Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed.Mechanistic studies reveal that the rhodium aryl complex,(por)Rh...Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed.Mechanistic studies reveal that the rhodium aryl complex,(por)Rh-C_(6)F_(4)R,is the key intermediate.展开更多
基金supported by the National Science Foundation of China(21322108 and 21321001).
文摘Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed.Mechanistic studies reveal that the rhodium aryl complex,(por)Rh-C_(6)F_(4)R,is the key intermediate.
