The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 ...The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 mm-l , A(MoKα) = 0. 71069, Mr = 438. 01, and the convergence factors R = 0. 045, Rw =0. 055 for 341 observed reflections (I>3σ(I)). The anion structure can be viewed as apolymeric single chain consisting of unlimited extended rhombic fragruents of -AgS2W-which are alternately perpendicular to each other. Additionally, influence of di- and tri-valent complex cations on the assembIy of WS2-4 and Ag+ is briefly discussed.展开更多
A multi-nucleon transfer and cluster decay experiment,^(7)Li(^(11)B,^(14)C^(*)→α+^(10)Be)α,is conducted at an incident beam energy of 55 MeV.This reaction channel has a significantly large 0-value,which favors popu...A multi-nucleon transfer and cluster decay experiment,^(7)Li(^(11)B,^(14)C^(*)→α+^(10)Be)α,is conducted at an incident beam energy of 55 MeV.This reaction channel has a significantly large 0-value,which favors populating the high lying resonant states in ^(14)C.The decay paths,from these resonances to various states of the final nucleus ^(10) Be,can be selected,owing to the experimentally achieved optimal resolution of the Q-value spectrum.A number of resonant states are reconstructed from the forward emitting 10Be+α fragments,and their major molecular structures can be detected according to the selective decay paths and relative decay widths.A state at 22.4(2)MeV validates the previously measured and theoretically predicted band head of the positive-parity σ-bond linear-chain mo-lecular band.Two additional resonances at 22.9(2)and 24.2(2)MeV are identified and consistent with the predicted 2^(+) and 4^(+) members of the same molecular band,thus providing novel evidences for the existence of the exotic clustering chain structure in neutron-rich carbon isotopes.A few high energy resonances,which also indicate the presence of the σ-bond molecular structure,are observed;however,further studies are still required to clarify their ascription in band systematics.展开更多
文摘The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 mm-l , A(MoKα) = 0. 71069, Mr = 438. 01, and the convergence factors R = 0. 045, Rw =0. 055 for 341 observed reflections (I>3σ(I)). The anion structure can be viewed as apolymeric single chain consisting of unlimited extended rhombic fragruents of -AgS2W-which are alternately perpendicular to each other. Additionally, influence of di- and tri-valent complex cations on the assembIy of WS2-4 and Ag+ is briefly discussed.
基金Supported by the National Key research and development Program of China(2018YFA0404403)the National Natural Science Foundation of China(11875074,11875073,12027809,11635015,11961141003)the Continuous Basic Scientific Research Project(WDJC-2019-13)。
文摘A multi-nucleon transfer and cluster decay experiment,^(7)Li(^(11)B,^(14)C^(*)→α+^(10)Be)α,is conducted at an incident beam energy of 55 MeV.This reaction channel has a significantly large 0-value,which favors populating the high lying resonant states in ^(14)C.The decay paths,from these resonances to various states of the final nucleus ^(10) Be,can be selected,owing to the experimentally achieved optimal resolution of the Q-value spectrum.A number of resonant states are reconstructed from the forward emitting 10Be+α fragments,and their major molecular structures can be detected according to the selective decay paths and relative decay widths.A state at 22.4(2)MeV validates the previously measured and theoretically predicted band head of the positive-parity σ-bond linear-chain mo-lecular band.Two additional resonances at 22.9(2)and 24.2(2)MeV are identified and consistent with the predicted 2^(+) and 4^(+) members of the same molecular band,thus providing novel evidences for the existence of the exotic clustering chain structure in neutron-rich carbon isotopes.A few high energy resonances,which also indicate the presence of the σ-bond molecular structure,are observed;however,further studies are still required to clarify their ascription in band systematics.
