Catalytic carbon dioxide(CO_(2))desorption has emerged as a promising approach to enhance the efficiency of CO_(2)capture while minimizing energy demands,crucial for advancing chemical absorption methods.This study in...Catalytic carbon dioxide(CO_(2))desorption has emerged as a promising approach to enhance the efficiency of CO_(2)capture while minimizing energy demands,crucial for advancing chemical absorption methods.This study investigates the catalytic potential of three metal phosphates(aluminium phosphate(AlPO4),cobaltous phosphate(Co_(3)(PO_(4))_(2)),and zinc phosphate(Zn_(3)(PO_(4))_(2)))in improving the MEA(monoethanolamine)-based CO_(2)absorption-desorption performance.Among the catalysts tested,AlPO_(4)demonstrated superior performance,enhancing CO_(2)absorption capacity by 4.2%to 9.3%and desorption capacity by 12.3%to 22.7%across five cycles.Notably,AlPO_(4)increased the CO_(2)desorption rate by over 104.4%at a desorption temperature of 81.3℃,simultaneously reducing the required sensible heat by 12.3%to 22.7%,compared to processes without catalysts.The improved efficiency is attributed to AlPO_(4)'s ability to effectively transfer hydrogen protons from protonated MEA to carbamate,thereby facilitating the decomposition of carbamate and regenerating CO_(2).This research introduces a viable,cost-effective,and eco-friendly solid acid catalyst strategy for CO_(2)desorption,contributing to the development of more energy-efficient CO_(2)capture technologies.展开更多
Electrocatalytic CO_(2)reduction(ECR)to produce value-added fuels and chemicals using renewable electricity is an emerging strategy to mitigate global warming and decrease reliance on fossil fuels.Among various ECR pr...Electrocatalytic CO_(2)reduction(ECR)to produce value-added fuels and chemicals using renewable electricity is an emerging strategy to mitigate global warming and decrease reliance on fossil fuels.Among various ECR products,liquid oxygenates(Oxys)are especially attractive due to their high energy density,high safety and transportability that could be adapted to the existing infrastructure and transportation system.However,efficiently generating these highly reduced oxygen-containing products by ECR remains challenging due to the complexity of coupled proton and electron transfer processes.In recent years,in-depth studies of reaction mechanisms have advanced the design of catalysts and the regulation of reaction systems for ECR to produce Oxys,Here,by focusing on the production of typical Oxys,such as methanol,acetic acid,ethanol,acetone,n-propanol,and isopropanol,we outline various reaction paths and key intermediates for the electrochemical conversion of CO_(2)into these target products.We also summarize the current research status and recent advances in catalysts based on their elemental composition,and consider recent studies on the change of catalyst geometry and electronic structure,as well as the optimization of reaction systems to increase ECR performance.Finally,we analyze the challenges in the field of ECR to Oxys and provide an outlook on future directions for high-efficiency catalyst prediction and design,as well as the development of advanced reaction systems.展开更多
As global climate governance moves into the implementation phase,the integration of bluetech and clean energy has emerged as a key driver of green transition.On the occasion of the 50th anniversary of China-EU diploma...As global climate governance moves into the implementation phase,the integration of bluetech and clean energy has emerged as a key driver of green transition.On the occasion of the 50th anniversary of China-EU diplomatic relations,China and Portugal have built a multi-level cooperation framework in the“ocean+clean energy”domain,leveraging complementary resource endowments,technological synergies,and policy alignment.展开更多
This paper systematically reviews the institutional evolution of the China-ASEAN Free Trade Area(CAFTA),from its inception in 2002 and full establishment in 2010,through the CAFTA 2.0 upgrade in 2015,to the substantiv...This paper systematically reviews the institutional evolution of the China-ASEAN Free Trade Area(CAFTA),from its inception in 2002 and full establishment in 2010,through the CAFTA 2.0 upgrade in 2015,to the substantive conclusion of CAFTA 3.0 negotiations in 2024.It highlights the key institutional innovations along this trajectory and examines the structural complementarities between China and ASEAN in terms of clean energy resources and industrial capabilities.Based on this foundation,the paper develops a“policy-technology-capital”analytical framework to explain the transition of regional clean energy cooperation from initial resource-industry complementarity toward deeper institution-market integration.Guided by this framework,the study proposes a roadmap and concrete policy recommendations for regional cooperation through 2030.These include:aligning regional emissions targets and renewable energy share goals;establishing a mutual recognition system for green standards;building a digitalized green supply chain and carbon traceability platform;designing cross-border green finance corridors;and constructing integrated electricity-hydrogen-storage corridors in synergy with the Belt and Road Initiative.The study concludes that,if effectively implemented,these measures could raise the regional share of renewable electricity generation to over 30%by 2030.China and ASEAN would then be well positioned to lead in forming a low-carbon,interconnected,and shared regional energy community,offering a replicable and scalable model for low-carbon transition across the Global South.展开更多
This paper examines the technological advancements,policy support,and market trends in the global hydrogen energy market by 2025.As technological innovation and international cooperation advance,hydrogen energy will a...This paper examines the technological advancements,policy support,and market trends in the global hydrogen energy market by 2025.As technological innovation and international cooperation advance,hydrogen energy will achieve commercial applications in transportation,industry,and energy storage,becoming a significant driving force in the global energy transition.展开更多
In the context of the global energy transition,the oil and gas industry faces the urgent challenge of green transformation.This article examines the ESG(Environmental,Social,and Governance)trajectory and sustainable d...In the context of the global energy transition,the oil and gas industry faces the urgent challenge of green transformation.This article examines the ESG(Environmental,Social,and Governance)trajectory and sustainable development within the oil and gas industry.It delves into the current application of the ESG framework within the industry,evaluates policy standards,and assesses the opportunities and challenges confronting it.展开更多
Fucoxanthin,a kind of exclusively algae-derived carotenoids,could reduce lipid content and regulate gut microbiota composition in obese mice,showing potential in preventing hyperlipidemia.This study aimed to illustrat...Fucoxanthin,a kind of exclusively algae-derived carotenoids,could reduce lipid content and regulate gut microbiota composition in obese mice,showing potential in preventing hyperlipidemia.This study aimed to illustrate fucoxanthin efficacy in modulating lipid metabolism in serum and liver of high-fat-induced hyperlipidemia mice,as well as investigate the underlying association with gut microbiota changes.Results showed that fucoxanthin significantly reduced body weight gain and body white fat of the mice.In the serum,total triglycerides(TG),total cholesterol(TC)contents were significantly decreased and high-densitylipoprotein cholesterol levels was significantly upregulated.Moreover,fucoxanthin remarkedly prevented lipid accumulation in the liver.Especially,metabolomics results showed that lipids and lipid-like molecules were significantly downregulated compared with the control,indicating the advance of hepatic lipid metabolism.Bile acids profile in the liver was also greatly changed by fucoxanthin.Meanwhile,fucoxanthin remodeled gut microbiota composition and promoted the relative abundance of Desulfovibrio,Blautia and Clostridia genera.Finally,correlation analysis revealed that these gut microbiota changes were closely related with hepatic metabolites/metabolism and serum lipids.Altogether,this study showed great potential of fucoxanthin in improving serum lipids profile,hepatic lipids and bile acids metabolism of hyperlipidemia mice,which was associated with gut microbiota alteration.展开更多
This study mainly investigates the influence of pore water characteristics on the adsorption properties of coalbed methane through integrated low field nuclear magnetic resonance(LF-NMR),adsorption experiments,and mol...This study mainly investigates the influence of pore water characteristics on the adsorption properties of coalbed methane through integrated low field nuclear magnetic resonance(LF-NMR),adsorption experiments,and molecular dynamics(MD)simulations.Pore water states in three coal ranks were characterized during progressive hydration.Multi-scale analysis revealed how pore water evolution regulates methane adsorption processes.During the diffusion-dominated stage(M2-M3),adsorbed water penetrates into the micropores.In the highly wettable brown coal(L1),the adsorbed water content reaches 2.12 g while in the anthracite(A1),it is only 0.29 g.During the active water injection stage(M4-M6),non-adsorbed water dominates in anthracite(over 85%of the total water content of 4.01 g),while adsorbed water remains dominant in lignite(over 60%of the total water content of 3.52 g).Water content plays a key role in methane adsorption in coal.During the water addition phase,the influence of methane adsorption on medium-to-low-rank coal is relatively weak,while the methane adsorption capacity of high-rank coal A1 shows a significant decrease during both the water diffusion and water addition phases,corresponding to a reduction in Langmuir volume of 21.22 cm^(3)/g.Molecular dynamics(MD)results further show that the free energy between molecules on the surface of hydroxyl-modified coal increases,with hydroxyl groups driving electrostatic interactions between coal and water molecules.Increased steric hindrance inhibits hydrogen bond formation and reduces the rate of hydrogen bond growth.There is a significant correlation between pore water content and coal-water molecular interaction energy,which cross-scale validates the results of LF-NMR testing and MD simulations.展开更多
To accelerate the large-scale integration of renewable energy and support the strategic goals of“carbon peaking and carbon neutrality,”High Voltage Direct Current(HVDC)transmission technology has made significant br...To accelerate the large-scale integration of renewable energy and support the strategic goals of“carbon peaking and carbon neutrality,”High Voltage Direct Current(HVDC)transmission technology has made significant breakthroughs.Among the various approaches,a hybrid DC transmission system that combines a line-commutated converter(LCC)and a voltage source converter(VSC)retains the inherent fault self-clearing capability of the LCC topology while mitigating the risk of commutation failure when connected to a weak grid.In this paper,based on the harmonic generation mechanisms of hybrid DC transmission systems,an improved 3-pulse harmonic source model of the LCC and a dynamic phase-sequence harmonic analysis model of the VSC are developed.The integrated harmonic model demonstrates strong adaptability in accurately calculating DC-side harmonics under the influence of power imbalances and background harmonics.Based on this model,the fundamental characteristics of DC-side harmonics in hybrid DC transmission systems are analyzed.To mitigate harmonic effects,this paper proposes an LCLC-trap2 high-order filter structure with parallel RC damping circuits and a co-optimized design of filter parameters.Finally,a±500 kV hybrid DC transmission systemismodeled using theMATLAB/Simulink platform,and the harmonic filtering performances of the conventional LC filter,the Butterworth filter,and the proposed filter are simulated and compared.The results verify that the proposed filter offers superior performance in suppressing low-order harmonics under nonideal operating conditions.展开更多
MgH_(2)is a promising solid-state hydrogen storage material.However,its high thermodynamics and sluggish kinetics hinder its practical application.Catalytic strategy is effective in improving its kinetic performance.N...MgH_(2)is a promising solid-state hydrogen storage material.However,its high thermodynamics and sluggish kinetics hinder its practical application.Catalytic strategy is effective in improving its kinetic performance.Nevertheless,the highly efficient catalysts or additives are normally of low-yield in fabrication with high cost.In this work,a novel structural LaVO_(4)fabricated by a low-cost method of spraying dry followed by a calcination is used as a catalytic additive for the hydrogen storage of MgH_(2).With an optimized addition of LaVO_(4),the overall hydrogen storage performances of MgH_(2)are significantly improved.An onset dehydrogenation temperature of only 183℃is obtained after an initial activation of dehydrogenation and hydrogenation.The system can desorb 5.7 wt%H_(2)at 250℃within 10 min and maintains a dehydrogenation capacity of 5.0 wt%H_(2)after 50 cycles.It is found that LaVO_(4)is transferred to lanthanum hydride and metallic vanadium in the initial dehydrogenation process,the former acts as a highly effective catalyst for the hydrogen storage of MgH_(2)and the latter undergoes reversible hydrogenation and dehydrogenation in the subsequent cycles.The structural design of the catalyst and its scalable fabrication are highly valuable in realizing the practical application of catalytic strategy for the hydrogen storage of MgH_(2).展开更多
The development of carbon materials with high electrochemical performance for next-generation energy device is emerging, especially N, S co-doped carbon materials have sparked intensive attention. However,the explorat...The development of carbon materials with high electrochemical performance for next-generation energy device is emerging, especially N, S co-doped carbon materials have sparked intensive attention. However,the exploration of N, S co-doped carbon with well-defined active sites and hierarchical porous structures are still limited. In this study, we prepared a series of edge-enriched N, S co-doped carbon materials through pyrolysis of thiourea(TU) encapsulated in zeolitic imidazolate frameworks(TU@ZIF) composites,which delivered very good oxygen reduction reaction(ORR) performance in alkaline medium with onset potential of 0.94 V vs. reversible hydrogen electrode(RHE), good stability and methanol tolerance. Density functional theory(DFT) calculations suggested that carbon atoms adjacent to N and S are probable active sites for ORR intermediates in edge-enriched N, S co-doped carbon materials because higher electron density can enhance O_(2)adsorption, lower formation barriers of intermediates, improving the ORR performance comparing to intact N, S co-doped carbon materials. This study might provide a new pathway for improving ORR activity by the integration engineering of edge sites, and electronic structure of heteroatom doped carbon electrocatalysts.展开更多
Western Guizhou is a favorable region for coalbed methane(CBM)exploration and development in Guizhou Province.Affected by complex geological conditions,the heterogeneity of middle-high rank coal reservoirs is strong,a...Western Guizhou is a favorable region for coalbed methane(CBM)exploration and development in Guizhou Province.Affected by complex geological conditions,the heterogeneity of middle-high rank coal reservoirs is strong,and the geological and engineering control effects on enrichment and high productivity of CBM are significantly different.This paper comparatively analyzes the characteristics of middle-and high-rank coal reservoirs in the western Guizhou region,revealing the productivity characteristics and gas/water production rules of typical middle-high rank CBM high-yield wells.Moreover,it establishes a geological-engineering control model for the enrichment and high productivity of CBM in middle-high-rank coal seams in the western Guizhou region and analyzes the exploration and development potential and direction of middle-high-rank CBM in the region.The results are as follows.First,the middle-rank coal in the western Guizhou region is represented by the Liupanshui coalfield,where cleats and fractures are well developed,the content of macropores and mesopores is relatively high,the permeability is good,and the adsorption capacity is relatively weak.The high-rank coal is represented by the Zhina coalfield,where micropores are well developed,the permeability is greatly affected by burial depth,and the adsorption capacity is strong.Second,the difference in the characteristics of middle-rank and high-rank coal reservoirs in the western Guizhou region is mainly reflected in the pore-permeability conditions and adsorption capacity.The porosity and permeability of middle-rank coal samples are both greater than those of high-rank coal samples,and the development of secondary microfractures is the main reason for the relatively high permeability of middle-rank coal,while the well-developed micropores in high-rank coal provide more space for CBM preservation.Third,the CBM highyield wells in middle-rank coal seams in the western Guizhou region have the characteristics of“relatively high water production and high gas production,”while those of high-rank coal seams have the characteristics of“low water production and high gas production”or“high water production and low gas production.”The gas content and permeability of the coal reservoirs are the common constraints on whether CBM in middle-high rank coal seams can be highly productive under complex geological conditions.Fourth,the enrichment and high productivity of CBM in middle-high rank coal seams under complex geological conditions is the result of the synergistic matching of depth structure hydrology and adaptive fracturing production techniques.The CBM enrichment model,reservoir reformability,and gas/water production characteristics under geological and engineering synergistic control are unique and complex.Fifth,the middle-high rank coal seams in the western Guizhou region exhibit the basic resource characteristics of high gas content and high CBM resource abundance.Carrying out a precise evaluation of the CBM dual sweet spot system and reservoir volume stimulation are important guarantees for the efficient exploration and development of CBM in the western Guizhou region.展开更多
The experimental design of defective carbon-based catalysts currently mainly focuses on the arrangement and combination of various types of defects.The distance effect of defects and defect-defect interaction on the o...The experimental design of defective carbon-based catalysts currently mainly focuses on the arrangement and combination of various types of defects.The distance effect of defects and defect-defect interaction on the oxygen reduction reaction(ORR)catalytic activity remains fully unexplored.Herein,we first investigated the potential effect of inter-defect distance on ORR activity along zigzag and armchair directions through density functional theory(DFT)calculations,and pronounced catalytic activity anisotropy was observed.The shortest inter-defect distance along the zigzag distance results in the highest ORR activity with an ORR overpotential of 0.50 V on the Stone-Wales defect.While the shortest inter-defect distance along the armchair direction cannot influence or even impede the ORR process.Meanwhile,restricting the expansion of intra-defect distance caused by variations in the inter-defect distance could further enhance the ORR activity with an ultralow overpotential of 0.43 V on the C585 defect.Furthermore,the p_(z) band centers of carbon active sites exhibit a linear relationship with the binding strength of O intermediates,which can be a good catalytic descriptor to describe the ORR activity of carbon defects.Our findings highlight interesting avenues for controllable design and synthesis of catalysts in the field of high-density defect catalysis.展开更多
Lithium sulfide(Li_(2)S)is widely regarded as the next-generation cathode material for rechargeable batteries due to its satisfactory theoretical capacity and excellent compatibility with lithium-free anodes.However,t...Lithium sulfide(Li_(2)S)is widely regarded as the next-generation cathode material for rechargeable batteries due to its satisfactory theoretical capacity and excellent compatibility with lithium-free anodes.However,the large-scale applications of Li_(2)S cathodes are limited by the shuttle effect of soluble intermediate lithium polysulfides(LiPSs)and the sluggish redox kinetics of the interconversion between Li_(2)S and sulfur(S).Herein,we report novel nitrogen-doped carbon nanoflakes in-situ embedded with WN-Ni_(2)P heterostructures(WN-Ni_(2)P@NCN)as a multifunctional host to promote the cycling performance and reaction kinetics of Li_(2)S.After loading Li_(2)S,the WNNi_(2)P@NCN/Li_(2)S exhibits stable reversible capacity of 597mAh g^(-1)at 0.5 A g^(-1)over 150 cycles,and superior cycling stability over 800 cycles.The high reversible capacities,excellent cycling properties and superior reaction kinetics of WN-Ni_(2)P@NCN/Li_(2)S are attributed to the strong LiPSs fixation,remarkable catalytic activation and high electronic/ionic conductivity of the WN-Ni_(2)P@NCN framework,confirmed by the experiment and the density function theory calculation results.This work offers a new strategy for designing heterostructure nanoflakes with metal nitride and metal phosphide to facilitate the applications of advanced lithium-sulfur batteries.展开更多
Compared to intact coal,tectonic coal exhibits unique characteristics.The deformation behaviours under cyclic loading with different confining pressures and loading rates are monitored by MTS815 test system,and the me...Compared to intact coal,tectonic coal exhibits unique characteristics.The deformation behaviours under cyclic loading with different confining pressures and loading rates are monitored by MTS815 test system,and the mechanical and energy properties are analysed using experimental data.The results show that the stress-strain curve could be divided into four stages in a single cycle.The elastic strain and elastic energy density increase linearly with deviatoric stress and are proportional to the confining pressure and loading rate;irreversible strain and dissipated energy density increase exponentially with deviatoric stress,inversely proportional to the confining pressure and loading rate.The internal structure of tectonic coal is divided into three types,all of which are damaged under different deviatoric stress levels,thereby explaining the segmentation phenomenon of stress-strain curve of tectonic coal in the cyclic loading process.Tectonic coal exhibits nonlinear energy storage characteristics,which verifies why the tectonic coal is prone to coal and gas outburst from the principle of energy dissipation.In addition,the damage mechanism of tectonic coal is described from the point of energy distribution by introducing the concepts of crushing energy and friction energy.展开更多
Designing high-efficiency photocatalysts responsive to visible light is important for the degradation of antibiotics in water.Heterojunction engineering is undoubtedly an effective strategy to improve the photocatalyt...Designing high-efficiency photocatalysts responsive to visible light is important for the degradation of antibiotics in water.Heterojunction engineering is undoubtedly an effective strategy to improve the photocatalytic performance.In this work,spinel-type metal oxides(NiAl_(2)O_(4),NAO)are synthesized by a simple sol-gel and calcination process.After compounding graphitic carbon nitride(g-C_(3)N_(4)),NAO/g-C_(3)N_(4) heterojunction is obtained,which then is used as the photocatalyst for tetracycline hydrochloride(TC).The effects of photocatalyst dosage,the initial concentration of TC,and solution pH on photodegradation performance are systematically studied.The removal rate of TC on NAO/g-C_(3)N_(4) reach up to∼90%after visible light irradiation for 2 hr and the degradation rate constant is∼7 times,and∼32 times higher than that of pure NAO and g-C_(3)N_(4).The significantly improved photocatalytic activity can be attributed to the synergistic effect between well matched energy levels in NAO/g-C_(3)N_(4) heterojunctions,improvement of interfacial charge transfer,and enhancement of visible light absorption.This study provides a way for the synthesis of efficient photocatalysts and an economic strategy for removing antibiotics contamination in water.展开更多
Deep unmineable coals are considered as economic and effective geological media for CO_(2) storage and CO_(2) enhanced coalbed methane(CO_(2)-ECBM) recovery is the key technology to realize CO_(2) geological sequestra...Deep unmineable coals are considered as economic and effective geological media for CO_(2) storage and CO_(2) enhanced coalbed methane(CO_(2)-ECBM) recovery is the key technology to realize CO_(2) geological sequestration in coals. Anthracite samples were collected from the Qinshui Basin and subjected to mercury intrusion porosimetry, low-pressure CO_(2) adsorption, and high-pressure CH_(4)/CO_(2) isothermal adsorption experiments. The average number of layers of adsorbed molecules(ANLAM) and the CH_(4)/CO_(2) absolute adsorption amounts and their ratio at experimental temperatures and pressures were calculated. Based on a comparison of the density of supercritical CO_(2) and supercritical CH_(4), it is proposed that the higher adsorption capacity of supercritical CO_(2) over supercritical CH_(4) is the result of their density differences at the same temperature. Lastly, the optimal depth for CO_(2)-ECBM in the Qinshui Basin is recommended. The results show that:(1) the adsorption capacity and the ANLAM of CO_(2) are about twice that of CH_(4) on SH-3 anthracite. The effect of pressure on the CO_(2)/CH_(4) absolute adsorption ratio decreases with the increase of pressure and tends to be consistent.(2) A parameter(the density ratio between gas free and adsorbed phase(DRFA)) is proposed to assess the absolute adsorption amount according to the supercritical CO_(2)/CH_(4) attributes. The DRFA of CO_(2) and CH_(4) both show a highly positive correlation with their absolute adsorption amounts, and therefore, the higher DRFA of CO_(2) is the significant cause of its higher adsorption capacity over CH_(4) under the same temperature and pressure.(3) CO_(2) adsorption on coal shows micropore filling with multilayer adsorption in the macro-mesopore, while methane exhibits monolayer surface coverage.(4) Based on the ideal CO_(2)/CH_(4) competitive adsorption ratio, CO_(2) storage capacity, and permeability variation with depth, it is recommended that the optimal depth for CO_(2)-ECBM in the Qinshui Basin ranges from 1000 m to 1500 m.展开更多
Since 2009,ultra-high voltage(UHV)transmission technology has been promoted and applied in China.Over the years,with the accumulation of experience in the construction and operation of UHV projects and the continuous ...Since 2009,ultra-high voltage(UHV)transmission technology has been promoted and applied in China.Over the years,with the accumulation of experience in the construction and operation of UHV projects and the continuous deepening of scientific and technological innovation,UHV technology and key equipment have made great progress.This paper introduces the main achievements of UHV technology innovation from various perspectives including electromagnetic environment,overvoltage and insulation coordination,external insulation and major equipment such as converter transformers,converter valves and gas-insulated transmission lines(GIL).展开更多
Photocatalytic CO_(2)cycloaddition reaction presents a promising CO_(2)conversion strategy to establish carbon neutrality.Among emerging catalysts,metal‑organic frameworks(MOFs)have been regarded as paradigmshifting p...Photocatalytic CO_(2)cycloaddition reaction presents a promising CO_(2)conversion strategy to establish carbon neutrality.Among emerging catalysts,metal‑organic frameworks(MOFs)have been regarded as paradigmshifting photocatalysts for their atomic precision in active site engineering,controllable porosity,and exceptional photochemical stability under ambient conditions.However,inherent limitations persist in conventional MOFs,including restricted solar spectrum utilization,inefficient charge carrier separation,and inadequate epoxide activation ability.Recent breakthroughs address these challenges through multiple strategies:ligand engineering,dopant incorporation,and composite construction.This review systematically maps the evolutionary trajectory of MOF‑based photocatalysts,providing mechanistic insights into structure‑activity relationships and providing insights and directions for the design of high‑performance MOF‑based photocatalysts.展开更多
The widely spread Carboniferous-Permian coal seam group in southern China has great potential for coalbed methane resources,but the extensively developed tectonically deformed coal seriously restricts its development....The widely spread Carboniferous-Permian coal seam group in southern China has great potential for coalbed methane resources,but the extensively developed tectonically deformed coal seriously restricts its development.Taking the Dahebian block in western Guizhou as the study area,the geological model of coalbed methane reservoirs in the tectonically deformed coal seam group was established,and the spatial distribution pattern of model parameters was clarified by clustering algorithms and factor analysis.The facies model suggests that the main coal body structures in Nos.1,4,and 7 coal seams are cataclastic coal and granulated coal,whereas the No.11 coal seam is dominated by granulated coal,which has larger thicknesses and spreads more continuously.The in situ permeability of primary undeformed coal,cataclastic coal,granulated coal,and mylonitized coal reservoirs are 0.333 mD,0.931 mD,0.146 mD,and 0.099 mD,respectively,according to the production performance analysis method.The property model constructed by facies-controlled modeling reveals that Nos.1,4,and 7 coal seams have a wider high-permeability area,but the gas content is lower;the high-permeability area in the No.11 coal seam is more limited,but the gas content is higher.The results of the self-organizing map neural network and K-means clustering indicate that the geological model can be divided into 6 clusters,the model parameter characteristics of the 6 clusters are summarized by data analysis in combination with 6 factors extracted by factor analysis,and the application of data analysis results in multi-layer coalbed methane co-development is presented.This study provides ideas for the geological modeling in the tectonically deformed coal seam group and its data analysis.展开更多
基金supports from the China Postdoctoral Science Foundation(2023M743768)National Natural Science Foundation of China(52006112)Xuzhou Bureau of Science and Technology(KC23293).
文摘Catalytic carbon dioxide(CO_(2))desorption has emerged as a promising approach to enhance the efficiency of CO_(2)capture while minimizing energy demands,crucial for advancing chemical absorption methods.This study investigates the catalytic potential of three metal phosphates(aluminium phosphate(AlPO4),cobaltous phosphate(Co_(3)(PO_(4))_(2)),and zinc phosphate(Zn_(3)(PO_(4))_(2)))in improving the MEA(monoethanolamine)-based CO_(2)absorption-desorption performance.Among the catalysts tested,AlPO_(4)demonstrated superior performance,enhancing CO_(2)absorption capacity by 4.2%to 9.3%and desorption capacity by 12.3%to 22.7%across five cycles.Notably,AlPO_(4)increased the CO_(2)desorption rate by over 104.4%at a desorption temperature of 81.3℃,simultaneously reducing the required sensible heat by 12.3%to 22.7%,compared to processes without catalysts.The improved efficiency is attributed to AlPO_(4)'s ability to effectively transfer hydrogen protons from protonated MEA to carbamate,thereby facilitating the decomposition of carbamate and regenerating CO_(2).This research introduces a viable,cost-effective,and eco-friendly solid acid catalyst strategy for CO_(2)desorption,contributing to the development of more energy-efficient CO_(2)capture technologies.
基金financial supports from the National Natural Science Foundation of China(52201237)the Talent Introduction Project of Chinese Academy of Sciences(E344011)+4 种基金the Shenzhen High Level Talent Team Project(KQTD2022110109364705)the Joint Research Project of China Merchants Group and SIAT(E2Z1521)the Cross Institute Joint Research Youth Team Project of SIAT(E25427)National Natural Science Foundation of China(52402136)the China Postdoctoral Science Foundation(E325281005)。
文摘Electrocatalytic CO_(2)reduction(ECR)to produce value-added fuels and chemicals using renewable electricity is an emerging strategy to mitigate global warming and decrease reliance on fossil fuels.Among various ECR products,liquid oxygenates(Oxys)are especially attractive due to their high energy density,high safety and transportability that could be adapted to the existing infrastructure and transportation system.However,efficiently generating these highly reduced oxygen-containing products by ECR remains challenging due to the complexity of coupled proton and electron transfer processes.In recent years,in-depth studies of reaction mechanisms have advanced the design of catalysts and the regulation of reaction systems for ECR to produce Oxys,Here,by focusing on the production of typical Oxys,such as methanol,acetic acid,ethanol,acetone,n-propanol,and isopropanol,we outline various reaction paths and key intermediates for the electrochemical conversion of CO_(2)into these target products.We also summarize the current research status and recent advances in catalysts based on their elemental composition,and consider recent studies on the change of catalyst geometry and electronic structure,as well as the optimization of reaction systems to increase ECR performance.Finally,we analyze the challenges in the field of ECR to Oxys and provide an outlook on future directions for high-efficiency catalyst prediction and design,as well as the development of advanced reaction systems.
文摘As global climate governance moves into the implementation phase,the integration of bluetech and clean energy has emerged as a key driver of green transition.On the occasion of the 50th anniversary of China-EU diplomatic relations,China and Portugal have built a multi-level cooperation framework in the“ocean+clean energy”domain,leveraging complementary resource endowments,technological synergies,and policy alignment.
文摘This paper systematically reviews the institutional evolution of the China-ASEAN Free Trade Area(CAFTA),from its inception in 2002 and full establishment in 2010,through the CAFTA 2.0 upgrade in 2015,to the substantive conclusion of CAFTA 3.0 negotiations in 2024.It highlights the key institutional innovations along this trajectory and examines the structural complementarities between China and ASEAN in terms of clean energy resources and industrial capabilities.Based on this foundation,the paper develops a“policy-technology-capital”analytical framework to explain the transition of regional clean energy cooperation from initial resource-industry complementarity toward deeper institution-market integration.Guided by this framework,the study proposes a roadmap and concrete policy recommendations for regional cooperation through 2030.These include:aligning regional emissions targets and renewable energy share goals;establishing a mutual recognition system for green standards;building a digitalized green supply chain and carbon traceability platform;designing cross-border green finance corridors;and constructing integrated electricity-hydrogen-storage corridors in synergy with the Belt and Road Initiative.The study concludes that,if effectively implemented,these measures could raise the regional share of renewable electricity generation to over 30%by 2030.China and ASEAN would then be well positioned to lead in forming a low-carbon,interconnected,and shared regional energy community,offering a replicable and scalable model for low-carbon transition across the Global South.
文摘This paper examines the technological advancements,policy support,and market trends in the global hydrogen energy market by 2025.As technological innovation and international cooperation advance,hydrogen energy will achieve commercial applications in transportation,industry,and energy storage,becoming a significant driving force in the global energy transition.
基金supported by“the Fundamental Research Funds for Zhejiang’s Provincial Universities and Colleges,Project No.:2024ZX26”。
文摘In the context of the global energy transition,the oil and gas industry faces the urgent challenge of green transformation.This article examines the ESG(Environmental,Social,and Governance)trajectory and sustainable development within the oil and gas industry.It delves into the current application of the ESG framework within the industry,evaluates policy standards,and assesses the opportunities and challenges confronting it.
基金funded by the National Natural Science Foundation of China(31901624)the Key-Area Research and Development Program of Guangdong Province(2018B020206001)+2 种基金Guangdong Province Zhujiang Talent Program(2019ZT08H476)Shenzhen Science and Technology Program(KQTD20180412181334790)the Innovation Team Project of Universities in Guangdong Province(2020KCXTD023)。
文摘Fucoxanthin,a kind of exclusively algae-derived carotenoids,could reduce lipid content and regulate gut microbiota composition in obese mice,showing potential in preventing hyperlipidemia.This study aimed to illustrate fucoxanthin efficacy in modulating lipid metabolism in serum and liver of high-fat-induced hyperlipidemia mice,as well as investigate the underlying association with gut microbiota changes.Results showed that fucoxanthin significantly reduced body weight gain and body white fat of the mice.In the serum,total triglycerides(TG),total cholesterol(TC)contents were significantly decreased and high-densitylipoprotein cholesterol levels was significantly upregulated.Moreover,fucoxanthin remarkedly prevented lipid accumulation in the liver.Especially,metabolomics results showed that lipids and lipid-like molecules were significantly downregulated compared with the control,indicating the advance of hepatic lipid metabolism.Bile acids profile in the liver was also greatly changed by fucoxanthin.Meanwhile,fucoxanthin remodeled gut microbiota composition and promoted the relative abundance of Desulfovibrio,Blautia and Clostridia genera.Finally,correlation analysis revealed that these gut microbiota changes were closely related with hepatic metabolites/metabolism and serum lipids.Altogether,this study showed great potential of fucoxanthin in improving serum lipids profile,hepatic lipids and bile acids metabolism of hyperlipidemia mice,which was associated with gut microbiota alteration.
基金supported by the National Science Fund for Distinguished Young Scholars(No.51925404)the National Natural Science Foundation of China(Nos.52104233,52104228 and 52404261)the Fundamental Research Funds for the Central Universities(No.2023ZDPY05).
文摘This study mainly investigates the influence of pore water characteristics on the adsorption properties of coalbed methane through integrated low field nuclear magnetic resonance(LF-NMR),adsorption experiments,and molecular dynamics(MD)simulations.Pore water states in three coal ranks were characterized during progressive hydration.Multi-scale analysis revealed how pore water evolution regulates methane adsorption processes.During the diffusion-dominated stage(M2-M3),adsorbed water penetrates into the micropores.In the highly wettable brown coal(L1),the adsorbed water content reaches 2.12 g while in the anthracite(A1),it is only 0.29 g.During the active water injection stage(M4-M6),non-adsorbed water dominates in anthracite(over 85%of the total water content of 4.01 g),while adsorbed water remains dominant in lignite(over 60%of the total water content of 3.52 g).Water content plays a key role in methane adsorption in coal.During the water addition phase,the influence of methane adsorption on medium-to-low-rank coal is relatively weak,while the methane adsorption capacity of high-rank coal A1 shows a significant decrease during both the water diffusion and water addition phases,corresponding to a reduction in Langmuir volume of 21.22 cm^(3)/g.Molecular dynamics(MD)results further show that the free energy between molecules on the surface of hydroxyl-modified coal increases,with hydroxyl groups driving electrostatic interactions between coal and water molecules.Increased steric hindrance inhibits hydrogen bond formation and reduces the rate of hydrogen bond growth.There is a significant correlation between pore water content and coal-water molecular interaction energy,which cross-scale validates the results of LF-NMR testing and MD simulations.
基金funded by the Natural Science Foundation of Chongqing(CSTB2023NSCQMSX0279)the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202201119).
文摘To accelerate the large-scale integration of renewable energy and support the strategic goals of“carbon peaking and carbon neutrality,”High Voltage Direct Current(HVDC)transmission technology has made significant breakthroughs.Among the various approaches,a hybrid DC transmission system that combines a line-commutated converter(LCC)and a voltage source converter(VSC)retains the inherent fault self-clearing capability of the LCC topology while mitigating the risk of commutation failure when connected to a weak grid.In this paper,based on the harmonic generation mechanisms of hybrid DC transmission systems,an improved 3-pulse harmonic source model of the LCC and a dynamic phase-sequence harmonic analysis model of the VSC are developed.The integrated harmonic model demonstrates strong adaptability in accurately calculating DC-side harmonics under the influence of power imbalances and background harmonics.Based on this model,the fundamental characteristics of DC-side harmonics in hybrid DC transmission systems are analyzed.To mitigate harmonic effects,this paper proposes an LCLC-trap2 high-order filter structure with parallel RC damping circuits and a co-optimized design of filter parameters.Finally,a±500 kV hybrid DC transmission systemismodeled using theMATLAB/Simulink platform,and the harmonic filtering performances of the conventional LC filter,the Butterworth filter,and the proposed filter are simulated and compared.The results verify that the proposed filter offers superior performance in suppressing low-order harmonics under nonideal operating conditions.
基金supported by the National Natural Science Foundation of PR China(Nos.52071287,52125104 and 52072342)Natural Science Foundation of Zhejiang Province,PR China(No.LZ23E010002).
文摘MgH_(2)is a promising solid-state hydrogen storage material.However,its high thermodynamics and sluggish kinetics hinder its practical application.Catalytic strategy is effective in improving its kinetic performance.Nevertheless,the highly efficient catalysts or additives are normally of low-yield in fabrication with high cost.In this work,a novel structural LaVO_(4)fabricated by a low-cost method of spraying dry followed by a calcination is used as a catalytic additive for the hydrogen storage of MgH_(2).With an optimized addition of LaVO_(4),the overall hydrogen storage performances of MgH_(2)are significantly improved.An onset dehydrogenation temperature of only 183℃is obtained after an initial activation of dehydrogenation and hydrogenation.The system can desorb 5.7 wt%H_(2)at 250℃within 10 min and maintains a dehydrogenation capacity of 5.0 wt%H_(2)after 50 cycles.It is found that LaVO_(4)is transferred to lanthanum hydride and metallic vanadium in the initial dehydrogenation process,the former acts as a highly effective catalyst for the hydrogen storage of MgH_(2)and the latter undergoes reversible hydrogenation and dehydrogenation in the subsequent cycles.The structural design of the catalyst and its scalable fabrication are highly valuable in realizing the practical application of catalytic strategy for the hydrogen storage of MgH_(2).
基金supported financially by the National Natural Science Foundation of China (No. 21905271)Liaoning Natural Science Foundation (No. 20180510029)the Dalian National Laboratory for Clean Energy (DNL), DNL Cooperation Fund, Chinese Academy of Sciences (No. DNL180402)。
文摘The development of carbon materials with high electrochemical performance for next-generation energy device is emerging, especially N, S co-doped carbon materials have sparked intensive attention. However,the exploration of N, S co-doped carbon with well-defined active sites and hierarchical porous structures are still limited. In this study, we prepared a series of edge-enriched N, S co-doped carbon materials through pyrolysis of thiourea(TU) encapsulated in zeolitic imidazolate frameworks(TU@ZIF) composites,which delivered very good oxygen reduction reaction(ORR) performance in alkaline medium with onset potential of 0.94 V vs. reversible hydrogen electrode(RHE), good stability and methanol tolerance. Density functional theory(DFT) calculations suggested that carbon atoms adjacent to N and S are probable active sites for ORR intermediates in edge-enriched N, S co-doped carbon materials because higher electron density can enhance O_(2)adsorption, lower formation barriers of intermediates, improving the ORR performance comparing to intact N, S co-doped carbon materials. This study might provide a new pathway for improving ORR activity by the integration engineering of edge sites, and electronic structure of heteroatom doped carbon electrocatalysts.
基金supported by the“Belt and Road”Innovation Cooperation Project of Jiangsu Province(Grant No.BZ2022015)the National Natural Science Foundation of China(No.42030810 and 42102207)Geological Exploration Foundation of Guizhou Province(No.52000021MGQSE7S7K6PRP).
文摘Western Guizhou is a favorable region for coalbed methane(CBM)exploration and development in Guizhou Province.Affected by complex geological conditions,the heterogeneity of middle-high rank coal reservoirs is strong,and the geological and engineering control effects on enrichment and high productivity of CBM are significantly different.This paper comparatively analyzes the characteristics of middle-and high-rank coal reservoirs in the western Guizhou region,revealing the productivity characteristics and gas/water production rules of typical middle-high rank CBM high-yield wells.Moreover,it establishes a geological-engineering control model for the enrichment and high productivity of CBM in middle-high-rank coal seams in the western Guizhou region and analyzes the exploration and development potential and direction of middle-high-rank CBM in the region.The results are as follows.First,the middle-rank coal in the western Guizhou region is represented by the Liupanshui coalfield,where cleats and fractures are well developed,the content of macropores and mesopores is relatively high,the permeability is good,and the adsorption capacity is relatively weak.The high-rank coal is represented by the Zhina coalfield,where micropores are well developed,the permeability is greatly affected by burial depth,and the adsorption capacity is strong.Second,the difference in the characteristics of middle-rank and high-rank coal reservoirs in the western Guizhou region is mainly reflected in the pore-permeability conditions and adsorption capacity.The porosity and permeability of middle-rank coal samples are both greater than those of high-rank coal samples,and the development of secondary microfractures is the main reason for the relatively high permeability of middle-rank coal,while the well-developed micropores in high-rank coal provide more space for CBM preservation.Third,the CBM highyield wells in middle-rank coal seams in the western Guizhou region have the characteristics of“relatively high water production and high gas production,”while those of high-rank coal seams have the characteristics of“low water production and high gas production”or“high water production and low gas production.”The gas content and permeability of the coal reservoirs are the common constraints on whether CBM in middle-high rank coal seams can be highly productive under complex geological conditions.Fourth,the enrichment and high productivity of CBM in middle-high rank coal seams under complex geological conditions is the result of the synergistic matching of depth structure hydrology and adaptive fracturing production techniques.The CBM enrichment model,reservoir reformability,and gas/water production characteristics under geological and engineering synergistic control are unique and complex.Fifth,the middle-high rank coal seams in the western Guizhou region exhibit the basic resource characteristics of high gas content and high CBM resource abundance.Carrying out a precise evaluation of the CBM dual sweet spot system and reservoir volume stimulation are important guarantees for the efficient exploration and development of CBM in the western Guizhou region.
基金the financial support of the Australian Research Council under the Discovery Project (DP210100721, and DP210100331)the support of the Australian Research Council (DP230102192)The support from the Ministry of Science and Technology (MOST) of China through the Key Project of Research & Development (2021YFF0500502) is appreciated
文摘The experimental design of defective carbon-based catalysts currently mainly focuses on the arrangement and combination of various types of defects.The distance effect of defects and defect-defect interaction on the oxygen reduction reaction(ORR)catalytic activity remains fully unexplored.Herein,we first investigated the potential effect of inter-defect distance on ORR activity along zigzag and armchair directions through density functional theory(DFT)calculations,and pronounced catalytic activity anisotropy was observed.The shortest inter-defect distance along the zigzag distance results in the highest ORR activity with an ORR overpotential of 0.50 V on the Stone-Wales defect.While the shortest inter-defect distance along the armchair direction cannot influence or even impede the ORR process.Meanwhile,restricting the expansion of intra-defect distance caused by variations in the inter-defect distance could further enhance the ORR activity with an ultralow overpotential of 0.43 V on the C585 defect.Furthermore,the p_(z) band centers of carbon active sites exhibit a linear relationship with the binding strength of O intermediates,which can be a good catalytic descriptor to describe the ORR activity of carbon defects.Our findings highlight interesting avenues for controllable design and synthesis of catalysts in the field of high-density defect catalysis.
基金financially supported by the National Key R&D Program of China(No.2022YFB2502000)the National Natural Science Foundation of China(Nos.51902079,52072342,52377216 and 52102324)+3 种基金Anhui Provincial Natural Science Foundation(Nos.2008085QE271 and 2208085ME108)Excellent Research and Innovation Team of Anhui Universities(No.2022AH010096)Natural Science Research Project for Anhui Universities(No.2024AH051519)Hefei Institutes of Physical Science,Chinese Academy of Sciences Director's Fund(Nos.BJPY2023B04,YZJJ-GGZX-2022-01 and YZJJ202102)
文摘Lithium sulfide(Li_(2)S)is widely regarded as the next-generation cathode material for rechargeable batteries due to its satisfactory theoretical capacity and excellent compatibility with lithium-free anodes.However,the large-scale applications of Li_(2)S cathodes are limited by the shuttle effect of soluble intermediate lithium polysulfides(LiPSs)and the sluggish redox kinetics of the interconversion between Li_(2)S and sulfur(S).Herein,we report novel nitrogen-doped carbon nanoflakes in-situ embedded with WN-Ni_(2)P heterostructures(WN-Ni_(2)P@NCN)as a multifunctional host to promote the cycling performance and reaction kinetics of Li_(2)S.After loading Li_(2)S,the WNNi_(2)P@NCN/Li_(2)S exhibits stable reversible capacity of 597mAh g^(-1)at 0.5 A g^(-1)over 150 cycles,and superior cycling stability over 800 cycles.The high reversible capacities,excellent cycling properties and superior reaction kinetics of WN-Ni_(2)P@NCN/Li_(2)S are attributed to the strong LiPSs fixation,remarkable catalytic activation and high electronic/ionic conductivity of the WN-Ni_(2)P@NCN framework,confirmed by the experiment and the density function theory calculation results.This work offers a new strategy for designing heterostructure nanoflakes with metal nitride and metal phosphide to facilitate the applications of advanced lithium-sulfur batteries.
基金funded by the National Major Scientific Research Instrument Development Project(No.41727801)the National Natural Science Foundation of China(Nos.42030810 and 41972168)+1 种基金the Dominant discipline support project of Jiangsu Province(No.2020CXNL11)the Foundation of Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization(No.2019A001).
文摘Compared to intact coal,tectonic coal exhibits unique characteristics.The deformation behaviours under cyclic loading with different confining pressures and loading rates are monitored by MTS815 test system,and the mechanical and energy properties are analysed using experimental data.The results show that the stress-strain curve could be divided into four stages in a single cycle.The elastic strain and elastic energy density increase linearly with deviatoric stress and are proportional to the confining pressure and loading rate;irreversible strain and dissipated energy density increase exponentially with deviatoric stress,inversely proportional to the confining pressure and loading rate.The internal structure of tectonic coal is divided into three types,all of which are damaged under different deviatoric stress levels,thereby explaining the segmentation phenomenon of stress-strain curve of tectonic coal in the cyclic loading process.Tectonic coal exhibits nonlinear energy storage characteristics,which verifies why the tectonic coal is prone to coal and gas outburst from the principle of energy dissipation.In addition,the damage mechanism of tectonic coal is described from the point of energy distribution by introducing the concepts of crushing energy and friction energy.
基金supported by the National Natural Science Foundation of China(No.21908242).
文摘Designing high-efficiency photocatalysts responsive to visible light is important for the degradation of antibiotics in water.Heterojunction engineering is undoubtedly an effective strategy to improve the photocatalytic performance.In this work,spinel-type metal oxides(NiAl_(2)O_(4),NAO)are synthesized by a simple sol-gel and calcination process.After compounding graphitic carbon nitride(g-C_(3)N_(4)),NAO/g-C_(3)N_(4) heterojunction is obtained,which then is used as the photocatalyst for tetracycline hydrochloride(TC).The effects of photocatalyst dosage,the initial concentration of TC,and solution pH on photodegradation performance are systematically studied.The removal rate of TC on NAO/g-C_(3)N_(4) reach up to∼90%after visible light irradiation for 2 hr and the degradation rate constant is∼7 times,and∼32 times higher than that of pure NAO and g-C_(3)N_(4).The significantly improved photocatalytic activity can be attributed to the synergistic effect between well matched energy levels in NAO/g-C_(3)N_(4) heterojunctions,improvement of interfacial charge transfer,and enhancement of visible light absorption.This study provides a way for the synthesis of efficient photocatalysts and an economic strategy for removing antibiotics contamination in water.
基金the financial support provided by National Natural Science Foundation of China (Nos. 42102207 and 42141012)Major Project supported by Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization, CUMT (2020ZDZZ01C)+1 种基金the Fundamental Research Funds for the Central Universities (2021YCPY0106)A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institution (PAPD)。
文摘Deep unmineable coals are considered as economic and effective geological media for CO_(2) storage and CO_(2) enhanced coalbed methane(CO_(2)-ECBM) recovery is the key technology to realize CO_(2) geological sequestration in coals. Anthracite samples were collected from the Qinshui Basin and subjected to mercury intrusion porosimetry, low-pressure CO_(2) adsorption, and high-pressure CH_(4)/CO_(2) isothermal adsorption experiments. The average number of layers of adsorbed molecules(ANLAM) and the CH_(4)/CO_(2) absolute adsorption amounts and their ratio at experimental temperatures and pressures were calculated. Based on a comparison of the density of supercritical CO_(2) and supercritical CH_(4), it is proposed that the higher adsorption capacity of supercritical CO_(2) over supercritical CH_(4) is the result of their density differences at the same temperature. Lastly, the optimal depth for CO_(2)-ECBM in the Qinshui Basin is recommended. The results show that:(1) the adsorption capacity and the ANLAM of CO_(2) are about twice that of CH_(4) on SH-3 anthracite. The effect of pressure on the CO_(2)/CH_(4) absolute adsorption ratio decreases with the increase of pressure and tends to be consistent.(2) A parameter(the density ratio between gas free and adsorbed phase(DRFA)) is proposed to assess the absolute adsorption amount according to the supercritical CO_(2)/CH_(4) attributes. The DRFA of CO_(2) and CH_(4) both show a highly positive correlation with their absolute adsorption amounts, and therefore, the higher DRFA of CO_(2) is the significant cause of its higher adsorption capacity over CH_(4) under the same temperature and pressure.(3) CO_(2) adsorption on coal shows micropore filling with multilayer adsorption in the macro-mesopore, while methane exhibits monolayer surface coverage.(4) Based on the ideal CO_(2)/CH_(4) competitive adsorption ratio, CO_(2) storage capacity, and permeability variation with depth, it is recommended that the optimal depth for CO_(2)-ECBM in the Qinshui Basin ranges from 1000 m to 1500 m.
文摘Since 2009,ultra-high voltage(UHV)transmission technology has been promoted and applied in China.Over the years,with the accumulation of experience in the construction and operation of UHV projects and the continuous deepening of scientific and technological innovation,UHV technology and key equipment have made great progress.This paper introduces the main achievements of UHV technology innovation from various perspectives including electromagnetic environment,overvoltage and insulation coordination,external insulation and major equipment such as converter transformers,converter valves and gas-insulated transmission lines(GIL).
文摘Photocatalytic CO_(2)cycloaddition reaction presents a promising CO_(2)conversion strategy to establish carbon neutrality.Among emerging catalysts,metal‑organic frameworks(MOFs)have been regarded as paradigmshifting photocatalysts for their atomic precision in active site engineering,controllable porosity,and exceptional photochemical stability under ambient conditions.However,inherent limitations persist in conventional MOFs,including restricted solar spectrum utilization,inefficient charge carrier separation,and inadequate epoxide activation ability.Recent breakthroughs address these challenges through multiple strategies:ligand engineering,dopant incorporation,and composite construction.This review systematically maps the evolutionary trajectory of MOF‑based photocatalysts,providing mechanistic insights into structure‑activity relationships and providing insights and directions for the design of high‑performance MOF‑based photocatalysts.
基金supported by the National Natural Science Foundation of China(Grant No.41727801)the Geological Exploration Foundation of Guizhou Province(No.208-9912-JBN-UTSO)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD).
文摘The widely spread Carboniferous-Permian coal seam group in southern China has great potential for coalbed methane resources,but the extensively developed tectonically deformed coal seriously restricts its development.Taking the Dahebian block in western Guizhou as the study area,the geological model of coalbed methane reservoirs in the tectonically deformed coal seam group was established,and the spatial distribution pattern of model parameters was clarified by clustering algorithms and factor analysis.The facies model suggests that the main coal body structures in Nos.1,4,and 7 coal seams are cataclastic coal and granulated coal,whereas the No.11 coal seam is dominated by granulated coal,which has larger thicknesses and spreads more continuously.The in situ permeability of primary undeformed coal,cataclastic coal,granulated coal,and mylonitized coal reservoirs are 0.333 mD,0.931 mD,0.146 mD,and 0.099 mD,respectively,according to the production performance analysis method.The property model constructed by facies-controlled modeling reveals that Nos.1,4,and 7 coal seams have a wider high-permeability area,but the gas content is lower;the high-permeability area in the No.11 coal seam is more limited,but the gas content is higher.The results of the self-organizing map neural network and K-means clustering indicate that the geological model can be divided into 6 clusters,the model parameter characteristics of the 6 clusters are summarized by data analysis in combination with 6 factors extracted by factor analysis,and the application of data analysis results in multi-layer coalbed methane co-development is presented.This study provides ideas for the geological modeling in the tectonically deformed coal seam group and its data analysis.
