The Marangoni effect induced by mass transfer at the interface between two immiscible liquids displays important influence on laboratory and industrial operation of solvent extraction. A systematic numerical study of ...The Marangoni effect induced by mass transfer at the interface between two immiscible liquids displays important influence on laboratory and industrial operation of solvent extraction. A systematic numerical study of the two-dimensional Marangoni effect in a two liquid layer system was conducted. The linear relationship of the inter- facial tension versus the solute concentration was incorporated into a mathematical model accounting for liquid flow and mass transfer in both phases. The typical cases analyzed by Sternling ＆ Scriven （AIChE J., 1959） using the linear instability theory were simulated bv the finite difference method and good agreement between the theory and the numerical simulation was observed. The simulation suggests that the Marangoni convection needs certain time to develop sufficiently in strength and scale to enhance the interphase mass transfer, the Marangoni effect is dynamic and transient, and remains at some stabilized level as long as the mass transfer driving force is kept con- stant. When certain level of shear is imposed at the interface as in most cases of practical significance, the Maran- goni effect is suppressed slightly but progressively as the shear is increased gradually. The present two-dimensional simulation of the Marangoni effect provides some insight into the underlying mechanism and also the basis for further theoretical study of the three-dimensional Marangoni effect in the real world and in chemical engineering applications.展开更多
This article presents the experimental investigation on instabilities of thermocapillary-buoyancy convection in the transition process in an open rectangular liquid layer subject to a horizontal temperature gradient. ...This article presents the experimental investigation on instabilities of thermocapillary-buoyancy convection in the transition process in an open rectangular liquid layer subject to a horizontal temperature gradient. In the experimental run,an infrared thermal imaging system was constructed to observe and record the surface wave of the rectangular liquid layer. It was found that there are distinct convection longitudinal rolls in the flow field in the thermocapillary-buoyancy convection transition process. There are different wave characterizations for liquid layers with different thicknesses. For sufficiently thin layers, oblique hydrothermal waves are observed, which was predicted by the linear-stability analysis of Smith ＆ Davis in 1983. For thicker layers, the surface flow is distinct and intensified, which is because the buoyancy convection plays a dominant role and bulk fluid flow from hot wall to cold wall in the free surface of liquid layers. In addition, the spatiotemporal evolution analysis has been carried out to conclude the rule of the temperature field destabilization in the transition process.展开更多
Based on elastic wave propagation theory, the dispersion equation for a thin anisotropic plate (such as commonly used Zinc okide in micro-transducers) bordered with liquid layers is derived. Higher symmetry crystals, ...Based on elastic wave propagation theory, the dispersion equation for a thin anisotropic plate (such as commonly used Zinc okide in micro-transducers) bordered with liquid layers is derived. Higher symmetry crystals, such as orthorhombic, tetragonal, cubic, isotropic, are included in this analysis as well. For the case of one liquid layer loading, numerical calcu- lations show that the phase velocity changes periodically with the thickness of the liquld layer. When the thickness 2d of the anisotropic plate is very small, mass sensing application of Ao mode Lamb wave is also discussed.展开更多
The influence of the thickness of a covering liquid layer and its viscosity as well as the impact velocity on energy loss during the normal impact on a flat steel wall of spherical granules with a liquid layer was stu...The influence of the thickness of a covering liquid layer and its viscosity as well as the impact velocity on energy loss during the normal impact on a flat steel wall of spherical granules with a liquid layer was studied. Free-fall experiments were performed to obtain the restitution coefficient of elastic-plastic γ- Al2O3 granules by impact on the liquid layer, using aqueous solutions of hydroxypropyl methylcellulose with different concentrations for variation of viscosity （1-300 mPa s）, In the presence of a liquid layer, increase of liquid viscosity decreases the restitution coefficient and the minimum thickness of the liquid layer at which the granule sticks to the wall. The measured restitution coefficients were compared with experiments performed without liquid layer. In contrast to the dry restitution coefficient, due to viscous losses at lower impact velocity, higher energy dissipation was obtained, A rational explanation for the effects obtained was given by results of numerically solved force and energy balances for a granule impact on a liquid layer on the wall. The model takes into account forces acting on the granule including viscous, surface tension, capillary, contact, drag, buoyancy and gravitational forces. Good agreement between simulations and experiments has been achieved.展开更多
The performance of an electrocatalyst, which is needed e.g. for key energy conversion reactions such as hydrogen evolution, oxygen reduction or CO2 reduction, is determined not only by the inherent structure of active...The performance of an electrocatalyst, which is needed e.g. for key energy conversion reactions such as hydrogen evolution, oxygen reduction or CO2 reduction, is determined not only by the inherent structure of active sites but also by the properties of the interfacial structures at catalytic surfaces. Ionic liquids（ILs）, as a unique class of metal salts with melting point below 100 ℃, present themselves as ideal modulators for manipulations of the interfacial structures. Due to their excellent properties such as good chemical stability, high ionic conductivity, wide electrochemical windows and tunable solvent properties the performance of electrocatalysts can be substantially improved through ILs. In the current minireview, we highlight the critical role of the IL phase at the microenvironments created by the IL, the liquid electrolyte, catalytic nanoparticles and/or support materials, by detailing the promotional effect of IL in electrocatalysis as reaction media, binders, and surface modifiers. Updated exemplary applications of IL in electrocatalysis are given and moreover, the latest developments of IL modified electrocatalysts following the ＂Solid Catalyst with Ionic Liquid Layer（SCILL）＂ concept are presented.展开更多
Many important applications of room temperature ionic liquids （RTILs）, e.g., lubrication, energy storage and catalysis, involve RTILs confined to solid surfaces. In order to optimize the performance, it is critical ...Many important applications of room temperature ionic liquids （RTILs）, e.g., lubrication, energy storage and catalysis, involve RTILs confined to solid surfaces. In order to optimize the performance, it is critical to understand the wettability of nanometer-thick RTILs on solid surfaces. In this review, the recent progress in this filed is presented. First, the macroscopic wettability of RTILs on solids will be discussed briefly. Afterwards, the wetting of nanometer-thick RTILs will be discussed with the emphasis on RTIL/mica and RTIL/graphite interfaces since mica and graphite not only are mostly studied but also have important real-life applications. For RTIL/mica interface, the extended layering that promotes the wetting has been extensively reported and it is generally accepted that the electrostatic interaction at the RTIL/mica interface is the key. However, recent works from others and us highlight the unexpected effect of water： Water enables ion exchange between K^＋ and the cations of RTILs on the mica surface and thus triggers the ordered packing of cations/anions in RTILs, resulting in extended layering. Different from mica, there is no electrical charge on the graphite surface. Interestingly, previous reports showed inconsistent results on the wettability of RTILs on graphite. Recent research from others and us suggested that π-π^＋ stacking between sp2 carbon and the imidazoliumcation in展开更多
This paper reports the doping effect of cholesteric liquid crystal 3β-Hydroxy-5-cholestene 3-oleate on polymer solar cells composed of the poly 3-hexyl thiophene and the fullerene derivative.With a doping ratio of 0....This paper reports the doping effect of cholesteric liquid crystal 3β-Hydroxy-5-cholestene 3-oleate on polymer solar cells composed of the poly 3-hexyl thiophene and the fullerene derivative.With a doping ratio of 0.3 wt%,the device achieves an ideal improvement on the shunt resistor and the fill factor.Compared with the reference cell,the power conversion efficiency of the doped cell is improved 24%.The photoelectric measurement and the active layer characterization indicate that the self-assembly liquid crystal can improve the film crystallization and reduce the membrane defect.展开更多
A novel fabrication process for micro patterns with curvature was introduced. The curved structures were made by compensating rectangular micro structures with liquid photoresist layer. Because of the surface tension ...A novel fabrication process for micro patterns with curvature was introduced. The curved structures were made by compensating rectangular micro structures with liquid photoresist layer. Because of the surface tension of the liquid in micro scale, various shapes of meniscus can he made on the micro channels. The micro channels were made on the silicon suhstrate in advance, and then the liquid layer was coated on the micro channels. From the nature of liquid behavior, the curved patterns with smooth surface are obtained, which cannot be made easily with the conventional mechanical machining, as well as with the microfabrication processes, such as wet and dry etching. With this principle, it is expected that the smooth and curved surfaces can be made by simple processes and the results can be applied widely, such as optical patterns.展开更多
We propose and demonstrate a pseudo Fabry–Pérot filter in the terahertz frequency range of 0.1–0.5 THz. It consists of alternative liquid crystal layers and metallic slats. Separate sharp resonant peaks are sho...We propose and demonstrate a pseudo Fabry–Pérot filter in the terahertz frequency range of 0.1–0.5 THz. It consists of alternative liquid crystal layers and metallic slats. Separate sharp resonant peaks are shown in the simulated transmission spectra, and their positions shift toward higher frequencies when the refractive index of liquid crystal decreases. The measured transmission spectra are consistent with corresponding simulations. Via thermally tuning the refractive index of the filled liquid crystal, the resonant transmission frequencies shift accordingly. The work supplies a novel design for tunable terahertz filters, which would play important roles in terahertz imaging, sensing, high speed communication, and security applications.展开更多
Even in the early stage,endocrine metabolism disease may lead to micro aneurysms in retinal capillaries whose diameters are less than 10 μm.However,the fundus cameras used in clinic diagnosis can only obtain images o...Even in the early stage,endocrine metabolism disease may lead to micro aneurysms in retinal capillaries whose diameters are less than 10 μm.However,the fundus cameras used in clinic diagnosis can only obtain images of vessels larger than 20 μm in diameter.The human retina is a thin and multiple layer tissue,and the layer of capillaries less than10 μm in diameter only exists in the inner nuclear layer.The layer thickness of capillaries less than 10 μm in diameter is about 40 μm and the distance range to rod＆cone cell surface is tens of micrometers,which varies from person to person.Therefore,determining reasonable capillary layer（CL） position in different human eyes is very difficult.In this paper,we propose a method to determine the position of retinal CL based on the rod＆cone cell layer.The public positions of CL are recognized with 15 subjects from 40 to 59 years old,and the imaging planes of CL are calculated by the effective focal length of the human eye.High resolution retinal capillary imaging results obtained from 17 subjects with a liquid crystal adaptive optics system（LCAOS） validate our method.All of the subjects＇ CLs have public positions from 127 μm to 147 μm from the rod＆cone cell layer,which is influenced by the depth of focus.展开更多
The "solidified liquid layer" model has been examined using a quartz crystal microbalance(QCM) with a polymeric matrix.The model is shown to give a reasonable explanation for the following experimental obser...The "solidified liquid layer" model has been examined using a quartz crystal microbalance(QCM) with a polymeric matrix.The model is shown to give a reasonable explanation for the following experimental observations:(i) The opposite response of the QCM and surface plasmon resonance(SPR) for the activation process;(ii) the marked difference in the responses for IgG/anti-IgG interaction between QCM and SPR.Theoretical analysis and experimental results indicated that QCM is sensitive to the thickness change of the "solidified liquid layer" but not the mass of captured biomolecules(i.e.,the immobilized mass),implying caution must be taken in interpreting QCM results.展开更多
The mechanism for transporting liquid from the bottom of the pipe to the top still to be established in the prediction of the film thickness distribution in horizontal annular two-phase flow. To resolve this issue, us...The mechanism for transporting liquid from the bottom of the pipe to the top still to be established in the prediction of the film thickness distribution in horizontal annular two-phase flow. To resolve this issue, using five parallel-wire conductance probes, time records of local liquid film thickness at five circumferential positions were collected. The characteristics of circumferential liquid film thickness profiles and its variation with gas and liquid velocities were obtained. The basic features of probability distribution function, probability density function, auto-correlation, cross-correlation and power spectrum density function of the disturbance waves in angular flow were studied respectively. The characteristics of circumferential profiles of disturbance waves and its variation with gas and liquid velocities were presented.展开更多
The growth of polycrystalline silicon layers on glass from tin solutions at low temperatures is presented.This approach is based on the steady-state solution growth of Si crystallites on nanocrystalline seed layers, w...The growth of polycrystalline silicon layers on glass from tin solutions at low temperatures is presented.This approach is based on the steady-state solution growth of Si crystallites on nanocrystalline seed layers, which are prepared in a preceding process step. Scanning electron microscopy and atomic force microscopy investigations reveal details about the seed layer surfaces, which consist of small hillocks, as well as about Sn inclusions and gaps along the glass substrate after solution growth. The successful growth of continuous microcrystalline Si layers with grain sizes up to several ten micrometers shows the feasibility of the process and makes it interesting for photovoltaics.展开更多
Experiments on the National Ignition Facility show that multi-dimensional effects currently dominate the implosion performance. Low mode implosion symmetry and hydrodynamic instabilities seeded by capsule mounting fea...Experiments on the National Ignition Facility show that multi-dimensional effects currently dominate the implosion performance. Low mode implosion symmetry and hydrodynamic instabilities seeded by capsule mounting features appear to be two key limiting factors for implosion performance. One reason these factors have a large impact on the performance of inertial confinement fusion implosions is the high convergence required to achieve high fusion gains.To tackle these problems, a predictable implosion platform is needed meaning experiments must trade-off high gain for performance. LANL has adopted three main approaches to develop a one-dimensional(1D) implosion platform where 1D means measured yield over the 1D clean calculation. A high adiabat, low convergence platform is being developed using beryllium capsules enabling larger case-to-capsule ratios to improve symmetry. The second approach is liquid fuel layers using wetted foam targets. With liquid fuel layers, the implosion convergence can be controlled via the initial vapor pressure set by the target fielding temperature. The last method is double shell targets. For double shells, the smaller inner shell houses the DT fuel and the convergence of this cavity is relatively small compared to hot spot ignition. However,double shell targets have a different set of trade-off versus advantages. Details for each of these approaches are described.展开更多
The coefficient of restitution is widely used to characterize the energy dissipation rate in numerical simulations involving particle collisions. The challenge in measuring the coefficient of restitution is the strong...The coefficient of restitution is widely used to characterize the energy dissipation rate in numerical simulations involving particle collisions. The challenge in measuring the coefficient of restitution is the strong scatter seen in experimental data that results from varying particle properties, i.e. shape and surface roughness, and from imperfections in the experimental technique. To minimize this scattering, a novel experimental setup was developed based on two synchronized high-speed cameras capturing the collision behaviour of a particle in three dimensions. To measure the wet restitution coefficient, which describes particle impact in the presence of a liquid layer in the contact region, additional accuracy can be achieved by measuring the liquid layer thickness by a high-precision optical confocal sensor. The coefficient of restitution was measured for glass particles with two different diameters, at different relative velocities and liquid layer thicknesses, with a focus on small collision velocities and thin liquid layers, using both the improved （three dimensional） and the conventional （two dimensional） approaches to quantify the improvement of the new method＇s accuracy.展开更多
基金Supported by the National Natural Science Foundation of China （20490206, 20576133, 20676134） and Petro China.
文摘The Marangoni effect induced by mass transfer at the interface between two immiscible liquids displays important influence on laboratory and industrial operation of solvent extraction. A systematic numerical study of the two-dimensional Marangoni effect in a two liquid layer system was conducted. The linear relationship of the inter- facial tension versus the solute concentration was incorporated into a mathematical model accounting for liquid flow and mass transfer in both phases. The typical cases analyzed by Sternling ＆ Scriven （AIChE J., 1959） using the linear instability theory were simulated bv the finite difference method and good agreement between the theory and the numerical simulation was observed. The simulation suggests that the Marangoni convection needs certain time to develop sufficiently in strength and scale to enhance the interphase mass transfer, the Marangoni effect is dynamic and transient, and remains at some stabilized level as long as the mass transfer driving force is kept con- stant. When certain level of shear is imposed at the interface as in most cases of practical significance, the Maran- goni effect is suppressed slightly but progressively as the shear is increased gradually. The present two-dimensional simulation of the Marangoni effect provides some insight into the underlying mechanism and also the basis for further theoretical study of the three-dimensional Marangoni effect in the real world and in chemical engineering applications.
基金Project supported by the Strategic Priority Research Program on Space Science,Chinese Academy of Sciences:SJ-10 Recoverable Scientific Experiment Satellite(Grant Nos.XDA04020405 and XDA04020202-05)the China Manned Space Engineering program(TG-2)+1 种基金Cooperative Research Project between China and Russiathe National Natural Science Foundation of China(Grant No.11372328)
文摘This article presents the experimental investigation on instabilities of thermocapillary-buoyancy convection in the transition process in an open rectangular liquid layer subject to a horizontal temperature gradient. In the experimental run,an infrared thermal imaging system was constructed to observe and record the surface wave of the rectangular liquid layer. It was found that there are distinct convection longitudinal rolls in the flow field in the thermocapillary-buoyancy convection transition process. There are different wave characterizations for liquid layers with different thicknesses. For sufficiently thin layers, oblique hydrothermal waves are observed, which was predicted by the linear-stability analysis of Smith ＆ Davis in 1983. For thicker layers, the surface flow is distinct and intensified, which is because the buoyancy convection plays a dominant role and bulk fluid flow from hot wall to cold wall in the free surface of liquid layers. In addition, the spatiotemporal evolution analysis has been carried out to conclude the rule of the temperature field destabilization in the transition process.
基金supported by the National Natural Science Foundation of China.
文摘Based on elastic wave propagation theory, the dispersion equation for a thin anisotropic plate (such as commonly used Zinc okide in micro-transducers) bordered with liquid layers is derived. Higher symmetry crystals, such as orthorhombic, tetragonal, cubic, isotropic, are included in this analysis as well. For the case of one liquid layer loading, numerical calcu- lations show that the phase velocity changes periodically with the thickness of the liquld layer. When the thickness 2d of the anisotropic plate is very small, mass sensing application of Ao mode Lamb wave is also discussed.
文摘The influence of the thickness of a covering liquid layer and its viscosity as well as the impact velocity on energy loss during the normal impact on a flat steel wall of spherical granules with a liquid layer was studied. Free-fall experiments were performed to obtain the restitution coefficient of elastic-plastic γ- Al2O3 granules by impact on the liquid layer, using aqueous solutions of hydroxypropyl methylcellulose with different concentrations for variation of viscosity （1-300 mPa s）, In the presence of a liquid layer, increase of liquid viscosity decreases the restitution coefficient and the minimum thickness of the liquid layer at which the granule sticks to the wall. The measured restitution coefficients were compared with experiments performed without liquid layer. In contrast to the dry restitution coefficient, due to viscous losses at lower impact velocity, higher energy dissipation was obtained, A rational explanation for the effects obtained was given by results of numerically solved force and energy balances for a granule impact on a liquid layer on the wall. The model takes into account forces acting on the granule including viscous, surface tension, capillary, contact, drag, buoyancy and gravitational forces. Good agreement between simulations and experiments has been achieved.
基金supported by the funding of the German Research Council (DFG), which, within the framework of its Excellence Initiative, supports the Cluster of Excellence “Engineering of Advanced Materials” (www.eam.uni-erlangen.de) at the University of Erlangen-Nürnberg
文摘The performance of an electrocatalyst, which is needed e.g. for key energy conversion reactions such as hydrogen evolution, oxygen reduction or CO2 reduction, is determined not only by the inherent structure of active sites but also by the properties of the interfacial structures at catalytic surfaces. Ionic liquids（ILs）, as a unique class of metal salts with melting point below 100 ℃, present themselves as ideal modulators for manipulations of the interfacial structures. Due to their excellent properties such as good chemical stability, high ionic conductivity, wide electrochemical windows and tunable solvent properties the performance of electrocatalysts can be substantially improved through ILs. In the current minireview, we highlight the critical role of the IL phase at the microenvironments created by the IL, the liquid electrolyte, catalytic nanoparticles and/or support materials, by detailing the promotional effect of IL in electrocatalysis as reaction media, binders, and surface modifiers. Updated exemplary applications of IL in electrocatalysis are given and moreover, the latest developments of IL modified electrocatalysts following the ＂Solid Catalyst with Ionic Liquid Layer（SCILL）＂ concept are presented.
基金the American Chemical Society Petroleum Research Fund (ACS PRF No. 54840-DNI5)Advanced Storage Technology Consortium (ASTC)+1 种基金Taiho Kogyo Tribology Research Foundation (TTRF) for the financial supportthe financial support of the National Natural Science Foundation of China (No. 21774098)
文摘Many important applications of room temperature ionic liquids （RTILs）, e.g., lubrication, energy storage and catalysis, involve RTILs confined to solid surfaces. In order to optimize the performance, it is critical to understand the wettability of nanometer-thick RTILs on solid surfaces. In this review, the recent progress in this filed is presented. First, the macroscopic wettability of RTILs on solids will be discussed briefly. Afterwards, the wetting of nanometer-thick RTILs will be discussed with the emphasis on RTIL/mica and RTIL/graphite interfaces since mica and graphite not only are mostly studied but also have important real-life applications. For RTIL/mica interface, the extended layering that promotes the wetting has been extensively reported and it is generally accepted that the electrostatic interaction at the RTIL/mica interface is the key. However, recent works from others and us highlight the unexpected effect of water： Water enables ion exchange between K^＋ and the cations of RTILs on the mica surface and thus triggers the ordered packing of cations/anions in RTILs, resulting in extended layering. Different from mica, there is no electrical charge on the graphite surface. Interestingly, previous reports showed inconsistent results on the wettability of RTILs on graphite. Recent research from others and us suggested that π-π^＋ stacking between sp2 carbon and the imidazoliumcation in
基金Project supported by the National Natural Science Foundation of China(Grant No.61540016)
文摘This paper reports the doping effect of cholesteric liquid crystal 3β-Hydroxy-5-cholestene 3-oleate on polymer solar cells composed of the poly 3-hexyl thiophene and the fullerene derivative.With a doping ratio of 0.3 wt%,the device achieves an ideal improvement on the shunt resistor and the fill factor.Compared with the reference cell,the power conversion efficiency of the doped cell is improved 24%.The photoelectric measurement and the active layer characterization indicate that the self-assembly liquid crystal can improve the film crystallization and reduce the membrane defect.
基金the support of Ministry of Knowledge and Economy through Strategic Technology Development ProjectConversing Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology
文摘A novel fabrication process for micro patterns with curvature was introduced. The curved structures were made by compensating rectangular micro structures with liquid photoresist layer. Because of the surface tension of the liquid in micro scale, various shapes of meniscus can he made on the micro channels. The micro channels were made on the silicon suhstrate in advance, and then the liquid layer was coated on the micro channels. From the nature of liquid behavior, the curved patterns with smooth surface are obtained, which cannot be made easily with the conventional mechanical machining, as well as with the microfabrication processes, such as wet and dry etching. With this principle, it is expected that the smooth and curved surfaces can be made by simple processes and the results can be applied widely, such as optical patterns.
基金supported by the National Natural Science Foundation of China(Nos.11304151,61490714,61435008,and 61575093)the Ph.D.Programs Foundation of the Ministry of Education of China(No.20120091120020)the Fundamental Research Funds for the Central Universities(Nos.021314380020 and 021314380023)
文摘We propose and demonstrate a pseudo Fabry–Pérot filter in the terahertz frequency range of 0.1–0.5 THz. It consists of alternative liquid crystal layers and metallic slats. Separate sharp resonant peaks are shown in the simulated transmission spectra, and their positions shift toward higher frequencies when the refractive index of liquid crystal decreases. The measured transmission spectra are consistent with corresponding simulations. Via thermally tuning the refractive index of the filled liquid crystal, the resonant transmission frequencies shift accordingly. The work supplies a novel design for tunable terahertz filters, which would play important roles in terahertz imaging, sensing, high speed communication, and security applications.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11174274,11174279,61205021,11204299,61475152,and 61405194)
文摘Even in the early stage,endocrine metabolism disease may lead to micro aneurysms in retinal capillaries whose diameters are less than 10 μm.However,the fundus cameras used in clinic diagnosis can only obtain images of vessels larger than 20 μm in diameter.The human retina is a thin and multiple layer tissue,and the layer of capillaries less than10 μm in diameter only exists in the inner nuclear layer.The layer thickness of capillaries less than 10 μm in diameter is about 40 μm and the distance range to rod＆cone cell surface is tens of micrometers,which varies from person to person.Therefore,determining reasonable capillary layer（CL） position in different human eyes is very difficult.In this paper,we propose a method to determine the position of retinal CL based on the rod＆cone cell layer.The public positions of CL are recognized with 15 subjects from 40 to 59 years old,and the imaging planes of CL are calculated by the effective focal length of the human eye.High resolution retinal capillary imaging results obtained from 17 subjects with a liquid crystal adaptive optics system（LCAOS） validate our method.All of the subjects＇ CLs have public positions from 127 μm to 147 μm from the rod＆cone cell layer,which is influenced by the depth of focus.
基金supported by the 100 Talents Programme of Chinese Academy of Sciences(08BM031001)the Fok Ying Tung Education Foundation (114013) to H.M.the National Basic Research Program of China (2009CB320300)
文摘The "solidified liquid layer" model has been examined using a quartz crystal microbalance(QCM) with a polymeric matrix.The model is shown to give a reasonable explanation for the following experimental observations:(i) The opposite response of the QCM and surface plasmon resonance(SPR) for the activation process;(ii) the marked difference in the responses for IgG/anti-IgG interaction between QCM and SPR.Theoretical analysis and experimental results indicated that QCM is sensitive to the thickness change of the "solidified liquid layer" but not the mass of captured biomolecules(i.e.,the immobilized mass),implying caution must be taken in interpreting QCM results.
文摘The mechanism for transporting liquid from the bottom of the pipe to the top still to be established in the prediction of the film thickness distribution in horizontal annular two-phase flow. To resolve this issue, using five parallel-wire conductance probes, time records of local liquid film thickness at five circumferential positions were collected. The characteristics of circumferential liquid film thickness profiles and its variation with gas and liquid velocities were obtained. The basic features of probability distribution function, probability density function, auto-correlation, cross-correlation and power spectrum density function of the disturbance waves in angular flow were studied respectively. The characteristics of circumferential profiles of disturbance waves and its variation with gas and liquid velocities were presented.
基金Project supported by the German Research Foundation(DFG)(No.BO 1129/5-1)
文摘The growth of polycrystalline silicon layers on glass from tin solutions at low temperatures is presented.This approach is based on the steady-state solution growth of Si crystallites on nanocrystalline seed layers, which are prepared in a preceding process step. Scanning electron microscopy and atomic force microscopy investigations reveal details about the seed layer surfaces, which consist of small hillocks, as well as about Sn inclusions and gaps along the glass substrate after solution growth. The successful growth of continuous microcrystalline Si layers with grain sizes up to several ten micrometers shows the feasibility of the process and makes it interesting for photovoltaics.
文摘Experiments on the National Ignition Facility show that multi-dimensional effects currently dominate the implosion performance. Low mode implosion symmetry and hydrodynamic instabilities seeded by capsule mounting features appear to be two key limiting factors for implosion performance. One reason these factors have a large impact on the performance of inertial confinement fusion implosions is the high convergence required to achieve high fusion gains.To tackle these problems, a predictable implosion platform is needed meaning experiments must trade-off high gain for performance. LANL has adopted three main approaches to develop a one-dimensional(1D) implosion platform where 1D means measured yield over the 1D clean calculation. A high adiabat, low convergence platform is being developed using beryllium capsules enabling larger case-to-capsule ratios to improve symmetry. The second approach is liquid fuel layers using wetted foam targets. With liquid fuel layers, the implosion convergence can be controlled via the initial vapor pressure set by the target fielding temperature. The last method is double shell targets. For double shells, the smaller inner shell houses the DT fuel and the convergence of this cavity is relatively small compared to hot spot ignition. However,double shell targets have a different set of trade-off versus advantages. Details for each of these approaches are described.
文摘The coefficient of restitution is widely used to characterize the energy dissipation rate in numerical simulations involving particle collisions. The challenge in measuring the coefficient of restitution is the strong scatter seen in experimental data that results from varying particle properties, i.e. shape and surface roughness, and from imperfections in the experimental technique. To minimize this scattering, a novel experimental setup was developed based on two synchronized high-speed cameras capturing the collision behaviour of a particle in three dimensions. To measure the wet restitution coefficient, which describes particle impact in the presence of a liquid layer in the contact region, additional accuracy can be achieved by measuring the liquid layer thickness by a high-precision optical confocal sensor. The coefficient of restitution was measured for glass particles with two different diameters, at different relative velocities and liquid layer thicknesses, with a focus on small collision velocities and thin liquid layers, using both the improved （three dimensional） and the conventional （two dimensional） approaches to quantify the improvement of the new method＇s accuracy.
