According to the Japanese Ministry of Health,Labour,and Welfare,14.2%of people were aged>75 years in Japan in 2018,and this number continues to rise.With population aging,the incidence of congestive heart failure(C...According to the Japanese Ministry of Health,Labour,and Welfare,14.2%of people were aged>75 years in Japan in 2018,and this number continues to rise.With population aging,the incidence of congestive heart failure(CHF)is also increasing.[1–3]Reports have shown that the presence of cognitive impairment(CI)in patients with CHF is associated with poor prognosis,[4–6]and the degree of CI is related to CHF severity.展开更多
Two metal-organic frameworks(MOFs),trans-[Co(L)(μ_(2)-H_(2)O)(H_(2)O)2]·2H_(2)O(1)and cis-[Mn(L)(Bipy)](2)(H_(2)L=2,2'-dimethyl-4,4'-biphenyldicarboxylic acid,Bipy=4,4'-bipyridine),have been synthesi...Two metal-organic frameworks(MOFs),trans-[Co(L)(μ_(2)-H_(2)O)(H_(2)O)2]·2H_(2)O(1)and cis-[Mn(L)(Bipy)](2)(H_(2)L=2,2'-dimethyl-4,4'-biphenyldicarboxylic acid,Bipy=4,4'-bipyridine),have been synthesized and character-ized by FTIR,thermogravimetric analysis(TGA),powder and single crystal X-ray diffraction.MOF 1 crystallizes in the triclinic system with a P1 space group and contains two crystallographically different Coions.Each trans-[CoO_(6)]octahedron is connected byμ_(2)-H_(2)O and L^(2-)ligand with a bis(unidentate)coordination mode to produce a 2D sql topological network.MOF 2 crystallizes in the monoclinic system with a C2/c space group.The Mncation adopts a cis-[MnO_(4)N_(2)]octahedron as a 6-connected node and is linked by L^(2-)ligand as a 4-connected node to gener-ate a binodal(4,6)-connected 3D fsc framework.The intermolecular interactions in 1 and 2 have been investigated by 3D Hirshfeld surface analyses and 2D fingerprint plots to reveal that the main interactions are H…H and O…H/H…O contacts in 1,and H…H and C…H/H…C contacts in 2.The TGA indicated that 1 and 2 were stable below 390 and 370℃,respectively.展开更多
文摘According to the Japanese Ministry of Health,Labour,and Welfare,14.2%of people were aged>75 years in Japan in 2018,and this number continues to rise.With population aging,the incidence of congestive heart failure(CHF)is also increasing.[1–3]Reports have shown that the presence of cognitive impairment(CI)in patients with CHF is associated with poor prognosis,[4–6]and the degree of CI is related to CHF severity.
文摘Two metal-organic frameworks(MOFs),trans-[Co(L)(μ_(2)-H_(2)O)(H_(2)O)2]·2H_(2)O(1)and cis-[Mn(L)(Bipy)](2)(H_(2)L=2,2'-dimethyl-4,4'-biphenyldicarboxylic acid,Bipy=4,4'-bipyridine),have been synthesized and character-ized by FTIR,thermogravimetric analysis(TGA),powder and single crystal X-ray diffraction.MOF 1 crystallizes in the triclinic system with a P1 space group and contains two crystallographically different Coions.Each trans-[CoO_(6)]octahedron is connected byμ_(2)-H_(2)O and L^(2-)ligand with a bis(unidentate)coordination mode to produce a 2D sql topological network.MOF 2 crystallizes in the monoclinic system with a C2/c space group.The Mncation adopts a cis-[MnO_(4)N_(2)]octahedron as a 6-connected node and is linked by L^(2-)ligand as a 4-connected node to gener-ate a binodal(4,6)-connected 3D fsc framework.The intermolecular interactions in 1 and 2 have been investigated by 3D Hirshfeld surface analyses and 2D fingerprint plots to reveal that the main interactions are H…H and O…H/H…O contacts in 1,and H…H and C…H/H…C contacts in 2.The TGA indicated that 1 and 2 were stable below 390 and 370℃,respectively.
