To elucidate the intrinsic reaction mechanism of cementitious materials composed of red mud and coal gangue（RGC）, the hydration kinetics of these cementitious materials at 20°C was investigated on the basis of ...To elucidate the intrinsic reaction mechanism of cementitious materials composed of red mud and coal gangue（RGC）, the hydration kinetics of these cementitious materials at 20°C was investigated on the basis of the Krstulovi？-Dabi？ model. An isothermal calorimeter was used to characterize the hydration heat evolution. The results show that the hydration of RGC is controlled by the processes of nucleation and crystal growth（NG）, interaction at phase boundaries（I）, and diffusion（D） in order, and the pozzolanic reactions of slag and compound-activated red mud-coal gangue are mainly controlled by the I process. Slag accelerates the clinker hydration during NG process, whereas the compound-activated red mud-coal gangue retards the hydration of RGC and the time required for I process increases with increasing dosage of red mud-coal gangue in RGC.展开更多
Red mud-fly ash based cementitious material mixed with different contents of oil shale calcined at 700 ℃ is investigated in this paper. The effect of active Si and A1 content on the solidification of Na＋ during the ...Red mud-fly ash based cementitious material mixed with different contents of oil shale calcined at 700 ℃ is investigated in this paper. The effect of active Si and A1 content on the solidification of Na＋ during the hydration process is determined by using X-ray diffraction （XRD）, 27A1 and 29Si magic-angle-spinning nuclear magnetic resonance （MAS-NMR）, infrared （IR）, scanning electronic microscopy （SEM） and X-ray photoelectron spectroscopy （XPS）. It is shown that the content of oil shale has a remarkable effect on the solidified content of Na＋. The hydration process generates a highly reactive intermediate gel phase formed by co-polymerisation of individual alumina and silicate species. This kind of gel is primarily considered as 3D framework of Si04 and A104 tetrahedra interlinked by the shared oxygen atoms randomly. The negative charges and four-coordinated A1 inside the network are mainly charge-balanced by Na＋. The solidifying mechanism of Na＋ is greatly attributed to the forming of this kind of gel.展开更多
The interaction of Si anions with Al sites during the hydration process was observed by NMR, IR and SEM to understand the reaction mechanism of the hydrates formation mixed with oil shale calcined at different tempera...The interaction of Si anions with Al sites during the hydration process was observed by NMR, IR and SEM to understand the reaction mechanism of the hydrates formation mixed with oil shale calcined at different temperatures. As the reaction progressed, the coordination of Al （Ⅳ, Ⅴ, and Ⅵ） changed almost completely to Ⅳ, when mixed with oil shale calcined at 700 ℃. However, when mixed with oil shale calcined at 400 ℃, some 6-coordination of Al still remained in the hydrates. Under the function of alkaline solutions, which were produced with the hydration of clinker, a certain amount of Si and Al atoms dissolved or hydrolyzed from aluminosilicate, formed geomonomers in solutions, and then polycondensed to form networks.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.51302012 and 51234008)the China Postdoctoral Science Foundation(No.2016M590046)
文摘To elucidate the intrinsic reaction mechanism of cementitious materials composed of red mud and coal gangue（RGC）, the hydration kinetics of these cementitious materials at 20°C was investigated on the basis of the Krstulovi？-Dabi？ model. An isothermal calorimeter was used to characterize the hydration heat evolution. The results show that the hydration of RGC is controlled by the processes of nucleation and crystal growth（NG）, interaction at phase boundaries（I）, and diffusion（D） in order, and the pozzolanic reactions of slag and compound-activated red mud-coal gangue are mainly controlled by the I process. Slag accelerates the clinker hydration during NG process, whereas the compound-activated red mud-coal gangue retards the hydration of RGC and the time required for I process increases with increasing dosage of red mud-coal gangue in RGC.
基金the National Natural Science Foundation of China(Nos.51034008 and 51104008)the China Postdoctoral Science Foundation Funded Project(No.20100480202)+1 种基金the Research Fund for the Doctoral Program of Higher Education of China(No.20100006120010)the Fundamental Research Funds for the Central Universities of China (No.FRF-TP-12-026A)
文摘Red mud-fly ash based cementitious material mixed with different contents of oil shale calcined at 700 ℃ is investigated in this paper. The effect of active Si and A1 content on the solidification of Na＋ during the hydration process is determined by using X-ray diffraction （XRD）, 27A1 and 29Si magic-angle-spinning nuclear magnetic resonance （MAS-NMR）, infrared （IR）, scanning electronic microscopy （SEM） and X-ray photoelectron spectroscopy （XPS）. It is shown that the content of oil shale has a remarkable effect on the solidified content of Na＋. The hydration process generates a highly reactive intermediate gel phase formed by co-polymerisation of individual alumina and silicate species. This kind of gel is primarily considered as 3D framework of Si04 and A104 tetrahedra interlinked by the shared oxygen atoms randomly. The negative charges and four-coordinated A1 inside the network are mainly charge-balanced by Na＋. The solidifying mechanism of Na＋ is greatly attributed to the forming of this kind of gel.
基金Supported by the National Science and Technology (2006BAE03A11)the National Natural Science Foundation of China(50674062)
文摘The interaction of Si anions with Al sites during the hydration process was observed by NMR, IR and SEM to understand the reaction mechanism of the hydrates formation mixed with oil shale calcined at different temperatures. As the reaction progressed, the coordination of Al （Ⅳ, Ⅴ, and Ⅵ） changed almost completely to Ⅳ, when mixed with oil shale calcined at 700 ℃. However, when mixed with oil shale calcined at 400 ℃, some 6-coordination of Al still remained in the hydrates. Under the function of alkaline solutions, which were produced with the hydration of clinker, a certain amount of Si and Al atoms dissolved or hydrolyzed from aluminosilicate, formed geomonomers in solutions, and then polycondensed to form networks.
