Smart hydrogels are environmentally sensitive hydrogels, which can produce a sensitive response to external stimuli, and often exhibit the characteristics of multi filed coupling. In this paper, a hydrogel rod under c...Smart hydrogels are environmentally sensitive hydrogels, which can produce a sensitive response to external stimuli, and often exhibit the characteristics of multi filed coupling. In this paper, a hydrogel rod under chemomechanical coupling was analytically studied based on a poroelastical model. The already known constitutive and governing equations were simplified into the one dimensional case, then two different boundary conditions were considered. The expressions of concentration, displacement,chemical potential and stress related to time were obtained in a series form. Examples illustrate the interaction mechanism of chemical and mechanical effect. It was found that there was a balance state in the diffusion of concentration and the diffusion process could lead to the expansion or the stress change of the hydrogel rod.展开更多
The analytical structures and the corresponding mathematical properties of the one dimensional and two dimensional fuzzy controllers are first investigated in detail. The nature of these two kinds of fuzzy controllers...The analytical structures and the corresponding mathematical properties of the one dimensional and two dimensional fuzzy controllers are first investigated in detail. The nature of these two kinds of fuzzy controllers is next probed from the perspective of control engineering. For the one dimensional fuzzy controller, it is concluded that this controller is a combination of a saturation element and a nonlinear proportional controller, and the system that employs the one dimensional fuzzy controller is the combination of an open-loop control system and a closedloop control system. For the latter case, it is concluded that it is a hybrid controller, which comprises the saturation part, zero-output part, nonlinear derivative part, nonlinear proportional part, as well as nonlinear proportional-derivative part, and the two dimensional fuzzy controller-based control system is a loop-varying system with varying number of control loops.展开更多
This paper shows that for a supercritical contact process in one dimension, if the initial distribution satisfies reasonable hypothesis, then the first hitting time of certain set with anomalous small density is asymp...This paper shows that for a supercritical contact process in one dimension, if the initial distribution satisfies reasonable hypothesis, then the first hitting time of certain set with anomalous small density is asymptotically exponentially distributed. We also show the similar result for the contact process on the finite set [0, N].展开更多
Based on Marcuse’s thought of“one-dimensional person”,this paper discusses the influence of TV talent show on teenagers’socialization.By analyzing the characteristics of TV talent shows that emphasize individual c...Based on Marcuse’s thought of“one-dimensional person”,this paper discusses the influence of TV talent show on teenagers’socialization.By analyzing the characteristics of TV talent shows that emphasize individual competition and success,appearance and image,and instant satisfaction,it is pointed out that these characteristics are easy for teenagers to produce the mentality of pursuing fame and fortune,appearance,and instant satisfaction,ignoring the development of other important values and qualities.Therefore,we need to guide teenagers to maintain a critical attitude toward TV talent shows,and pay attention to cultivating their independent thinking and all-round development.展开更多
In this paper,we consider the one dimensional third order p-Laplacian equation(Фp(u″))′+h(t)f(t,u(t))=0 with integral boundary conditions u(0)-αu′(0)=∫_(0)^(1) g1(s)u(s)ds,u(1)+βu′(1)=∫_(0)^(1)g2(s)u(s)ds,u″...In this paper,we consider the one dimensional third order p-Laplacian equation(Фp(u″))′+h(t)f(t,u(t))=0 with integral boundary conditions u(0)-αu′(0)=∫_(0)^(1) g1(s)u(s)ds,u(1)+βu′(1)=∫_(0)^(1)g2(s)u(s)ds,u″(0)=0.By using kernel functions and the Avery-Peterson fixed point theorem,we establish the existence of at least three positive solutions.展开更多
1D europium coordination polymer wires were successfully prepared by reacting europium chloride with tributyl phosphate(TBP) at 160 oC for 12 h. The products were characterized by XRD,IR,TG,DTA,SEM,and EDS. SEM result...1D europium coordination polymer wires were successfully prepared by reacting europium chloride with tributyl phosphate(TBP) at 160 oC for 12 h. The products were characterized by XRD,IR,TG,DTA,SEM,and EDS. SEM results showed that the wires were with diameters ranging from several hundreds of nanometers to ～5 μm and lengths going up to several hundreds of micrometers. Influencing factors such as the dosage of reactants and reaction time on the preparation were systematically investigated. Strong emission centering at 590 nm was realized in the coordination polymer wires on excitation at 395 nm.展开更多
Cu-Zn-Al alloy of one dimensional nano-structure was prepared and thestructure of obtained nano-material was characterized by transmission electron microscope (TEM). Itwas shown that there are non-linear oscillations ...Cu-Zn-Al alloy of one dimensional nano-structure was prepared and thestructure of obtained nano-material was characterized by transmission electron microscope (TEM). Itwas shown that there are non-linear oscillations on the surface of Cu-Zn-Al alloy and theconsanguineous connection exists between non-linear oscillation and the growth process of onedimensional nano-structure. The diameter of one dimensional nano-structure is about 40 nm, and theratio of length to diameter is over 40. Finally, the growth mechanism of one dimensionalnano-structure was also studied.展开更多
A facile method is reported to controllably fabricate one dimensional （1D） polymer nan,astructures via metallogel template polymerization. The metallogel was prepared through coordination interactions between silver...A facile method is reported to controllably fabricate one dimensional （1D） polymer nan,astructures via metallogel template polymerization. The metallogel was prepared through coordination interactions between silver ions and a ligand （L） bearing three pyridyl groups in tetrahydrofuran （THF）. The diameters of the metallogel nanofibers could be tuned by the gel concentration （GC）. Due to its high thermal stability and facility of removal, the metallogel was used as the template for radical polymerization of diacryolyl-2,6-diaminopyridine （DADAP） to form poly-diacryolyl-2,6-diaminopyridine （PDADAP） nanostructures. The gradually eroding of the templates by PDADAP provided us an effective way to fabricate various nanostructures of the polymer. We have demonstrated that different 1D nanostructures, including n^noribbons, nanotubes and nanowires, could be selectively fabricated by adjusting polymerization time, monomer concentration and GC. The rheological properties of the gel samples were tested by a rheometer. As prolonging the reaction time, more and more polymers were formed and the strength of the resulting polymer gels became higher and higher. The simple preparation process, easy controlled microstructures and adequate gel strength would make it a facile synthetic method for different 1D polymer nanosturctures.展开更多
The reactions of 18 crown 6 with each of K 2(M=Zn, Hg; mnt=1,2 dicyanoethene 1,2 dithiolate, C 2S 2(CN) 2- 2) were studied and novel complexes [K(18 C 6)] 2[Zn(mnt) 2](1) and [K(18 C 6)] 2[Hg(mnt)...The reactions of 18 crown 6 with each of K 2(M=Zn, Hg; mnt=1,2 dicyanoethene 1,2 dithiolate, C 2S 2(CN) 2- 2) were studied and novel complexes [K(18 C 6)] 2[Zn(mnt) 2](1) and [K(18 C 6)] 2[Hg(mnt) 2](2) were characterized by elemental analysis, IR spectrum and X ray diffraction analysis. Complex 1 displays a one dimensional chain of [K(18 C 6)] 2[Zn(mnt) 2] bridged by K O interactions between adjacent [K(18 C 6)] + units. Complex 2 is also a one dimensional chain of [K(18 C 6)] 2[Hg(mnt) 2] bridged by K...S weak interactions between adjacent [K(18 C 6)] + and [Hg(mnt) 2] 2- .展开更多
The variation of effective stress ratio of stratfied soil with semi pervious boundaries and under cyclic loading was analyzed on the basis of Terzaghi's one dimensional consolidation assumptions. A solution by L...The variation of effective stress ratio of stratfied soil with semi pervious boundaries and under cyclic loading was analyzed on the basis of Terzaghi's one dimensional consolidation assumptions. A solution by Laplace Transform was obtained for the case when the soil was under time varied loading. With numerical inversion of Laplace Transform, some useful results were obtained for several kinds of commonly encountered loadings. The results can be meaningful in engineering practice.展开更多
The nitrogen-vacancy(NV)color center in diamond is a promising solid-state quantum system at room temperature.However,its sensitivity is limited by its low fluorescence collection efficiency,and its coherence time is ...The nitrogen-vacancy(NV)color center in diamond is a promising solid-state quantum system at room temperature.However,its sensitivity is limited by its low fluorescence collection efficiency,and its coherence time is limited by spin interference of impurity electrons around the NV color center.Here,we innovatively fabricated a one-dimensional photonic crystal on the surface of diamond,which greatly improved the fluorescence intensity of the NV color centers and increased the sensitivity of NV ensembles by a factor of 2.92.In addition,the laser reflected by the photonic crystal excites impurity electrons around the NV color centers,improving the electric field environment around the NV color centers,which exponentially prolongs the dephasing time(from 209 to841 ns),opening avenues for NV color-center ensemble sensors.展开更多
Two novel 18-crown-6-ether(18-C-6)directed one-dimensional silver(I)coordination polymers(1D Ag(I)CPs),formulated as{[(18-C-6)Ag(bpy)]⋅X}_(∞)and{[(18-C-6)Ag(pyz)]⋅X}_(∞){bpy=4,4′-bipyridine;pyz=pyrazine;X=BF_(4)^(...Two novel 18-crown-6-ether(18-C-6)directed one-dimensional silver(I)coordination polymers(1D Ag(I)CPs),formulated as{[(18-C-6)Ag(bpy)]⋅X}_(∞)and{[(18-C-6)Ag(pyz)]⋅X}_(∞){bpy=4,4′-bipyridine;pyz=pyrazine;X=BF_(4)^(-)(Ⅰa,Ⅱa),CF_(3)SO_(3)^(-)(Ⅰb,Ⅱb)},are prepared and structurally determined.The protection of the 18-C-6 macrocycle not only efficiently prevents intermolecular interactions within each 1D Ag(I)CP but also significantly enhances the rigidity of the chain structures,allowing these polymers to exhibit remarkable phosphorescence with intense green-light emission at room temperature.Moreover,Ⅱa and Ⅱb show enhanced photoluminescence quantum yields and aggregation-induced emission properties,which can be attributed to their close-packed structure modes in the crystalline states.Interestingly,upon mixing with commercial resin,Ⅱa can serve as an efficient and stable luminescent ink for 3D printing.The resulting printed structures demonstrate exceptional irradiation stability,retaining their luminescence properties without any quenching over a three-month period.This work not only provides a facile strategy to prepare luminescent 1D Ag(I)CPs but also shows the promise of their utilization in optical devices.展开更多
The solid solution formed by the combination of multiple cations has been extensively investigated due to its distinctive lattice distortion effect,which imparts unique electromagnetic properties.In particular,the reg...The solid solution formed by the combination of multiple cations has been extensively investigated due to its distinctive lattice distortion effect,which imparts unique electromagnetic properties.In particular,the regulation of dielectric and magnetic properties can be achieved through element selection.Herein,the stability of Ta_(x)Nb_(1-x)C was predicted through geometric optimization of crystal structure,and Ta_(x)Nb_(1-x)C nanowires were successfully synthesized through F-ion-assisted carbothermal reduction method.The introduction of bimetallic ions forms significant carbon defects and lattice distortion,which undoubtedly induces the formation of strong interface polarization and defect polarization,resulting in high dielectric loss.Furthermore,the significant presence of imperfections leads to a decrease in both the dielectric constant and conductivity,thereby achieving impedance balance.The design of a one-dimensional structure also facilitates the formation of conductive pathways,promoting carrier transitions.Benefiting from a variety of loss mechanisms and appropriate impedance matching,solid solution Ta_(x)Nb_(1-x)C shows excellent electromagnetic wave absorption(EWA)performance.This research presents a promising strategy for developing single-phase materials with excellent EWA performance.展开更多
Objective:We conducted a comprehensive physicochemical analysis of one-dimensional ZnO nanowires(1DZnO),incorporating anti-CYFRA 21-1 immobilization to promote fast optical biomarker detection up to 10 ng ml−1.Impact ...Objective:We conducted a comprehensive physicochemical analysis of one-dimensional ZnO nanowires(1DZnO),incorporating anti-CYFRA 21-1 immobilization to promote fast optical biomarker detection up to 10 ng ml−1.Impact Statement:This study highlights the effectiveness of proof-of-concept 1DZnO nanoplatforms for rapid cancer biomarker detection by examining the nanoscale integration of 1DZnO with these bioreceptors to deliver reliable photoluminescent output signals.Introduction:The urgent need for swift and accurate prognoses in healthcare settings drives the rise of sensitive biosensing nanoplatforms for cancer detection,which has benefited from biomarker identification.CYFRA 21-1 is a reliable target for the early prediction of cancer formation that can be perceptible in blood,saliva,and serum.However,1DZnO nanostructures have been barely applied for CYFRA 21-1 detection.Methods:We assessed the nanoscale interaction between 1DZnO and anti-CYFRA 21-1 antibodies to develop rapid CYFRA 21-1 detection in two distinct matrices:PhosphateBuffered Saline(PBS)buffer and artificial saliva.The chemical modifications were tracked utilizing Fourier transform infrared spectroscopy,while transmission electron microscopy and energy dispersive spectroscopy confirmed antigen-antibody interplay over nanostructures.Results:Our results show high antibody immobilization efficiencies,affirming the effectiveness of 1DZnO nanoplatforms for rapid CYFRA 21-1 testing within a 5-min detection window in both PBS and artificial saliva.Photoluminescence measurements also revealed distinct optical responses across biomarker concentrations ranging from 10 to 1,000 ng ml^(−1).Conclusion:Discernible PL signal responses obtained after 5 min affirm the potential of 1DZnO nanoplatforms for further advancement in optical biomarker detection for application in early cancer prognosis.展开更多
One-dimensional （1D） ZnO nanostructures have been studied intensively and extensively over the last decade not only for their remarkable chemical and physical properties, but also for their diverse current and futur...One-dimensional （1D） ZnO nanostructures have been studied intensively and extensively over the last decade not only for their remarkable chemical and physical properties, but also for their diverse current and future technological applications. This article gives a comprehensive overview of the progress that has been made within the context of 1D ZnO nanostructures synthesized via wet chemical methods. We will cover the synthetic methodologies and the corresponding growth mechanisms, various nanostructures grown, their doping and alloying, and position-controlled growth on substrates. Finally, we will review their functional properties in catalysis, hydrophobic surface modification, sensing, and electronic, optical, optoelectronic, and energy harvesting devices.展开更多
Nanocarbon-based materials, such as carbon nanotubes(CNTs) and graphene have been attached much attention by scientific and industrial community. As two representative nanocarbon materials, one-dimensional CNTs and tw...Nanocarbon-based materials, such as carbon nanotubes(CNTs) and graphene have been attached much attention by scientific and industrial community. As two representative nanocarbon materials, one-dimensional CNTs and twodimensional graphene both possess remarkable mechanical properties. In the past years, a large amount of work have been done by using CNTs or graphene as building blocks for constructing novel, macroscopic, mechanically strong fibrous materials. In this review, we summarize the assembly approaches of CNT-based fibers and graphene-based fibers in chronological order, respectively. The mechanical performances of these fibrous materials are compared, and the critical influences on the mechanical properties are discussed. Personal perspectives on the fabrication methods of CNT-and graphene-based fibers are further presented.展开更多
Ni-rich oxides,LiNixMnyCozO2(NMC),are among leading candidates for cathode materials in Li-ion batteries.However,they are mostly fabricated by coprecipitation approach under complex conditions,which usually produces l...Ni-rich oxides,LiNixMnyCozO2(NMC),are among leading candidates for cathode materials in Li-ion batteries.However,they are mostly fabricated by coprecipitation approach under complex conditions,which usually produces large secondary particles composed of aggregated primary particles.Undesirable cation mixing and crack propagation upon cycling block ion and electron transport,result in fast capacity fading and poor rate capability.Herein,we present an ultrasound-triggered cation chelation and reassembly route for synthesizing one-dimensional precursor with homogeneous element distribution at the atomic level.This process is accomplished by the synergistic combination of ultrasound and surfactant,which can disperse reactants and remove hydration shells surrounding cations so as to accelerate chelating reaction,and then separate and assemble chelates into one dimensional structure.The whole synthesis time is only 20 min(8.9 min of ultrasonic working time)in an open vessel under natural ambient conditions.One-dimensional LiNi0.6Mn0.2Co0.2O2 has a high reversible capacity(184 mAh·g^−1 at 0.1 C)and long cycling stability(95.1%and 82.4%capacity retention for 100 and 1000 cycles,respectively).The short charging time of 76 s is realized at super high current rate of 20 C,which is very important to improve the competitiveness of electric vehicles relative to fuel vehicles.Our synthetic approach can provide a general strategy for the growth of mixed-metal-EDTA chelate precursors by changing the feeding ratio of Ni2+,Mn2+and Co2+cations in reaction for fabricating NMC cathode materials with other compositions.展开更多
A photonic heterostructure with multi-channel and sharp angular defect modes by combining two different one-dimensional defective photonic crystals is proposed. The filters designed on the basis of this heterostructur...A photonic heterostructure with multi-channel and sharp angular defect modes by combining two different one-dimensional defective photonic crystals is proposed. The filters designed on the basis of this heterostructure possess both functions of multi-channel narrow band filtering and sharp angular filtering. The channels, channel interval, and number of channels can be tuned by adjusting the geometric and physical parameters of the heterostuctures. This kind of filters will benefit the development of multi-channel interstellar or atmosphere optical communication.展开更多
Band structures of one-dimensional （1D） photonic crystals （PCs） containing dispersive left-handed metamaterials are studied theoretically. The results show that the structure possesses a type of photonic band gap ...Band structures of one-dimensional （1D） photonic crystals （PCs） containing dispersive left-handed metamaterials are studied theoretically. The results show that the structure possesses a type of photonic band gap originating from total internal reflection （TIR）. In contrast to photonic band gaps corresponding to zero average refractive index and zero phase, the TIR gap exhibits sharp angular effect and has no polarization effect. It should also be noted that band structures of transverse electric （TE） and transverse magnetic （TM） mode waves are exactly the same in the PCs we studied.展开更多
Reactions of CuBr with equimolar PyHBr orγMePyHBr afforded two novel one dimensional bromocuprate?polymers{(PyH)_(3)[Cu_(3)Br_(6)]}_(∞)(1)and{(γMePyH)_(2)[Cu_(2)Br_(4)]}_(∞)(2),respectively.Both 1 and 2 were chara...Reactions of CuBr with equimolar PyHBr orγMePyHBr afforded two novel one dimensional bromocuprate?polymers{(PyH)_(3)[Cu_(3)Br_(6)]}_(∞)(1)and{(γMePyH)_(2)[Cu_(2)Br_(4)]}_(∞)(2),respectively.Both 1 and 2 were characterized by IR,elemental analysis,and X ray crystallography.Crystal data for 1:monoclinic,space group P2_(1)/n,a=0.93262(12)nm,b=1.3497(2)nm,c=1.9149(2)nm,β=93.465(7)°,V=2.4060(5)nm^(3),Z=4.Crystal data for 2:orthorhombic,space group Pbcm,a=0.8659(4)nm,b=1.5669(6)nm,c=1.2849(5)nm,V=1.7432(2)nm^(3),Z=4.The structure of 1 has a unique helical chain composed of units andμbromide anions while that of 2 shows a linear chain consisted of[Cu_(2)(μBr)_(2)]units bridged by pairs ofμBr atoms.CCDC:1,208412;2,208413.展开更多
基金financial supports from the National Natural Science Foundation of China (Grants 11472020, 11502007, and 11632005)Hong Kong Scholars Program (Grant XJ2016021)
文摘Smart hydrogels are environmentally sensitive hydrogels, which can produce a sensitive response to external stimuli, and often exhibit the characteristics of multi filed coupling. In this paper, a hydrogel rod under chemomechanical coupling was analytically studied based on a poroelastical model. The already known constitutive and governing equations were simplified into the one dimensional case, then two different boundary conditions were considered. The expressions of concentration, displacement,chemical potential and stress related to time were obtained in a series form. Examples illustrate the interaction mechanism of chemical and mechanical effect. It was found that there was a balance state in the diffusion of concentration and the diffusion process could lead to the expansion or the stress change of the hydrogel rod.
基金This project was supported by the fundation of the Academy of Finland (201353)
文摘The analytical structures and the corresponding mathematical properties of the one dimensional and two dimensional fuzzy controllers are first investigated in detail. The nature of these two kinds of fuzzy controllers is next probed from the perspective of control engineering. For the one dimensional fuzzy controller, it is concluded that this controller is a combination of a saturation element and a nonlinear proportional controller, and the system that employs the one dimensional fuzzy controller is the combination of an open-loop control system and a closedloop control system. For the latter case, it is concluded that it is a hybrid controller, which comprises the saturation part, zero-output part, nonlinear derivative part, nonlinear proportional part, as well as nonlinear proportional-derivative part, and the two dimensional fuzzy controller-based control system is a loop-varying system with varying number of control loops.
基金Supported in part by the National Natural Science Foundation of China.
文摘This paper shows that for a supercritical contact process in one dimension, if the initial distribution satisfies reasonable hypothesis, then the first hitting time of certain set with anomalous small density is asymptotically exponentially distributed. We also show the similar result for the contact process on the finite set [0, N].
文摘Based on Marcuse’s thought of“one-dimensional person”,this paper discusses the influence of TV talent show on teenagers’socialization.By analyzing the characteristics of TV talent shows that emphasize individual competition and success,appearance and image,and instant satisfaction,it is pointed out that these characteristics are easy for teenagers to produce the mentality of pursuing fame and fortune,appearance,and instant satisfaction,ignoring the development of other important values and qualities.Therefore,we need to guide teenagers to maintain a critical attitude toward TV talent shows,and pay attention to cultivating their independent thinking and all-round development.
基金supported by the National Natural Science Foundation of China(No.12071491)。
文摘In this paper,we consider the one dimensional third order p-Laplacian equation(Фp(u″))′+h(t)f(t,u(t))=0 with integral boundary conditions u(0)-αu′(0)=∫_(0)^(1) g1(s)u(s)ds,u(1)+βu′(1)=∫_(0)^(1)g2(s)u(s)ds,u″(0)=0.By using kernel functions and the Avery-Peterson fixed point theorem,we establish the existence of at least three positive solutions.
基金Project supported by the China Postdoctoral Science Foundation (20100470841)the Natural Science Foundation of Jiangxi Province (2009GQH0057)
文摘1D europium coordination polymer wires were successfully prepared by reacting europium chloride with tributyl phosphate(TBP) at 160 oC for 12 h. The products were characterized by XRD,IR,TG,DTA,SEM,and EDS. SEM results showed that the wires were with diameters ranging from several hundreds of nanometers to ～5 μm and lengths going up to several hundreds of micrometers. Influencing factors such as the dosage of reactants and reaction time on the preparation were systematically investigated. Strong emission centering at 590 nm was realized in the coordination polymer wires on excitation at 395 nm.
基金This work was financially supported by the National Climbing Programme of China (No. 1999-444)the Natural Science Foundation of Tianjin (No.003805611 and 033610611) the Center of Liuhui Application Mathematics of Nankai University and Tianjin Univers
文摘Cu-Zn-Al alloy of one dimensional nano-structure was prepared and thestructure of obtained nano-material was characterized by transmission electron microscope (TEM). Itwas shown that there are non-linear oscillations on the surface of Cu-Zn-Al alloy and theconsanguineous connection exists between non-linear oscillation and the growth process of onedimensional nano-structure. The diameter of one dimensional nano-structure is about 40 nm, and theratio of length to diameter is over 40. Finally, the growth mechanism of one dimensionalnano-structure was also studied.
基金financially supported by the National Natural Science Foundation of China(Nos.20874055 and 21174079)Hi-tech Research and Development Program(863 plan) of China(No.2009AA062903)
文摘A facile method is reported to controllably fabricate one dimensional （1D） polymer nan,astructures via metallogel template polymerization. The metallogel was prepared through coordination interactions between silver ions and a ligand （L） bearing three pyridyl groups in tetrahydrofuran （THF）. The diameters of the metallogel nanofibers could be tuned by the gel concentration （GC）. Due to its high thermal stability and facility of removal, the metallogel was used as the template for radical polymerization of diacryolyl-2,6-diaminopyridine （DADAP） to form poly-diacryolyl-2,6-diaminopyridine （PDADAP） nanostructures. The gradually eroding of the templates by PDADAP provided us an effective way to fabricate various nanostructures of the polymer. We have demonstrated that different 1D nanostructures, including n^noribbons, nanotubes and nanowires, could be selectively fabricated by adjusting polymerization time, monomer concentration and GC. The rheological properties of the gel samples were tested by a rheometer. As prolonging the reaction time, more and more polymers were formed and the strength of the resulting polymer gels became higher and higher. The simple preparation process, easy controlled microstructures and adequate gel strength would make it a facile synthetic method for different 1D polymer nanosturctures.
文摘The reactions of 18 crown 6 with each of K 2(M=Zn, Hg; mnt=1,2 dicyanoethene 1,2 dithiolate, C 2S 2(CN) 2- 2) were studied and novel complexes [K(18 C 6)] 2[Zn(mnt) 2](1) and [K(18 C 6)] 2[Hg(mnt) 2](2) were characterized by elemental analysis, IR spectrum and X ray diffraction analysis. Complex 1 displays a one dimensional chain of [K(18 C 6)] 2[Zn(mnt) 2] bridged by K O interactions between adjacent [K(18 C 6)] + units. Complex 2 is also a one dimensional chain of [K(18 C 6)] 2[Hg(mnt) 2] bridged by K...S weak interactions between adjacent [K(18 C 6)] + and [Hg(mnt) 2] 2- .
文摘The variation of effective stress ratio of stratfied soil with semi pervious boundaries and under cyclic loading was analyzed on the basis of Terzaghi's one dimensional consolidation assumptions. A solution by Laplace Transform was obtained for the case when the soil was under time varied loading. With numerical inversion of Laplace Transform, some useful results were obtained for several kinds of commonly encountered loadings. The results can be meaningful in engineering practice.
基金National Key Research and Development Program of China(2023YFB3811700,2022YFF0503600)Fundamental Research Funds for the Central Universities(HIT.OCEF.2022048,HIT.DZJJ.2023041)+3 种基金National Natural Science Foundation of China(52072087)Henan Provincial Science and Technology Research Project(231100230300)Natural Science Foundation of Heilongjiang Province(YQ2021E018)National Key Laboratory of Science,Technology on Advanced Composites in Special Environments,HIT。
文摘The nitrogen-vacancy(NV)color center in diamond is a promising solid-state quantum system at room temperature.However,its sensitivity is limited by its low fluorescence collection efficiency,and its coherence time is limited by spin interference of impurity electrons around the NV color center.Here,we innovatively fabricated a one-dimensional photonic crystal on the surface of diamond,which greatly improved the fluorescence intensity of the NV color centers and increased the sensitivity of NV ensembles by a factor of 2.92.In addition,the laser reflected by the photonic crystal excites impurity electrons around the NV color centers,improving the electric field environment around the NV color centers,which exponentially prolongs the dephasing time(from 209 to841 ns),opening avenues for NV color-center ensemble sensors.
基金K.-G.Liu is grateful for financial support from the National Natural Science Foundation of China(Grant No.92161106)the Natural Science Foundation of Ningxia(Grant No.2023AA02004)+2 种基金J.Wei is grateful for financial support from the Natural Science Foundation of Ningxia(Grant No.2024AAC03032)X.Yang is grateful for financial support from the Key Research and Development Program of Ningxia(Grant No.2021BEB04066)The authors acknowledge the French Grand Equipment National de Calcul Intensif for HCP support(Project a0010807367).
文摘Two novel 18-crown-6-ether(18-C-6)directed one-dimensional silver(I)coordination polymers(1D Ag(I)CPs),formulated as{[(18-C-6)Ag(bpy)]⋅X}_(∞)and{[(18-C-6)Ag(pyz)]⋅X}_(∞){bpy=4,4′-bipyridine;pyz=pyrazine;X=BF_(4)^(-)(Ⅰa,Ⅱa),CF_(3)SO_(3)^(-)(Ⅰb,Ⅱb)},are prepared and structurally determined.The protection of the 18-C-6 macrocycle not only efficiently prevents intermolecular interactions within each 1D Ag(I)CP but also significantly enhances the rigidity of the chain structures,allowing these polymers to exhibit remarkable phosphorescence with intense green-light emission at room temperature.Moreover,Ⅱa and Ⅱb show enhanced photoluminescence quantum yields and aggregation-induced emission properties,which can be attributed to their close-packed structure modes in the crystalline states.Interestingly,upon mixing with commercial resin,Ⅱa can serve as an efficient and stable luminescent ink for 3D printing.The resulting printed structures demonstrate exceptional irradiation stability,retaining their luminescence properties without any quenching over a three-month period.This work not only provides a facile strategy to prepare luminescent 1D Ag(I)CPs but also shows the promise of their utilization in optical devices.
基金supported by the National Natural Science Foundation of China(NSFC)(No.U21A2064)Henan Key Laboratory of Aeronautical Material and Technology Open Foundation(No.ZHKF-230101)+1 种基金We also thank the Scientific Research Team Plan of Zhengzhou University of Aeronautics(No.23ZHTD01002)ZUA Innovation Fund for Graduate Education(No.2023CX70)for their sponsorship.
文摘The solid solution formed by the combination of multiple cations has been extensively investigated due to its distinctive lattice distortion effect,which imparts unique electromagnetic properties.In particular,the regulation of dielectric and magnetic properties can be achieved through element selection.Herein,the stability of Ta_(x)Nb_(1-x)C was predicted through geometric optimization of crystal structure,and Ta_(x)Nb_(1-x)C nanowires were successfully synthesized through F-ion-assisted carbothermal reduction method.The introduction of bimetallic ions forms significant carbon defects and lattice distortion,which undoubtedly induces the formation of strong interface polarization and defect polarization,resulting in high dielectric loss.Furthermore,the significant presence of imperfections leads to a decrease in both the dielectric constant and conductivity,thereby achieving impedance balance.The design of a one-dimensional structure also facilitates the formation of conductive pathways,promoting carrier transitions.Benefiting from a variety of loss mechanisms and appropriate impedance matching,solid solution Ta_(x)Nb_(1-x)C shows excellent electromagnetic wave absorption(EWA)performance.This research presents a promising strategy for developing single-phase materials with excellent EWA performance.
基金R.A.S.(CVU 703153)acknowledges the DGAPA-UNAM postdoctoral grant.S.E.M.T.(CVU 703157)acknowledges the DGAPA-UNAM postdoctoral grantP.G.Z.-B.(CVU 787342)acknowledges the CONAHCyT postdoctoral grant received.A.D.+2 种基金G.S.thank the projects PAPIIT-DGAPA-UNAM IA100123 and IG100123The authors also acknowledge the UIC-UNAM joint collaborative project for the supportThis work was supported by DGAPA PAPIIT funding IA100123.
文摘Objective:We conducted a comprehensive physicochemical analysis of one-dimensional ZnO nanowires(1DZnO),incorporating anti-CYFRA 21-1 immobilization to promote fast optical biomarker detection up to 10 ng ml−1.Impact Statement:This study highlights the effectiveness of proof-of-concept 1DZnO nanoplatforms for rapid cancer biomarker detection by examining the nanoscale integration of 1DZnO with these bioreceptors to deliver reliable photoluminescent output signals.Introduction:The urgent need for swift and accurate prognoses in healthcare settings drives the rise of sensitive biosensing nanoplatforms for cancer detection,which has benefited from biomarker identification.CYFRA 21-1 is a reliable target for the early prediction of cancer formation that can be perceptible in blood,saliva,and serum.However,1DZnO nanostructures have been barely applied for CYFRA 21-1 detection.Methods:We assessed the nanoscale interaction between 1DZnO and anti-CYFRA 21-1 antibodies to develop rapid CYFRA 21-1 detection in two distinct matrices:PhosphateBuffered Saline(PBS)buffer and artificial saliva.The chemical modifications were tracked utilizing Fourier transform infrared spectroscopy,while transmission electron microscopy and energy dispersive spectroscopy confirmed antigen-antibody interplay over nanostructures.Results:Our results show high antibody immobilization efficiencies,affirming the effectiveness of 1DZnO nanoplatforms for rapid CYFRA 21-1 testing within a 5-min detection window in both PBS and artificial saliva.Photoluminescence measurements also revealed distinct optical responses across biomarker concentrations ranging from 10 to 1,000 ng ml^(−1).Conclusion:Discernible PL signal responses obtained after 5 min affirm the potential of 1DZnO nanoplatforms for further advancement in optical biomarker detection for application in early cancer prognosis.
文摘One-dimensional （1D） ZnO nanostructures have been studied intensively and extensively over the last decade not only for their remarkable chemical and physical properties, but also for their diverse current and future technological applications. This article gives a comprehensive overview of the progress that has been made within the context of 1D ZnO nanostructures synthesized via wet chemical methods. We will cover the synthetic methodologies and the corresponding growth mechanisms, various nanostructures grown, their doping and alloying, and position-controlled growth on substrates. Finally, we will review their functional properties in catalysis, hydrophobic surface modification, sensing, and electronic, optical, optoelectronic, and energy harvesting devices.
基金supported by the National Natural Science Foundation of China (Nos. 21325417, 51533008)the MOST National Key Research and Development Plan (2016YFA0200200)+1 种基金the National Postdoctoral Program for Innovative Talents (No. BX201700209)the State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University (No. LK1403)
文摘Nanocarbon-based materials, such as carbon nanotubes(CNTs) and graphene have been attached much attention by scientific and industrial community. As two representative nanocarbon materials, one-dimensional CNTs and twodimensional graphene both possess remarkable mechanical properties. In the past years, a large amount of work have been done by using CNTs or graphene as building blocks for constructing novel, macroscopic, mechanically strong fibrous materials. In this review, we summarize the assembly approaches of CNT-based fibers and graphene-based fibers in chronological order, respectively. The mechanical performances of these fibrous materials are compared, and the critical influences on the mechanical properties are discussed. Personal perspectives on the fabrication methods of CNT-and graphene-based fibers are further presented.
基金This work was financially supported by the National Natural Science Foundation of China(No.51772337)Free Exploration Fund of State Key Laboratory of Optoelectronic Materials and Technologies of China(No.OEMT-2017-ZY-09).
文摘Ni-rich oxides,LiNixMnyCozO2(NMC),are among leading candidates for cathode materials in Li-ion batteries.However,they are mostly fabricated by coprecipitation approach under complex conditions,which usually produces large secondary particles composed of aggregated primary particles.Undesirable cation mixing and crack propagation upon cycling block ion and electron transport,result in fast capacity fading and poor rate capability.Herein,we present an ultrasound-triggered cation chelation and reassembly route for synthesizing one-dimensional precursor with homogeneous element distribution at the atomic level.This process is accomplished by the synergistic combination of ultrasound and surfactant,which can disperse reactants and remove hydration shells surrounding cations so as to accelerate chelating reaction,and then separate and assemble chelates into one dimensional structure.The whole synthesis time is only 20 min(8.9 min of ultrasonic working time)in an open vessel under natural ambient conditions.One-dimensional LiNi0.6Mn0.2Co0.2O2 has a high reversible capacity(184 mAh·g^−1 at 0.1 C)and long cycling stability(95.1%and 82.4%capacity retention for 100 and 1000 cycles,respectively).The short charging time of 76 s is realized at super high current rate of 20 C,which is very important to improve the competitiveness of electric vehicles relative to fuel vehicles.Our synthetic approach can provide a general strategy for the growth of mixed-metal-EDTA chelate precursors by changing the feeding ratio of Ni2+,Mn2+and Co2+cations in reaction for fabricating NMC cathode materials with other compositions.
基金This work was supported by the National Natural Science Foundation of China (No. 10274108)the National "973" Project of China (No. 2004CB719804)the National "863" Project of China (No. 2003AA311022)the Natural Science Foundation of Guangdong Province of China.
文摘A photonic heterostructure with multi-channel and sharp angular defect modes by combining two different one-dimensional defective photonic crystals is proposed. The filters designed on the basis of this heterostructure possess both functions of multi-channel narrow band filtering and sharp angular filtering. The channels, channel interval, and number of channels can be tuned by adjusting the geometric and physical parameters of the heterostuctures. This kind of filters will benefit the development of multi-channel interstellar or atmosphere optical communication.
基金the Shanghai Rising-Star Program(No.05QMX1459)the National Natural Science Foundation of China(No.60508018)
文摘Band structures of one-dimensional （1D） photonic crystals （PCs） containing dispersive left-handed metamaterials are studied theoretically. The results show that the structure possesses a type of photonic band gap originating from total internal reflection （TIR）. In contrast to photonic band gaps corresponding to zero average refractive index and zero phase, the TIR gap exhibits sharp angular effect and has no polarization effect. It should also be noted that band structures of transverse electric （TE） and transverse magnetic （TM） mode waves are exactly the same in the PCs we studied.
文摘Reactions of CuBr with equimolar PyHBr orγMePyHBr afforded two novel one dimensional bromocuprate?polymers{(PyH)_(3)[Cu_(3)Br_(6)]}_(∞)(1)and{(γMePyH)_(2)[Cu_(2)Br_(4)]}_(∞)(2),respectively.Both 1 and 2 were characterized by IR,elemental analysis,and X ray crystallography.Crystal data for 1:monoclinic,space group P2_(1)/n,a=0.93262(12)nm,b=1.3497(2)nm,c=1.9149(2)nm,β=93.465(7)°,V=2.4060(5)nm^(3),Z=4.Crystal data for 2:orthorhombic,space group Pbcm,a=0.8659(4)nm,b=1.5669(6)nm,c=1.2849(5)nm,V=1.7432(2)nm^(3),Z=4.The structure of 1 has a unique helical chain composed of units andμbromide anions while that of 2 shows a linear chain consisted of[Cu_(2)(μBr)_(2)]units bridged by pairs ofμBr atoms.CCDC:1,208412;2,208413.
