Pseudo-bulk heterojunction(BHJ)fabricated by sequential casting of donor and acceptor layers has been recently demonstrated as a superior structure to prepare organic solar cells(OSCs)with enhanced efficiency compared...Pseudo-bulk heterojunction(BHJ)fabricated by sequential casting of donor and acceptor layers has been recently demonstrated as a superior structure to prepare organic solar cells(OSCs)with enhanced efficiency compared to the conventional BHJ OSCs cast from a common solution of donors and acceptors.However,molecular diffusion and aggregation within the pseudo-BHJ layer bring great challenges to fully realize the advantage of pseudo-BHJ structure.Herein,a solution-incubated pre-aggregation strategy is employed to tune the nanoscale aggregates of non-fullerene acceptor(NFA)BTP-e C11 and N3 to substantially enhance device power-conversion efficiency(PCE).NFA pre-aggregates are incubated in solutions via aging or adding antisolvent,and then sequentially cast onto D18 fibrillar network,which then penetrate to form a pseudo-BHJ structure with appropriate domain sizes to ensure superior charge mobilities.While the conventional pseudo-BHJ OSCs obtain inferior PCEs below 17%compared with normal BHJ OSCs,NFA pre-aggregates help to achieve remarkable PCEs of 17.7%and 17.5%for D18/BTP-e C11 and D18/N3 pseudo-BHJ OSCs.This work demonstrates that the solution-incubated nanoscale pre-aggregation is an efficient approach to regulate molecular diffusion and aggregation to guarantee high performance pseudo-BHJ OSCs.展开更多
This paper presents the design of an ultra low-voltage (ULV) pseudo operational transconductance amplifier (P-OTA) that is able to operate with a single supply voltage as low as 0.4 V. The proposed circuit is based on...This paper presents the design of an ultra low-voltage (ULV) pseudo operational transconductance amplifier (P-OTA) that is able to operate with a single supply voltage as low as 0.4 V. The proposed circuit is based on the bulk-driven technique and use of cross-coupled self-cascode pairs that boosts the differential DC gain. The stability condition of this structure for the DC gain is considered by definition of two coefficients to cancel out a controllable percentage of the denominator. This expression for stability condition yield optimized value for the DC gain. Also, as the principle of operation of the proposed technique relies on matching conditions, Monte Carlo analyzes are considered to study of the behavior of the proposed circuit against mismatches. The designed P-OTA have a DC gain of 64 dB, 212 KHz unity gain bandwidth, 57phase margin that is loaded by 10 pF differential capacitive loads, while consume only 16 μW. Eventually, from the proposed P-OTA, a low-power Sample and Hold (S/H) circuit with sampling frequency of 10 KS/s has been designed and simulated. The correct functionality for this configuration is verified from –30℃ to 70℃. The simulated data presented is obtained using the HSPICE Environment and is valid for the 90 nm triple-well CMOS process.展开更多
基金supported by the National Natural Science Foundation of China(52073221,21774097)the Fundamental Research Funds for the Central Universities(WUT:2021III016JC,2020YB-004)of China。
文摘Pseudo-bulk heterojunction(BHJ)fabricated by sequential casting of donor and acceptor layers has been recently demonstrated as a superior structure to prepare organic solar cells(OSCs)with enhanced efficiency compared to the conventional BHJ OSCs cast from a common solution of donors and acceptors.However,molecular diffusion and aggregation within the pseudo-BHJ layer bring great challenges to fully realize the advantage of pseudo-BHJ structure.Herein,a solution-incubated pre-aggregation strategy is employed to tune the nanoscale aggregates of non-fullerene acceptor(NFA)BTP-e C11 and N3 to substantially enhance device power-conversion efficiency(PCE).NFA pre-aggregates are incubated in solutions via aging or adding antisolvent,and then sequentially cast onto D18 fibrillar network,which then penetrate to form a pseudo-BHJ structure with appropriate domain sizes to ensure superior charge mobilities.While the conventional pseudo-BHJ OSCs obtain inferior PCEs below 17%compared with normal BHJ OSCs,NFA pre-aggregates help to achieve remarkable PCEs of 17.7%and 17.5%for D18/BTP-e C11 and D18/N3 pseudo-BHJ OSCs.This work demonstrates that the solution-incubated nanoscale pre-aggregation is an efficient approach to regulate molecular diffusion and aggregation to guarantee high performance pseudo-BHJ OSCs.
文摘This paper presents the design of an ultra low-voltage (ULV) pseudo operational transconductance amplifier (P-OTA) that is able to operate with a single supply voltage as low as 0.4 V. The proposed circuit is based on the bulk-driven technique and use of cross-coupled self-cascode pairs that boosts the differential DC gain. The stability condition of this structure for the DC gain is considered by definition of two coefficients to cancel out a controllable percentage of the denominator. This expression for stability condition yield optimized value for the DC gain. Also, as the principle of operation of the proposed technique relies on matching conditions, Monte Carlo analyzes are considered to study of the behavior of the proposed circuit against mismatches. The designed P-OTA have a DC gain of 64 dB, 212 KHz unity gain bandwidth, 57phase margin that is loaded by 10 pF differential capacitive loads, while consume only 16 μW. Eventually, from the proposed P-OTA, a low-power Sample and Hold (S/H) circuit with sampling frequency of 10 KS/s has been designed and simulated. The correct functionality for this configuration is verified from –30℃ to 70℃. The simulated data presented is obtained using the HSPICE Environment and is valid for the 90 nm triple-well CMOS process.
