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Research and Development Trend of Shape Control for Cold Rolling Strip 被引量:26
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作者 Dong-Cheng Wang Hong-Min Liu Jun Liu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第5期1248-1261,共14页
Shape is an important quality index of cold rolling strip. Up to now, many problems in the shape control domain have not been solved satisfactorily, and a review on the research progress in the shape control domain ca... Shape is an important quality index of cold rolling strip. Up to now, many problems in the shape control domain have not been solved satisfactorily, and a review on the research progress in the shape control domain can help to seek new breakthrough directions. In the past 10 years, researches and applications of shape control models, shape control means, shape detection technology, and shape con- trol system have achieved significant progress. In the aspect of shape control models, the researches in the past improve the accuracy, speed and robustness of the models. The intelligentization of shape control models should be strengthened in the future. In the aspect of the shape control means, the researches in the past focus on the roll opti- mization, mill type selection, process optimization, local strip shape control, edge drop control, and so on. In the future, more attention should be paid to the coordination control of both strip shape and other quality indexes, and the refinement of control objective should be strengthened. In the aspects of shape detection technology and shape control system, some new types of shape detection meters and shape control systems are developed and have successfully indus- trial applications. In the future, the standardization of shape detection technology and shape control system should be promoted to solve the problem of compatibility. In general,the four expected development trends of shape control for cold roiling strip in the future are intelligentization, coordi- nation, refinement, and standardization. The proposed research provides new breakthrough directions for improv- ing shape quality. 展开更多
关键词 Cold rolling strip - shape control Development trend Theory models shape detectioncontrol system
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Application of Smith Predictor Based on Single Neural Network in Cold Rolling Shape Control 被引量:15
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作者 WANG Yiqun SUN Fu +2 位作者 LIU Jian SUN Menghui XIE Yihan 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2009年第2期282-286,共5页
Flatness is one of the most important criterion factors to evaluate the quality of the steel strip.To improve the strip's flatness quality,the most frequently used methodology is to employ the closed-loop automati... Flatness is one of the most important criterion factors to evaluate the quality of the steel strip.To improve the strip's flatness quality,the most frequently used methodology is to employ the closed-loop automatic shape control system.However,in the shape control system,the shape-meter is always installed at the down way of the exit of the cold rolling mill and can not sense the changes of the strip flatness in the rolling gap directly.This kind of installation results in the delay of the feedback in the control system.Therefore,the stability and response performance of the system are strongly affected by the delay.At present,there is still no mature way to design controllers for systems with time delay.Although the conventional PID controller used in most practical applications has the capability to compensate the delay,the effect of the compensation is limited,especially for the systems with long time delay.Smith predictor,as a compensator for solving this problem,is now widely used in industry systems.However,the request of highly precise model of the system and the poor adaptive performance to the changes of related parameters limit the application of the Smith predictor in practice.In order to overcome the drawbacks of the Smith predictor,a new Smith predictor based on single neural network PID(SNN-PID)is proposed.Because the single neural network is employed into the Smith predictor to improve the controller's self-adaptability,the adaptive capability to the varying parameters of the system is improved.Meanwhile,for the purpose of solving the problems such as time-consuming and complicated calculation of the neural networks in real time,the learning coefficient of neural network is divided into several stages as usually done in expert control system.Therefore,the control system can obtain fast response due to the improved calculation speed of the neural networks.In order to validate the performance of the proposed controller,the experiment is conducted on the shape control system in a 300 mm four-high reversing cold rolling mill.The experimental results show that the SNN-PID with Smith predictor controller can effectively compensate the delay effects and achieve better control performance than the conventional PID controller. 展开更多
关键词 shape control time delay single neural network Smith predictor
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Simulation of type selection for 6-high cold tandem mill based on shape control ability 被引量:10
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作者 彭艳 刘宏民 王东城 《Journal of Central South University of Technology》 EI 2007年第2期278-284,共7页
A theoretical method for selecting strip rolling mill type that considered shape control ability was established using the figure alteration range that was worked by the alteration track of vector expressing strip'... A theoretical method for selecting strip rolling mill type that considered shape control ability was established using the figure alteration range that was worked by the alteration track of vector expressing strip's cross section (crown) to express the shape control ability of rolling mill. With the mathematical models and simulation software that were developed by the authors' own models, four types of mills were aimed, including HCM (6-high middle rolls shift type HC (high crown) -mill), HCMW (6-high middle rolls and work rolls shift type HC-mill), UCM (6-high middle rolls shift type HC-mill with middle roll bender) and UCMW (6-high middle rolls and work rolls shift type HC-mill with middle roll bender), and the shape and crown control ability of every mill type was analyzed and compared. An appropriate arrangement mode of tandem mill was brought forward. The results show that UCMW mill is a perfect choice for controlling shape and crown, and the area of control characteristics curve of UCMW (or UCM) is twice than that of HCM, but UCM mill is also a good choice for its simple frame. In other word, the shape and crown controlling ability of UCMW mill is better than that of UCM mill, but the frame of UCM mill is simpler than that of UCMW mill. As for the final type of mill, should be synthetically decided by thinking over fund and equipment technology. 展开更多
关键词 6-high mill mill type selection shape control CROWN SIMULATION
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Shape control of spacecraft formation using a virtual spring-damper mesh 被引量:4
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作者 Chen Qifeng Meng Yunhe Xing Jianjun 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2016年第6期1730-1739,共10页
This paper derives a distance-based formation control method to maintain the desired formation shape for spacecraft in a gravitational potential field. The method is an analogy of a virtual spring-damper mesh. Spacecr... This paper derives a distance-based formation control method to maintain the desired formation shape for spacecraft in a gravitational potential field. The method is an analogy of a virtual spring-damper mesh. Spacecraft are connected virtually by spring-damper pairs. Convergence analysis is performed using the energy method. Approximate expressions for the distance errors and control accelerations at steady state are derived by using algebraic graph representations and results of graph rigidity. Analytical results indicate that if the underlying graph of the mesh is rigid, the convergence to a static shape is assured, and higher formation control precision can be achieved by increasing the elastic coefficient without increasing the control accelerations. A numerical example of spacecraft formation in low Earth orbit confirms the theoretical analysis and shows that the desired formation shape can be well achieved using the presented method, whereas the orientation of the formation can be kept pointing to the center of the Earth by the gravity gradient. The method is decentralized, and uses only relative measurement information. Constructing a distributed virtual structure in space can be the general application area. The proposed method can serve as an active shape control law for the spacecraft formations using propellantless internal forces. 展开更多
关键词 Formation shape control Graph rigidity Internal forces PD control Spacecraft formation flying Spacecraft guidance and control Spring-damper mesh
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Experimental Study on Characteristics of NiMnGa Magnetically Controlled Shape Memory Alloy 被引量:8
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作者 Fengxiang WANG Wenjun LI Qingxin ZHANG Chenxi LI Xinjie WU 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2006年第1期55-58,共4页
The static and dynamic magnetic controlling characteristics of NiMnGa magnetically controlled shape memory alloy (MSMA) were experimentally studied. The results show that the characteristics of induced strain with r... The static and dynamic magnetic controlling characteristics of NiMnGa magnetically controlled shape memory alloy (MSMA) were experimentally studied. The results show that the characteristics of induced strain with respect to the magnetic field are nonlinear with saturation nature, and dependent on the temperature as well as the load applied to the MSMA. The magnetic shape memory effect can be observed only in complete martensite phase at room temperature. The magnetic permeability of MSMA is not constant and reduces with the increment of magnetic field. The relative saturation magnetic permeability of MSMA is about 1.5. 展开更多
关键词 NIMNGA Magnetically controlled shape memory alloy CHARACTERISTICS Experimental study
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Head and Tail Shape Control in Vertical-Horizontal Rolling Process by FEM 被引量:3
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作者 ZANG Xin-liang LI Xue-tong DU Feng-shan 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2009年第5期35-42,共8页
Using 3D rigid-plastic finite element method (FEM), a numerical simulation model for nonsteady state vertical-horizontal rolling process in roughing trains was built and was validated by comparing the simulated valu... Using 3D rigid-plastic finite element method (FEM), a numerical simulation model for nonsteady state vertical-horizontal rolling process in roughing trains was built and was validated by comparing the simulated values with experimental ones of width and shape of the stock ends. According to certain 2050 roughing processing technologies, the short shape control (SSC) of the stock ends was investigated using the model. Based on the simulated results, a new SSC model was developed. The analyzed results showed that the new SSC model is effective in improving the shape of the stock ends. 展开更多
关键词 hot rolling FEM simulation edging shape control
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Collaborative force and shape control for large composite fuselage panels assembly 被引量:5
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作者 Zhanghao WANG Dongsheng LI +2 位作者 Liheng SHEN Yi SUI Yunong ZHAI 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第7期213-225,共13页
This study proposed a force and shape collaborative control method that combined method of influence coefficients(MIC)and the elitist nondominated sorting genetic algorithm(NSGA-II)to reduce the shape deviation caused... This study proposed a force and shape collaborative control method that combined method of influence coefficients(MIC)and the elitist nondominated sorting genetic algorithm(NSGA-II)to reduce the shape deviation caused by manufacturing errors,gravity deformation,and fixturing errors and improve the shape accuracy of the assembled large composite fuselage panel.This study used a multi-point flexible assembly system driven by hexapod parallel robots.The proposed method simultaneously considers the shape deviation and assembly load of the panel.First,a multi-point flexible assembly system driven by hexapod parallel robots was introduced,with the relevant variables defined in the control process.In addition,the corresponding mathematical model was constructed.Subsequently,MIC was used to establish the prediction models between the displacements of actuators and displacements of panel shape control points,deformation loads applied by the actuators.Following the modeling,the shape deviation of the panel and the assembly load were used as the optimization objectives,and the displacements of actuators were optimized using NSGA-II.Finally,a typical composite fuselage panel case study was considered to demonstrate the effectiveness of the proposed method. 展开更多
关键词 ASSEMBLY Collaborative force and shape control Composite panel Hexapod parallel robots Method of influence coefficients
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Shape control on probability density function in stochastic systems 被引量:5
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作者 Lingzhi Wang Fucai Qian Jun Liu 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2014年第1期144-149,共6页
A novel strategy of probability density function (PDF) shape control is proposed in stochastic systems. The control er is designed whose parameters are optimal y obtained through the improved particle swarm optimiza... A novel strategy of probability density function (PDF) shape control is proposed in stochastic systems. The control er is designed whose parameters are optimal y obtained through the improved particle swarm optimization algorithm. The parameters of the control er are viewed as the space position of a particle in particle swarm optimization algorithm and updated continual y until the control er makes the PDF of the state variable as close as possible to the expected PDF. The proposed PDF shape control technique is compared with the equivalent linearization technique through simulation experiments. The results show the superiority and the effectiveness of the proposed method. The control er is excellent in making the state PDF fol ow the expected PDF and has the very smal error between the state PDF and the expected PDF, solving the control problem of the PDF shape in stochastic systems effectively. 展开更多
关键词 stochastic systems probability density function (PDF) shape control improved particle swarm optimization.
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Shape control technology during electrochemical synthesis of gold nanoparticles 被引量:2
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作者 Xiu-yu Liu Cong-ying Cui +2 位作者 Ying-wen Cheng Hou-yi Ma Duo Liu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2013年第5期486-492,共7页
Gold nanoparticles with different shapes and sizes were prepared by adding gold precursor (HAuC14) to an electrolyzed aqueous solution of poly(N-vinylpyrrolidone) (PVP) and KN03, which indicates the good reducin... Gold nanoparticles with different shapes and sizes were prepared by adding gold precursor (HAuC14) to an electrolyzed aqueous solution of poly(N-vinylpyrrolidone) (PVP) and KN03, which indicates the good reducing capacity of the PVP-containing solution after being treated by electrolysis. Using a catholyte and an anolyte as the reducing agents for HAuC14,' respectively, most gold nanoparticles were spherical particles in the former case but plate-like particles in the latter case. The change in the pH value of electrolytes caused by the electrolysis of water would be the origin of the differences in shape and morphology of gold nanoparticles. A hypothesis of the H+ or OH- catalyzed PVP degradation mechanism was proposed to interpret why the pH value played a key role in determining the shape or morphology of gold nanoparticles. These experiments open up a new method for effectively controlling the shape and morphology of metal nanoparticles by using electrochemical methods. 展开更多
关键词 metal nanopaxticles SYNTHESIS GOLD shape control electrochemical methods
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Adaptive Shape Control for Thermal Deformation of Membrane Mirror with In-plane PVDF Actuators 被引量:2
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作者 Yi-Fan Lu Hong-Hao Yue +1 位作者 Zong-Quan Deng Horn-Sen Tzou 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2018年第1期187-197,共11页
Optical membrane mirrors are promising key components for future space telescopes. Due to their ultra-thin and high flexible properties, the surfaces of these membrane mirrors are susceptible to temperature variations... Optical membrane mirrors are promising key components for future space telescopes. Due to their ultra-thin and high flexible properties, the surfaces of these membrane mirrors are susceptible to temperature variations. Therefore adaptive shape control of the mirror is essential to maintain the surface precision and to ensure its working performance. However, researches on modeling and control of membrane mirrors under thermal loads are sparse in open literatures. A 0.2 m diameter scale model of a polyimide membrane mirror is developed in this study. Three Polyvinylidene fluoride(PVDF) patches are laminated on the non-reflective side of the membrane mirror to serve as in-plane actuators. A new mathematical model of the piezoelectric actuated membrane mirror in multiple fields,(i.e., thermal,mechanical, and electrical field) is established, with which dynamic and static behaviors of the mirror can be analyzed.A closed-loop membrane mirror shape control system is set up and a surface shape control method based on an influence function matrix of the mirror is then investigated. Several experiments including surface displacement tracking and thermal deformation alleviation are performed. The deviations range from 15 μm to 20 μm are eliminated within 0.1 s and the residual deformation is controlled to micron level, which demonstrates the effectiveness of the proposed membrane shape control strategy and shows a satisfactory real-time performance. The proposed research provides a technological support and instruction for shape control of optical membrane mirrors. 展开更多
关键词 Adaptive shape control Membrane mirror Thermal deformation PVDF Influence function matrix
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Technique of Probability Density Function Shape Control for Nonlinear Stochastic Systems 被引量:3
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作者 王玲芝 钱富才 《Journal of Shanghai Jiaotong university(Science)》 EI 2015年第2期129-134,共6页
The shape control of probability density function(PDF) of the system state is an important topic in stochastic systems. In this paper, we propose a control technique for PDF shape of the state variable in nonlinear st... The shape control of probability density function(PDF) of the system state is an important topic in stochastic systems. In this paper, we propose a control technique for PDF shape of the state variable in nonlinear stochastic systems. Firstly, we derive and prove the form of the controller by investigating the Fokker-PlanckKolmogorov(FPK) equation arising from the stochastic system. Secondly, an approach for getting approximate solution of the FPK equation is provided. A special function including some parameters is taken as the approximate stationary solution of the FPK equation. We use nonlinear least square method to solve the parameters in the function, and capture the approximate solution of the FPK equation. Substituting the approximate solution into the form of the controller, we can acquire the PDF shape controller. Lastly, some example simulations are conducted to verify the algorithm. 展开更多
关键词 nonlinear stochastic systems probability density function(PDF) shape control Fokker-PlanckKolmogorov(FPK) equation
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Advances in Compact Manufacturing for Shape and Performance Controllability of Large-scale Components-A Review 被引量:4
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作者 QIN Fangcheng LI Yongtang +1 位作者 QI Huiping JU Li 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第1期7-21,共15页
Research on compact manufacturing technology for shape and performance controllability of metallic components can reanze the simplification and high-reliability of manufacturing process on the premise of satisfying th... Research on compact manufacturing technology for shape and performance controllability of metallic components can reanze the simplification and high-reliability of manufacturing process on the premise of satisfying the requirement of macro/micro-structure. It is not only the key paths in improving performance, saving material and energy, and green manufacturing of components used in major equipments, but also the challenging subjects in frontiers of advanced plastic forming. To provide a novel horizon for the manufacturing in the critical components is significant. Focused on the high-performance large-scale components such as bearing rings, flanges, railway wheels, thick-walled pipes, etc, the conventional processes and their developing situations are summarized. The existing problems including multi-pass heating, wasting material and energy, high cost and high-emission are discussed, and the present study unable to meet the manufacturing in high-quality components is also pointed out. Thus, the new techniques related to casting-rolling compound precise forming of rings, compact manufacturing for duplex-metal composite rings, compact manufacturing for railway wheels, and casting-extruding continuous forming of thick-walled pipes are introduced in detail, respectively. The corresponding research contents, such as casting ring blank, hot ring rolling, near solid-state pressure forming, hot extruding, are elaborated. Some findings in through-thickness microstructure evolution and mechanical properties are also presented. The components produced by the new techniques are mainly characterized by fine and homogeneous grains. Moreover, the possible directions for fin'ther development of those techniques are suggested. Finally, the key scientific problems are first proposed. All of these results and conclusions have reference value and guiding significance for the integrated control of shape and performance in advanced compact manufacturing. 展开更多
关键词 compact manufacturing shape and performance controllability HIGH-PERFORMANCE ring parts thick-walled pipes
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Fuzzy Shape Control Based on El man Dynamic Recursion Network Prediction Model 被引量:2
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作者 JIA Chun-yu LIU Hong-min 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2006年第1期31-35,共5页
In the strip rolling process, shape control system possesses the characteristics of nonlinearity, strong coupling, time delay and time variation. Based on self adapting Elman dynamic recursion network prediction model... In the strip rolling process, shape control system possesses the characteristics of nonlinearity, strong coupling, time delay and time variation. Based on self adapting Elman dynamic recursion network prediction model, the fuzzy control method was used to control the shape on four-high cold mill. The simulation results showed that the system can be applied to real time on line control of the shape. 展开更多
关键词 shape prediction shape control Elman dynamic recursion network parameter self-adjusting fuzzy control
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Control Strategies of Asymmetric Strip Shape in Six-High Cold Rolling Mill 被引量:5
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作者 ZHANG Yun YANG Quan WANG Xiao-chen 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2011年第9期27-32,共6页
It is a complicated problem for cold-rolled strip to improve asymmetric strip shape in strip production. A roll system and strip coupled model of six-high cold rolling mill was established with finite element method t... It is a complicated problem for cold-rolled strip to improve asymmetric strip shape in strip production. A roll system and strip coupled model of six-high cold rolling mill was established with finite element method to estimate the effect of intermediate roll shifting, tilting, symmetric and asymmetric bending technologies on strip profile. To reduce asymmetric defects of strip shape as much as possible, some control strategies were proposed, including tilting and asymmetric bending of intermediate roll and work roll. The combinations of these three control strategies can effectively eliminate asymmetric strip shape defects. Finally, the closed-loop control model of asymmetric flat- ness at the last stand was given, and the flatness control system with the function of asymmetric strip shape control was also designed for cold tandem mill. 展开更多
关键词 cold rolling monitoring characteristics asymmetric strip shape control strategy
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Fabrication of Shape-Controlled Au Nanoparticles in a TiO_2-Containing Mesoporous Template Using UV Irradiation and Their Shape-Dependent Photocatalysis 被引量:1
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作者 Teruhisa Okuno Go Kawamura +1 位作者 Hiroyuki Muto Atsunori Matsuda 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2014年第1期8-12,共5页
A SiO2-TiO2 template with ordered tubular mesochannels has been prepared by the sol-gel method. Au nanorods are deposited in the tubular mesochannels of the SiO2-TiO2 template, and the shape of Au is changed from nano... A SiO2-TiO2 template with ordered tubular mesochannels has been prepared by the sol-gel method. Au nanorods are deposited in the tubular mesochannels of the SiO2-TiO2 template, and the shape of Au is changed from nanorods to nanospheres by ultraviolet irradiation during thermal deposition. The photocatalytic activity of mesoporous SiO2-TiO2 with/without Au nanorods/nanospheres is evaluated. Deposition of Au in the mesoporous SiO2-TiO2 template enhances the photocatalysis of TiO2. Interestingly, the sample containing Au nanorods exhibits higher photocatalytic activity than that with Au nanospheres. Photocatalysis by exciting surface plasmon resonance is not detected in the composite samples regardless of the shape of the deposited Au nanoparticles. 展开更多
关键词 MESOPOROUS TITANIA GOLD shape control PHOTOCATALYSIS Surface plasmon resonance
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Plate Shape Control Theory and Experiment for 20-high Mill 被引量:6
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作者 Zheng-wen YUAN Hong XIAO 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2015年第11期996-1001,共6页
Roll flattening theory is an important part of plate shape control theories for 20-high mill. In order to improve the accuracy of roll flattening calculation for 20-high mill, a new and more accurate roll flattening m... Roll flattening theory is an important part of plate shape control theories for 20-high mill. In order to improve the accuracy of roll flattening calculation for 20-high mill, a new and more accurate roll flattening model was proposed. In this model, the roll barrel was considered as a finite length semi-infinite body. Based on the boundary integral equation method, the numerical solution of the finite length semi-infinite body under the distributed force was obtained and an accurate roll flattening model was established. Coupled with roll bending model and strip plastic deformation, a new and more accurate plate control model for 20-high mill was established. Moreover, the effects of the first intermediate roll taper angle and taper length were analyzed. The tension distribution calculated by analytical model was consistent with the experimental results. 展开更多
关键词 20-high mill roll flattening finite length semi-infinite body boundary integral equation method plate shape control
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A Fuzzy Shape Control Method for Stainless Steel Strip on Sendzimir Rolling Mill 被引量:1
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作者 HUR Yone-gi CHOI Young-kiu 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2011年第3期17-23,共7页
The strip shape in the stainless steel process has made an issue of the strip quality.The objective of the shape control is to minimize the shape deviation and to maintain symmetrical shape patterns in the lateral dir... The strip shape in the stainless steel process has made an issue of the strip quality.The objective of the shape control is to minimize the shape deviation and to maintain symmetrical shape patterns in the lateral direction.The method of the shape recognition employs the least square method.The shape deviation is controlled by the fuzzy shape controller(FSC).The experiments have been performed online for various stainless materials,thicknesses,and strip widths.The test results show very efficient performances in respect of stable target tracking and symmetrical and minimal fluctuation of the strip shape. 展开更多
关键词 shape control fuzzy control stainless steel Sendzimir mill
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STATIC SHAPE CONTROL OF LAMINATED PLATE CONTAINING PIEZOELECTRIC PATCHES 被引量:1
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作者 Lin Xiqiang Ren Junguo 《Acta Mechanica Solida Sinica》 SCIE EI 1998年第2期113-122,共10页
By applying the Heaviside function, the equations governinglaminated plates possess- ing spatially distributed piezoelectricpatches have been established. Based on these equations, static shapecontrol of laminated pla... By applying the Heaviside function, the equations governinglaminated plates possess- ing spatially distributed piezoelectricpatches have been established. Based on these equations, static shapecontrol of laminated plates is discussed. BY using a genetic andcollocation algorithm, the opti- mal locations and scales of thesepiezoelectric patches have been selected. Numerical examples are pre-sented to illustrate the efficiency of the algorithm and thepiezoelectric actuators. 展开更多
关键词 laminated plate piezoelectric material shape control
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Shape-controlled synthesis of nanocubic Co_3O_4 by hydrothermal oxidation method 被引量:1
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作者 杨幼平 黄可龙 +3 位作者 刘人生 王丽平 曾雯雯 张平民 《中国有色金属学会会刊:英文版》 EI CSCD 2007年第5期1082-1086,共5页
The nanocubic Co3O4 was synthesized by hydrothermal oxidation method. The effects of cobalt salt, precipitating agent, surfactant, solvent, pH value of the suspension and the amount of oxidant H2O2 on the morphology a... The nanocubic Co3O4 was synthesized by hydrothermal oxidation method. The effects of cobalt salt, precipitating agent, surfactant, solvent, pH value of the suspension and the amount of oxidant H2O2 on the morphology and structure of Co3O4 were investigated. The Co3O4 powders were characterized by transmission electron microscope and X-ray diffraction. The results show that the morphology of Co3O4 is closely dependant on the anion in cobalt salts, but it is not so sensitive to the precipitating agents and solvents. The amount of H2O2 is the key factor to obtain Co3O4 with spinel crystal structure. The optimum synthetic conditions of uniform shape-controlled Co3O4 nanocubes are as follows: Co(CH3COO)2·4H2O as cobalt salt, KOH as precipitating agent, polyethylene glycol with relative molecular mass of about 20 000 as surfactant, water-n-butanol as solvent system, pH value of 8-9, the molar ratio of H2O2 to Co2+ above 2.5∶1.0, hydrothermal temperature of 160 ℃ and hydrothermal holding time of 10 h. The tap density and apparent density of nanocubic Co3O4 obtained with the average particle size of 20 nm are 1.01 g/cm3 and 0.70 g/cm3, respectively. 展开更多
关键词 CO3O4 水热氧化 金属复合物 处理技术
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One-step Synthesis of Shape-controllable Gold Nanoparticles and Their Application in Surface-enhanced Raman Scattering 被引量:1
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作者 Lanlan Sun Dongxu Zhao +4 位作者 Meng Ding Haifeng Zhao Zhenzhong Zhang Binghui Li Dezhen Shen 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2013年第7期613-618,共6页
Gold nanoparticles (NPs) of various shapes were synthesized by a one-step method at ambient temperature in the presence of NaCl. 2-mercaptosuccinic acid (MSA) was used as both reducing agent and stabilizing agent.... Gold nanoparticles (NPs) of various shapes were synthesized by a one-step method at ambient temperature in the presence of NaCl. 2-mercaptosuccinic acid (MSA) was used as both reducing agent and stabilizing agent. The shapes of gold NPs were controllable by simply tuning S/Au ratio (S is from MSA molecule, and S/Au ratio is controlled by tuning the volume of added MSA solution), and triangle, polygonal and spherical nanoparticles were obtained. This result suggested a new way to consider the effects of MSA on the growth of nanoparticles, which showed that MSA is a strong capping agent and facilitates more uniform growth of nanoparticles in every dimension. And other important factors on nanoparticles growth including NaCl and temperature were discussed. Furthermore, a typical probe molecule, 4-aminothiophenol (4-ATP) was used to test the surface-enhanced Raman scattering (SERS) activity of these gold NPs and the results indicated good Raman activity on these substrates. And the enhancement factor (EF) at 1078 cm^- 1 (a1) was estimated to be as large as 6.3 × 10^4 and 5.5 × 10^4 for triangular plates and truncated particles, respectively. 展开更多
关键词 NANOPARTICLE shape controlled synthesis Surface-enhanced Raman scattering (SERS)
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