Effects of additions of trace Sn on the bake-hardening responses of a pre-aged Al-0.85 Mg-0.85 Si(in wt%)alloy were investigated through mechanical tests,differential scanning calorimetry,electrical resistivity and tr...Effects of additions of trace Sn on the bake-hardening responses of a pre-aged Al-0.85 Mg-0.85 Si(in wt%)alloy were investigated through mechanical tests,differential scanning calorimetry,electrical resistivity and transmission electron microscopy.Results indicate that trace Sn additions reduced the number density of pre-aging clusters by inhibiting the formation of unstable counterpart during pre-aging treatment,leading to low strength and high supersaturation of solute atoms.In a subsequent paint-bake treatment,the presence of highly supersaturated solute atoms and high concentrated free vacancies moderated the activation energy barrier ofβ’’phase and thus kinetically accelerated the formation ofβ’’.Consequently,the trace Sn additions enhanced the bake-hardening responses of the pre-aged alloys significantly.The Sn-containing pre-aged Al-Mg-Si alloys with low strength and great bake-hardening responses hold promising potential for automotive body skin applications.展开更多
Rare earth and trace elements are determined for cassiterite from a vein-type orebody , a lens and a sheeted-type orebody in the Dachang Sn-polymetallic ore field ,Guangxi Province .Cassiterite from the vein-type oreb...Rare earth and trace elements are determined for cassiterite from a vein-type orebody , a lens and a sheeted-type orebody in the Dachang Sn-polymetallic ore field ,Guangxi Province .Cassiterite from the vein-type orebody has rare earth and trace dement characteristics similar to that of Dachang biotite granite of Late Yanshan age, showing an inheritable and a genetic relationship. Cassiterites from the kns and sheeted-vein orebody have rare earth and trace element characteristics greatly different from those of the vein-type cassiterite and the granite,showing distinctly higher contents of the ore-forming elements As, Sb,Zn,Ag etc.and a positive Eu anomaly and a negative Ce anomaly.The difference of rare earth and trace element characteristics for cassiterite from two kinds of orebodies reflects the compositional difference of ore-forming solutions. Authors suggest that the kns and sheeted-vein orebody was of nonmagmatic , mixed with underground hot brine origin , and that this kind of hot brine reacted with Devonian and Predevonian older strata and extraced some ore-forming metals from the strata and finaly empbced along the bedding and interbyer fracture zone etc. on its ascending way driven by the Indonisian orogenic movement . The vein-type orebody was formed chiefly by post-magmatic hydrothermal sobtions derived from magma differentiation of the Dachang biotite granite .展开更多
The Nanling Range in South China is well known for its rich granite-related W–Sn deposits.To elucidate the controls of different granite-related W–Sn metallogenesis in the region,we chose five representative orerela...The Nanling Range in South China is well known for its rich granite-related W–Sn deposits.To elucidate the controls of different granite-related W–Sn metallogenesis in the region,we chose five representative orerelated granites(Yanbei,Mikengshan,Tieshanlong,Qianlishan,and Yaogangxian intrusions)in the Hunan–Jiangxi region,and studied their magmatic zircon ages and trace element geochemistry.Our new zircon data showed the differences in ages,temperatures and oxygen fugacity of the ore-forming magmas.Zircon U–Pb ages of the Yanbei and Mikengshan intrusions are characterized by 142.4±2.4 and 143.0±2.3 Ma,respectively,whereas the Tieshanlong and Qianlishan intrusions are 159.5±2.3and 153.2±3.3 Ma,respectively.The Sn-related intrusions were younger than the W-related intrusions.The Tiin-zircon thermometry showed that there was no systematic difference between the Sn-related Yanbei(680–744℃)and Mikengshan(697–763℃)intrusions and the W-related Tieshanlong(730–800℃),Qianlishan(690–755℃)and Yaogangxian(686–751℃)intrusions.However,the zircon Ce^4+/Ce^3+ratios of the Yanbei(averaged at 18.3)and Mikengshan(averaged at 18.8)intrusions are lower than those of the Tieshanlong(averaged at 36.9),Qianlishan(averaged at 38.4)and Yaogangxian(averaged at 37)intrusions,indicating that the Sn-related granitic magmas might have lower oxygen fugacities than those of the W-related.This can be explained by that,in more reduced magmas,Sn is more soluble than W and thus is more enriched in the residual melt to form Sn mineralization.The difference in source materials between the Sn-related and the W-related granites seems to have contributed to the different redox conditions of the melts.展开更多
基金financially supported by the National Key R&D Program of China(No.2018YFB2001800).
文摘Effects of additions of trace Sn on the bake-hardening responses of a pre-aged Al-0.85 Mg-0.85 Si(in wt%)alloy were investigated through mechanical tests,differential scanning calorimetry,electrical resistivity and transmission electron microscopy.Results indicate that trace Sn additions reduced the number density of pre-aging clusters by inhibiting the formation of unstable counterpart during pre-aging treatment,leading to low strength and high supersaturation of solute atoms.In a subsequent paint-bake treatment,the presence of highly supersaturated solute atoms and high concentrated free vacancies moderated the activation energy barrier ofβ’’phase and thus kinetically accelerated the formation ofβ’’.Consequently,the trace Sn additions enhanced the bake-hardening responses of the pre-aged alloys significantly.The Sn-containing pre-aged Al-Mg-Si alloys with low strength and great bake-hardening responses hold promising potential for automotive body skin applications.
基金The project is supported by Professional Foundation of Geology Carl Duesberg Gesellschaft
文摘Rare earth and trace elements are determined for cassiterite from a vein-type orebody , a lens and a sheeted-type orebody in the Dachang Sn-polymetallic ore field ,Guangxi Province .Cassiterite from the vein-type orebody has rare earth and trace dement characteristics similar to that of Dachang biotite granite of Late Yanshan age, showing an inheritable and a genetic relationship. Cassiterites from the kns and sheeted-vein orebody have rare earth and trace element characteristics greatly different from those of the vein-type cassiterite and the granite,showing distinctly higher contents of the ore-forming elements As, Sb,Zn,Ag etc.and a positive Eu anomaly and a negative Ce anomaly.The difference of rare earth and trace element characteristics for cassiterite from two kinds of orebodies reflects the compositional difference of ore-forming solutions. Authors suggest that the kns and sheeted-vein orebody was of nonmagmatic , mixed with underground hot brine origin , and that this kind of hot brine reacted with Devonian and Predevonian older strata and extraced some ore-forming metals from the strata and finaly empbced along the bedding and interbyer fracture zone etc. on its ascending way driven by the Indonisian orogenic movement . The vein-type orebody was formed chiefly by post-magmatic hydrothermal sobtions derived from magma differentiation of the Dachang biotite granite .
基金supported by the National Basic Research Program of China (973 Program) (Grants No. 2014CB440906)Innovation Team Program of Chinese Academy of Sciences (Overseas Famous Scholars Program)‘‘Light of West China’’ Program of Chinese Academy of Sciences
文摘The Nanling Range in South China is well known for its rich granite-related W–Sn deposits.To elucidate the controls of different granite-related W–Sn metallogenesis in the region,we chose five representative orerelated granites(Yanbei,Mikengshan,Tieshanlong,Qianlishan,and Yaogangxian intrusions)in the Hunan–Jiangxi region,and studied their magmatic zircon ages and trace element geochemistry.Our new zircon data showed the differences in ages,temperatures and oxygen fugacity of the ore-forming magmas.Zircon U–Pb ages of the Yanbei and Mikengshan intrusions are characterized by 142.4±2.4 and 143.0±2.3 Ma,respectively,whereas the Tieshanlong and Qianlishan intrusions are 159.5±2.3and 153.2±3.3 Ma,respectively.The Sn-related intrusions were younger than the W-related intrusions.The Tiin-zircon thermometry showed that there was no systematic difference between the Sn-related Yanbei(680–744℃)and Mikengshan(697–763℃)intrusions and the W-related Tieshanlong(730–800℃),Qianlishan(690–755℃)and Yaogangxian(686–751℃)intrusions.However,the zircon Ce^4+/Ce^3+ratios of the Yanbei(averaged at 18.3)and Mikengshan(averaged at 18.8)intrusions are lower than those of the Tieshanlong(averaged at 36.9),Qianlishan(averaged at 38.4)and Yaogangxian(averaged at 37)intrusions,indicating that the Sn-related granitic magmas might have lower oxygen fugacities than those of the W-related.This can be explained by that,in more reduced magmas,Sn is more soluble than W and thus is more enriched in the residual melt to form Sn mineralization.The difference in source materials between the Sn-related and the W-related granites seems to have contributed to the different redox conditions of the melts.
