Against the backdrop of increasingly prominent global energy shortages and environmental issues,the development of efficient energy conversion and storage technologies has become crucial.Zero-dimensional(0D)metal oxid...Against the backdrop of increasingly prominent global energy shortages and environmental issues,the development of efficient energy conversion and storage technologies has become crucial.Zero-dimensional(0D)metal oxide composites exhibit significant application value in the field of energy chemistry due to their unique properties,such as quantum size effect and high specific surface area.From a broad perspective,this paper reviews the main synthesis methods of these composites,including sol-gel method,hydrothermal/solvothermal method,precipitation method,and template method,while analyzing the characteristics of each method.It further discusses their applications in photocatalytic hydrogen production,fuel cells,lithium-ion batteries,and supercapacitors.Additionally,the current challenges,such as material dispersibility and interface bonding,are pointed out,and future development directions are prospected,aiming to provide references for related research.展开更多
随着全球供应链的日益复杂化和不确定性增加,提升供应链韧性成为我国面临的重要挑战。本文基于Web of Science数据库和知网数据库,结合可视化分析方法,对2013—2024年国内外供应链韧性领域相关文献进行对比分析,研究结果表明:(1)国内研...随着全球供应链的日益复杂化和不确定性增加,提升供应链韧性成为我国面临的重要挑战。本文基于Web of Science数据库和知网数据库,结合可视化分析方法,对2013—2024年国内外供应链韧性领域相关文献进行对比分析,研究结果表明:(1)国内研究起步晚于国外,且发文量少于国外。国外整体合作密切程度强于国内,国内、国外均未形成核心作者群。(2)国内相关研究主要集中在技术创新对供应链韧性的影响、供应链韧性战略以及供应链韧性评价等方面;国外相关研究主要集中在供应链韧性内涵、供应链韧性作用机制、供应链韧性评估模型等方面。(3)国内研究演进脉络分为两个阶段,国外研究演进脉络分为三个阶段。(4)在研究前沿方面,国内现阶段聚焦数字化方面,反映了产业升级需求;国外现阶段侧重于数字化与地缘政治方面。展开更多
Zero-dimensional(0D)hybrid metal halides,which consist of organic cations and isolated inorganic metal halide anions,have emerged as phosphors with efficient broadband emissions.However,these materials generally have ...Zero-dimensional(0D)hybrid metal halides,which consist of organic cations and isolated inorganic metal halide anions,have emerged as phosphors with efficient broadband emissions.However,these materials generally have too wide bandgaps and thus cannot be excited by blue light,which hinders their applications for efficient white light-emitting diodes(WLEDs).The key to achieving a blue-light-excitable 0D hybrid metal halide phosphor is to reduce the fundamental bandgap by rational chemical design.In this work,we report two designed hybrid copper(I)iodides,(Ph_(3)MeP)_(2)Cu_(4)I_(6)and(Cy_(3)MeP)_(2)Cu_(4)I_(6),as blue-light-excitable yellow phosphors with ultrabroadband emission.In these compounds,the[Cu_(4)I_(6)]^(2-)anion forms an I6 octahedron centered on a cationic Cu_(4)tetrahedron.The strong cation-cation bonding within the unique cationic Cu_(4)tetrahedra enables significantly lowered conduction band minimums and thus narrowed bandgaps,as compared to other reported hybrid copper(I)iodides.The ultrabroadband emission is attributed to the coexistence of free and self-trapped excitons.The WLED using the[Cu_(4)I_(6)]^(2-)anion-based single phosphor shows warm white light emission,with a high luminous efficiency of 65 Im W^(-1)and a high color rendering index of 88.This work provides strategies to design narrow-bandgap 0D hybrid metal halides and presents two first examples of blue-light-excitable 0D hybrid metal halide phosphors for efficient WLEDs.展开更多
本文基于知识图谱理论,选取1986—2024年中国知网(CNKI)收录的1072篇中文文献为样本,并辅以Web of Science核心合集中的英文文献,运用CiteSpace和VOSviewer软件,从发文数量、研究机构、载文期刊、关键词突现、时间演进与聚类等维度,对...本文基于知识图谱理论,选取1986—2024年中国知网(CNKI)收录的1072篇中文文献为样本,并辅以Web of Science核心合集中的英文文献,运用CiteSpace和VOSviewer软件,从发文数量、研究机构、载文期刊、关键词突现、时间演进与聚类等维度,对制造业转型研究的演化脉络和热点主题进行系统梳理。研究发现:制造业转型相关文献数量持续增长,呈现出显著的多学科交叉特征;研究主题经历了从早期的价值链优化,逐步拓展至数字化、绿色化、智能化与服务化等多个路径;近年来,研究重点进一步聚焦于企业绩效、人才培养与国际竞争力等议题。整体来看,制造业转型正由要素驱动向数字技术主导、多路径融合演进。本文研究成果可为理论拓展与政策制定提供系统参考。展开更多
Clarifying the mechanisms that control the evolution of territorial space patterns is essential for regulating and optimizing the geographical structure and processes related to sustainable development.Using the Guang...Clarifying the mechanisms that control the evolution of territorial space patterns is essential for regulating and optimizing the geographical structure and processes related to sustainable development.Using the Guangdong and Guangxi sections of the Pearl River Basin as examples,the transfer-matrix method and standard deviation ellipse model were applied to characterize the evolution of territorial space patterns from 1990 to 2020.A trend surface analysis and the Theil index were used to analyze regional differences in the evolution process,and geodetectors were used to identify the underlying mechanisms of the changes.There were three key results.(1)In these critical areas of the Pearl River Basin,agricultural and ecological spaces have rapidly declined due to urban expansion,with transfers between these spaces dominating the evolution of territorial space patterns.Spatial pattern changes in the Guangdong section were more intense than in the Guangxi section.(2)Regional differences in urban space have decreased,whereas differences in agricultural and ecological spaces have intensified.Driven by socio-economic growth,the cross-regional transfers of territorial space have created a“high in the east,while low in the west”inter-regional difference,and a“high in the south,while low in the north”intra-regional difference shaped by natural conditions.The regional differences in space patterns were greater in Guangdong than in Guangxi.(3)The evolution of watershed territorial space patterns resulted from scale changes,locational shifts,structural reorganizations,and directional changes driven by multiple factors.Natural environment,social life,economic development,and policy factors played foundational,leading,key driving,and guiding roles,respectively.Additionally,the regional differences in the evolution of watershed territorial space patterns originated from the differential transmission of the influence of various factors affecting spatial evolution.Enhancing urban space efficiency,restructuring agricultural space,and optimizing ecological space are key strategies for building a complementary and synergistic territorial space pattern in the basin.展开更多
Depolarizing behavior is commonly observed in most natural samples.For this reason,optical tools measuring the differences in depolarization response among spatially separated structures are highly useful in a wide ra...Depolarizing behavior is commonly observed in most natural samples.For this reason,optical tools measuring the differences in depolarization response among spatially separated structures are highly useful in a wide range of imaging applications for enhanced visualization of structures,target identification,etc.One commonly used tool for depolarizing discrimination is the so-called depolarizing spaces.In this article,we exploit the combined use of two depolarizing spaces,the indices of polarization purity(IPP)and polarizance–reflection–transformation(PRT)spaces,to improve the capability of optical systems to identify polarization–anisotropy depolarizers.The potential of these spaces to discriminate among different depolarizers is first studied from a series of simulations by incoherently adding diattenuations or retarders,with some control parameters emulating samples in nature.The simulated results demonstrate that the proposed methods are capable of increasing differences among depolarizers beyond other well-known techniques.Experimentally,validation is provided by conducting diverse phantom experiments of easy interpretation and mimicking the stated simulations.As a useful application of our approach,we developed a model able to retrieve intrinsic microscopic information of samples from macroscopic polarimetric measurements.The proposed methods enable non-invasive,straightforward,macroscopic characterization of depolarizing samples,and may be of interest for enhanced visualization of samples in multiple imaging scenarios.展开更多
目的理清中医药的热点和动态,展望中医药研学未来的发展方向。方法检索中国知识资源总库(CNKI)2013-2023年发表的关于中医药研学旅行的相关文献,利用Cite Space 6.2.R4版本,对发文量、关键词等进行分析挖掘。结果有311篇文献被纳入研究...目的理清中医药的热点和动态,展望中医药研学未来的发展方向。方法检索中国知识资源总库(CNKI)2013-2023年发表的关于中医药研学旅行的相关文献,利用Cite Space 6.2.R4版本,对发文量、关键词等进行分析挖掘。结果有311篇文献被纳入研究,25所研究机构被纳入,包括北京中医药大学等。278个关键词被纳入,热点关键词为“中医药”“研学旅行”等,并出现关键词聚类。结论通过Cite Space的引导,中医药研学旅行领域有望取得更为广阔的发展空间。展开更多
文摘Against the backdrop of increasingly prominent global energy shortages and environmental issues,the development of efficient energy conversion and storage technologies has become crucial.Zero-dimensional(0D)metal oxide composites exhibit significant application value in the field of energy chemistry due to their unique properties,such as quantum size effect and high specific surface area.From a broad perspective,this paper reviews the main synthesis methods of these composites,including sol-gel method,hydrothermal/solvothermal method,precipitation method,and template method,while analyzing the characteristics of each method.It further discusses their applications in photocatalytic hydrogen production,fuel cells,lithium-ion batteries,and supercapacitors.Additionally,the current challenges,such as material dispersibility and interface bonding,are pointed out,and future development directions are prospected,aiming to provide references for related research.
文摘随着全球供应链的日益复杂化和不确定性增加,提升供应链韧性成为我国面临的重要挑战。本文基于Web of Science数据库和知网数据库,结合可视化分析方法,对2013—2024年国内外供应链韧性领域相关文献进行对比分析,研究结果表明:(1)国内研究起步晚于国外,且发文量少于国外。国外整体合作密切程度强于国内,国内、国外均未形成核心作者群。(2)国内相关研究主要集中在技术创新对供应链韧性的影响、供应链韧性战略以及供应链韧性评价等方面;国外相关研究主要集中在供应链韧性内涵、供应链韧性作用机制、供应链韧性评估模型等方面。(3)国内研究演进脉络分为两个阶段,国外研究演进脉络分为三个阶段。(4)在研究前沿方面,国内现阶段聚焦数字化方面,反映了产业升级需求;国外现阶段侧重于数字化与地缘政治方面。
基金financially supported by the National Natural Science Foundation of China(Grant No.51972130)the Startup Fund of Huazhong University of Science and Technologythe Director Fund of Wuhan National Laboratory for Optoelectronics
文摘Zero-dimensional(0D)hybrid metal halides,which consist of organic cations and isolated inorganic metal halide anions,have emerged as phosphors with efficient broadband emissions.However,these materials generally have too wide bandgaps and thus cannot be excited by blue light,which hinders their applications for efficient white light-emitting diodes(WLEDs).The key to achieving a blue-light-excitable 0D hybrid metal halide phosphor is to reduce the fundamental bandgap by rational chemical design.In this work,we report two designed hybrid copper(I)iodides,(Ph_(3)MeP)_(2)Cu_(4)I_(6)and(Cy_(3)MeP)_(2)Cu_(4)I_(6),as blue-light-excitable yellow phosphors with ultrabroadband emission.In these compounds,the[Cu_(4)I_(6)]^(2-)anion forms an I6 octahedron centered on a cationic Cu_(4)tetrahedron.The strong cation-cation bonding within the unique cationic Cu_(4)tetrahedra enables significantly lowered conduction band minimums and thus narrowed bandgaps,as compared to other reported hybrid copper(I)iodides.The ultrabroadband emission is attributed to the coexistence of free and self-trapped excitons.The WLED using the[Cu_(4)I_(6)]^(2-)anion-based single phosphor shows warm white light emission,with a high luminous efficiency of 65 Im W^(-1)and a high color rendering index of 88.This work provides strategies to design narrow-bandgap 0D hybrid metal halides and presents two first examples of blue-light-excitable 0D hybrid metal halide phosphors for efficient WLEDs.
文摘本文基于知识图谱理论,选取1986—2024年中国知网(CNKI)收录的1072篇中文文献为样本,并辅以Web of Science核心合集中的英文文献,运用CiteSpace和VOSviewer软件,从发文数量、研究机构、载文期刊、关键词突现、时间演进与聚类等维度,对制造业转型研究的演化脉络和热点主题进行系统梳理。研究发现:制造业转型相关文献数量持续增长,呈现出显著的多学科交叉特征;研究主题经历了从早期的价值链优化,逐步拓展至数字化、绿色化、智能化与服务化等多个路径;近年来,研究重点进一步聚焦于企业绩效、人才培养与国际竞争力等议题。整体来看,制造业转型正由要素驱动向数字技术主导、多路径融合演进。本文研究成果可为理论拓展与政策制定提供系统参考。
基金National Social Science Foundation Program,No.22VRC163National Natural Science Foundation of China,No.42061043+1 种基金Postgraduate Research&Practice Innovation Program of Jiangsu Province,No.KYCX24_1008Innovation Project of Guangxi Graduate Education,No.YCSW2024473。
文摘Clarifying the mechanisms that control the evolution of territorial space patterns is essential for regulating and optimizing the geographical structure and processes related to sustainable development.Using the Guangdong and Guangxi sections of the Pearl River Basin as examples,the transfer-matrix method and standard deviation ellipse model were applied to characterize the evolution of territorial space patterns from 1990 to 2020.A trend surface analysis and the Theil index were used to analyze regional differences in the evolution process,and geodetectors were used to identify the underlying mechanisms of the changes.There were three key results.(1)In these critical areas of the Pearl River Basin,agricultural and ecological spaces have rapidly declined due to urban expansion,with transfers between these spaces dominating the evolution of territorial space patterns.Spatial pattern changes in the Guangdong section were more intense than in the Guangxi section.(2)Regional differences in urban space have decreased,whereas differences in agricultural and ecological spaces have intensified.Driven by socio-economic growth,the cross-regional transfers of territorial space have created a“high in the east,while low in the west”inter-regional difference,and a“high in the south,while low in the north”intra-regional difference shaped by natural conditions.The regional differences in space patterns were greater in Guangdong than in Guangxi.(3)The evolution of watershed territorial space patterns resulted from scale changes,locational shifts,structural reorganizations,and directional changes driven by multiple factors.Natural environment,social life,economic development,and policy factors played foundational,leading,key driving,and guiding roles,respectively.Additionally,the regional differences in the evolution of watershed territorial space patterns originated from the differential transmission of the influence of various factors affecting spatial evolution.Enhancing urban space efficiency,restructuring agricultural space,and optimizing ecological space are key strategies for building a complementary and synergistic territorial space pattern in the basin.
基金supported by the China Scholarship Council(Grant No.202306690024)the Ministerio de Ciencia e Innovación and Fondos FEDER(Grant Nos.PID2021-562126509OB-C21 and PDC2022-133332-C21)+1 种基金the Generalitat de Catalunya(Grant No.2021SGR00138)the Beatriu de Pinós Fellowship(Grant No.2021-BP-00206).
文摘Depolarizing behavior is commonly observed in most natural samples.For this reason,optical tools measuring the differences in depolarization response among spatially separated structures are highly useful in a wide range of imaging applications for enhanced visualization of structures,target identification,etc.One commonly used tool for depolarizing discrimination is the so-called depolarizing spaces.In this article,we exploit the combined use of two depolarizing spaces,the indices of polarization purity(IPP)and polarizance–reflection–transformation(PRT)spaces,to improve the capability of optical systems to identify polarization–anisotropy depolarizers.The potential of these spaces to discriminate among different depolarizers is first studied from a series of simulations by incoherently adding diattenuations or retarders,with some control parameters emulating samples in nature.The simulated results demonstrate that the proposed methods are capable of increasing differences among depolarizers beyond other well-known techniques.Experimentally,validation is provided by conducting diverse phantom experiments of easy interpretation and mimicking the stated simulations.As a useful application of our approach,we developed a model able to retrieve intrinsic microscopic information of samples from macroscopic polarimetric measurements.The proposed methods enable non-invasive,straightforward,macroscopic characterization of depolarizing samples,and may be of interest for enhanced visualization of samples in multiple imaging scenarios.
文摘目的理清中医药的热点和动态,展望中医药研学未来的发展方向。方法检索中国知识资源总库(CNKI)2013-2023年发表的关于中医药研学旅行的相关文献,利用Cite Space 6.2.R4版本,对发文量、关键词等进行分析挖掘。结果有311篇文献被纳入研究,25所研究机构被纳入,包括北京中医药大学等。278个关键词被纳入,热点关键词为“中医药”“研学旅行”等,并出现关键词聚类。结论通过Cite Space的引导,中医药研学旅行领域有望取得更为广阔的发展空间。
