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Axion Gamma-Ray Signatures from Quark Matter in Neutron Stars and Gravitational Wave Comparisons
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作者 Bijan Berenji 《Journal of Modern Physics》 2025年第1期152-166,共15页
We present a theoretical model for detecting axions from neutron stars in a QCD phase of quark matter. The axions would be produced from a quark-antiquark pair uu¯or dd¯, in loop(s) involving gluons. The chi... We present a theoretical model for detecting axions from neutron stars in a QCD phase of quark matter. The axions would be produced from a quark-antiquark pair uu¯or dd¯, in loop(s) involving gluons. The chiral anomaly of QCD and the spontaneously broken symmetry are invoked to explain the non-conservation of the axion current. From the coupling form factors, the axion emissivities ϵacan be derived, from which fluxes can be determined. We predict a photon flux, which may be detectable by Fermi LAT, and limits on the QCD mass ma. In this model, axions decay to gamma rays in a 2-photon vertex. We may determine the expected fluxes from the theoretical emissivity. The sensitivity curve from the Fermi Large Area Telescope (Fermi LAT) would allow axion mass constraints for neutron stars as low as ma≤10−14eV 95% C.L. Axions could thus be detectable in gamma rays for neutron stars as distant as 100 kpc. A signal from LIGO GWS 170817 could be placed from the NS-NS merger, which gives an upper limit of ma≤10−10eV. 展开更多
关键词 Astrophysics PHENOMENOLOGY QCD Axion Neutron Stars Nuclear Theory Gamma Rays Gravitational Waves Fermi-LAT
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Uncovering Hidden Spin of Scalar Fields with Higher-Order Derivative Lagrangian:On the Wave Spin in Drifted and Dissipative Fields
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作者 Shuo Xin Mengxiang Xie Jie Ren 《Chinese Physics Letters》 2025年第6期70-77,共8页
Scalar fields should have no spin angular momentum according to conventional textbook understandings inclassical field theory.Yet,recent studies demonstrate the undoubted existence of wave spin endowed by acousticand ... Scalar fields should have no spin angular momentum according to conventional textbook understandings inclassical field theory.Yet,recent studies demonstrate the undoubted existence of wave spin endowed by acousticand elastic longitudinal waves,which are of irrotational curl-free nature without vorticity and can be describedby scalar fields.Moreover,the conventional theory cannot even answer the question of whether wave spin existsin dissipative fields,given the ubiquitous dissipation in reality.Here,to resolve the seeming paradox and answerthe challenging question,we uncover the origin of wave spin in scalar fields beyond traditional formalism byclarifying that the presence of higher-order derivatives in scalar field Lagrangians can give rise to non-vanishingwave spin.For“spinless”scalar fields of only first-order derivatives,we can make the hidden wave spin emergeby revealing a latent field that leads to the original field through a time derivative,thus giving higher-order termsin Lagrangian.Based on the standard Noether theorem approach,we exemplify the wave spin for unconventionaldrifted acoustic fields,and even for dissipative media,in scalar fields with higher-order derivative Lagrangian.The results would prompt people to build more comprehensive and fundamental understandings of structuralwave spin in classical fields. 展开更多
关键词 higher order derivative Lagrangian hidden spin acousticand elastic longitudinal waveswhich acoustic waves wave spin spin angular momentum scalar fields
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Neodymium-doped hollow Ir/IrO_(2)nanospheres with low geometric iridium density enable excellent acidic water oxidation performance
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作者 Xiaoqian Wei Hanyu Gao +7 位作者 Tiantian Wang Zijian Li Yanru Geng Guiping Zheng Min Gyu Kim Haeseong Jang Xien Liu Qing Qin 《Chinese Journal of Structural Chemistry》 2025年第7期3-10,共8页
Reducing the Ir loading while preserving catalytic performance and mechanical robustness in anodic catalyst layers remains a critical challenge for the large-scale implementation of proton exchange membrane water elec... Reducing the Ir loading while preserving catalytic performance and mechanical robustness in anodic catalyst layers remains a critical challenge for the large-scale implementation of proton exchange membrane water electrolysis(PEMWE).Herein,we present a structural engineering strategy involving neodymium-doped Ir/IrO_(2)(Nd-Ir/IrO_(2))hollow nanospheres with precisely adjustable shell thickness and cavity dimensions.The optimized catalyst demonstrates excellent oxygen evolution reaction(OER)performance in acidic media,achieving a remarkably low overpotential of 259 mV at a benchmark current density of 10 mA cm^(-2) while exhibiting substantially enhanced durability compared to commercial IrO_(2) and Ir/IrO_(2) counterparts.Notably,the Nd-Ir/IrO_(2) catalyst delivers a mass activity of 541.6 A gIr^(-1) at 1.50 V vs RHE,representing a 74.5-fold enhancement over conventional IrO_(2).Through comprehensive electrochemical analysis and advanced characterization techniques reveal that,the hierarchical hollow architecture simultaneously addresses multiple critical requirements:(i)abundant exposed active sites enabled by an enhanced electrochemical surface area,(ii)optimized mass transport pathways through engineered porosity,and(iii)preserved structural integrity via a continuous conductive framework,collectively enabling significant Ir loading reduction without compromising catalytic layer performance.Fundamental mechanistic investigations further disclose that Nd doping induces critical interfacial Nd-O-Ir configurations that stabilize lattice oxygen,together with intensified electron effect among mixed valent Ir that inhibits the overoxidation of Ir active sites during the OER process,synergistically ensuring enhanced catalytic durability.Our work establishes a dual-modulation paradigm integrating nanoscale architectural engineering with atomic-level heteroatom doping,providing a viable pathway toward high-performance PEMWE systems with drastically reduced noble metal requirements. 展开更多
关键词 Oxygen evolution catalyst Low iridium geometric density Electronic effect Nanoscale architectural engineering Anodic catalyst layer
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Molecular Engineering of Benzobisoxazole-Based Conjugated Polymers for High-Performance Organic Photodetectors and Fingerprint Image Sensors
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作者 Cheol Shin WonJo Jeong +7 位作者 Ezgi Darici Lee Jong Baek Park Hyungju Ahn Seyeon Baek Myeong In Kim Dae Sung Chung Kang-Il Seo In Hwan Jung 《Energy & Environmental Materials》 2025年第1期151-163,共13页
Various novel conjugated polymers(CPs)have been developed for organic photodetectors(OPDs),but their application to practical image sensors such as X-ray,R/G/B,and fingerprint sensors is rare.In this article,we report... Various novel conjugated polymers(CPs)have been developed for organic photodetectors(OPDs),but their application to practical image sensors such as X-ray,R/G/B,and fingerprint sensors is rare.In this article,we report the entire process from the synthesis and molecular engineering of novel CPs to the development of OPDs and fingerprint image sensors.We synthesized six benzo[1,2-d:4,5-d’]bis(oxazole)(BBO)-based CPs by modifying the alkyl side chains of the CPs.Several relationships between the molecular structure and the OPD performance were revealed,and increasing the number of linear octyl side chains on the conjugated backbone was the best way to improve Jph and reduce Jd in the OPDs.The optimized CP demonstrated promising OPD performance with a responsivity(R)of 0.22 A/W,specific detectivity(D^(*))of 1.05×10^(13)Jones at a bias of-1 V,rising/falling response time of 2.9/6.9μs,and cut-off frequency(f_(-3dB))of 134 kHz under collimated 530 nm LED irradiation.Finally,a fingerprint image sensor was fabricated by stacking the POTB1-based OPD layer on the organic thin-film transistors(318 ppi).The image contrast caused by the valleys and ridges in the fingerprints was obtained as a digital signal. 展开更多
关键词 alkyl side chain engineering fingerprint image sensor on/off ratio organic photodetector specific detectivity
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Targeted construction of high-performance single-atom platinum-based electrocatalysts for hydrogen evolution reaction
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作者 Jing Liu Xiandi Ma +8 位作者 Jeonghan Roh Dongwon Shin Ara Cho Jeong Woo Han Jianping Long Zhen Zhou Menggai Jiao Kug-Seung Lee EunAe Cho 《Chinese Journal of Catalysis》 2025年第2期259-270,共12页
Exploring platinum single-atom electrocatalysts(SACs)is of great significance for effectively catalyzing the hydrogen evolution reaction in order to maximize the utilization of metal atoms.Herein,ruthenium clusters wi... Exploring platinum single-atom electrocatalysts(SACs)is of great significance for effectively catalyzing the hydrogen evolution reaction in order to maximize the utilization of metal atoms.Herein,ruthenium clusters with several atoms(Rux)supported on nitrogen-doped,cost-efficient Black Pearls 2000(Ru_(x)NBP),were synthesized as initial materials via a simple hydrothermal method.Then,[PtCl_(4)]^(2–)ion was reductively deposited on RuxNBP to obtain a Pt SAC(Pt1/RuxNBP).Electrochemical measurements demonstrate the excellent HER performance of Pt_(1)/Ru_(x)NBP with a 5.7-fold increase in mass activity compared to the commercial Pt/C at 20 mV.Moreover,the cell voltage of the proton exchange membrane electrolyzer with Pt_(1)/Ru_(x)NBP is 20 mV lower compared to that with commercial Pt/C at 1.0 A cm^(−2).Physical characterization and density functional theory calculations revealed that the preserved Pt–Cl bond of[PtCl_(4)]^(2–)and the RuxNBP support co-regulate the 5d state of isolated Pt atoms and enhance the catalytic HER capacity of Pt1/RuxNBP. 展开更多
关键词 PLATINUM Single-atomeletrocatalyst Ruthenium cluster Hydrogen evolution reaction Density functional theory
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A Narrative Review of the Laboratory Information System and Its Role in Antimicrobial Resistance Surveillance in South Africa
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作者 Peter S. Nyasulu Christine Paszko Nontombi Mbelle 《Advances in Microbiology》 2014年第10期692-696,共5页
A laboratory information system (LIS) established in a microbiology department has the potential to play an important role in the quality of microbiology data such as culture of blood, urine, stool, pus swab samples e... A laboratory information system (LIS) established in a microbiology department has the potential to play an important role in the quality of microbiology data such as culture of blood, urine, stool, pus swab samples etc. Such data could be effectively utilised to measure the burden of antimicrobial resistance among patients presented to various hospitals and clinics with an episode of an infectious illness of bacterial origin. A variety of clinical and epidemiological investigations are conducted using culture data and the presence of an electronic system such as LIS enhances such investigations and improves the reliability of measures of antimicrobial resistance owing to improved data quality as well as completeness of data gathered as opposed to paper based system. Therefore to improve surveillance of antimicrobial resistance in South Africa, there is a need to reinforce the functionality of the LIS in both public and private microbiology laboratories as this will help to improve internal quality control methodologies. 展开更多
关键词 LABORATORY Information Systems ANTIMICROBIAL Resistance BACTERIAL PATHOGENS Surveillance South Africa
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Modified TiO_(2)/In_(2)O_(3) heterojunction with efficient charge separation for visible-light-driven photocatalytic CO_(2) reduction to C_(2) product 被引量:3
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作者 Mengfang Liang Xiaodong Shao +8 位作者 Ji Yoon Choi Young Dok Kim Trang Thu Tran Jeongyong Kim Yosep Hwang Min Gyu Kim Yunhee Cho Sophia Akhtar Hyoyoung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第11期714-720,共7页
Utilizing sunlight to convert CO_(2) into chemical fuels could address the greenhouse effect and fossil fuel crisis,Heterojunction structure catalysts with oxygen vacancy are attractive in the field of photocatalytic ... Utilizing sunlight to convert CO_(2) into chemical fuels could address the greenhouse effect and fossil fuel crisis,Heterojunction structure catalysts with oxygen vacancy are attractive in the field of photocatalytic CO_(2) conversion.Herein,a modified TiO_(2)/In_(2)O_(3)(R-P2 5/In_(2)O_(3-x)) type Ⅱ heterojunction composite with oxygen vacancies is designed for photocatalytic CO_(2) reduction,which exhibits excellent CO_(2) reduction activity,with a C_(2) selectivity of 56.66%(in terms of R_(electron)).In situ Fourier-transform infrared spectroscopy(DRIFTS) and time-resolved photoluminescence(TR-PL) spectroscopy are used to reveal the intermediate formation of the photocatalytic mechanism and photogenerated electron lifetime,respectively.The experimental characterizations reveal that the R-P25/In_(2)O_(3-x) composite shows a remarkable behavior for coupling C-C bonds.Besides,efficient charge separation contributes to the improved CO_(2) conversion performance of photocatalysts.This work introduces a type Ⅱ heterojunction composite photocatalyst,which promotes understanding the CO_(2) reduction mechanisms on heterojunction composites and is valuable for the development of photocatalysts. 展开更多
关键词 HETEROJUNCTION Oxygen vacancy Photocatalytic CO_(2)reduction C_(2)product Charge separation
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Fine-tuning electronic structure of N-doped graphitic carbon-supported Co-and Fe-incorporated Mo_(2)C to achieve ultrahigh electrochemical water oxidation activity 被引量:2
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作者 Md.Selim Arif Sher Shah Hyeonjung Jung +3 位作者 Vinod K.Paidi Kug-Seung Lee Jeong Woo Han Jong Hyeok Park 《Carbon Energy》 SCIE EI CAS CSCD 2024年第7期134-149,共16页
Mo_(2)C is an excellent electrocatalyst for hydrogen evolution reaction(HER).However,Mo_(2)C is a poor electrocatalyst for oxygen evolution reaction(OER).Herein,two different elements,namely Co and Fe,are incorporated... Mo_(2)C is an excellent electrocatalyst for hydrogen evolution reaction(HER).However,Mo_(2)C is a poor electrocatalyst for oxygen evolution reaction(OER).Herein,two different elements,namely Co and Fe,are incorporated in Mo_(2)C that,therefore,has a finely tuned electronic structure,which is not achievable by incorporation of any one of the metals.Consequently,the resulting electrocatalyst Co_(0.8)Fe_(0.2)-Mo_(2)C-80 displayed excellent OER catalytic performance,which is evidenced by a low overpotential of 214.0(and 246.5)mV to attain a current density of 10(and 50)mA cm^(-2),an ultralow Tafel slope of 38.4 mV dec^(-1),and longterm stability in alkaline medium.Theoretical data demonstrates that Co_(0.8)Fe_(0.2)-Mo_(2)C-80 requires the lowest overpotential(1.00 V)for OER and Co centers to be the active sites.The ultrahigh catalytic performance of the electrocatalyst is attributed to the excellent intrinsic catalytic activity due to high Brunauer-Emmett-Teller specific surface area,large electrochemically active surface area,small Tafel slope,and low chargetransfer resistance. 展开更多
关键词 fine-tuning electronic structures heteronanostructures Mo_(2)C multimetal(Co/Fe) oxygen evolution reaction
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Tuning electronic structure of RuO_(2)by single atom Zn and oxygen vacancies to boost oxygen evolution reaction in acidic medium 被引量:1
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作者 Qing Qin Tiantian Wang +7 位作者 Zijian Li Guolin Zhang Haeseong Jang Liqiang Hou Yu Wang Min Gyu Kim Shangguo Liu Xien Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期94-102,I0003,共10页
The poor stability of RuO_(2)electrocatalysts has been the primary obstacles for their practical application in polymer electrolyte membrane electrolyzers.To dramatically enhance the durability of RuO_(2)to construct ... The poor stability of RuO_(2)electrocatalysts has been the primary obstacles for their practical application in polymer electrolyte membrane electrolyzers.To dramatically enhance the durability of RuO_(2)to construct activity-stability trade-off model is full of significance but challenging.Herein,a single atom Zn stabilized RuO_(2)with enriched oxygen vacancies(SA Zn-RuO_(2))is developed as a promising alternative to iridium oxide for acidic oxygen evolution reaction(OER).Compared with commercial RuO_(2),the enhanced Ru–O bond strength of SA Zn-RuO_(2)by forming Zn-O-Ru local structure motif is favorable to stabilize surface Ru,while the electrons transferred from Zn single atoms to adjacent Ru atoms protects the Ru active sites from overoxidation.Simultaneously,the optimized surrounding electronic structure of Ru sites in SA ZnRuO_(2)decreases the adsorption energies of OER intermediates to reduce the reaction barrier.As a result,the representative SA Zn-RuO_(2)exhibits a low overpotential of 210 mV to achieve 10 mA cm^(-2)and a greatly enhanced durability than commercial RuO_(2).This work provides a promising dual-engineering strategy by coupling single atom doping and vacancy for the tradeoff of high activity and catalytic stability toward acidic OER. 展开更多
关键词 ELECTROCATALYST Acidic oxygen evolution reaction Electronic structure engineering DURABILITY Reaction barrier
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Enhancement of vertical phase separation in sequentially deposited organic photovoltaics through the independent processing of additives 被引量:1
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作者 Damin Lee Changwoo Park +6 位作者 Gayoung Ham Young Yong Kim Sung-Nam Kwon Junyeong Lee Sungjin Jo Seok-In Na Hyojung Cha 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期768-777,共10页
Herein,the impact of the independent control of processing additives on vertical phase separation in sequentially deposited (SD) organic photovoltaics (OPVs) and its subsequent effects on charge carrier kinetics at th... Herein,the impact of the independent control of processing additives on vertical phase separation in sequentially deposited (SD) organic photovoltaics (OPVs) and its subsequent effects on charge carrier kinetics at the electron donor-acceptor interface are investigated.The film morphology exhibits notable variations,significantly depending on the layer to which 1,8-diiodooctane (DIO) was applied.Grazing incidence wide-angle X-ray scattering analysis reveals distinctly separated donor/acceptor phases and vertical crystallinity details in SD films.Time-of-flight secondary ion mass spectrometry analysis is employed to obtain component distributions in diverse vertical phase structures of SD films depending on additive control.In addition,nanosecond transient absorption spectroscopy shows that DIO control significantly affects the dynamics of separated charges in SD films.In SD OPVs,DIO appears to act through distinct mechanisms with minimal restriction,depending on the applied layer.This study emphasizes the significance of morphological optimization in improving device performance and underscores the importance of independent additive control in the advancement of OPV technology. 展开更多
关键词 Sequential deposition Vertical phase separation Charge dynamics Organic photovoltaics Nonfullerene acceptors
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Correction:Impact of Transition Metal Layer Vacancy on the Structure and Performance of P2 Type Layered Sodium Cathode Material 被引量:2
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作者 Orynbay Zhanadilov Sourav Baiju +7 位作者 Natalia Voronina Jun Ho Yu A-Yeon Kim Hun-Gi Jung Kyuwook Ihm Olivier Guillon Payam Kaghazchi Seung-Taek Myung 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第12期532-532,共1页
Following publication of the original article[1],the authors reported that the author Hun-Gi Jung should be affiliated as 3,4 and 5 instead of 4 and 5.The author’s name“A.-Yeon Kim”needed to be updated to“A-Yeon ... Following publication of the original article[1],the authors reported that the author Hun-Gi Jung should be affiliated as 3,4 and 5 instead of 4 and 5.The author’s name“A.-Yeon Kim”needed to be updated to“A-Yeon Kim”,removing the period.The correct author’s name and affiliation have been provided in this Correction.The original article[1]has been corrected. 展开更多
关键词 removing Transition IMPACT
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Impact of Transition Metal Layer Vacancy on the Structure and Performance of P2 Type Layered Sodium Cathode Material 被引量:1
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作者 Orynbay Zhanadilov Sourav Baiju +7 位作者 Natalia Voronina Jun Ho Yu A.-Yeon Kim Hun‑Gi Jung Kyuwook Ihm Olivier Guillon Payam Kaghazchi Seung‑Taek Myung 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期340-358,共19页
This study explores the impact of introducing vacancy in the transition metal layer of rationally designed Na_(0.6)[Ni_(0.3)Ru_(0.3)Mn_(0.4)]O_(2)(NRM)cathode material.The incorporation of Ru,Ni,and vacancy enhances t... This study explores the impact of introducing vacancy in the transition metal layer of rationally designed Na_(0.6)[Ni_(0.3)Ru_(0.3)Mn_(0.4)]O_(2)(NRM)cathode material.The incorporation of Ru,Ni,and vacancy enhances the structural stability during extensive cycling,increases the operation voltage,and induces a capacity increase while also activating oxygen redox,respectively,in Na_(0.7)[Ni_(0.2)V_(Ni0.1)Ru_(0.3)Mn_(0.4)]O_(2)(V-NRM)compound.Various analytical techniques including transmission electron microscopy,X-ray absorption near edge spectroscopy,operando X-ray diffraction,and operando differential electrochemical mass spectrometry are employed to assess changes in the average oxidation states and structural distortions.The results demonstrate that V-NRM exhibits higher capacity than NRM and maintains a moderate capacity retention of 81%after 100 cycles.Furthermore,the formation of additional lone-pair electrons in the O 2p orbital enables V-NRM to utilize more capacity from the oxygen redox validated by density functional calculation,leading to a widened dominance of the OP4 phase without releasing O_(2) gas.These findings offer valuable insights for the design of advanced high-capacity cathode materials with improved performance and sustainability in sodium-ion batteries. 展开更多
关键词 Layered oxide Oxygen evolution Sodium battery VACANCY CATHODE
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Tailoring local structures of atomically dispersed copper sites for highly selective CO_(2) electroreduction
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作者 Kyung‐Jong Noh Byoung Joon Park +5 位作者 Ying Wang Yejung Choi Sang‐Hoon You Yong‐Tae Kim Kug‐Seung Lee Jeong Woo Han 《Carbon Energy》 SCIE EI CAS CSCD 2024年第4期79-90,共12页
Atomically‐dispersed copper sites coordinated with nitrogen‐doped carbon(Cu–N–C)can provide novel possibilities to enable highly selective and active electrochemical CO_(2) reduction reactions.However,the construc... Atomically‐dispersed copper sites coordinated with nitrogen‐doped carbon(Cu–N–C)can provide novel possibilities to enable highly selective and active electrochemical CO_(2) reduction reactions.However,the construction of optimal local electronic structures for nitrogen‐coordinated Cu sites(Cu–N_(4))on carbon remains challenging.Here,we synthesized the Cu–N–C catalysts with atomically‐dispersed edge‐hosted Cu–N_(4) sites(Cu–N_(4)C_(8))located in a micropore between two graphitic sheets via a facile method to control the concentration of metal precursor.Edge‐hosted Cu–N_(4)C_(8) catalysts outperformed the previously reported M–N–C catalysts for CO_(2)‐to‐CO conversion,achieving a maximum CO Faradaic efficiency(FECO)of 96%,a CO current density of–8.97 mA cm^(–2) at–0.8 V versus reversible hydrogen electrode(RHE),and over FECO of 90%from–0.6 to–1.0 V versus RHE.Computational studies revealed that the micropore of the graphitic layer in edge‐hosted Cu–N_(4)C_(8) sites causes the d‐orbital energy level of the Cu atom to shift upward,which in return decreases the occupancy of antibonding states in the*COOH binding.This research suggests new insights into tailoring the locally coordinated structure of the electrocatalyst at the atomic scale to achieve highly selective electrocatalytic reactions. 展开更多
关键词 atomic local structure density functional theory electrochemical CO_(2)reduction metal nitrogen‐doped carbon single‐atom catalyst
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Disordered Structure and Reversible Phase Transformation from K-Birnessite to Zn-Buserite Enable High-Performance Aqueous Zinc-lon Batteries
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作者 Nibagani Naresh Suyoon Eom +4 位作者 Sang Jun Lee Su Hwan Jeong Ji-Won Jung Young Hwa Jung Joo-Hyung Kim 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期100-111,共12页
The layeredδ-MnO_(2)(dMO)is an excellent cathode material for rechargeable aqueous zinc-ion batteries owing to its large interlayer distance(~0.7 nm),high capacity,and low cost;however,such cathodes suffer from struc... The layeredδ-MnO_(2)(dMO)is an excellent cathode material for rechargeable aqueous zinc-ion batteries owing to its large interlayer distance(~0.7 nm),high capacity,and low cost;however,such cathodes suffer from structural degradation during the long-term cycling process,leading to capacity fading.In this study,a Co-doped dMO composite with reduced graphene oxide(GC-dMO)is developed using a simple cost-effective hydrothermal method.The degree of disorderness increases owing to the hetero-atom doping and graphene oxide composites.It is demonstrated that layered dMO and GC-dMO undergo a structural transition from K-birnessite to the Zn-buserite phase upon the first discharge,which enhances the intercalation of Zn^(2+)ions,H_(2)O molecules in the layered structure.The GC-dMO cathode exhibits an excellent capacity of 302 mAh g^(-1)at a current density of 100 mAg^(-1)after 100 cycles as compared with the dMO cathode(159 mAhg^(-1)).The excellent electrochemical performance of the GC-dMO cathode owing to Co-doping and graphene oxide sheets enhances the interlayer gap and disorderness,and maintains structural stability,which facilitates the easy reverse intercalation and de-intercalation of Zn^(2+)ions and H_(2)O molecules.Therefore,GC-dMO is a promising cathode material for large-scale aqueous ZIBs. 展开更多
关键词 aqueous zinc-ion batteries BIRNESSITE buserite disordered structure phase transformation
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Unravelling the role of the combined effect of metallic charge transfer channel and SiO_(x) overlayer in the Zr/Si-Fe_(2)O_(3):Au:SiO_(x) nanorod arrays to boost photoelectrochemical water splitting
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作者 Tae Sik Koh Periyasamy Anushkkaran +5 位作者 Love Kumar Dhandole Mahadeo A.Mahadik Weon-Sik Chae Hyun Hwi Lee Sun Hee Choi Jum Suk Jang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期370-379,I0009,共11页
Hematite(α-Fe_(2)O_(3)) based photoanodes have been extensively studied due to various intriguing features that make them viable candidates for a photoelectrochemical(PEC) water splitting photoanode.Herein,we propose... Hematite(α-Fe_(2)O_(3)) based photoanodes have been extensively studied due to various intriguing features that make them viable candidates for a photoelectrochemical(PEC) water splitting photoanode.Herein,we propose a Zr-doped Fe_(2)O_(3) photoanode decorated with facilely spin-coated Au nanoparticles(NPs) and microwave-assisted attached Si co-doping in conjunction with a SiO_(x) overlayer that displayed a remarkable photocurrent density of 2.01 mA/cm^(2) at 1.23 V vs.RHE.The kinetic dynamics at the photoelectrode/-electrolyte interface was examined by employing systematic electrochemical investigations.The Au NPs played a dual role in increasing PEC water splitting.First,the Schottky interface that was formed between Au NPs and Zr-Fe_(2)O_(3) lectrode ensured the prevention of electron flow from the photoanode to the metal,increasing the number of available charges as well as suppressing surface charge recombination.Second,Au extracted photoholes from the bulk of the Zr-Fe_(2)O_(3) and transported them to the outer SiO_(x) overlayer,while the SiO_(x) overlayer efficiently collected the photoholes and promoted the hole injection into the electrolyte.Further,Si co-doping enhanced bulk conductivity by reducing bulk charge transfer resistance and improving charge carrier density.This study outlines a technique to design a metallic charge transfer path with an overlayer for solar energy conversion. 展开更多
关键词 HEMATITE Microwave attachment Au nanoparticles SiO_(x) overlayer Water splitting
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Electronic structure and effective mass of pristine and Cl-doped CsPbBr_(3)
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作者 魏志远 魏愉昊 +7 位作者 徐申东 彭舒婷 Makoto Hashimoto 路东辉 潘旭 匡泯泉 肖正国 何俊峰 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期167-171,共5页
Organic–inorganic lead halide perovskites(LHPs) have attracted great interest owing to their outstanding optoelectronic properties.Typically,the underlying electronic structure would determinate the physical properti... Organic–inorganic lead halide perovskites(LHPs) have attracted great interest owing to their outstanding optoelectronic properties.Typically,the underlying electronic structure would determinate the physical properties of materials.But as for now,limited studies have been done to reveal the underlying electronic structure of this material system,comparing to the huge amount of investigations on the material synthesis.The effective mass of the valance band is one of the most important physical parameters which plays a dominant role in charge transport and photovoltaic phenomena.In pristine CsPbBr_(3),the Fr?hlich polarons associated with the Pb–Br stretching modes are proposed to be responsible for the effective mass renormalization.In this regard,it would be very interesting to explore the electronic structure in doped LHPs.Here,we report high-resolution angle-resolved photoemission spectroscopy(ARPES) studies on both pristine and Cl-doped CsPbBr_(3).The experimental band dispersions are extracted from ARPES spectra along both ■ and ■ high symmetry directions.DFT calculations are performed and directly compared with the ARPES data.Our results have revealed the band structure of Cl-doped CsPbBr_(3) for the first time,which have also unveiled the effective mass renormalization in the Cl-doped CsPbBr_(3) compound.Doping dependent measurements indicate that the chlorine doping could moderately tune the renormalization strength.These results will help understand the physical properties of LHPs as a function of doping. 展开更多
关键词 lead halide perovskites electronic structure effective mass
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The FRB-searching Pipeline of the Tianlai Cylinder Pathfinder Array
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作者 Zijie Yu Furen Deng +14 位作者 Shijie Sun Chenhui Niu Jixia Li Fengquan Wu Wei-Yang Wang Yougang Wang Shifan Zuo Lin Shu Jie Hao Xiaohui Liu Reza Ansari Ue-Li Pen Albert Stebbins Peter Timbie Xuelei Chen 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2024年第8期113-132,共20页
This paper presents the design,calibration,and survey strategy of the Fast Radio Burst(FRB)digital backend and its real-time data processing pipeline employed in the Tianlai Cylinder Pathfinder Array.The array,consist... This paper presents the design,calibration,and survey strategy of the Fast Radio Burst(FRB)digital backend and its real-time data processing pipeline employed in the Tianlai Cylinder Pathfinder Array.The array,consisting of three parallel cylindrical reflectors and equipped with 96 dual-polarization feeds,is a radio interferometer array designed for conducting drift scans of the northern celestial semi-sphere.The FRB digital backend enables the formation of 96 digital beams,effectively covering an area of approximately 40 square degrees with the 3 dB beam.Our pipeline demonstrates the capability to conduct an automatic search of FRBs,detecting at quasi-realtime and classifying FRB candidates automatically.The current FRB searching pipeline has an overall recall rate of88%.During the commissioning phase,we successfully detected signals emitted by four well-known pulsars:PSR B0329+54,B2021+51,B0823+26,and B2020+28.We report the first discovery of an FRB by our array,designated as FRB 20220414A.We also investigate the optimal arrangement for the digitally formed beams to achieve maximum detection rate by numerical simulation. 展开更多
关键词 instrumentation interferometers-methods data analysis-(stars )pulsars general-telescopes
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Constraints on Axions from a Relativistic Model of Spatially Extended Gamma-Ray Emission from Neutron Stars
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作者 Bijan Berenji 《Journal of Modern Physics》 2024年第11期1980-1997,共18页
Axions are hypothetical particles proposed to solve the strong CP problem in QCD and may constitute a significant fraction of the dark matter in the universe. Axions are expected to be produced in superfluid neutron s... Axions are hypothetical particles proposed to solve the strong CP problem in QCD and may constitute a significant fraction of the dark matter in the universe. Axions are expected to be produced in superfluid neutron stars and subsequently decay, producing gamma-rays detectable by the Fermi Large Area Telescope (Fermi-LAT). Considering that light QCD axions, as opposed to axions > 1 eV, may travel a long range before they decay into gamma rays, neutron stars may appear as a spatially extended source of gamma rays. We extend our previous search for gamma rays from axions, based on a point source model, to consider the neutron star as an extended source of gamma rays. The extended consideration of neutron stars leads to higher sensitivity to searches for axions, as it will be shown. We investigate the spatial emission of gamma rays using phenomenological models of neutron star axion emission. We present models including the fundamental astrophysics and relativistic, extended gamma-ray emission from axions around neutron stars. A Monte Carlo simulation of the LAT gives us an expectation for the extended angular profile and spectrum. For a source of ≃100 pc, we predict a mean angular spread of ≃2˚ with gamma-ray energies in the range 10 - 200 MeV, due to the cutoff of the spin-structure function Sσ(ω). We demonstrate the feasibility of setting more stringent limits for axions in this mass range, excluding a range not probed by observations before. We consider projected sensitivities for mass limits on axions from RX J1856-3754, a neutron star at a distance of 130 pc. The limit based on 7.9 years of Fermi-LAT data is 3.9 meV for an inner temperature of the neutron star of 20 MeV. 展开更多
关键词 AXIONS Particle Astrophysics Dark Matter
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强子对撞中测量J/Ψ极化的方法(英文)
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作者 胡震 郭爽 +1 位作者 Eric James 钱思进 《北京大学学报(自然科学版)》 EI CAS CSCD 北大核心 2011年第3期397-403,共7页
描述测量J/Ψ介子极化的方法,该方法能够测量质心能量为10 TeV(或以上)的质子对撞中产生的J/Ψ介子的极化参量随其横向动量的变化,LHC上的CMS探测器收集到的前50 pb-1的数据就可以完成这项测量。研究了用于提取极化参量α的拟合过程的误... 描述测量J/Ψ介子极化的方法,该方法能够测量质心能量为10 TeV(或以上)的质子对撞中产生的J/Ψ介子的极化参量随其横向动量的变化,LHC上的CMS探测器收集到的前50 pb-1的数据就可以完成这项测量。研究了用于提取极化参量α的拟合过程的误差,并分析了相应的测量精度。该方法的测量精度受到统计误差和系统误差的影响,其量级为Δαstat<0.13,Δαsyst<0.01。在费米实验室的CDF实验上曾进行过J/Ψ极化的测量,其结果与非相对论QCD理论预言不符,在CMS上进行的再次测量将为这项研究提供更充足的信息。 展开更多
关键词 极化 J/Ψ B强子 CMS 模板 非相对论QCD
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Beam and image experiment of beam deflection electron gun for distributed X-ray sources 被引量:8
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作者 Cheng-Jun Tan Chuan-Xiang Tang +7 位作者 Wen-Hui Huang Qing-Xiu Jin Ying-Chao Du Qun Luo Pei-Dong Wu Dong-Hai Liu Lu-Ming Zhang Cong Xu 《Nuclear Science and Techniques》 SCIE CAS CSCD 2019年第3期127-138,共12页
Distributed X-ray sources comprise a single vacuum chamber containing multiple X-ray sources that are triggered and emit X-rays at a specific time and location. This process facilitates an application for innovative s... Distributed X-ray sources comprise a single vacuum chamber containing multiple X-ray sources that are triggered and emit X-rays at a specific time and location. This process facilitates an application for innovative system concepts in X-ray and computer tomography. This paper proposes a novel electron beam focusing, shaping,and deflection electron gun for distributed X-ray sources.The electron gun uses a dispenser cathode as an electron emitter, a mesh grid to control emission current, and two electrostatic lenses for beam shaping, focusing, and deflection. Novel focusing and deflecting electrodes were designed to increase the number of focal spots in the distributed source. Two identical half-rectangle opening electrodes are controlled by adjusting the potential of the two electrodes to control the electron beam trajectory, and then, multifocal spots are obtained on the anode target. The electron gun can increase the spatial density of the distributed X-ray sources, thereby improving the image quality. The beam experimental results show that the focal spot sizes of the deflected(deflected amplitude 10.5 mm)and non-deflected electron beams at full width at half maximum are 0.80 mm 90.50 mm and 0.55 mm 90.40 mm, respectively(anode voltage 160 kV; beam current 30 mA). The imaging experimental results demonstrate the excellent spatial resolution and time resolution of an imaging system built with the sources, which has an excellent imaging effect on a field-programmable gate array chip and a rotating metal disk. 展开更多
关键词 BEAM DEFLECTION electron GUN X-RAY imaging DISTRIBUTED X-RAY sources STATIONARY CT
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