A new metal-organic framework（MOF） based on metal clusters as secondary building units（SBU）,has been synthesized and structurally characterized.The reported MOF presents an interesting 8-connected self-penetrating...A new metal-organic framework（MOF） based on metal clusters as secondary building units（SBU）,has been synthesized and structurally characterized.The reported MOF presents an interesting 8-connected self-penetrating coordination network based on dinuclear cadmium cluster with a 4^（24）·5·6~3 topology. Moreover,the thermal stability and luminescence property of this compound have been investigated.展开更多
One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and...One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and thermogravimetric analyses. Complex 1 crystallizes in orthorhombic crystal system, space group Pbca with a = 21.573（19）, b = 5.404（5）, c = 33.78（3） ？, C21H（12）O7Cu2, Mr = 503.39, V = 3938（6） A^3, Z = 8, Dc = 1.698 g·cm^-3, μ = 2.202 mm^-1, F（000） = 2016, 1.531〈θ〈25.009°, λ（Mo Kα） = 0.71073 A, T = 293（2） K, the final R = 0.0448 and wR = 0.1002. The structure of complex 1 is a three-dimensional（3D） framework based on infinite rod-shaped secondary building units and can be simplified as kgd topology. The gas adsorption measurements for N2, CO2, H2O, CH3OH and CH3CH2OH have been done. Fortunately, the selective sorption of CO2 over N2 was found at 195 K.展开更多
The reliability of the on-wing aircraft Auxiliary Power Unit(APU)decides the cost and the comfort of flight to a large degree.The most important function of APU is to help start main engines by providing compressed ai...The reliability of the on-wing aircraft Auxiliary Power Unit(APU)decides the cost and the comfort of flight to a large degree.The most important function of APU is to help start main engines by providing compressed air.Especially on the condition of sudden shutdown in the air,APU can offer additional thrust for landing.Therefore,its condition monitoring has drawn much attention from the academic and industrial field.Among the on-wing sensing data which can reflect its condition,Exhaust Gas Temperature(EGT)is one of the most important parameters.To ensure the reliability of EGT,one kind of data-driven anomaly detection framework for EGT sensing data is proposed based on the Gaussian Process Regression and Kernel Principal Component Analysis.The situations of one-dimensional and two-dimensional input data for EGT anomaly detection are considered,respectively.The cross-validation experiments are carried out by utilizing the real condition data of APU,which are provided by China Southern Airlines Company Limited Shenyang Maintenance Base.The anomalous stuck condition of EGT sensing data is also detected.Experimental results show that the proposed EGT sensing data anomaly detection method can achieve better performance of false positive ratio,false negative ratio and accuracy.展开更多
Frameworks provide large scale reuse by providing skeleton structure of similar applications. But the generality, that a framework may have, makes it fairly complex, hard to understand and thus to reuse. Frameworks ha...Frameworks provide large scale reuse by providing skeleton structure of similar applications. But the generality, that a framework may have, makes it fairly complex, hard to understand and thus to reuse. Frameworks have been classified according to many criteria. This paper proposes two types of framework (based on the concept of ‘generality’) named as: tight framework and loose framework. A case study is done by developing loose and tight frameworks for the appli-cation sets of Environment for Unit testing (EUT) domain. Based on the experience that we got by during this case study, we tried to find out the benefits of one (tight or loose) framework over the other. This work attempts to provide an initial background for meaningful studies related to the concept of ‘Design and Development of Framework’.展开更多
A new metal-organic framework (MOF),{[Zn_7 (BPS)_4 (OH)_6 (H_2O)_2]·5 H_2O]_n}(1), (H_2 BPS=4,4′-bibenzoic acid-2,2′-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthe...A new metal-organic framework (MOF),{[Zn_7 (BPS)_4 (OH)_6 (H_2O)_2]·5 H_2O]_n}(1), (H_2 BPS=4,4′-bibenzoic acid-2,2′-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and further confirmed by PXRD, TGA and IR spectrum. The solid-state emission spectra reveal that compound 1 presents strong luminescence emission bands at room temperature. The fluorescent properties of compound 1 in diverse organic solvents indicated that 1 has palpable luminescent sense effects for DMF and DMAC.展开更多
Hydrothermal reaction between mixed ligand（1,2,4-triazole and benzoic acid） and Zn（NO3）2·6H2O afforded a three-dimensional（3D） metal-organic framework Zn3（C2H2N3）2（C7H5O2）4（C2H2N3=1,2,4-triazole, C7H5O...Hydrothermal reaction between mixed ligand（1,2,4-triazole and benzoic acid） and Zn（NO3）2·6H2O afforded a three-dimensional（3D） metal-organic framework Zn3（C2H2N3）2（C7H5O2）4（C2H2N3=1,2,4-triazole, C7H5O2=benzoic acid）. The compound was crystallized in the hexagonal system with space group R3： a=2.90234（9） nm, b=2.90234（9） nm, c=1.08597（5） nm, γ=120°, V=7.9222（5） nm^3, Mr=816.68, Dc=1.541 g/cm^3, Z=9, F（000）=3708, R=0.0636, and wR=0. 1777. Its structure consists of ZnN2O2 tetrahedron and ZnN204 octahedron, which are connected by 1,2,4-triazole and benzoic acid ligands to form a 3D framework with helical units. This compound forms an interpenetrated NbO topology. The compound was characterized by single-crystal X-ray diffraction, elemental analysis, FTIR spectra, and TGA measurements.展开更多
基金supported by the National Science Foundation of China(No.51073079)the Natural Science Fund of Tianjin,China (No.10JCZDJC22100)the Fundamental Research Funds for the Central Universities
文摘A new metal-organic framework（MOF） based on metal clusters as secondary building units（SBU）,has been synthesized and structurally characterized.The reported MOF presents an interesting 8-connected self-penetrating coordination network based on dinuclear cadmium cluster with a 4^（24）·5·6~3 topology. Moreover,the thermal stability and luminescence property of this compound have been investigated.
基金Supported by the Natural Science Foundation of Shandong Province(No.ZR2016BL01)the Talent Introduction Project of Dezhou University(No.320116)
文摘One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and thermogravimetric analyses. Complex 1 crystallizes in orthorhombic crystal system, space group Pbca with a = 21.573（19）, b = 5.404（5）, c = 33.78（3） ？, C21H（12）O7Cu2, Mr = 503.39, V = 3938（6） A^3, Z = 8, Dc = 1.698 g·cm^-3, μ = 2.202 mm^-1, F（000） = 2016, 1.531〈θ〈25.009°, λ（Mo Kα） = 0.71073 A, T = 293（2） K, the final R = 0.0448 and wR = 0.1002. The structure of complex 1 is a three-dimensional（3D） framework based on infinite rod-shaped secondary building units and can be simplified as kgd topology. The gas adsorption measurements for N2, CO2, H2O, CH3OH and CH3CH2OH have been done. Fortunately, the selective sorption of CO2 over N2 was found at 195 K.
基金partially supported by the National Natural Science Foundation of China(No.61803121)China Postdoctoral Science Foundation(No.2019M651277).
文摘The reliability of the on-wing aircraft Auxiliary Power Unit(APU)decides the cost and the comfort of flight to a large degree.The most important function of APU is to help start main engines by providing compressed air.Especially on the condition of sudden shutdown in the air,APU can offer additional thrust for landing.Therefore,its condition monitoring has drawn much attention from the academic and industrial field.Among the on-wing sensing data which can reflect its condition,Exhaust Gas Temperature(EGT)is one of the most important parameters.To ensure the reliability of EGT,one kind of data-driven anomaly detection framework for EGT sensing data is proposed based on the Gaussian Process Regression and Kernel Principal Component Analysis.The situations of one-dimensional and two-dimensional input data for EGT anomaly detection are considered,respectively.The cross-validation experiments are carried out by utilizing the real condition data of APU,which are provided by China Southern Airlines Company Limited Shenyang Maintenance Base.The anomalous stuck condition of EGT sensing data is also detected.Experimental results show that the proposed EGT sensing data anomaly detection method can achieve better performance of false positive ratio,false negative ratio and accuracy.
文摘Frameworks provide large scale reuse by providing skeleton structure of similar applications. But the generality, that a framework may have, makes it fairly complex, hard to understand and thus to reuse. Frameworks have been classified according to many criteria. This paper proposes two types of framework (based on the concept of ‘generality’) named as: tight framework and loose framework. A case study is done by developing loose and tight frameworks for the appli-cation sets of Environment for Unit testing (EUT) domain. Based on the experience that we got by during this case study, we tried to find out the benefits of one (tight or loose) framework over the other. This work attempts to provide an initial background for meaningful studies related to the concept of ‘Design and Development of Framework’.
基金supported by the National Natural Science Foundation of China(Nos. 21771111, 21601092 and 21371104)the Tianjin Natural Science Foundation(Nos. 15JCZDJC38800 and 16JCZDJC36900)
文摘A new metal-organic framework (MOF),{[Zn_7 (BPS)_4 (OH)_6 (H_2O)_2]·5 H_2O]_n}(1), (H_2 BPS=4,4′-bibenzoic acid-2,2′-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and further confirmed by PXRD, TGA and IR spectrum. The solid-state emission spectra reveal that compound 1 presents strong luminescence emission bands at room temperature. The fluorescent properties of compound 1 in diverse organic solvents indicated that 1 has palpable luminescent sense effects for DMF and DMAC.
基金Supported by the National Natural Science Foundation of China(Nos.20121103, 20671040 and 20601010)the National High Technology Research and Development Program of ChinaFox Ying Dong Education Foundation, China.
文摘Hydrothermal reaction between mixed ligand（1,2,4-triazole and benzoic acid） and Zn（NO3）2·6H2O afforded a three-dimensional（3D） metal-organic framework Zn3（C2H2N3）2（C7H5O2）4（C2H2N3=1,2,4-triazole, C7H5O2=benzoic acid）. The compound was crystallized in the hexagonal system with space group R3： a=2.90234（9） nm, b=2.90234（9） nm, c=1.08597（5） nm, γ=120°, V=7.9222（5） nm^3, Mr=816.68, Dc=1.541 g/cm^3, Z=9, F（000）=3708, R=0.0636, and wR=0. 1777. Its structure consists of ZnN2O2 tetrahedron and ZnN204 octahedron, which are connected by 1,2,4-triazole and benzoic acid ligands to form a 3D framework with helical units. This compound forms an interpenetrated NbO topology. The compound was characterized by single-crystal X-ray diffraction, elemental analysis, FTIR spectra, and TGA measurements.
