To avoid stray current and maintain the benefit of no phase-split in the DC traction power supply system, an AC traction power supply system was proposed for the urban public transport such as metro and light rail tra...To avoid stray current and maintain the benefit of no phase-split in the DC traction power supply system, an AC traction power supply system was proposed for the urban public transport such as metro and light rail transit. The proposed system consists of a main substation （MSS） and cable traction network （CTN）. The MSS includes a single-phase main traction transformer and a negative-se- quence compensation device, while the CTN includes double-core cables, traction transformers, overhead catenary system, rails, etc. Several key techniques for the proposed system were put forward and discussed, which can be summarized as （1） the power supply principle, equivalent circuit and transmission ability of the CTN, the cable-catenary matching technique, and the selection of catenary voltage level; （2） the segmentation technology and status identification method for traction power supply network, distributed and centralized protection schemes, etc.; （3） a power supply scheme for single-line MSS and a power supply scheme of MSS shared by two or more lines. The proposed industrial frequency single-phase AC traction power supply system shows an excellent technical performance, good economy, and high reliability, hence provides a new alternative for metro and urban rail transit power supply systems.展开更多
The HC-55 single-phase AC series-excitation commutator motor exported to Japan by the Linquan Motor Factory is an open-type motor characterized by simple structure, small volume, high rotary speed, large starting torq...The HC-55 single-phase AC series-excitation commutator motor exported to Japan by the Linquan Motor Factory is an open-type motor characterized by simple structure, small volume, high rotary speed, large starting torque, reliable operation and easy installation. It can be used as a driving component for various kinds of household electrical appliances, such as electric mills, pulverlizers, small stirrers, vacuum cleaners and electric hair dryers, an ideal product for electrical equipment.展开更多
This paper discusses a novel boost single-phase active AC-DC converters, named low-end semi-controlled bridge AC-DC converter. By analysis, its topology and principle can be derived from the conventional single-phase ...This paper discusses a novel boost single-phase active AC-DC converters, named low-end semi-controlled bridge AC-DC converter. By analysis, its topology and principle can be derived from the conventional single-phase power factor corrector （ PFC）. But it has also some differences, such as power device positions, inductor type, input voltage waveform detection and induction current detection, so its design is also different. The converter is implemented by employing two current detection approaches, i.e., current transformer detection and shunt resistor detection. Consequently, it can provide a steady DC output voltage with a low voltage ripple, approximately unitary input power factor and 2.5 kW output power. The experimental results show validity of the theoretical analysis.展开更多
A novel topology of Integrated Boost-SEPIC (IBS) AC-DC converter using common part sharing method (CPSM) has been proposed in this paper. Conventional boost converters with bridge rectifier configuration are inefficie...A novel topology of Integrated Boost-SEPIC (IBS) AC-DC converter using common part sharing method (CPSM) has been proposed in this paper. Conventional boost converters with bridge rectifier configuration are inefficient due to limited voltage step-up ratio which may not be applicable for high step-up applications as in the case of micro generators. The proposed IBS topology is based on the common part sharing method capable of operating both for positive and negative half cycle of the input signal. Result and simulation were conducted using PSIM environment. The proposed AC-DC IBS topology eliminates the requirement of bridge rectifier achieving high efficiency (about 99%), improved power factor (0.75, leading) and lower THD (about 38.8%) which is within IEEE standard.展开更多
This paper presents a single-phase Z-source inverter as a power conditioning system for a single phase utility connected system. Z-source inverter is a single-stage topology that has buck-boost feature, which is possi...This paper presents a single-phase Z-source inverter as a power conditioning system for a single phase utility connected system. Z-source inverter is a single-stage topology that has buck-boost feature, which is possible because of additional shoot through state introduced in zero state of the conventional inverter pulse width modulation and provides desired output AC voltage. Small distributed generation （DG） system with alternate energy sources requires power conditioning units with low cost, high efficiency and tolerance to wide range of input voltage variation and has to perform various functions such as dc-ac conversion, system control and achieve power quality norms. To meet some of these requirements a two-loop control strategy for ac side control with grid current feedback with PI control and inner filter capacitor current feedback with proportional control and on dc side PID control for Z-source capacitor voltage regulation are employed, which gives good transient response also suppress load and source disturbances effectively. Theoretical analysis of proposed scheme is established and then simulation results are presented to validate proposed control strategy.展开更多
Due to the wide and adjustable emission range,Ce^(3+)is an indispensable luminous center for full spectrum lighting.However,it needs to be sintered at high temperature in a reducing atmosphere,resulting in difficulty ...Due to the wide and adjustable emission range,Ce^(3+)is an indispensable luminous center for full spectrum lighting.However,it needs to be sintered at high temperature in a reducing atmosphere,resulting in difficulty to coexisting with other multivalent activated ions(such as Eu^(3+),Tm^(3+)),which greatly hinders the formation of full spectrum.In this study,a calcium vacancy enhanced self-reduction of Ce^(4+)is realized in CaNaSb_(2)O_(6)F(CNSOF)host under air atmosphere sintering,through which Ce^(3+),Tm^(3+)and Eu^(3+)coexisting in a single-phase full spectrum phosphor was prepared.Notably,the artificial introduction of a calcium vacancy was designed to verify this self-reduction mechanism.Moreover,the energy transfer kinetics among Tm^(3+),Ce^(3+)and Eu^(3+)were explored.Finally,combined with a 340 nm UV chip,a full spectrum phosphor-converted light-emitting diode(pc-LED)was fabricated,showing a broad emission range from 400 to 750 nm,Commission Internationale de I'Edairage(CIE)of(0.3485,0.3673),Ra of 92 and correlated color temperature(CCT)of 4933 K.Utilizing the variation in emission colors of this phosphor under different UV wavelengths,a dual encryption method combining point character code and fluorescent encryption technique is proposed.This work provides an effective path for Ce^(4+)self-reduction to apply in full spectrum pc-LED and information encryption.展开更多
In contemporary medium-voltage distribution networks heavily penetrated by distributed energy resources(DERs),the harmonic components injected by power-electronic interfacing converters,together with the inherently in...In contemporary medium-voltage distribution networks heavily penetrated by distributed energy resources(DERs),the harmonic components injected by power-electronic interfacing converters,together with the inherently intermittent output of renewable generation,distort the zero-sequence current and continuously reshape its frequency spectrum.As a result,single-line-to-ground(SLG)faults exhibit a pronounced,strongly non-stationary behaviour that varies with operating point,load mix and DER dispatch.Under such circumstances the performance of traditional rule-based algorithms—or methods that rely solely on steady-state frequency-domain indicators—degrades sharply,and they no longer satisfy the accuracy and universality required by practical protection systems.To overcome these shortcomings,the present study develops an SLG-fault identification scheme that transforms the zero-sequence currentwaveforminto two-dimensional image representations and processes themwith a convolutional neural network(CNN).First,the causes of sample-distribution imbalance are analysed in detail by considering different neutralgrounding configurations,fault-inception mechanisms and the statistical probability of fault occurrence on each phase.Building on these insights,a discriminator network incorporating a Convolutional Block Attention Module(CBAM)is designed to autonomously extract multi-layer spatial-spectral features,while Gradient-weighted Class Activation Mapping(Grad-CAM)is employed to visualise the contribution of every salient image region,thereby enhancing interpretability.A comprehensive simulation platform is subsequently established for a DER-rich distribution system encompassing several representative topologies,feeder lengths and DER penetration levels.Large numbers of realistic SLG-fault scenarios are generated—including noise and measurement uncertainty—and are used to train,validate and test the proposed model.Extensive simulation campaigns,corroborated by field measurements from an actual utility network,demonstrate that the proposed approach attains an SLG-fault identification accuracy approaching 100 percent and maintains robust performance under severe noise conditions,confirming its suitability for real-world engineering applications.展开更多
In order to increase the stability of the Mongolia power system, a single-phase automatic reclosing device (SPAR) was introduced on double-circuit power lines built with a size of 330 kV, operating on a voltage of 220...In order to increase the stability of the Mongolia power system, a single-phase automatic reclosing device (SPAR) was introduced on double-circuit power lines built with a size of 330 kV, operating on a voltage of 220 kV and a length of 250 km. These overhead power lines (L-213, L-214) connect the 220/110/35 kV “Songino” substation with the “Mandal” substation and form system networks. This paper presents the challenges encountered when implementing single-phase automatic reclosing (SPAR) devices and compares the changes in power system parameters before and after SPAR deployment for a long 220 kV line. Simulations and analyses were carried out using DIgSILENT PowerFactory software, focusing on rotor angle stability, and the overall impact on the power system during short-circuit faults. The evaluation also utilized measurement data from the Wide Area Monitoring System (WAMS) to compare system behavior pre- and post-implementation of SPAR. The findings reveal that SPAR significantly enhances system reliability and stability, effectively mitigating the risk of oscillations and stability loss triggered by short circuits. This improvement contributes to a more resilient power system, reducing the potential for disturbances caused by faults.展开更多
Complex dynamical phenomenon was studied in the single phase H-bridge inverter which was controlled by either a peak current or a valley current. The state functions and the discrete iterative map equations were estab...Complex dynamical phenomenon was studied in the single phase H-bridge inverter which was controlled by either a peak current or a valley current. The state functions and the discrete iterative map equations were established to analyze the dynamical phenomenon in the single phase H-bridge inverter. The dynamical characteristics of the single phase H- bridge inverter, such as time domain waveform diagram, bifurcation diagram, and folding map, were obtained by using the numerical calculation when the circuit parameters varied in specific range. Moreover, the simulation results were obtained by using the OrCAD-PSpice software to validate the numerical calculation. Both the numerical calculation and the circuit simulation show that the symmetrical dynamical phenomenon occurs in the single phase H-bridge inverter controlled by the peak current or the valley current.展开更多
According to the characteristics of single-phase circuits and demand of using active filter for real-time detecting harmonic and reactive currents, a detecting method based on Fryze＇s power definition is proposed. Th...According to the characteristics of single-phase circuits and demand of using active filter for real-time detecting harmonic and reactive currents, a detecting method based on Fryze＇s power definition is proposed. The results of theoretical analysis and simula- tion show that the proposed method is effective in realtime detecting of instantaneous harmonic and reactive currents in single-phase circuits. When only detecting the total reactive currents, this method does not need a phase-locked loop circuit, and it also can be used in some special applications to provide different compensations on the ground of different requirements of electric network. Compared with the other methods based on the theory of instantaneous reactive power, this method is simple and easy to realize.展开更多
A single-phase lattice Boltzmann model with modified surface tension is developed in this paper to solve the problem of high-density-ratio free surface flow.The computational efficiency and accuracy are both enhanced....A single-phase lattice Boltzmann model with modified surface tension is developed in this paper to solve the problem of high-density-ratio free surface flow.The computational efficiency and accuracy are both enhanced.The restriction to the relaxation factor （which needs to be smaller than 1） is circumvented by the new surface tension algebra,due to its rational physical nature compared with the treatment of Xing,Buther and Yang in their paper （Comp.Mater.Sci.,2007,39（2）：282-290）.The proposed stable surface tension scheme is applied to simulate the free deformation of a square droplet with surface tension effect and the process of a droplet impinging on a liquid film.The numerical solution for free deformation of a droplet agrees well with thermodynamic principles,and also achieves high accuracy in comparison with Xing,et al.＇s model.Three typical impinging modes are successfully obtained with the new scheme,and another particular mode found by Wang and Chen is also successfully simulated.The evolutions of liquid crown agree well with the power law related to time.展开更多
The electrolytic-capacitor-less(EL-cap-less)technique has been attracting more and more interests in these years.The EL-cap-less single-phase to three-phase inverter(STI)with front-end diode rectifier is applied to ho...The electrolytic-capacitor-less(EL-cap-less)technique has been attracting more and more interests in these years.The EL-cap-less single-phase to three-phase inverter(STI)with front-end diode rectifier is applied to home electrical appliances.In EL-cap-less systems,film-type capacitor is used to suppress the high-frequency ripple components instead of smoothing the DC-link voltage.By using the EL-cap-less solution,reliability can be improved,lifetime can be increased and high power factor(PF)also can be realized.The EL-cap-less STI brings the opportunity to simplify system structure and lower cost.Because a certain DC-link capacitance is still required,the real PF is limited.To further improve the PF,the ripple components of current references are made in synchronous with the DClink voltage.And the capacitance chosen guideline of the film-type capacitor also be presented.A prototype is built to verify its real performance.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
文摘To avoid stray current and maintain the benefit of no phase-split in the DC traction power supply system, an AC traction power supply system was proposed for the urban public transport such as metro and light rail transit. The proposed system consists of a main substation （MSS） and cable traction network （CTN）. The MSS includes a single-phase main traction transformer and a negative-se- quence compensation device, while the CTN includes double-core cables, traction transformers, overhead catenary system, rails, etc. Several key techniques for the proposed system were put forward and discussed, which can be summarized as （1） the power supply principle, equivalent circuit and transmission ability of the CTN, the cable-catenary matching technique, and the selection of catenary voltage level; （2） the segmentation technology and status identification method for traction power supply network, distributed and centralized protection schemes, etc.; （3） a power supply scheme for single-line MSS and a power supply scheme of MSS shared by two or more lines. The proposed industrial frequency single-phase AC traction power supply system shows an excellent technical performance, good economy, and high reliability, hence provides a new alternative for metro and urban rail transit power supply systems.
文摘The HC-55 single-phase AC series-excitation commutator motor exported to Japan by the Linquan Motor Factory is an open-type motor characterized by simple structure, small volume, high rotary speed, large starting torque, reliable operation and easy installation. It can be used as a driving component for various kinds of household electrical appliances, such as electric mills, pulverlizers, small stirrers, vacuum cleaners and electric hair dryers, an ideal product for electrical equipment.
文摘This paper discusses a novel boost single-phase active AC-DC converters, named low-end semi-controlled bridge AC-DC converter. By analysis, its topology and principle can be derived from the conventional single-phase power factor corrector （ PFC）. But it has also some differences, such as power device positions, inductor type, input voltage waveform detection and induction current detection, so its design is also different. The converter is implemented by employing two current detection approaches, i.e., current transformer detection and shunt resistor detection. Consequently, it can provide a steady DC output voltage with a low voltage ripple, approximately unitary input power factor and 2.5 kW output power. The experimental results show validity of the theoretical analysis.
文摘A novel topology of Integrated Boost-SEPIC (IBS) AC-DC converter using common part sharing method (CPSM) has been proposed in this paper. Conventional boost converters with bridge rectifier configuration are inefficient due to limited voltage step-up ratio which may not be applicable for high step-up applications as in the case of micro generators. The proposed IBS topology is based on the common part sharing method capable of operating both for positive and negative half cycle of the input signal. Result and simulation were conducted using PSIM environment. The proposed AC-DC IBS topology eliminates the requirement of bridge rectifier achieving high efficiency (about 99%), improved power factor (0.75, leading) and lower THD (about 38.8%) which is within IEEE standard.
文摘This paper presents a single-phase Z-source inverter as a power conditioning system for a single phase utility connected system. Z-source inverter is a single-stage topology that has buck-boost feature, which is possible because of additional shoot through state introduced in zero state of the conventional inverter pulse width modulation and provides desired output AC voltage. Small distributed generation （DG） system with alternate energy sources requires power conditioning units with low cost, high efficiency and tolerance to wide range of input voltage variation and has to perform various functions such as dc-ac conversion, system control and achieve power quality norms. To meet some of these requirements a two-loop control strategy for ac side control with grid current feedback with PI control and inner filter capacitor current feedback with proportional control and on dc side PID control for Z-source capacitor voltage regulation are employed, which gives good transient response also suppress load and source disturbances effectively. Theoretical analysis of proposed scheme is established and then simulation results are presented to validate proposed control strategy.
基金Project supported by National Natural Science Foundation of China(62075203,12304460)Zhejiang Provincial Natural Science Foundation of China(LQ23A040007)Basic Public Welfare Research Program of Zhejiang Province(LDT23F05013F05)。
文摘Due to the wide and adjustable emission range,Ce^(3+)is an indispensable luminous center for full spectrum lighting.However,it needs to be sintered at high temperature in a reducing atmosphere,resulting in difficulty to coexisting with other multivalent activated ions(such as Eu^(3+),Tm^(3+)),which greatly hinders the formation of full spectrum.In this study,a calcium vacancy enhanced self-reduction of Ce^(4+)is realized in CaNaSb_(2)O_(6)F(CNSOF)host under air atmosphere sintering,through which Ce^(3+),Tm^(3+)and Eu^(3+)coexisting in a single-phase full spectrum phosphor was prepared.Notably,the artificial introduction of a calcium vacancy was designed to verify this self-reduction mechanism.Moreover,the energy transfer kinetics among Tm^(3+),Ce^(3+)and Eu^(3+)were explored.Finally,combined with a 340 nm UV chip,a full spectrum phosphor-converted light-emitting diode(pc-LED)was fabricated,showing a broad emission range from 400 to 750 nm,Commission Internationale de I'Edairage(CIE)of(0.3485,0.3673),Ra of 92 and correlated color temperature(CCT)of 4933 K.Utilizing the variation in emission colors of this phosphor under different UV wavelengths,a dual encryption method combining point character code and fluorescent encryption technique is proposed.This work provides an effective path for Ce^(4+)self-reduction to apply in full spectrum pc-LED and information encryption.
基金supported by the Science and Technology Program of China Southern Power Grid(031800KC23120003).
文摘In contemporary medium-voltage distribution networks heavily penetrated by distributed energy resources(DERs),the harmonic components injected by power-electronic interfacing converters,together with the inherently intermittent output of renewable generation,distort the zero-sequence current and continuously reshape its frequency spectrum.As a result,single-line-to-ground(SLG)faults exhibit a pronounced,strongly non-stationary behaviour that varies with operating point,load mix and DER dispatch.Under such circumstances the performance of traditional rule-based algorithms—or methods that rely solely on steady-state frequency-domain indicators—degrades sharply,and they no longer satisfy the accuracy and universality required by practical protection systems.To overcome these shortcomings,the present study develops an SLG-fault identification scheme that transforms the zero-sequence currentwaveforminto two-dimensional image representations and processes themwith a convolutional neural network(CNN).First,the causes of sample-distribution imbalance are analysed in detail by considering different neutralgrounding configurations,fault-inception mechanisms and the statistical probability of fault occurrence on each phase.Building on these insights,a discriminator network incorporating a Convolutional Block Attention Module(CBAM)is designed to autonomously extract multi-layer spatial-spectral features,while Gradient-weighted Class Activation Mapping(Grad-CAM)is employed to visualise the contribution of every salient image region,thereby enhancing interpretability.A comprehensive simulation platform is subsequently established for a DER-rich distribution system encompassing several representative topologies,feeder lengths and DER penetration levels.Large numbers of realistic SLG-fault scenarios are generated—including noise and measurement uncertainty—and are used to train,validate and test the proposed model.Extensive simulation campaigns,corroborated by field measurements from an actual utility network,demonstrate that the proposed approach attains an SLG-fault identification accuracy approaching 100 percent and maintains robust performance under severe noise conditions,confirming its suitability for real-world engineering applications.
文摘In order to increase the stability of the Mongolia power system, a single-phase automatic reclosing device (SPAR) was introduced on double-circuit power lines built with a size of 330 kV, operating on a voltage of 220 kV and a length of 250 km. These overhead power lines (L-213, L-214) connect the 220/110/35 kV “Songino” substation with the “Mandal” substation and form system networks. This paper presents the challenges encountered when implementing single-phase automatic reclosing (SPAR) devices and compares the changes in power system parameters before and after SPAR deployment for a long 220 kV line. Simulations and analyses were carried out using DIgSILENT PowerFactory software, focusing on rotor angle stability, and the overall impact on the power system during short-circuit faults. The evaluation also utilized measurement data from the Wide Area Monitoring System (WAMS) to compare system behavior pre- and post-implementation of SPAR. The findings reveal that SPAR significantly enhances system reliability and stability, effectively mitigating the risk of oscillations and stability loss triggered by short circuits. This improvement contributes to a more resilient power system, reducing the potential for disturbances caused by faults.
基金Project supported by the National Natural Science Foundation of China(Grant No.51107016)the National Basic Research Program of China(Grant No.2013CB035605)the Postdoctoral Science Research Developmental Foundation of Heilongjiang Province,China(Grant No.LHB-Q12086)
文摘Complex dynamical phenomenon was studied in the single phase H-bridge inverter which was controlled by either a peak current or a valley current. The state functions and the discrete iterative map equations were established to analyze the dynamical phenomenon in the single phase H-bridge inverter. The dynamical characteristics of the single phase H- bridge inverter, such as time domain waveform diagram, bifurcation diagram, and folding map, were obtained by using the numerical calculation when the circuit parameters varied in specific range. Moreover, the simulation results were obtained by using the OrCAD-PSpice software to validate the numerical calculation. Both the numerical calculation and the circuit simulation show that the symmetrical dynamical phenomenon occurs in the single phase H-bridge inverter controlled by the peak current or the valley current.
文摘According to the characteristics of single-phase circuits and demand of using active filter for real-time detecting harmonic and reactive currents, a detecting method based on Fryze＇s power definition is proposed. The results of theoretical analysis and simula- tion show that the proposed method is effective in realtime detecting of instantaneous harmonic and reactive currents in single-phase circuits. When only detecting the total reactive currents, this method does not need a phase-locked loop circuit, and it also can be used in some special applications to provide different compensations on the ground of different requirements of electric network. Compared with the other methods based on the theory of instantaneous reactive power, this method is simple and easy to realize.
基金supported by the National Natural Science Foundation of China (Grant Nos.10625210,50609020 and 10902070)the Leading Academic Discipline Project of Shanghai Municipal Education Commission (Grant No.J50501)
文摘A single-phase lattice Boltzmann model with modified surface tension is developed in this paper to solve the problem of high-density-ratio free surface flow.The computational efficiency and accuracy are both enhanced.The restriction to the relaxation factor （which needs to be smaller than 1） is circumvented by the new surface tension algebra,due to its rational physical nature compared with the treatment of Xing,Buther and Yang in their paper （Comp.Mater.Sci.,2007,39（2）：282-290）.The proposed stable surface tension scheme is applied to simulate the free deformation of a square droplet with surface tension effect and the process of a droplet impinging on a liquid film.The numerical solution for free deformation of a droplet agrees well with thermodynamic principles,and also achieves high accuracy in comparison with Xing,et al.＇s model.Three typical impinging modes are successfully obtained with the new scheme,and another particular mode found by Wang and Chen is also successfully simulated.The evolutions of liquid crown agree well with the power law related to time.
基金supported by the Fundamental Research Funds for the Central Universities (No.NT2018011)the China Postdoctoral Science Foundation (No.2015M580424)
文摘The electrolytic-capacitor-less(EL-cap-less)technique has been attracting more and more interests in these years.The EL-cap-less single-phase to three-phase inverter(STI)with front-end diode rectifier is applied to home electrical appliances.In EL-cap-less systems,film-type capacitor is used to suppress the high-frequency ripple components instead of smoothing the DC-link voltage.By using the EL-cap-less solution,reliability can be improved,lifetime can be increased and high power factor(PF)also can be realized.The EL-cap-less STI brings the opportunity to simplify system structure and lower cost.Because a certain DC-link capacitance is still required,the real PF is limited.To further improve the PF,the ripple components of current references are made in synchronous with the DClink voltage.And the capacitance chosen guideline of the film-type capacitor also be presented.A prototype is built to verify its real performance.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
