Iron isotopes,represented byδ^(56)Fe,serve as valuable tools for constraining the surface iron processes and as potent tracers for studying the biogeochemical cycle of iron.Nevertheless,our comprehension of iron isot...Iron isotopes,represented byδ^(56)Fe,serve as valuable tools for constraining the surface iron processes and as potent tracers for studying the biogeochemical cycle of iron.Nevertheless,our comprehension of iron isotopes in the land surface processes of the Tibetan Plateau(TP)remains limited.In this study,we present the results of iron isotopic composition(δ^(56)Fe)in the surface soils of the TP,encompassing both glacial and non-glacial regions characterized by rugged and flat topographies.Our findings reveal that soilδ^(56)Fe values ranged from-0.01‰±0.05‰to 0.14‰±0.01‰,with the highest values observed in eastern locations(0.14‰)and the lowest appeared in the northeast(-0.1‰).On a global scale,theδ^(56)Fe values observed in Tibetan soils exhibited relatively small variability compared to reservoirs marked by significant iron isotope fractionation.By contrast,the range of TP soils measured here was slightly larger than that of the Chinese Loess.Furthermore,we discerned noticeable spatial variations inδ^(56)Fe across the large-scale region of TP,indicating a gradual increase trend from the northeast to the south and from the west to the east.These regional disparities inδ^(56)Fe likely arise from a combination of constraining factors,including differences in mineralogy,lithological variations,organic matter content,and variations in chemical weathering intensity.This study is pivotal in advancing our understanding of land surface iron isotope dynamics and its role in the biogeochemical cycle within the TP region.展开更多
An unsteady numerical simulation is conducted to examine the dynamic runback characteristics of a water film flow driven by a boundary layer airflow over a solid surface pertinent to the dynamic glaze ice accretion pr...An unsteady numerical simulation is conducted to examine the dynamic runback characteristics of a water film flow driven by a boundary layer airflow over a solid surface pertinent to the dynamic glaze ice accretion process over aircraft wing surfaces.The multiphase flow simulation results of the wind-driven water runback(WDWR)flow are compared quantitatively with the experimental results in terms of the time-dependent variations of the water film thickness profiles and evolution of the front contact point of the runback water film flow.The underlying mechanism of the intermittent water runback behavior is elucidated by analyzing the time evolution of the airflow velocity and vorticity fields above the runback water film flow over the solid surface.To the best knowledge of the authors,the work presented here is the first successful attempt to numerically examine the transient runback characteristics of WDWR flows.It serves as an excellent benchmark case for the development of best practices to model the important micro-physical processes responsible for the transient water transport over aircraft wing surfaces.展开更多
The Mg-9Li-1Zn(LZ91)alloy was subjected to an ultrasonic surface rolling process(USRP)with varying passes for the purpose of modifying its surface state.The USRP transformed surface residual stress from initial tensil...The Mg-9Li-1Zn(LZ91)alloy was subjected to an ultrasonic surface rolling process(USRP)with varying passes for the purpose of modifying its surface state.The USRP transformed surface residual stress from initial tensile stress to compressive stress,decreasing the surface roughness and increasing the ratio of the β-Li phase.The USRPed LZ91 sample(3 passes)showed superior corrosion resistance,with the corrosion current density changing from 57.11 to 24.70μA cm^(-2),and the polarization resistance increasing from 576.3 to 1146.1Ωcm^(2).According to the corrosion procedure evaluations,in situ observation revealed that the LZ91 alloy initially experiences pitting,which subsequently develops into cracking.The substantial area coverage of the β-Li phase facilitates the formation of a protective film on the surface,effectively delaying localized corrosion.展开更多
Mantle plumes and surface erosion and sediment deposition affect the modes of continental lithospheric rupturing in extensional tectonic settings,modulating the evolution of rifting margins.However,their relative cont...Mantle plumes and surface erosion and sediment deposition affect the modes of continental lithospheric rupturing in extensional tectonic settings,modulating the evolution of rifting margins.However,their relative contributions to the overall evolution of rifting margins and possible roles in the formation of microcontinent are still elusive.Here,we use coupled geodynamic and surface processes numerical modeling to assess the extent to which surface processes may determine the formation of microcontinent during lithospheric stretching in presence or absence of a mantle plume underneath.Our modeling results indicate that fast extension rates and hillslope(i.e.,diffusion)erosion promote ridge jump events and therefore the formation of microcontinents.On the contrary,efficient fluvial erosion and far-reaching sediment transport(i.e.,stream power erosion)inhibits ridge jump events and the formation of microcontinents.The ridge jump event and overall evolution in our numerical models is consistent with the shift from the Mascarene Ridge to the Carlsberg Ridge that determined the formation of the Seychelles microcontinent.We therefore speculate that hillslope erosion,rather than fluvial erosion,was predominant during the formation of the Seychelles,a possible indication of overall dry local climate conditions.展开更多
[Objectives] To optimize the crystallization process of ceftriaxone sodium using response surface methodology (RSM) for enhancing both the crystallization rate and the quality of the final product. [Methods] Four key ...[Objectives] To optimize the crystallization process of ceftriaxone sodium using response surface methodology (RSM) for enhancing both the crystallization rate and the quality of the final product. [Methods] Four key factors, including crystallization temperature, stirring speed, solvent drop rate, and seed crystal content, were employed as independent variables, while the crystallization rate served as the response variable. The Box-Behnken response surface method was utilized for the optimization design. [Results] The optimal parameters for the crystallization process, determined through optimization, were as follows: a temperature of 10.6 ℃, a stirring rate of 150 rpm, a solvent drop rate of 1.50 mL/min, and a seed crystal content of 0.12 g. Validation tests conducted under these conditions yielded an average crystallization rate of 94.38% for the refined product. [Conclusions] The crystallization efficiency of ceftriaxone sodium is markedly enhanced, thereby offering substantial support for its industrial production and clinical application.展开更多
To promote early rapid osteogenesis and prevent late implant-related infection,it is critical to develop ef-fective and reliable surface treatment technologies for enhancing both osteogenic and antibacterial prop-erti...To promote early rapid osteogenesis and prevent late implant-related infection,it is critical to develop ef-fective and reliable surface treatment technologies for enhancing both osteogenic and antibacterial prop-erties of titanium alloy implants.Reduced graphene oxide(rGO)is considered a promising modification candidate.However,whether rGO retains its osteogenic and antibacterial functions after being applied to modify titanium alloy surfaces depends on the surface treatment technology employed.In this study,rGO was integrated onto the surface of Ti-35Nb-2Ta-3Zr(TNTZ)alloy through friction stir processing(FSP),yielding a consolidated TNTZ/F-rGO composite.The incorporation of rGO not only significantly im-proved the microhardness and hydrophilicity of the material,but also exhibited positive biological effects in vitro experiments:it effectively promoted the proliferation,osteogenic differentiation,alkaline phos-phatase(ALP)production and extracellular matrix mineralization of BMSCs.Furthermore,TNTZ/F-rGO ex-hibited potent antibacterial activity via surface-contact mechanisms.In summary,the rGO-modified in-tegrated titanium alloy has excellent osteogenic properties and high-efficiency antibacterial ability.This study provides new insights and strategies for the design of graphene-based biomaterials and implant surface modification technologies.展开更多
This study investigates the effects of the ultrasonic surface rolling process(USRP)on the surface microstructure,texture,and wear behavior of commercial AZ31 magnesium alloy sheet.The application of USRP induces a dep...This study investigates the effects of the ultrasonic surface rolling process(USRP)on the surface microstructure,texture,and wear behavior of commercial AZ31 magnesium alloy sheet.The application of USRP induces a depth-dependent gradient microstructure characterized by a gradual transition from fine-grained surface layers to coarser-grained regions.Severe plastic deformation at the surface significantly enhances surface microhardness,with values increasing from 63.8 HV in the untreated specimen to 132.9 HV after USRP-4 passes.The thickness of the plastic deformation layer exhibits process-dependent behavior,growing from 200μm(two passes)to 250μm(four passes).Wear test results indicate that the wear resistance of the material is significantly enhanced after USRP treatment.This improvement is primarily attributed to the combined effects of the following factors:surface grain refinement,the role of dislocation-induced twinning,increased hardness,the formation of nanoscale secondary phases,introduction of residual compressive stresses,weakened surface texture,and reduced surface roughness.Notably,both friction coefficients and wear volumes show a direct dependence on the number of rolling passes.This study systematically elucidates the underlying mechanisms linking USRP-induced microstructural evolution to enhanced wear performance,providing critical insights for optimizing surface engineering strategies in magnesium alloys.展开更多
Inconel 718 superalloy has extensive applications in a variety of industries such as the moulding,aerospace and medical due to its excellent mechanical features such as poor thermal conductivity,high strength at high ...Inconel 718 superalloy has extensive applications in a variety of industries such as the moulding,aerospace and medical due to its excellent mechanical features such as poor thermal conductivity,high strength at high temperatures and corrosion resistance.However,it is very difficult to process by traditional machining and finishing methods.Abrasive based finishing process is one of non-traditional finishing method applied to complex surfaces.Shot peening process is one of the surface treatment processes mostly applied to improve the surface strength.The superior advantages of these two processes are combined into one process.This newly developed and patented process is called as GOV process.In this study,the effects of GOV process parameters(number of cycles,steel ball size,media concentration)on the surface quality of Inconel 718 already pre-processed by wire electric discharge machining are investigated.The performance parameters are identified as surface roughness,material removal and white layer thickness.Surface finishing with the GOV process improves the surface roughness,Ra value by decreasing from 2.63μm to 0.46μm by removing micro-level chips up to 10.7 mg which is supported by SEM images.White layer formed due to nature of EDM process is completely removed from specimen surface.展开更多
The Zoige Basin,located in the eastern region of the Tibetan Plateau of China,is characterized by its climate sensitivity and complex surface environment.It is vital to understand the response of the surface processes...The Zoige Basin,located in the eastern region of the Tibetan Plateau of China,is characterized by its climate sensitivity and complex surface environment.It is vital to understand the response of the surface processes to environmental changes in the Zoige Basin since the last deglaciation,as well as the response of environmental changes and surface processes on the Tibetan Plateau relate to global changes.In August 2020,a field investigation was conducted in the Zoige Basin.A complete set of stratigraphic profile from the high platform at the front of the glacial-diluvial fan in the Maqu reach of the western basin was selected as the research subject.Optically stimulated luminescence(OSL)dating samples and sedimentary samples were collected from key layers and brought back to the laboratory for experimental analysis,and the surface processes and environment changes since the last deglaciation in the Zoige Basin were investigated through particle size analysis and OSL dating.The results showed that during the last glacial period before 14.5 kyr,a substantial glacial-alluvial fan composed of sand and gravel layers was formed by flash flood processes triggered by glacial meltwater and heavy precipitation.In the Bølling-Allerød warm period of 14.5–11.7 kyr,a warm and humid climate prevailed,with the formation of silty bog environments in the shallow depressions at the glacial-alluvial fan's forefront and the development of gray-green bog soil deposits.However,during the Younger Dryas period,an abrupt climate deterioration occurred,with the upper section of the gray-green bog soil layer in the shallow depression to experience folding and deformation due to surface freeze-thaw actions.During the early Holocene period from 11.7 kyr to 8.5 kyr,the climate was relatively dry,resulting in prevalent aeolian sand activitities.Coarse silt accumulated in the shallow depression,and sedimentary facies alternating between aeolian sand and bog soil deposits developed owing to strong wind patterns on the plateau surface.In the warm and humid period from 8.5 kyr to 3.1 kyr,increased weathering and pedogenesis enhanced clay content in sediments,which developed into the paleosol.In the late Holocene,starting from 3.1 kyr,the climate became relatively dry once more,with aeolian sand activity prevalent.The coarse silt that accumulated during the late Holocene transformed into subalpine meadow black soil because of rising temperature and humidity levels.These findings indicated that the developmental process of the high platform in the Maqu reach of the Zoige Basin,which was significant for understanding the environmental changes and surface processes in the source region of the Yellow River since the last deglaciation.展开更多
To solve the problems of deformation,micro-cracks,and residual tensile stress in laser cladding coatings,the technique of laser cladding with Fe-based memory alloy can be considered.However,the process of in-situ synt...To solve the problems of deformation,micro-cracks,and residual tensile stress in laser cladding coatings,the technique of laser cladding with Fe-based memory alloy can be considered.However,the process of in-situ synthesis of Fe-based memory alloy coatings is extremely complex.At present,there is no clear guidance scheme for its preparation process,which limits its promotion and application to some extent.Therefore,in this study,response surface methodology(RSM)was used to model the response surface between the target values and the cladding process parameters.The NSGA-2 algorithm was employed to optimize the process parameters.The results indicate that the composite optimization method consisting of RSM and the NSGA-2 algorithm can establish a more accurate model,with an error of less than 4.5%between the predicted and actual values.Based on this established model,the optimal scheme for process parameters corresponding to different target results can be rapidly obtained.The prepared coating exhibits a uniform structure,with no defects such as pores,cracks,and deformation.The surface roughness and microhardness of the coating are enhanced,the shaping quality of the coating is effectively improved,and the electrochemical corrosion performance of the coating in 3.5%NaCl solution is obviously better than that of the substrate,providing an important guide for engineering applications.展开更多
Identifying suitable processing window is necessary but difficult for achieving favorable microstructure and performance in extrusion of large thick-walled pipe with difficult-to-deform Inconel 625 alloy. In this work...Identifying suitable processing window is necessary but difficult for achieving favorable microstructure and performance in extrusion of large thick-walled pipe with difficult-to-deform Inconel 625 alloy. In this work, a method was established for identifying the extrusion process window considering temperature control using response surface methodology. Firstly, the response surface models, which correlate temperature rise and peak temperature to key extrusion parameters, have been developed by orthogonal regression based on finite element calculated data. Secondly, the coupled effects of the key extrusion parameters on the temperature rise and peak temperature have been disclosed based on the regression models. Lastly, suitable extrusion processing windows, which are described by contour map of peak temperature in the space of extrusion speed and initial billet temperature, have been established for different extrusion ratios. Using the identified process window, a suitable combination of the key extrusion parameters can be determined conveniently and quickly.展开更多
Commercial purity and high purity titanium sheets were initially strained by a new technique, named as friction roll surface processing （FRSP）. Severe strain was imposed into the surface layer and strain gradient wa...Commercial purity and high purity titanium sheets were initially strained by a new technique, named as friction roll surface processing （FRSP）. Severe strain was imposed into the surface layer and strain gradient was formed through the thickness of the sheet. The microstructure and texture in as-strained state were investigated by optical microscopy and X-ray diffraction technique On the surface of the sheets, ultra-fine grains were found to have a sharp texture with a preferred orientation strongly related to the FRSP direction. The evolution of microstructure and crystallographic texture of FRSPed samples during recrystallization were also studied by electron back-scattered diffraction （EBSD） technique after being annealed at selected temperatures and time. The results indicated that the preferred orientations resulting from FRSP and annealing in the surface layer were formed during rolling and its recrystallization textures were reduced by FRSP. In addition, the texture evolved stably without change in main components during the annealing.展开更多
The effect of a gradient nanostructured(GNS) surface layer obtained by ultrasonic surface rolling process(USRP) on the fatigue behavior of Ti-6Al-4V alloy has been studied in this paper. Microstructure, surface topogr...The effect of a gradient nanostructured(GNS) surface layer obtained by ultrasonic surface rolling process(USRP) on the fatigue behavior of Ti-6Al-4V alloy has been studied in this paper. Microstructure, surface topography, surface roughness and residual stress measurements were performed to characterize the surface under different conditions. Rotating bending fatigue tests were carried out to evaluate the fatigue behavior of different treatments. The results present a remarkable fatigue performance enhancement for the Ti-6Al-4V alloy with a GNS surface layer obtained by application of USRP with respect to the untreated condition, notwithstanding its considerable surface roughness due to severe ultrasonic impacts and extrusions. Mechanical surface polishing treatment further enhances the beneficial effects of USRP on the fatigue performance. The significantly improved fatigue performance can mainly be ascribed to the compressive residual stress. Simultaneously, the GNS surface layer and surface work hardening have a synergistic effect that accompanies the effect of compressive residual stress.展开更多
In this work,ultrasonic surface rolling process(USRP)was utilized to produce a gradient structured layer on 7 B50-T7751 aluminum alloy,and the mechanical properties and corrosion fatigue behavior of treated samples we...In this work,ultrasonic surface rolling process(USRP)was utilized to produce a gradient structured layer on 7 B50-T7751 aluminum alloy,and the mechanical properties and corrosion fatigue behavior of treated samples were studied.These results reveal that underwent USRP,a 425~m thick gradient structure and a 700~m deep compressive residual stress field are created,aluminum grain size become fine(~67 nm),and the corrosion rate of treated surface reduces by 60.08%owing to the combined effect of compressive residual stress and surface nanocrystallization.The corrosion fatigue strength is enhanced to 117%of that of 7 B50 Al alloys by means of USRP due to the introduced compressive residual stress,which is considered as the major favorable factor in suppressing the initiation and early propagation of corrosion fatigue cracks.Besides,the gradient structure is an important factor in providing a significant synergistic contribution to the improvement of corrosion fatigue performance.展开更多
On 12 August 2004, Typhoon Rananim （0414） moved inland over China and stagnated over the Poyang Lake area, resulting in torrential rainfall and severe geologic hazards. The Advanced Weather Research and Forecasting ...On 12 August 2004, Typhoon Rananim （0414） moved inland over China and stagnated over the Poyang Lake area, resulting in torrential rainfall and severe geologic hazards. The Advanced Weather Research and Forecasting （ARW-WRF） model and its different land surface models （LSMs） were employed to study the impacts of land surface process on the inland behavior of Typhoon Rananim. Results show that simulations, coupled with LSMs or not, have no significant differences in predicting typhoon track, intensity, and largescale circulation. However, the simulations of mesoscale structure, rainfall rate, and rainfall distribution of typhoon are more reasonable with LSMs than without LSMs. Although differences are slight among LSMs, NOAH is better than the others. Based on outputs using the NOAH scheme, the interaction between land surtace and typhoon was explored in this study. Notably, typhoon rainfall and cloud cover can cool land surface, but rainfall expands the underlying saturated wetland area, which exacerbates the asymmetric distribution of surface heat fluxes. Accordingly, an energy frontal zone may form in the lower troposphere that enhances ascending motion and local convection, resulting in heavier rainfall. Moreover, the expanded underlying saturated wetlands provide plentiful moisture and unstable energy for the maintenance of Typhoon Rananim and increased rainfall in return.展开更多
There is a wide diversity of landforms in China. The topography of three major ter- races, decreasing in height stepwise from west to east, was formed by the early Miocene. With the commencement of the Great Northern ...There is a wide diversity of landforms in China. The topography of three major ter- races, decreasing in height stepwise from west to east, was formed by the early Miocene. With the commencement of the Great Northern Hemisphere Glaciations （GHGs） and the glacial-interglacial cycles in the Pleistocene, thick loess deposits accumulated in north China, and fluvial terraces were formed and lakes expanded and contracted in eastern and central China. The earliest evidence of hominins in China is dated to ~1.7 Ma; they occupied the monsoon-dominated region for a long interval, until the late Pleistocene, ~50 ka. In this study, we investigated a large area rich in the relics and artifacts of early man. The results indicate that the early humans occupied riverine areas, especially medium-sized fluvial basins, and lake shores. Even in the relatively recent geological past, the occupation and abandonment of settlements were directly forced by the shifting of sand dune fields in the desert-loess transi- tional zone, which in turn was closely associated with variations in the monsoon climate and vegetation patterns. Our observations indicate that landforms were one of the main determi- nants of early human behavior, in that loess tableland, large alluvial plains, desert-Gobi areas, and the Tibetan Plateau, were not suitable environments for early human settlement. We infer that the early humans in China adapted their behavior to specific landforms and landform processes. The monsoon climate, which shapes the large-scale step-like pattern of fluvial landforms, promotes vegetation coverage and dominates soil formation, provides a crucial context for early human adaptation. The adaptation of early humans to earth surface proc- esses in East Asia is investigated for the first time in this study. Future investigations will provide further information that will increase our understanding of the linkage between early human behavior and landform processes in East Asia.展开更多
This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary la...This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary layer processes and land surface processes. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feasibility of the model is well proved in this paper. The numerical simulation results from MSPAS show good agreement with reality. The scheme is used to obtain reasonable simulations for diurnal variations of heat balance, potential temperature of boundary layer, and wind field, and spatial distributions of temperature, specific humidity, vertical velocity, turbulence kinetic energy, and turbulence exchange coefficient over desert and oasis. In addition, MSPAS is used to simulate the interaction between desert and oasis at night, and again it obtains reasonable results. This indicates that MSPAS can be used to study the interaction between land surface processes and the atmospheric boundary layer over various underlying surfaces and can be extended for regional climate and numerical weather prediction study.展开更多
Water is the important resource to guarantee the existence and development of oases in arid areas. To improve the utilization efficiency of water resources in Manas River Basin, this paper investigated the trends and ...Water is the important resource to guarantee the existence and development of oases in arid areas. To improve the utilization efficiency of water resources in Manas River Basin, this paper investigated the trends and periods of runoff based on the runoff and climate data for the past 50 years. Subsequently, with the socioeconomic and water resources data, we studied a comprehensive evaluation on the water security in this area. The results indicated that the stream flows in the three hydrological stations of Hongshanzui, Kensiwat and Bajiahu have sig- nificantly increased and undergone abrupt changes, with periods of 18 and 20 years. According to assessment, water security in the Manas River Basin was at an unsafe level in 2008. In criterion layer, the ecological security index and the index of supply-demand situation are both at the relatively secure level; the quantity index and so- cioeconomic index of water resources are at the unsafe level and basic security level, respectively. Therefore, in order to achieve sustainable economic and social development within the Manas River Basin, it is vital to take a series of effective measures to improve the status of water security.展开更多
The behavior of gaseous nitriding on the surface nanocrystallized (SNCed) steel was investigated. The mild steel discs were SNCed on one side by using the method of ultrasonic shot peening. The opposite side of the di...The behavior of gaseous nitriding on the surface nanocrystallized (SNCed) steel was investigated. The mild steel discs were SNCed on one side by using the method of ultrasonic shot peening. The opposite side of the discs maintained the original coarse-grained condition. The gaseous nitriding was subsequently carried out at three different temperatures: 460, 500 and 560℃. The compound layer growth and diffusion behavior were then studied. It was revealed that SNC pretreatment greatly enhances both diffusion coefficient D and surface reaction rate. As a result, nitriding time could be reduced to the half. It was also found that the growth of compound layer with nitriding time conformed with parabolic relationship from the start of nitriding process in the SNCed samples.展开更多
Due to large deserts on Earth surface a thorough understanding of climate change, landscape evolution and geomorphological processes having occurred in deserts is crucial for Earth System Science. The landscapes in de...Due to large deserts on Earth surface a thorough understanding of climate change, landscape evolution and geomorphological processes having occurred in deserts is crucial for Earth System Science. The landscapes in deserts are, however, diverse and different over the globe with regard to their geomorphological nature, human activities and geological histories. In the last decades a great number of efforts have been put to the investigation of the initial timing of the occurrence of arid climate, e. g. in northwestern China. Silty sediments in the downwind directions have been used to deduce the histories of deserts. In general, there is a lack of knowledge about processes and landscapes in Chinese drylands between the initial Miocene silt sedimentation at desert margins and the late Quaternary multiple occurrences of wetter climate with assumed large lakes in many of the deserts in northern China. The geomorphological concept of three primary triggering factors, i.e., the sediment supply, sediment availability and transport capacity of wind, and additionally the underground geology need to be fully considered for a better understanding of the environmental histories of sand seas which should not be viewed as equivalent for deserts because sand seas cover between 〈 1% and ca. 45% of the desert areas in various continents dependent on a complex interaction between various processes of both exogenous and endogenous origins.展开更多
基金supported by the National Natural Science Foundation of China(Nos.42201152,42371139)the Gansu Province Natural Science Foundation Key Project(No.23JRRA858)+2 种基金the Fundamental Research Funds for the Central Universities,China University of Geosciences(Wuhan)(No.CUG240629)the“CUG Scholar”Scientific Research Funds at China University of Geosciences(Wuhan)(No.2023092)EJRP is supported by the German Research Foundation(DFG)through the Heisenberg Programme“Multiscale Simulation of Earth Surface Processes”。
文摘Iron isotopes,represented byδ^(56)Fe,serve as valuable tools for constraining the surface iron processes and as potent tracers for studying the biogeochemical cycle of iron.Nevertheless,our comprehension of iron isotopes in the land surface processes of the Tibetan Plateau(TP)remains limited.In this study,we present the results of iron isotopic composition(δ^(56)Fe)in the surface soils of the TP,encompassing both glacial and non-glacial regions characterized by rugged and flat topographies.Our findings reveal that soilδ^(56)Fe values ranged from-0.01‰±0.05‰to 0.14‰±0.01‰,with the highest values observed in eastern locations(0.14‰)and the lowest appeared in the northeast(-0.1‰).On a global scale,theδ^(56)Fe values observed in Tibetan soils exhibited relatively small variability compared to reservoirs marked by significant iron isotope fractionation.By contrast,the range of TP soils measured here was slightly larger than that of the Chinese Loess.Furthermore,we discerned noticeable spatial variations inδ^(56)Fe across the large-scale region of TP,indicating a gradual increase trend from the northeast to the south and from the west to the east.These regional disparities inδ^(56)Fe likely arise from a combination of constraining factors,including differences in mineralogy,lithological variations,organic matter content,and variations in chemical weathering intensity.This study is pivotal in advancing our understanding of land surface iron isotope dynamics and its role in the biogeochemical cycle within the TP region.
基金supported by the National Science Foundation(NSF)of the USA(Grant Nos.TIP-2140489,CBET-2313310,and CBET-2415347).
文摘An unsteady numerical simulation is conducted to examine the dynamic runback characteristics of a water film flow driven by a boundary layer airflow over a solid surface pertinent to the dynamic glaze ice accretion process over aircraft wing surfaces.The multiphase flow simulation results of the wind-driven water runback(WDWR)flow are compared quantitatively with the experimental results in terms of the time-dependent variations of the water film thickness profiles and evolution of the front contact point of the runback water film flow.The underlying mechanism of the intermittent water runback behavior is elucidated by analyzing the time evolution of the airflow velocity and vorticity fields above the runback water film flow over the solid surface.To the best knowledge of the authors,the work presented here is the first successful attempt to numerically examine the transient runback characteristics of WDWR flows.It serves as an excellent benchmark case for the development of best practices to model the important micro-physical processes responsible for the transient water transport over aircraft wing surfaces.
基金financially supported by the National Natural Science Foundation of China(No.52271091)the National Key Research and Development Program of China(No.2021YFB3701100)the Natural Science Foundation Project of Ningxia Province(No.2023AAC03324).
文摘The Mg-9Li-1Zn(LZ91)alloy was subjected to an ultrasonic surface rolling process(USRP)with varying passes for the purpose of modifying its surface state.The USRP transformed surface residual stress from initial tensile stress to compressive stress,decreasing the surface roughness and increasing the ratio of the β-Li phase.The USRPed LZ91 sample(3 passes)showed superior corrosion resistance,with the corrosion current density changing from 57.11 to 24.70μA cm^(-2),and the polarization resistance increasing from 576.3 to 1146.1Ωcm^(2).According to the corrosion procedure evaluations,in situ observation revealed that the LZ91 alloy initially experiences pitting,which subsequently develops into cracking.The substantial area coverage of the β-Li phase facilitates the formation of a protective film on the surface,effectively delaying localized corrosion.
基金financially supported by the National Science Foundation of China(No.41920104010)the China Postdoctoral Science Foundation(No.2024M762767)+3 种基金the Fundamental Research Funds for the Central University,CHD(No.300102264104)by the Postdoctoral Fellowship Program of CPSF(No.GZC20241444)supported by Fondazione Cariplo and Fondazione CDP(No.2022-1546_001)by the Italian Ministry of Education,MUR(Project Dipartimenti di Eccellenza,TECLA,Department of Earth and Environmental Sciences,University of Milano-Bicocca)。
文摘Mantle plumes and surface erosion and sediment deposition affect the modes of continental lithospheric rupturing in extensional tectonic settings,modulating the evolution of rifting margins.However,their relative contributions to the overall evolution of rifting margins and possible roles in the formation of microcontinent are still elusive.Here,we use coupled geodynamic and surface processes numerical modeling to assess the extent to which surface processes may determine the formation of microcontinent during lithospheric stretching in presence or absence of a mantle plume underneath.Our modeling results indicate that fast extension rates and hillslope(i.e.,diffusion)erosion promote ridge jump events and therefore the formation of microcontinents.On the contrary,efficient fluvial erosion and far-reaching sediment transport(i.e.,stream power erosion)inhibits ridge jump events and the formation of microcontinents.The ridge jump event and overall evolution in our numerical models is consistent with the shift from the Mascarene Ridge to the Carlsberg Ridge that determined the formation of the Seychelles microcontinent.We therefore speculate that hillslope erosion,rather than fluvial erosion,was predominant during the formation of the Seychelles,a possible indication of overall dry local climate conditions.
基金Supported by Central Guided Local Science and Technology Development Funds(ZY20230102)Guilin Scientific Research and Technology Development Programme Project(2023010301-1,20220104-4)+1 种基金Guangxi Science and Technology Programme Project(GK AB24010263)Guangxi Innovation Driving Development Special Funds Project(GK AA22096020).
文摘[Objectives] To optimize the crystallization process of ceftriaxone sodium using response surface methodology (RSM) for enhancing both the crystallization rate and the quality of the final product. [Methods] Four key factors, including crystallization temperature, stirring speed, solvent drop rate, and seed crystal content, were employed as independent variables, while the crystallization rate served as the response variable. The Box-Behnken response surface method was utilized for the optimization design. [Results] The optimal parameters for the crystallization process, determined through optimization, were as follows: a temperature of 10.6 ℃, a stirring rate of 150 rpm, a solvent drop rate of 1.50 mL/min, and a seed crystal content of 0.12 g. Validation tests conducted under these conditions yielded an average crystallization rate of 94.38% for the refined product. [Conclusions] The crystallization efficiency of ceftriaxone sodium is markedly enhanced, thereby offering substantial support for its industrial production and clinical application.
基金financially supported by the National Natural Science Foundation of China(Nos.52272283,52311530772,and 52274387)the Science and Technology Commission of Shanghai Municipality(No.22S31902900)+4 种基金the Shanghai Medical Key Specialty(No.2024ZDXK0048)the Medical Key Subject of Xuhui District(No.SHXHZDXK202302)the National Key Research and Development Program of China(No.2024YFE0109000)the Medical-Engineering Cross Foundation of Shanghai Jiao Tong University(No.YG2024LC04)the Institute-level Research Project of Xuhui District Dental Center(No.SHXYF202212).
文摘To promote early rapid osteogenesis and prevent late implant-related infection,it is critical to develop ef-fective and reliable surface treatment technologies for enhancing both osteogenic and antibacterial prop-erties of titanium alloy implants.Reduced graphene oxide(rGO)is considered a promising modification candidate.However,whether rGO retains its osteogenic and antibacterial functions after being applied to modify titanium alloy surfaces depends on the surface treatment technology employed.In this study,rGO was integrated onto the surface of Ti-35Nb-2Ta-3Zr(TNTZ)alloy through friction stir processing(FSP),yielding a consolidated TNTZ/F-rGO composite.The incorporation of rGO not only significantly im-proved the microhardness and hydrophilicity of the material,but also exhibited positive biological effects in vitro experiments:it effectively promoted the proliferation,osteogenic differentiation,alkaline phos-phatase(ALP)production and extracellular matrix mineralization of BMSCs.Furthermore,TNTZ/F-rGO ex-hibited potent antibacterial activity via surface-contact mechanisms.In summary,the rGO-modified in-tegrated titanium alloy has excellent osteogenic properties and high-efficiency antibacterial ability.This study provides new insights and strategies for the design of graphene-based biomaterials and implant surface modification technologies.
基金supported by the National Natural Science Foundation of China(Nos.52271107 and 52301164)Natural Science Foundation of Shandong Province(No.ZR2021ME241)supported by Young Talent of Lifting engineering for Science and Technology in Shandong,China(SDAST2025 QTA034).
文摘This study investigates the effects of the ultrasonic surface rolling process(USRP)on the surface microstructure,texture,and wear behavior of commercial AZ31 magnesium alloy sheet.The application of USRP induces a depth-dependent gradient microstructure characterized by a gradual transition from fine-grained surface layers to coarser-grained regions.Severe plastic deformation at the surface significantly enhances surface microhardness,with values increasing from 63.8 HV in the untreated specimen to 132.9 HV after USRP-4 passes.The thickness of the plastic deformation layer exhibits process-dependent behavior,growing from 200μm(two passes)to 250μm(four passes).Wear test results indicate that the wear resistance of the material is significantly enhanced after USRP treatment.This improvement is primarily attributed to the combined effects of the following factors:surface grain refinement,the role of dislocation-induced twinning,increased hardness,the formation of nanoscale secondary phases,introduction of residual compressive stresses,weakened surface texture,and reduced surface roughness.Notably,both friction coefficients and wear volumes show a direct dependence on the number of rolling passes.This study systematically elucidates the underlying mechanisms linking USRP-induced microstructural evolution to enhanced wear performance,providing critical insights for optimizing surface engineering strategies in magnesium alloys.
文摘Inconel 718 superalloy has extensive applications in a variety of industries such as the moulding,aerospace and medical due to its excellent mechanical features such as poor thermal conductivity,high strength at high temperatures and corrosion resistance.However,it is very difficult to process by traditional machining and finishing methods.Abrasive based finishing process is one of non-traditional finishing method applied to complex surfaces.Shot peening process is one of the surface treatment processes mostly applied to improve the surface strength.The superior advantages of these two processes are combined into one process.This newly developed and patented process is called as GOV process.In this study,the effects of GOV process parameters(number of cycles,steel ball size,media concentration)on the surface quality of Inconel 718 already pre-processed by wire electric discharge machining are investigated.The performance parameters are identified as surface roughness,material removal and white layer thickness.Surface finishing with the GOV process improves the surface roughness,Ra value by decreasing from 2.63μm to 0.46μm by removing micro-level chips up to 10.7 mg which is supported by SEM images.White layer formed due to nature of EDM process is completely removed from specimen surface.
基金Under the auspices of the National Natural Science Foundation of China(No.41971116,42271046,42277449)Fundamental Research Funds for the Central Universities(No.2020TS102)。
文摘The Zoige Basin,located in the eastern region of the Tibetan Plateau of China,is characterized by its climate sensitivity and complex surface environment.It is vital to understand the response of the surface processes to environmental changes in the Zoige Basin since the last deglaciation,as well as the response of environmental changes and surface processes on the Tibetan Plateau relate to global changes.In August 2020,a field investigation was conducted in the Zoige Basin.A complete set of stratigraphic profile from the high platform at the front of the glacial-diluvial fan in the Maqu reach of the western basin was selected as the research subject.Optically stimulated luminescence(OSL)dating samples and sedimentary samples were collected from key layers and brought back to the laboratory for experimental analysis,and the surface processes and environment changes since the last deglaciation in the Zoige Basin were investigated through particle size analysis and OSL dating.The results showed that during the last glacial period before 14.5 kyr,a substantial glacial-alluvial fan composed of sand and gravel layers was formed by flash flood processes triggered by glacial meltwater and heavy precipitation.In the Bølling-Allerød warm period of 14.5–11.7 kyr,a warm and humid climate prevailed,with the formation of silty bog environments in the shallow depressions at the glacial-alluvial fan's forefront and the development of gray-green bog soil deposits.However,during the Younger Dryas period,an abrupt climate deterioration occurred,with the upper section of the gray-green bog soil layer in the shallow depression to experience folding and deformation due to surface freeze-thaw actions.During the early Holocene period from 11.7 kyr to 8.5 kyr,the climate was relatively dry,resulting in prevalent aeolian sand activitities.Coarse silt accumulated in the shallow depression,and sedimentary facies alternating between aeolian sand and bog soil deposits developed owing to strong wind patterns on the plateau surface.In the warm and humid period from 8.5 kyr to 3.1 kyr,increased weathering and pedogenesis enhanced clay content in sediments,which developed into the paleosol.In the late Holocene,starting from 3.1 kyr,the climate became relatively dry once more,with aeolian sand activity prevalent.The coarse silt that accumulated during the late Holocene transformed into subalpine meadow black soil because of rising temperature and humidity levels.These findings indicated that the developmental process of the high platform in the Maqu reach of the Zoige Basin,which was significant for understanding the environmental changes and surface processes in the source region of the Yellow River since the last deglaciation.
基金financial supports from the National Natural Science Foundation of China-Youth Project(51801076)the Provincial Colleges and Universities Natural Science Research Project of Jiangsu Province(18KJB430009)+1 种基金the Postdoctoral Research Support Project of Jiangsu Province(1601055C)the Senior Talents Research Startup of Jiangsu University(14JDG126)。
文摘To solve the problems of deformation,micro-cracks,and residual tensile stress in laser cladding coatings,the technique of laser cladding with Fe-based memory alloy can be considered.However,the process of in-situ synthesis of Fe-based memory alloy coatings is extremely complex.At present,there is no clear guidance scheme for its preparation process,which limits its promotion and application to some extent.Therefore,in this study,response surface methodology(RSM)was used to model the response surface between the target values and the cladding process parameters.The NSGA-2 algorithm was employed to optimize the process parameters.The results indicate that the composite optimization method consisting of RSM and the NSGA-2 algorithm can establish a more accurate model,with an error of less than 4.5%between the predicted and actual values.Based on this established model,the optimal scheme for process parameters corresponding to different target results can be rapidly obtained.The prepared coating exhibits a uniform structure,with no defects such as pores,cracks,and deformation.The surface roughness and microhardness of the coating are enhanced,the shaping quality of the coating is effectively improved,and the electrochemical corrosion performance of the coating in 3.5%NaCl solution is obviously better than that of the substrate,providing an important guide for engineering applications.
基金Project(2009ZX04005-031-11)supported by the Major National Science and Technology Special Project of ChinaProject(318968)supported by the Marie Curie International Research Staff Exchange Scheme(IRSES,Mat Pro Future)within the 7th EC Framework Program(FP7)Project(B08040)supported by the 111 Plan,China
文摘Identifying suitable processing window is necessary but difficult for achieving favorable microstructure and performance in extrusion of large thick-walled pipe with difficult-to-deform Inconel 625 alloy. In this work, a method was established for identifying the extrusion process window considering temperature control using response surface methodology. Firstly, the response surface models, which correlate temperature rise and peak temperature to key extrusion parameters, have been developed by orthogonal regression based on finite element calculated data. Secondly, the coupled effects of the key extrusion parameters on the temperature rise and peak temperature have been disclosed based on the regression models. Lastly, suitable extrusion processing windows, which are described by contour map of peak temperature in the space of extrusion speed and initial billet temperature, have been established for different extrusion ratios. Using the identified process window, a suitable combination of the key extrusion parameters can be determined conveniently and quickly.
基金support in part by Grant-in-aid for Scientific Research from the Japan Society for Promotion of Science under Contract No. 16560605
文摘Commercial purity and high purity titanium sheets were initially strained by a new technique, named as friction roll surface processing （FRSP）. Severe strain was imposed into the surface layer and strain gradient was formed through the thickness of the sheet. The microstructure and texture in as-strained state were investigated by optical microscopy and X-ray diffraction technique On the surface of the sheets, ultra-fine grains were found to have a sharp texture with a preferred orientation strongly related to the FRSP direction. The evolution of microstructure and crystallographic texture of FRSPed samples during recrystallization were also studied by electron back-scattered diffraction （EBSD） technique after being annealed at selected temperatures and time. The results indicated that the preferred orientations resulting from FRSP and annealing in the surface layer were formed during rolling and its recrystallization textures were reduced by FRSP. In addition, the texture evolved stably without change in main components during the annealing.
基金financially supported by the National Natural Science Foundation of China (No. 51771155)
文摘The effect of a gradient nanostructured(GNS) surface layer obtained by ultrasonic surface rolling process(USRP) on the fatigue behavior of Ti-6Al-4V alloy has been studied in this paper. Microstructure, surface topography, surface roughness and residual stress measurements were performed to characterize the surface under different conditions. Rotating bending fatigue tests were carried out to evaluate the fatigue behavior of different treatments. The results present a remarkable fatigue performance enhancement for the Ti-6Al-4V alloy with a GNS surface layer obtained by application of USRP with respect to the untreated condition, notwithstanding its considerable surface roughness due to severe ultrasonic impacts and extrusions. Mechanical surface polishing treatment further enhances the beneficial effects of USRP on the fatigue performance. The significantly improved fatigue performance can mainly be ascribed to the compressive residual stress. Simultaneously, the GNS surface layer and surface work hardening have a synergistic effect that accompanies the effect of compressive residual stress.
基金supported financially by the National Natural Science Foundation of China(No.51771155)the Equipment Pre-research Field Foundation(No.61409220202).
文摘In this work,ultrasonic surface rolling process(USRP)was utilized to produce a gradient structured layer on 7 B50-T7751 aluminum alloy,and the mechanical properties and corrosion fatigue behavior of treated samples were studied.These results reveal that underwent USRP,a 425~m thick gradient structure and a 700~m deep compressive residual stress field are created,aluminum grain size become fine(~67 nm),and the corrosion rate of treated surface reduces by 60.08%owing to the combined effect of compressive residual stress and surface nanocrystallization.The corrosion fatigue strength is enhanced to 117%of that of 7 B50 Al alloys by means of USRP due to the introduced compressive residual stress,which is considered as the major favorable factor in suppressing the initiation and early propagation of corrosion fatigue cracks.Besides,the gradient structure is an important factor in providing a significant synergistic contribution to the improvement of corrosion fatigue performance.
基金financed by the National Grand Fundamental Research 973 Program of China (Grant No. 2009CB421504)the Natural Science Foundation of China (Grant Nos. 41175063,40975032,and 41275066)
文摘On 12 August 2004, Typhoon Rananim （0414） moved inland over China and stagnated over the Poyang Lake area, resulting in torrential rainfall and severe geologic hazards. The Advanced Weather Research and Forecasting （ARW-WRF） model and its different land surface models （LSMs） were employed to study the impacts of land surface process on the inland behavior of Typhoon Rananim. Results show that simulations, coupled with LSMs or not, have no significant differences in predicting typhoon track, intensity, and largescale circulation. However, the simulations of mesoscale structure, rainfall rate, and rainfall distribution of typhoon are more reasonable with LSMs than without LSMs. Although differences are slight among LSMs, NOAH is better than the others. Based on outputs using the NOAH scheme, the interaction between land surtace and typhoon was explored in this study. Notably, typhoon rainfall and cloud cover can cool land surface, but rainfall expands the underlying saturated wetland area, which exacerbates the asymmetric distribution of surface heat fluxes. Accordingly, an energy frontal zone may form in the lower troposphere that enhances ascending motion and local convection, resulting in heavier rainfall. Moreover, the expanded underlying saturated wetlands provide plentiful moisture and unstable energy for the maintenance of Typhoon Rananim and increased rainfall in return.
基金Foundation： National Natural Science Foundation of China, No.41472138, No.41401220, No.41472026 The CAS Strate- gic Priority Research Program Grant B, No.XDPB05 The Ministry of Science and Technology of China, No.2016YFA0600503
文摘There is a wide diversity of landforms in China. The topography of three major ter- races, decreasing in height stepwise from west to east, was formed by the early Miocene. With the commencement of the Great Northern Hemisphere Glaciations （GHGs） and the glacial-interglacial cycles in the Pleistocene, thick loess deposits accumulated in north China, and fluvial terraces were formed and lakes expanded and contracted in eastern and central China. The earliest evidence of hominins in China is dated to ~1.7 Ma; they occupied the monsoon-dominated region for a long interval, until the late Pleistocene, ~50 ka. In this study, we investigated a large area rich in the relics and artifacts of early man. The results indicate that the early humans occupied riverine areas, especially medium-sized fluvial basins, and lake shores. Even in the relatively recent geological past, the occupation and abandonment of settlements were directly forced by the shifting of sand dune fields in the desert-loess transi- tional zone, which in turn was closely associated with variations in the monsoon climate and vegetation patterns. Our observations indicate that landforms were one of the main determi- nants of early human behavior, in that loess tableland, large alluvial plains, desert-Gobi areas, and the Tibetan Plateau, were not suitable environments for early human settlement. We infer that the early humans in China adapted their behavior to specific landforms and landform processes. The monsoon climate, which shapes the large-scale step-like pattern of fluvial landforms, promotes vegetation coverage and dominates soil formation, provides a crucial context for early human adaptation. The adaptation of early humans to earth surface proc- esses in East Asia is investigated for the first time in this study. Future investigations will provide further information that will increase our understanding of the linkage between early human behavior and landform processes in East Asia.
基金supported by the National Natural Science Foundation of China (Grant No.40275004)the State Key Laboratory of Atmosphere Physics and Chemistry,and the City University of Hong Kong(Grant No.8780046)the City University of Hong Kong Strategic Research(Grant No.7001038)
文摘This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary layer processes and land surface processes. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feasibility of the model is well proved in this paper. The numerical simulation results from MSPAS show good agreement with reality. The scheme is used to obtain reasonable simulations for diurnal variations of heat balance, potential temperature of boundary layer, and wind field, and spatial distributions of temperature, specific humidity, vertical velocity, turbulence kinetic energy, and turbulence exchange coefficient over desert and oasis. In addition, MSPAS is used to simulate the interaction between desert and oasis at night, and again it obtains reasonable results. This indicates that MSPAS can be used to study the interaction between land surface processes and the atmospheric boundary layer over various underlying surfaces and can be extended for regional climate and numerical weather prediction study.
基金supported by the National Natural Science Foundation of China (41001066)the National Basic Research Program of China (Program 973) (2009CB421308)the Ministry of Water Resources’ Special Funds for Scientific Research on Public Causes (201101049)
文摘Water is the important resource to guarantee the existence and development of oases in arid areas. To improve the utilization efficiency of water resources in Manas River Basin, this paper investigated the trends and periods of runoff based on the runoff and climate data for the past 50 years. Subsequently, with the socioeconomic and water resources data, we studied a comprehensive evaluation on the water security in this area. The results indicated that the stream flows in the three hydrological stations of Hongshanzui, Kensiwat and Bajiahu have sig- nificantly increased and undergone abrupt changes, with periods of 18 and 20 years. According to assessment, water security in the Manas River Basin was at an unsafe level in 2008. In criterion layer, the ecological security index and the index of supply-demand situation are both at the relatively secure level; the quantity index and so- cioeconomic index of water resources are at the unsafe level and basic security level, respectively. Therefore, in order to achieve sustainable economic and social development within the Manas River Basin, it is vital to take a series of effective measures to improve the status of water security.
文摘The behavior of gaseous nitriding on the surface nanocrystallized (SNCed) steel was investigated. The mild steel discs were SNCed on one side by using the method of ultrasonic shot peening. The opposite side of the discs maintained the original coarse-grained condition. The gaseous nitriding was subsequently carried out at three different temperatures: 460, 500 and 560℃. The compound layer growth and diffusion behavior were then studied. It was revealed that SNC pretreatment greatly enhances both diffusion coefficient D and surface reaction rate. As a result, nitriding time could be reduced to the half. It was also found that the growth of compound layer with nitriding time conformed with parabolic relationship from the start of nitriding process in the SNCed samples.
基金the National Natural Science Foundation of China(grant no.:41430532)the Alexander von Humboldt Stiftung/Foundation,Germany for support
文摘Due to large deserts on Earth surface a thorough understanding of climate change, landscape evolution and geomorphological processes having occurred in deserts is crucial for Earth System Science. The landscapes in deserts are, however, diverse and different over the globe with regard to their geomorphological nature, human activities and geological histories. In the last decades a great number of efforts have been put to the investigation of the initial timing of the occurrence of arid climate, e. g. in northwestern China. Silty sediments in the downwind directions have been used to deduce the histories of deserts. In general, there is a lack of knowledge about processes and landscapes in Chinese drylands between the initial Miocene silt sedimentation at desert margins and the late Quaternary multiple occurrences of wetter climate with assumed large lakes in many of the deserts in northern China. The geomorphological concept of three primary triggering factors, i.e., the sediment supply, sediment availability and transport capacity of wind, and additionally the underground geology need to be fully considered for a better understanding of the environmental histories of sand seas which should not be viewed as equivalent for deserts because sand seas cover between 〈 1% and ca. 45% of the desert areas in various continents dependent on a complex interaction between various processes of both exogenous and endogenous origins.
