In order to prepare high density magnesium aluminate spinel materials,the light-burned magnesia and alumina powder were used as the main raw materials.Active magnesium aluminate spinel powders were synthesized at diff...In order to prepare high density magnesium aluminate spinel materials,the light-burned magnesia and alumina powder were used as the main raw materials.Active magnesium aluminate spinel powders were synthesized at different temperatures,and the sintering properties of the synthesized materials were characterized.The results show that the optimal light-burned temperature for synthesizing active magnesium aluminate spinel raw materials with small grain sizes and high sintering activity is 1400℃.The active spinel raw materials were sintered at 1750℃ for 3 h to form a dense spinel material,in which the spinel grains were well developed,exhibited a dense interlocking structure,and were uniformly distributed,with an average grain size of about 7.26μm.The bulk density and apparent porosity of the dense spinel material were 3.29 g·cm^(-3) and 3.5%,respectively.展开更多
Ethylene(C_(2)H_(4))in vehicle exhaust is a highly reactive volatile organic compound(VOC).Its photooxidative reaction with NOx contributes to the formation of O3 and secondary organic aerosols(SOA),the latter being a...Ethylene(C_(2)H_(4))in vehicle exhaust is a highly reactive volatile organic compound(VOC).Its photooxidative reaction with NOx contributes to the formation of O3 and secondary organic aerosols(SOA),the latter being a key precursor of PM_(2.5).In this study,a novel MgO-supported Ag-Cu bimetallic catalyst was designed and investigated using density functional theory(DFT).The effects of Ag and Cu loading on the geometric structure,stability,and reactant adsorption characteristics of the catalyst were analyzed,and the catalytic oxidation pathways of C_(2)H_(4)over AgCu-MgO was elucidated.The results indicate that loading Ag significantly enhances the adsorption of C_(2)H_(4).The incorporation of Cu into Ag-MgO to form a AgCu-MgO bimetallic catalyst(dual atom catalyst,DACS)further improves the oxidative activity toward C_(2)H_(4).Based on the binding energies of the Ag and Cu bimetallic sites and the adsorption energies of C_(2)H_(4)and O_(2),three representative configurations were selected for detailed reaction pathway analysis.Among them,Configuration 6 of AgCu-MgO exhibited the highest catalytic oxidation performance.This study provides new atomic-scale insights for the rational design of efficient catalysts targeting olefinic pollutants in automotive emissions and offers valuable guidance for advancing exhaust after-treatment technologies.展开更多
The advanced temperature and stress test machine was introduced to determine the early cracking tendency of concrete with inclusion of light-burnt MgO under full restraint by tracking the development of thermal,physic...The advanced temperature and stress test machine was introduced to determine the early cracking tendency of concrete with inclusion of light-burnt MgO under full restraint by tracking the development of thermal,physical and deformation properties.Results showed that light-burnt MgO being incorporated ranging between 4 wt% and 6 wt% of cementitious materials was beneficial to increase the maximum compressive stress and cracking stress of concrete by 0.37 MPa and 0.2 MPa on average respectively.The second zero stress temperature was reduced by 11.4 ℃ and the maximum temperature was slightly reduced while cracking thermal impact was significantly enhanced from 59.8 ℃ to 66.2 ℃.Sensitive anti-cracking coefficient F was forwarded to assess the early cracking tendency of concrete and the inclusion of 4 wt% light-burnt MgO with activity of 109 s ranked the best in crack resistance.展开更多
文摘为抑制碱激发胶凝材料(AASM)因水化反应集中、孔隙失水引起的显著自收缩,本文提出采用MgO与Na_(2)SiO_(3)复配为复合激发剂,系统研究其对AASM凝结行为、水化产物组成、孔结构特征、强度发展与自收缩性能的影响规律。通过XRD(X-ray diffraction)与NMR(nuclear magnetic resonance)等手段表征发现:随着复合激发剂中MgO比例的增加,体系内类水滑石相生成显著增多,同时最可几孔径向10~20 nm区间集中,孔隙率有所上升。上述微观结构演变导致以下宏观性能变化:一方面,MgO的弱碱性质延缓了矿渣的水化进程,凝结时间延长,抗压强度随其掺量增加而降低;另一方面,类水滑石相的体积膨胀效应与孔隙率的提高共同缓解了毛细孔应力,使AASM的自收缩显著减小。研究表明,MgO与Na_(2)SiO_(3)在调控反应进程与水化产物组成方面具有协同作用。Na_(2)SiO_(3)提供强碱性环境以保障早期强度发展,而MgO则通过促进膨胀性产物生成,优化孔隙结构,有效抑制收缩开裂。该复合激发策略为兼顾AASM力学性能与体积稳定性提供了可行途径。
文摘In order to prepare high density magnesium aluminate spinel materials,the light-burned magnesia and alumina powder were used as the main raw materials.Active magnesium aluminate spinel powders were synthesized at different temperatures,and the sintering properties of the synthesized materials were characterized.The results show that the optimal light-burned temperature for synthesizing active magnesium aluminate spinel raw materials with small grain sizes and high sintering activity is 1400℃.The active spinel raw materials were sintered at 1750℃ for 3 h to form a dense spinel material,in which the spinel grains were well developed,exhibited a dense interlocking structure,and were uniformly distributed,with an average grain size of about 7.26μm.The bulk density and apparent porosity of the dense spinel material were 3.29 g·cm^(-3) and 3.5%,respectively.
基金Supported by the National Natural Science Foundation of China Project(22362018)the Yunnan Fundamental Research Projects(202401AS070102)。
文摘Ethylene(C_(2)H_(4))in vehicle exhaust is a highly reactive volatile organic compound(VOC).Its photooxidative reaction with NOx contributes to the formation of O3 and secondary organic aerosols(SOA),the latter being a key precursor of PM_(2.5).In this study,a novel MgO-supported Ag-Cu bimetallic catalyst was designed and investigated using density functional theory(DFT).The effects of Ag and Cu loading on the geometric structure,stability,and reactant adsorption characteristics of the catalyst were analyzed,and the catalytic oxidation pathways of C_(2)H_(4)over AgCu-MgO was elucidated.The results indicate that loading Ag significantly enhances the adsorption of C_(2)H_(4).The incorporation of Cu into Ag-MgO to form a AgCu-MgO bimetallic catalyst(dual atom catalyst,DACS)further improves the oxidative activity toward C_(2)H_(4).Based on the binding energies of the Ag and Cu bimetallic sites and the adsorption energies of C_(2)H_(4)and O_(2),three representative configurations were selected for detailed reaction pathway analysis.Among them,Configuration 6 of AgCu-MgO exhibited the highest catalytic oxidation performance.This study provides new atomic-scale insights for the rational design of efficient catalysts targeting olefinic pollutants in automotive emissions and offers valuable guidance for advancing exhaust after-treatment technologies.
基金Funded by National Natural Science Foundation of China(No.50539010)China Central Non-profit Research Funds of MWR(Nos.200901066,YWF0907)
文摘The advanced temperature and stress test machine was introduced to determine the early cracking tendency of concrete with inclusion of light-burnt MgO under full restraint by tracking the development of thermal,physical and deformation properties.Results showed that light-burnt MgO being incorporated ranging between 4 wt% and 6 wt% of cementitious materials was beneficial to increase the maximum compressive stress and cracking stress of concrete by 0.37 MPa and 0.2 MPa on average respectively.The second zero stress temperature was reduced by 11.4 ℃ and the maximum temperature was slightly reduced while cracking thermal impact was significantly enhanced from 59.8 ℃ to 66.2 ℃.Sensitive anti-cracking coefficient F was forwarded to assess the early cracking tendency of concrete and the inclusion of 4 wt% light-burnt MgO with activity of 109 s ranked the best in crack resistance.
