Up-conversion lasing actions are normally difficult to realize in light-emitting materials due to small multi-photon absorp-tion cross section and fast dephasing of excited states during multi-photon excitation.This p...Up-conversion lasing actions are normally difficult to realize in light-emitting materials due to small multi-photon absorp-tion cross section and fast dephasing of excited states during multi-photon excitation.This paper reports an easily ac-cessible up-conversion amplified spontaneous emission(ASE)in organic-inorganic hybrid perovskites(MAPbBr3)films by optically exciting broad gap states with sub-bandgap laser excitation.The broad absorption was optimized by adjust-ing the grain sizes in the MAPbBr3 films.At low sub-bandgap pumping intensities,directly exciting the gap states leads to 2-photon,3-photon,and 4-photon up-conversion spontaneous emission,revealing a large optical cross section of multi-photon excitation occurring in such hybrid perovskite films.At moderate pumping intensity(1.19 mJ/cm2)of 700 nm laser excitation,a significant spectral narrowing phenomenon was observed with the full width at half maximum(FWHM)de-creasing from 18 nm to 4 nm at the peak wavelength of 550 nm,simultaneously with a nonlinear increase on spectral peak intensity,showing an up-conversion ASE realized at low threshold pumping fluence.More interestingly,the up-con-version ASE demonstrated a giant magnetic field effect,leading to a magneto-ASE reaching 120%.In contrast,the up-conversion photoluminescence(PL)showed a negligible magnetic field effect(<1%).This observation provides an evid-ence to indicate that the light-emitting states responsible for up-conversion ASE are essentially formed as spatially exten-ded states.The angular dependent spectrum results further verify the existence of spatially extended states which are polarized to develop coherent in-phase interaction.Clearly,using broad gap states with spatially extended light-emitting states presents a new approach to develop up-conversion ASE in organic-inorganic hybrid perovskites.展开更多
This study examines the perception of pollution in Rivers state, to find out the inhabitants opinion of how the government is handling pollution in the area. The study used the survey research design and primary data ...This study examines the perception of pollution in Rivers state, to find out the inhabitants opinion of how the government is handling pollution in the area. The study used the survey research design and primary data which were collected using copies of questionnaire were the main data used for the study. Data collected were presented using tables and statistical diagrams, while data analysis was achieved using the welch statistics. It was observed that 37.75% of the respondents suggested that the air quality in the area is very bad, suggesting that they were suffering as a result. The main sources of environmental pollution were petroleum refining (44.25%), illegal refining of petroleum products (52.75%) and fumes from vehicles (46%). Also noted was that vast majority of inhabitants (86.75%) were willing to partake in the cleaner environmental process, but they stated that the government was not forceful enough to achieve the pollution free environment in the area. The welch statistics identified that there was no statistically significant difference in the perception of polluted environment in the area at P > 0.05. The study as a result of the findings advocates partnership between government, individuals and NGOs to achieve cleaner and safer environment in the area.展开更多
In material science, half filled 3d orbital of transition metals is essentially an important factor controlling characteristics of alloys and compounds. This paper presents a result of the challenge of excitation of i...In material science, half filled 3d orbital of transition metals is essentially an important factor controlling characteristics of alloys and compounds. This paper presents a result of the challenge of excitation of inner-core electron system with long lifetime of zinc films. The advanced zinc films with excited inner-core electron, 3dn (n = 9, 8). We report experimental results of XPS measurements of 9 points in the sample along vertical direction, respectively. The most pronounced futures are existence of satellites, which are about 4 eV higher than the main lines. According to the charge transfer mechanism proposed by A. Kotani and K. Okada, it was clarified that the origins of these peaks are c3d9L for the main peak and c3d9 for the satellite, respectively. From the energy difference, δEB, and peak intensity ratio, I+/I-, between c3d9 and c3d10L, the energy for charge transfer, Δ, and mixing energy, T, were estimated. In the region where the intensity of c3d10L becomes large, Δ becomes small, 1.2 Δdc = 5.5 eV and Udd = 5.5 eV. In the analysis along vertical direction, intensity profile of Zn3d9 showed odd functional symmetry and that of Zn3d10L showed even functional symmetry. Only the intensity profile of C1s (288 eV) showed the same spatial correlation with Zn3d9. In our experiment, the sample also showed high mobility of the constituting elements. These suggest that charge conservation in excited zinc atom suggests combination between Zn3d9 and C2-.展开更多
The present document describes the experience of using a Geography Information System (GIS) tool to map the spatial distribution of the population of the State of Mexico, Mexico, for 2010. Prior to the development of ...The present document describes the experience of using a Geography Information System (GIS) tool to map the spatial distribution of the population of the State of Mexico, Mexico, for 2010. Prior to the development of the experience, dif- ferent projects, tools and products, which offered cartographic representations of the population, were presented, se- lecting one that was developed to function in Idrisi Taiga GIS. Likewise, the GIS tool and the process followed to apply it to a case study in the State of Mexico are described. The result is a raster image that shows the distribution of the population on the analyzed state, offering the possibility to identify the zones where the population concentrates and disperses and to produce an opinion from a geographic point of view on what the origin of these distribution patterns is. Among the conclusions from the analysis of results, distinguishable are the applications that the obtained image can have;for instance, the population can be estimated by basins or risk zones by only adding the values of the cells inside these zones. It is also concluded that the degree of detail expressed by the spatial distribution image of the population will depend on several factors, among them the scale and resolution of the input information and the resolution fixed for the output information.展开更多
The purpose of this study is to analyze the characteristics of the spatial distribution and change trend of the marketing level of stateowned land supply so as to provide policy recommendations. Method of spatial auto...The purpose of this study is to analyze the characteristics of the spatial distribution and change trend of the marketing level of stateowned land supply so as to provide policy recommendations. Method of spatial autocorrelation analysis is employed. The results indicate that the spatial layout of the land supply marketing level is generally dispersed,but it does assemble in some specific area. The correlation between the marketing level of state-owned land supply and the economic development is not statistically significant. But their relations fluctuate obviously. The overall marketing level of state-owned land supply is increasing and spatially concentrated. The expansion rate of marketing has decreased first and then increased and stabilized now. The high-value cluster center of marketing level of state-owned land supply exists all over the country; however the existence probability of the cluster is bigger in undeveloped areas. It is concluded that spatial autocorrelation analysis is a good method to quantitatively analyze the spatial variation of marketing level of state-owned land supply in China. To grasp the spatial and temporal variations of the marketing level of state-owned land supply is also good to enhance running of the state-owned land market.展开更多
There has been an increasing global and local interest in developing renewable, clean, and cheap energy towards achieving Goal number 7 of the Sustainable Development Goals (SDG). However, decisions involving suitable...There has been an increasing global and local interest in developing renewable, clean, and cheap energy towards achieving Goal number 7 of the Sustainable Development Goals (SDG). However, decisions involving suitable and sustainable locations for renewable energy projects remain an important task. This study employed Geographic Information System (GIS) and Multi-Criteria Decision Analysis (MCDA) to spatially analyze and model wind farm site suitability in Nasarawa State. The aim is to integrate the environmental, social, and economic aspects of decision-making for identifying sustainable wind farm sites. The study distinguished between two sets of decision criteria: decision constraints and decision factors. The former defined the exclusion zones while the latter were standardized based on fuzzy logic to depict varying degrees of suitability across the State. The MCDA applied the weighted linear combination method, with relative weights generated through pairwise comparisons of the analytic hierarchy process to analyze three policy scenarios: equal weights, environmental/social priority, and economic priority scenario. A combination of resulting composite maps from the constraints and the factors gave the final suitability maps. The resulting suitability index (SI) for the respective policy scenario describes the degrees of suitability: Ideal locations were denoted by one (1) and the not suitable locations by zero (0), with values in-between depicting varying degrees of wind farm site suitability. Based on the SI, priority locations indicating areas with good prospects, in addition to the most suitable parcels of land, were identified and delineated. The composite decision constraint revealed that wind farm projects would not be viable in more than half (57.58%) of the State. Wind speed was the major constraint and accounted for the exclusion of 46.25%, with a mean fuzzy membership value of 0.2008 indicating low suitability across the State. Also, the average acceptable wind farm location for the three-policy scenario was 33.33% of the entire study area. Lafia, Obi, Keana, Awe, Nasarawa-Eggon, Wamba and Kokona LGAs were the identified priority Local Government Areas (LGAs). However, only Lafia, Obi, and Nasarawa-Eggon were consistent with changes in the policy objectives. All the priority LGAs have one or more of the most suitable parcels within their administrative boundaries except for Wamba. Despite the severe limitations of wind speed, substantial parts of Nasarawa State still provide great development potentials for wind energy. The “most suitable” locations in Lafia, Nasarawa-Eggon, and Obi LGAs should have first consideration for the development of wind energy in the State.展开更多
基金This work was supported by the 973 Program and China National Key Basic Research Program(2016YFA0301100,2016YFA0302000,and 2018YFA0306201)National Science Foundation of China(11774063 and 11727811)+2 种基金Science and Technology Commission of Shanghai Municipality(19XD1434600,2019SHZDZX01 and 19DZ2253000)Air Force Office of Scientific Research(AFOSR)under the grant number FA 9550-15-1-0064,AOARD(FA2386-15-1-4104)National Science Foundation(NSF-1911659).
文摘Up-conversion lasing actions are normally difficult to realize in light-emitting materials due to small multi-photon absorp-tion cross section and fast dephasing of excited states during multi-photon excitation.This paper reports an easily ac-cessible up-conversion amplified spontaneous emission(ASE)in organic-inorganic hybrid perovskites(MAPbBr3)films by optically exciting broad gap states with sub-bandgap laser excitation.The broad absorption was optimized by adjust-ing the grain sizes in the MAPbBr3 films.At low sub-bandgap pumping intensities,directly exciting the gap states leads to 2-photon,3-photon,and 4-photon up-conversion spontaneous emission,revealing a large optical cross section of multi-photon excitation occurring in such hybrid perovskite films.At moderate pumping intensity(1.19 mJ/cm2)of 700 nm laser excitation,a significant spectral narrowing phenomenon was observed with the full width at half maximum(FWHM)de-creasing from 18 nm to 4 nm at the peak wavelength of 550 nm,simultaneously with a nonlinear increase on spectral peak intensity,showing an up-conversion ASE realized at low threshold pumping fluence.More interestingly,the up-con-version ASE demonstrated a giant magnetic field effect,leading to a magneto-ASE reaching 120%.In contrast,the up-conversion photoluminescence(PL)showed a negligible magnetic field effect(<1%).This observation provides an evid-ence to indicate that the light-emitting states responsible for up-conversion ASE are essentially formed as spatially exten-ded states.The angular dependent spectrum results further verify the existence of spatially extended states which are polarized to develop coherent in-phase interaction.Clearly,using broad gap states with spatially extended light-emitting states presents a new approach to develop up-conversion ASE in organic-inorganic hybrid perovskites.
文摘This study examines the perception of pollution in Rivers state, to find out the inhabitants opinion of how the government is handling pollution in the area. The study used the survey research design and primary data which were collected using copies of questionnaire were the main data used for the study. Data collected were presented using tables and statistical diagrams, while data analysis was achieved using the welch statistics. It was observed that 37.75% of the respondents suggested that the air quality in the area is very bad, suggesting that they were suffering as a result. The main sources of environmental pollution were petroleum refining (44.25%), illegal refining of petroleum products (52.75%) and fumes from vehicles (46%). Also noted was that vast majority of inhabitants (86.75%) were willing to partake in the cleaner environmental process, but they stated that the government was not forceful enough to achieve the pollution free environment in the area. The welch statistics identified that there was no statistically significant difference in the perception of polluted environment in the area at P > 0.05. The study as a result of the findings advocates partnership between government, individuals and NGOs to achieve cleaner and safer environment in the area.
文摘In material science, half filled 3d orbital of transition metals is essentially an important factor controlling characteristics of alloys and compounds. This paper presents a result of the challenge of excitation of inner-core electron system with long lifetime of zinc films. The advanced zinc films with excited inner-core electron, 3dn (n = 9, 8). We report experimental results of XPS measurements of 9 points in the sample along vertical direction, respectively. The most pronounced futures are existence of satellites, which are about 4 eV higher than the main lines. According to the charge transfer mechanism proposed by A. Kotani and K. Okada, it was clarified that the origins of these peaks are c3d9L for the main peak and c3d9 for the satellite, respectively. From the energy difference, δEB, and peak intensity ratio, I+/I-, between c3d9 and c3d10L, the energy for charge transfer, Δ, and mixing energy, T, were estimated. In the region where the intensity of c3d10L becomes large, Δ becomes small, 1.2 Δdc = 5.5 eV and Udd = 5.5 eV. In the analysis along vertical direction, intensity profile of Zn3d9 showed odd functional symmetry and that of Zn3d10L showed even functional symmetry. Only the intensity profile of C1s (288 eV) showed the same spatial correlation with Zn3d9. In our experiment, the sample also showed high mobility of the constituting elements. These suggest that charge conservation in excited zinc atom suggests combination between Zn3d9 and C2-.
文摘The present document describes the experience of using a Geography Information System (GIS) tool to map the spatial distribution of the population of the State of Mexico, Mexico, for 2010. Prior to the development of the experience, dif- ferent projects, tools and products, which offered cartographic representations of the population, were presented, se- lecting one that was developed to function in Idrisi Taiga GIS. Likewise, the GIS tool and the process followed to apply it to a case study in the State of Mexico are described. The result is a raster image that shows the distribution of the population on the analyzed state, offering the possibility to identify the zones where the population concentrates and disperses and to produce an opinion from a geographic point of view on what the origin of these distribution patterns is. Among the conclusions from the analysis of results, distinguishable are the applications that the obtained image can have;for instance, the population can be estimated by basins or risk zones by only adding the values of the cells inside these zones. It is also concluded that the degree of detail expressed by the spatial distribution image of the population will depend on several factors, among them the scale and resolution of the input information and the resolution fixed for the output information.
基金Supported by Chongqing Key Humanities and Social Sciences Base--Research Center of Rural Economics and Management of Southwest University
文摘The purpose of this study is to analyze the characteristics of the spatial distribution and change trend of the marketing level of stateowned land supply so as to provide policy recommendations. Method of spatial autocorrelation analysis is employed. The results indicate that the spatial layout of the land supply marketing level is generally dispersed,but it does assemble in some specific area. The correlation between the marketing level of state-owned land supply and the economic development is not statistically significant. But their relations fluctuate obviously. The overall marketing level of state-owned land supply is increasing and spatially concentrated. The expansion rate of marketing has decreased first and then increased and stabilized now. The high-value cluster center of marketing level of state-owned land supply exists all over the country; however the existence probability of the cluster is bigger in undeveloped areas. It is concluded that spatial autocorrelation analysis is a good method to quantitatively analyze the spatial variation of marketing level of state-owned land supply in China. To grasp the spatial and temporal variations of the marketing level of state-owned land supply is also good to enhance running of the state-owned land market.
文摘There has been an increasing global and local interest in developing renewable, clean, and cheap energy towards achieving Goal number 7 of the Sustainable Development Goals (SDG). However, decisions involving suitable and sustainable locations for renewable energy projects remain an important task. This study employed Geographic Information System (GIS) and Multi-Criteria Decision Analysis (MCDA) to spatially analyze and model wind farm site suitability in Nasarawa State. The aim is to integrate the environmental, social, and economic aspects of decision-making for identifying sustainable wind farm sites. The study distinguished between two sets of decision criteria: decision constraints and decision factors. The former defined the exclusion zones while the latter were standardized based on fuzzy logic to depict varying degrees of suitability across the State. The MCDA applied the weighted linear combination method, with relative weights generated through pairwise comparisons of the analytic hierarchy process to analyze three policy scenarios: equal weights, environmental/social priority, and economic priority scenario. A combination of resulting composite maps from the constraints and the factors gave the final suitability maps. The resulting suitability index (SI) for the respective policy scenario describes the degrees of suitability: Ideal locations were denoted by one (1) and the not suitable locations by zero (0), with values in-between depicting varying degrees of wind farm site suitability. Based on the SI, priority locations indicating areas with good prospects, in addition to the most suitable parcels of land, were identified and delineated. The composite decision constraint revealed that wind farm projects would not be viable in more than half (57.58%) of the State. Wind speed was the major constraint and accounted for the exclusion of 46.25%, with a mean fuzzy membership value of 0.2008 indicating low suitability across the State. Also, the average acceptable wind farm location for the three-policy scenario was 33.33% of the entire study area. Lafia, Obi, Keana, Awe, Nasarawa-Eggon, Wamba and Kokona LGAs were the identified priority Local Government Areas (LGAs). However, only Lafia, Obi, and Nasarawa-Eggon were consistent with changes in the policy objectives. All the priority LGAs have one or more of the most suitable parcels within their administrative boundaries except for Wamba. Despite the severe limitations of wind speed, substantial parts of Nasarawa State still provide great development potentials for wind energy. The “most suitable” locations in Lafia, Nasarawa-Eggon, and Obi LGAs should have first consideration for the development of wind energy in the State.
