Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium
摘要
Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed.Mechanistic studies reveal that the rhodium aryl complex,(por)Rh-C_(6)F_(4)R,is the key intermediate.
基金
supported by the National Science Foundation of China(21322108 and 21321001).
