections in the driest month （ with guarantee rate of 90% ） was calculated by means of isoline, runoff coefficient and hydrologic analogy method, and the calculated value of Gaocun Bridge section in Linying was contrasted with the measured value in 2010. [Result] The results showed that the cal- culated value and measured value of Gaecun Bridge section in Linying in the driest month of 2010 were 6.03 and 5.93 m^3/s respectively, with relative error of 1.69%, which revealed that the result of calculated runoff was reasonable. [ Conclusion] The way to divide controlling units was reason- able, and the calculation result of runoff was accurate and can meet the precision of water environment capacity calculation.
文摘Sediments are complex environments, with varying physicochemical characteristics, such as composition and type of organic matter, particle size distribution, and pH. Contaminated sediment is a significant environmental problem affecting many marine, estuarine and freshwater environments throughout the world. Most assessments of water quality have historically focused on water-soluble compounds, with relatively little attention paid to sediment. The aim of this research is to assess the physical and chemical parameters of sediments from Nwaja Creek, Niger Delta, Nigeria. Monitoring of this sediment quality is an important part of preserving and restoring the biological integrity of water bodies as well as protecting aquatic life, wild life and human health. Sediment samples from Nwaja Creek were sampled from seven sampling stations along the creek for over three months May to July, 2015, rainfall peak period, for assessment of their physical and chemical characteristics, such as grain size, organic carbon, pH, conductivity, nitrate and phosphate. These parameters are known to influence the interactions and dynamics of pollutants within sediment matrix. Sediment particle size distribution indicates that they have higher proportion of clay (clay > silt > sand), the mean percentage composition of clay, silt and sand ranged between 64.28% ± 22.04% - 72.36% ± 14.00%, 18.71% ± 12.03% - 27.32% ± 22.17% and 8.40% ± 6.28% - 9.76% ± 4.59% respectively. TOC in the study area is generally above 1% across all stations during the study period with a range between 0.98% and 4.58%. Minimal monthly and spatial variations are observed in particle distribution, pH (3.9 - 8.5) and phosphate (5.5 - 15.5 kg/mg) while significant variations are observed in conductivity (23.0 - 567.0 uS/cm), total organic carbon (0.98% - 4.58%) and nitrate (0.45 - 11.9 mg/kg) concentration. It is concluded that physicochemical characteristics of the sediments from Nwaja Creek are influenced by anthropogenic sources rather than natural as shown by the elevated phosphate and nitrate levels because the Niger Delta geology is not essentially rich in nitrate and its excess in surface or groundwater is considered as pollutant.
文摘With the implementation of the Official Mexican Standard NOM-011-CONAGUA-2000 [1], the water balance of 730 basins has been calculated and its water availability agreement is published. This rule points out to allocate water for the environment only as an annual volume since methods for estimating environmental flows were not standardized in the country. For this reason, The Water Agency (CONAGUA) issued the standard NMX-AA-159-SCFI-2012 [2], to assess environmental flows needed both, at the strategic level in Integrated Water Resources Management (IWRM), or as part of the Environmental Impact Assessment (EIA) of large hydraulic projects. For over ten years, this standard was developed and finally published in September 2012 [3]. It explains different methods from hydrological to holistic approaches, with examples for the country. Its application will cover the urgent need to preserve water for ecosystems in watersheds with high ecological importance and low stress for water use. In this paper, an analysis of the environmental flow standard and examples of the suggested hydrological methods are presented. For its implementation, some steps are taking place, mainly establishing environmental water reserves and building capacities. In addition, environmental allocations are becoming a common practice for all water projects, as well as setting limits to hydrological alterations by hydroelectric dams. The standard promotes the use of technical integration tools to analyze the responses of ecosystems to changes in the flow regime and adaptive management under different scenarios of water use. Although the main steps have been taken, its implementation as mandatory rule will take time.
文摘During the Environmental Impact Assessment procedure (EIA) for hydropower projects, apart from the compliance with environmental standards and regulations, important environmental and ecosystem changes are foreseen from planning and construction stages. In Mexico, the EIA and environmental standards are being systematically applied and fulfilled at planning and construction stages for hydropower projects. These are mainly related to control air emissions, solid and hazardous wastes, water discharges and deal with protected species. In addition, due to land use changes, forestry compensation procedures have already been established. To comply with project approval conditions, an Environmental Management Plan (EMP) is carried out during construction;it includes mitigation measures, standards, regulations and approval conditions resulting of project review and in some cases requests from the public audience. Monitoring is carried out in the area of influence that is in the works and where it is expected that natural processes are modified. However, indicators to track these changes are minimal. This paper analyzes the regulatory and organizational frameworks to address environmental management during the planning and construction of hydropower facilities in Mexico and gives recommendations to expand the scope of the supervision and management of ecosystem changes.
文摘The present study aims at measuring the activity concentrations of ^210Po and ^210Pb in the potable water of Eloor, a major industrial belt in the Ernakulam district of Kerala, India with an aim of evaluating resultant ingestion dose to critical population. The industrial units located in Eloor discharge their treated effluents into the river Periyar and the surrounding environs. The two major industries of interest with respect to NORMs are the fertilizer plant, processing rock phosphate and the monazite processing plant, which had been in operation for the last 50 years. For sampling, Eloor region was divided into four zones and a total of 55 water samples from different locations were collected and analysed as per standard analytical procedure manual of BARC. The ^210Po concentration ranged between 0.3 to 4.7 mBq.L^-1 and ^210Pb ranged from 0.6 to 4.3 mBq.L^-1. All values are well below the limit of 0.1 Bq.Ll recommended by World Health Organization. Statistical analysis shows a good co-relation between ^210Po and ^210Pb in the water samples analyzed and the mean activity concentration is found to be relatively high in the western region of Eloor compared to other regions. The annual effective dose equivalent to man from ^210Po and ^210Pb through drinking water intake were estimated and found to be 1.13 μSv.y^-1 and 0.99 μSv.y^-1 respectively, which is well below the reference level of committed effective dose （100 μSv.y^-1） recommended by WHO.
文摘In this study, eleven soil samples and twenty-twoplants samples were collected in the vicinity of eleven industries and a thermal station was analyzed for zinc, copper, iron, lead and cadmium. Soil sample from Egbin thermal station had the highest concentration of Zn (141.06 mg/kg) and Cu (131.70 mg/kg). Soil from international textile had the highest level of Fe and the soil from Ni-chemtex had the highest concentration Pb and Cd was the highest in soil from Guinness (28.91 mg/kg, 59.80 mg/kg and 1.72 mg/kg respectively). The highest concentrations of the heavy metals were observed from different plants species. Analyses of variance (p < 0.05) showed that heavy metal variation in plant and soil samples were not significant (p > 0.5). There were positive correlations between the heavy metals in the soils and the plant samples indicated that the plants obtained the heavy metals from the soil. Plants having BCF values less than one had limited ability to accumulate, translocate and phytoextract heavy metals. These plants in this study with higher Bioconcentration Factor value especially those greater than one (Croton lobatus, Borreria sp., Cy-athula prostrata, Lantana camara, Ficus sp., Mimosa pudica, Eclipta prostrata, Commelina sp. etc.) were suggested for further research and assessment on their bioaccumulation abilities and phy-toremediation potential.
