With the rapid development of wearable electronic skin technology, flexible strain sensors have shown great application prospects in the fields of human motion and physiological signal detection, medical diagnostics, ...With the rapid development of wearable electronic skin technology, flexible strain sensors have shown great application prospects in the fields of human motion and physiological signal detection, medical diagnostics, and human-computer interaction owing to their outstanding sensing performance. This paper reports a strain sensor with synergistic conductive network, consisting of stable carbon nanotube dispersion (CNT) layer and brittle MXene layer by dip-coating and electrostatic self-assembly method, and breathable three-dimensional (3D) flexible substrate of thermoplastic polyurethane (TPU) fibrous membrane prepared through electrospinning technology. The MXene/CNT@PDA-TPU (MC@p-TPU) flexible strain sensor had excellent air permeability, wide operating range (0–450 %), high sensitivity (Gauge Factor, GFmax = 8089.7), ultra-low detection limit (0.05 %), rapid response and recovery times (40 ms/60 ms), and excellent cycle stability and durability (10,000 cycles). Given its superior strain sensing capabilities, this sensor can be applied in physiological signals detection, human motion pattern recognition, and driving exoskeleton robots. In addition, MC@p-TPU fibrous membrane also exhibited excellent photothermal conversion performance and can be used as a wearable photo-heater, which has far-reaching application potential in the photothermal therapy of human joint diseases.展开更多
Adsorption as an effective technique for the remediation of wastewater has been widely used in industrial wastewater treatment due to the advantage of cost-effectiveness,availability of the adsorbent and ease of opera...Adsorption as an effective technique for the remediation of wastewater has been widely used in industrial wastewater treatment due to the advantage of cost-effectiveness,availability of the adsorbent and ease of operation.However,the low adsorption capacity of the reported adsorbents is still a challenge for wastewater treatment with highefficiency.Here,we developed a super adsorbent(SUA-1),which was a kind of porous carbon nanofibers derived from a composite of PAN-based electrospinning and ZIF-8(PAN/ZIF-8)via simple heat treatment process.The asprepared SUA showed an ultra-high adsorption capacity for adsorbing methyl blue(MB)at nearly three times its own weight,as high as 2998.18 mg/g.A series tests demonstrated that the pore-making effect of ZIF-8 during heat treatment process endowed high BET surface area and generated ZnO components as chemical adsorption center.Under the synergistic effect of bonding and non-bonding forces including ionic bond,electrostatic interaction,andπ-πinteraction,the adsorption capacity has been greatly improved.In view of promising efficiency,this work provides guidance and insights for the preparation of highly efficient adsorbents based on electrospinning derived porous carbon nanofibers.展开更多
Electrospinning technology has emerged as a promising method for fabricating flexible lithium-ion batter-ies(FLIBs)due to its ability to create materials with desir-able properties for energy storage applications.FLIB...Electrospinning technology has emerged as a promising method for fabricating flexible lithium-ion batter-ies(FLIBs)due to its ability to create materials with desir-able properties for energy storage applications.FLIBs,which are foldable and have high energy densities,are be-coming increasingly important as power sources for wear-able devices,flexible electronics,and mobile energy applica-tions.Carbon materials,especially carbon nanofibers,are pivotal in improving the performance of FLIBs by increas-ing electrical conductivity,chemical stability,and surface area,as well as reducing costs.These materials also play a significant role in establishing conducting networks and im-proving structural integrity,which are essential for extend-ing the cycle life and enhancing the safety of the batteries.This review considers the role of electrospinning in the fabrication of critical FLIB components,with a particular emphasis on the integration of carbon materials.It explores strategies to optimize FLIB performance by fine-tuning the electrospinning para-meters,such as electric field strength,spinning rate,solution concentration,and carbonization process.Precise control over fiber properties is crucial for enhancing battery reliability and stability during folding and bending.It also highlights the latest research findings in carbon-based electrode materials,high-performance electrolytes,and separator structures,discussing the practical challenges and opportunities these materials present.It underscores the significant impact of carbon materials on the evolution of FLIBs and their potential to shape future energy storage technologies.展开更多
The increasing consciousness about the depletion of natural resources and the sustainability agenda are the major driving forces to try to reuse and recycle organic materials such as agri-food and industrial wastes.In...The increasing consciousness about the depletion of natural resources and the sustainability agenda are the major driving forces to try to reuse and recycle organic materials such as agri-food and industrial wastes.In this context,keratin fibers,as a waste from the tannery industry,represent a great opportunity for the development of green functional materials.In this paper,keratin fibers were surface functionalized using the Layer-by-Layer(LbL)deposition technique and then freeze-dried in order to obtain a lightweight,fire-resistant,and sustainable material.The LbL coating,made with chitosan and carboxymethylated cellulose nanofibers,is fundamental in enabling the formation of a self-sustained structure after freeze-drying.The prepared porous fiber networks(density 100 kg m^(-3))display a keratin fiber content greater than 95 wt%and can easily self-extinguish the flame during a flammability test in a vertical configuration.In addition,during forced combustion tests(50 kW m^(-2))the samples exhibited a reduction of 37% in heat release rate and a reduction of 75%in smoke production if compared with a commercial polyurethane foam.The results obtained represent an excellent opportunity for the development of fire-safe sustainable materials based on fiber wastes.展开更多
Electrospinning has gained significant importance across various fields,including biomedicine,filtration,and packaging due to the control it provides over the properties of the resulting materials,such as fiber diamet...Electrospinning has gained significant importance across various fields,including biomedicine,filtration,and packaging due to the control it provides over the properties of the resulting materials,such as fiber diameter and membrane thickness.Chitosan is a biopolymer that can be utilized with both natural and synthetic copolymers,owing to its therapeutic potential,biocompatibility,and biodegradability.However,producing electrospun chitosan is challenging due to its high solution viscosity,which often results in the formation of beads instead of uniform fibers.To address this issue,the spinnability of chitosan is significantly enhanced,and the production of continuous nanofibers is facilitated by combining it with polymers such as polyethylene oxide(PEO)in suitable ratios.These chitosan–PEO nanofibers are primarily used in biomedical applications,including wound healing,drug delivery systems,and tissue engineering scaffolds.Additionally,they have shown promise in water treatment,filtration membranes,and packaging.Among all the nanofiber mats,chitosan/PEO-AC had the smallest fiber diameter(83±12.5 nm),chitosan/PEO_45S5 had the highest tensile strength(1611±678 MPa).This comprehensive review highlights recent advancements,ongoing challenges,and future directions in the electrospinning of chitosan-based fibers assisted by PEO.展开更多
Layer-by-layer(LBL)assembly shows great potential in fabrication of flexible conductive cotton fabrics(FCCF)with carbon nanotubes(CNT)as conductive components but is limited because complicated chemical modification o...Layer-by-layer(LBL)assembly shows great potential in fabrication of flexible conductive cotton fabrics(FCCF)with carbon nanotubes(CNT)as conductive components but is limited because complicated chemical modification of CNT is usually required.Herein,we reported a facile and eco-friendly LBL approach to fabricating FCCF by dipping in chitosan(CS)aqueous solution and poly(sodium 4-styrenesulfonate)(PSS)wrapped CNT aqueous dispersion alternately.The FCCF with electrical conductivity higher than 30 S/m was achieved when 4 layers of CNT were coated on the cotton fabric(CF).The obtained FCCF possessed outstanding mechanical stability with electrical resistivity almost unchanged after exposure to 500 times mechanical abrasion and 500 circles of tape peeling.The FCCF showed excellent strain sensing performance with high sensitivity(with a gauge factor up to 35.1)and a fast response time(70 ms).It can be used as a strain sensor to accurately detect various human deformations such as finger bending and joint movements.The FCCF could be used as a temperature sensor in that it exhibited stable and reproducible negative temperature sensing behavior in the temperature range of 30-100℃.展开更多
The over-exploitation of fossil fuel energy has brought about serious environmental problems.It would be of great significance to construct efficient energy conversion and storage system to maximize utilize renewable ...The over-exploitation of fossil fuel energy has brought about serious environmental problems.It would be of great significance to construct efficient energy conversion and storage system to maximize utilize renewable energy,which contributes to reducing environmental hazards.For the past few years,in terms of electrocatalysis and energy storage,carbon fiber materials show great advantages due to its outstanding electrical conductivity,good flexibility and mechanical property.As a simple and low-cost technique,electrospinning can be employed to prepare various nanofibers.It is noted that the functional fiber materials with different special structure and composition can be obtained for energy conversion and storage by combining electrospinning with other post-processing.In this paper,the structural design,controllable synthesis and multifunctional applications of electrospinning-derived functional carbon-based materials(EFCMs)is reviewed.Firstly,we briefly introduce the history,basic principle and typical equipment of electrospinning.Then we discuss the strategies for preparing EFCMs with different structures and composition in detail.In addition,we show recently the application of advanced EFCMs in energy conversion and storage,such as nitrogen species reduction reaction,CO_(2) reduction reaction,oxygen reduction reaction,water-splitting,supercapacitors and ion batteries.In the end,we propose some perspectives on the future development direction of EFCMs.展开更多
In this paper,1-butyl-3-methylimidazole tetrafluoroborate([BMIM]BF4)is used as corrosion inhibitor.Polyacrylonitrile(PAN)is used to load the corrosion inhibitor.PAN/[BMIM]BF4 hybrid nanofibers are successfullysynthesi...In this paper,1-butyl-3-methylimidazole tetrafluoroborate([BMIM]BF4)is used as corrosion inhibitor.Polyacrylonitrile(PAN)is used to load the corrosion inhibitor.PAN/[BMIM]BF4 hybrid nanofibers are successfullysynthesized by electrospinning technology.The alkyd varnish is coated on the fiber membrane to prepare a compositecoating,and then a series of tests are carried out on the self-healing and anticorrosive performance of the compositecoating.It is observed by scanning electron microscope that the fiber morphology is stable and there is no bead-likestructure.The composition of the composite fiber is analyzed by Fourier infrared spectroscopy,and it is confirmed thatthe hybrid nanofiber was successfully prepared.3D laser confocal scanning microscope was used to observe thecorrosion morphology and profile of the carbon steel.The composite coating shows good self-healing performance.[BMIM]BF4 can form a protective film on the surface of the bare carbon steel substrate through physical adsorption orchemical adsorption in an alkaline environment.Electrochemical impedance spectroscopy was tested and analyzed.It isfound that the maximum corrosion inhibition efficiency of the coating is 88.5%in 3.5 wt.%alkaline NaCl solution.Compared with the blank coating without nanofibers,the composite fiber varnish composite coating exhibits good selfhealingand anti-corrosion properties.展开更多
The abuse of plastic food packaging has brought about severe white pollution issues around the world.Developing green and sustainable biomass packaging is an effective way to solve this problem.Hence,a chitosan/sodium...The abuse of plastic food packaging has brought about severe white pollution issues around the world.Developing green and sustainable biomass packaging is an effective way to solve this problem.Hence,a chitosan/sodium alginate-based multilayer film is fabricated via a layer-by-layer(LBL)self-assembly method.With the help of superior interaction between the layers,the multilayer film possesses excellent mechanical properties(with a tensile strength of 50 MPa).Besides,the film displays outstanding water retention property(blocking moisture of 97.56%)and ultraviolet blocking property.Anthocyanin is introduced into the film to detect the food quality since it is one natural plant polyphenol that is sensitive to the pH changes ranging from 1 to 13 in food when spoilage occurs.It is noted that the film is also bacteriostatic which is desired for food packaging.This study describes a simple technique for the development of advanced multifunctional and fully biodegradable food packaging film and it is a sustainable alternative to plastic packaging.展开更多
Owing to the significant increase in air pollutants and the spread of infectious diseases,it seems that the use of face masks will become an essential item in human societies.Therefore,there is a need to conduct more ...Owing to the significant increase in air pollutants and the spread of infectious diseases,it seems that the use of face masks will become an essential item in human societies.Therefore,there is a need to conduct more research to develop novel types of respirators utilizing upto-date science such as nanotechnology.In this study,we fabricated a nanocomposite fibrous filter containing modified graphene oxide(GO)and zinc oxide(ZnO)nanoparticles.This layer was used as an active filter for absorbing and removing air pollutants,such as suspended submicron particles(below 2.5 microns)and CO_(2),NO_(2),and SO_(2)gases.The synthesized nanostructures and fibrous filters were characterized by different analysis(FTIR,XRD,TGA,and FESEM),and the performance of the filters was surveyed by tests such as pressure drop,CO_(2),NO_(2),SO_(2)gas rejection,and particulate removal.The results showed that the stabilization of the modified GO and ZnO nanostructures on the fibrous filter improved the effectiveness of this filter as a mask for removing toxic particles and gases,and the filter containing nanoparticles had the best performance.展开更多
Flexible wearable batteries are widely used in smartwatches, foldable phones, and fitness trackers due to their thinness and small size. Zinc-based batteries have the advantages of low cost, high safety, and ecofriend...Flexible wearable batteries are widely used in smartwatches, foldable phones, and fitness trackers due to their thinness and small size. Zinc-based batteries have the advantages of low cost, high safety, and ecofriendliness, which are considered to be the best alternative to flexible lithium-ion batteries(LIBs).Therefore, wearable flexible zinc-ion batteries(FZIBs) have attracted considerable interest as a promising energy storage device. Electrospun nanofibers(ESNFs) have great potential for application in wearable FZIBs due to their low density, high porosity, large specific surface area, and flexibility. Moreover, electrospinning technology can achieve the versatility of nanofibers through structural design and incorporation of other multifunctional materials. This paper reviews a wide range of applications of electrospinning in FZIBs, mainly in terms of cathode, anode, separator, polymer electrolyte, and all-inone flexible batteries. Firstly, the electrospinning device, principles, and influencing parameters are briefly described, showing its positive impact on FZIBs. Subsequently, the energy storage principles and electrode configurations of FZIBs are described, and some of the common problems of the batteries are illustrated, including zinc anode dendrite growth, corrosion, cathode structure collapse, and poor electrical conductivity. This is followed by a comprehensive overview of research progress on the individual components of FZIBs(cathode, anode, separator, and polymer electrolyte) from the perspective of electrostatically spun fiber materials and an in-depth study of all-in-one flexible batteries. Finally, the challenges and future development of FZIBs are individually concluded and look forward. We hope that this work will provide new ideas and avenues for the development of advanced energy technologies and smart wearable systems.展开更多
In recent years,nanogenerators(NGs)have attracted wide attention in the energy field,among which triboelectric nanogenerators(TENGs)have shown superior performance.Multiple reports of electrospinning(ES)-based TENGs h...In recent years,nanogenerators(NGs)have attracted wide attention in the energy field,among which triboelectric nanogenerators(TENGs)have shown superior performance.Multiple reports of electrospinning(ES)-based TENGs have been reported,but there is a lack of deep analysis of the designing method from microstructure,limiting the creative of new ES-based TENGs.Most TENGs use polymer materials to achieve corresponding design,which requires structural design of polymer materials.The existing polymer molding design methods include macroscopic molding methods,such as injection,compression,extrusion,calendering,etc.,combined with liquid-solid changes such as soluting and melting;it also includes micro-nano molding technology,such as melt-blown method,coagulation bath method,ES method,and nanoimprint method.In fact,ES technology has good controllability of thickness dimension and rich means of nanoscale structure regulation.At present,these characteristics have not been reviewed.Therefore,in this paper,we combine recent reports with some microstructure regulation functions of ES to establish a more general TENGs design method.Based on the rich microstructure research results in the field of ES,much more new types of TENGs can be designed in the future.展开更多
A series of flexible and self-standing coal-derived carbon fibers(CCFs)were fabricated through electro-spinning coupled with carbonization using bituminous coal and polyacrylonitrile(PAN)as the carbon precursors.These...A series of flexible and self-standing coal-derived carbon fibers(CCFs)were fabricated through electro-spinning coupled with carbonization using bituminous coal and polyacrylonitrile(PAN)as the carbon precursors.These CCFs were utilized as free-standing lithium-ion battery(LIB)anodes.Optimizing car-bonization temperature reveals that the CCFs exhibit a one-dimensional solid linear structure with a uni-form distribution of graphite-like microcrystals.These fibers possess a dense structure and smooth surface,with averaging diameter from approximately 125.0 to 210.0 nm at carbonization temperatures ranging from 600 to 900℃.During electrospinning and carbonization,the aromatic rings enriched in bituminous coal crosslink with PAN chains,forming a robust three-dimensional(3D)framework.This 3D microstructure significantly enhances the flexibility and tensile strength of CCFs,while increasing the graphite-like sp^(2)microcrystalline carbon content,thus improving electrical conductivity.The CCFs carbonized at 700℃demonstrate an optimal balance of sp^(3)amorphous and sp^(2)graphite-like carbons.The average diameter of CCFs-700 is 177 nm and the specific surface area(SSA)is 7.2 m^(2)g^(-1).Additionally,the fibers contain oxygen-containing functional groups,as well as nitrogen-containing func-tional groups,including pyridinic nitrogen and pyrrolic nitrogen.Owing to its characteristics,the CCFs-700 showcases remarkable electrochemical performance,delivering a high reversible capacity of 631.4 mAh g^(-1).CCFs-700 also exhibit outstanding cycle stability,which retains approximately all of their first capacity(400.1 mAh g^(-1))after 120 cycles.This research offers an economical yet scalable approach for producing flexible and self-supporting anodes for LIBs that do not require current collectors,binders and conductive additives,thereby simplifying the electrode fabrication process.展开更多
The combined use of guided tissue/bone regeneration(GTR/GBR)membranes and bone filling grafts represents a classical therapy for guiding the regeneration and functional reconstruction of oral soft and hard tissues.Nev...The combined use of guided tissue/bone regeneration(GTR/GBR)membranes and bone filling grafts represents a classical therapy for guiding the regeneration and functional reconstruction of oral soft and hard tissues.Nevertheless,due to its displacement and poor mechanical support,bone meal is not suitable for implantation in the case of insufficient cortical bone support and large dimensional defects.The combination of GTR/GBR membrane with a three-dimensional(3D)porous scaffold may offer a resolution for the repair and functional reconstruction of large soft and hard tissue defects.In this study,a novel integrated gradient biodegradable porous scaffold was prepared by bonding a poly(lactic-co-glycolic acid)(PLGA)/fish collagen(FC)electrospun membrane(PFC)to a 3D-printed PLGA/nano-hydroxyapatite(HA)(PHA)scaffold.The consistency of the composition(PLGA)ensured strong interfacial bonding between the upper fibrous membrane and the lower 3D scaffold.In vitro cell experiments showed that the PFC membrane(upper layer)effectively prevented the unwanted migration of L929 cells.Further in vivo investigations with an oral soft and hard tissue defect model in beagles revealed that the integrated scaffold effectively guided the regeneration of defective oral tissues.These results suggest that the designed integrated scaffold has great potential for guiding the regeneration and reconstruction of large oral soft and hard tissues.展开更多
The excellent performance of laser-induced removal has been widely recognized,yet the limitation of its applications has been gradually approached for complex multilayer coatings in practical situations.Therefore,it i...The excellent performance of laser-induced removal has been widely recognized,yet the limitation of its applications has been gradually approached for complex multilayer coatings in practical situations.Therefore,it is necessary to clarify the laser-induced removal mechanisms of different material layers,which may contribute to guiding precise and controllable layer-by-layer removal and subsequent repair.Herein,the laser-induced layer-by-layer removal of FeCo-based multilayer wave-absorbing coatings was designed and verified.The macro/micro morphologies and elemental analysis indicated that the removal of the topcoat and wave-absorbing layer was dominated by thermal ablation.Interestingly,experiments and simulations demonstrated that a shift in the removal mechanism,i.e.,from the ablation mechanism to the stripping mechanism,occurred when the laser irradiated the primer.It is mainly attributed to the competing contributions of temperature rise and thermal stress to the removal effect.Subsequent macrodynamic behavior captured by a high-speed camera also validated the combination of both re-moval mechanisms.Additionally,the evolution of the crystalline phase and element valence state was revealed.Further laser-induced breakdown spectroscopy revealed the microscopic material motions dur-ing the layer-by-layer removal,including molecular bond breaking induced by multiphoton absorption,atomic ionization,excitation and compounding of electrons and ions,crystal lattice deformation caused by electron-phonon coupling,etc.Based on the above analysis,the thermo-mechanical action mechanisms and microscopic motion models of laser-induced layer-by-layer removal for FeCo-based multilayer wave-absorbing coatings were established,which is expected to be an ideal method for breaking through the limitation of laser-induced removal’s applications.展开更多
Lithium-gas batteries(LGBs)have garnered significant attention due to their impressive high-energy densities and unique gas conversion capability.Nevertheless,the practical application of LGBs faces substantial challe...Lithium-gas batteries(LGBs)have garnered significant attention due to their impressive high-energy densities and unique gas conversion capability.Nevertheless,the practical application of LGBs faces substantial challenges,including sluggish gas conversion kinetics inducing in low-rate performance and high overpotential,along with limited electrochemical reversibility leading to poor cycle life.The imperative task is to develop gas electrodes with remarkable catalytic activity,abundant active sites,and exceptional electrochemical stability.Electrospinning,a versatile and well-established technique for fabricating fibrous nanomaterials,has been extensively explored in LGB applications.In this work,we emphasize the critical structure-property for ideal gas electrodes and summarize the advancement of employing electrospun nanofibers(NFs)for performance enhancement in LGBs.Beyond elucidating the fundamental principles of LGBs and the electrospinning technique,we focus on the systematic design of electrospun NF-based gas electrodes regarding optimal structural fabrication,catalyst handling and activation,and catalytic site optimization,as well as considerations for large-scale implementation.The demonstrated principles and regulations for electrode design are expected to inspire broad applications in catalyst-based energy applications.展开更多
The development of high-performance non-fullerene acceptors with extended exciton diffusion lengths has positioned the sequential layer-by-layer(LBL)solution processing technique as a promising approach for fabricatin...The development of high-performance non-fullerene acceptors with extended exciton diffusion lengths has positioned the sequential layer-by-layer(LBL)solution processing technique as a promising approach for fabricating high-performance and large-area organic solar cells(OSCs).This method allows for the independent dissolution and deposition of donor and acceptor materials,enabling precise morphology control.In this review,we provide a comprehensive overview of the LBL processing technique,focusing on the morphology of the active layer.The swelling intercalation phase-separation(SIPS)model is introduced as the mainstream theory of morphology evolution,with a detailed discussion on vertical phase separation.We summarize recent strategies for morphology optimization.Additionally,we review the progress in LBL-based large-area device and module fabrication,as well as green processing approaches.Finally,we highlight current challenges and future prospects,paving the way for the commercialization of LBL-processed OSCs.展开更多
To enhance the corrosion resistance of magnesium（Mg） alloy and to impart its surface with antibacterial functionality for inhibiting biofilm formation and biocorrosion, Mg（OH）2 films were fabricated on AZ31 magnes...To enhance the corrosion resistance of magnesium（Mg） alloy and to impart its surface with antibacterial functionality for inhibiting biofilm formation and biocorrosion, Mg（OH）2 films were fabricated on AZ31 magnesium alloy substrates by an in-situ hydrothermal method and well-defined multilayer coatings, consisting of gentamicin sulfate（GS） and poly（sodium 4-styrene sulfonate）（PSS）, were prepared via layer-by-layer（Lb L） assembly. The morphologies, chemical compositions and corrosion resistance of the obtained（PSS/GS）n/Mg sample were investigated using scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, electrochemical methods and immersion tests. Finally, the bactericidal activity of（PSS/GS）n/Mg samples against Staphylococcus aureus was assessed by the zone of inhibition methods and plate-counting method. The so-synthesized composite coating on the Mg alloy substrates exhibits good corrosion resistance and antibacterial performance, which make them attractive as coatings for medical implanted devices.展开更多
A new type of vascular stent is designed for treating stenotic vessels. Aiming at overcoming the shortcomings of existing equipment and technology for preparing a bioabsorbable vascular stent （BVS）, a new method whi...A new type of vascular stent is designed for treating stenotic vessels. Aiming at overcoming the shortcomings of existing equipment and technology for preparing a bioabsorbable vascular stent （BVS）, a new method which combines 3D bio-printing and electrospinning to prepare the composite bioabsorbable vascular stent （CBVS） is proposed. The inner layer of the CBVS can be obtained through 3D bio- printing using poly-p-dioxanone （PPDO）. The thin nanofiber film that serves as the outer layer can be built through electrospinning using mixtures of chitosan-PVA （poly （vinyl alcohol））. Tests of mechanical properties show that the stent prepared through 3D bio-printing combined with electrospinning is better than that prepared through 3D bio- printing alone. Cells cultivated on the CBVS adhere and proliferate better due to the natural, biological chitosan in the outer layer. The proposed complex process and method can provide a good basis for preparing a controllable drug-carrying vascular stent. Overall, the CBVS can be a good candidate for treating stenotic vessels.展开更多
Vanadium pentoxide（V2O5）/molybdenum trioxide（MoO 3） composites with different molar ratios of vanadium（V） to molybdenum（Mo） were synthesized via a simple electrospinning technique. The photocatalytic activity ...Vanadium pentoxide（V2O5）/molybdenum trioxide（MoO 3） composites with different molar ratios of vanadium（V） to molybdenum（Mo） were synthesized via a simple electrospinning technique. The photocatalytic activity of the composites were evaluated by their ability to photodegrade methylene blue and dimethyl phthalate（DMP） under visible-light irradiation. Compared with pure V2O5 and MoO 3,the V2O5/MoO 3 composites showed enhanced visible-light photocatalytic activity because of a V 3d impurity energy level and the formation of heterostructures at the interface between V2O5 and MoO 3. The optimal molar ratio of V to Mo in the V2O5/MoO 3 composites was found to be around 1/2. Furthermore,high-performance liquid chromatographic monitoring revealed that phthalic acid was the main intermediate in the photocatalytic degradation process of DMP.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52373093 and 12072325)the Outstanding Youth Fund of Henan Province(No.242300421062)+1 种基金National Key R&D Program of China(No.2019YFA0706802)the 111 project(No.D18023).
文摘With the rapid development of wearable electronic skin technology, flexible strain sensors have shown great application prospects in the fields of human motion and physiological signal detection, medical diagnostics, and human-computer interaction owing to their outstanding sensing performance. This paper reports a strain sensor with synergistic conductive network, consisting of stable carbon nanotube dispersion (CNT) layer and brittle MXene layer by dip-coating and electrostatic self-assembly method, and breathable three-dimensional (3D) flexible substrate of thermoplastic polyurethane (TPU) fibrous membrane prepared through electrospinning technology. The MXene/CNT@PDA-TPU (MC@p-TPU) flexible strain sensor had excellent air permeability, wide operating range (0–450 %), high sensitivity (Gauge Factor, GFmax = 8089.7), ultra-low detection limit (0.05 %), rapid response and recovery times (40 ms/60 ms), and excellent cycle stability and durability (10,000 cycles). Given its superior strain sensing capabilities, this sensor can be applied in physiological signals detection, human motion pattern recognition, and driving exoskeleton robots. In addition, MC@p-TPU fibrous membrane also exhibited excellent photothermal conversion performance and can be used as a wearable photo-heater, which has far-reaching application potential in the photothermal therapy of human joint diseases.
基金Natural Science Foundation of China(22134005,22204011)Chongqing Talents Program for Outstanding Scientists(cstc2021ycjh-bgzxm0179)。
文摘Adsorption as an effective technique for the remediation of wastewater has been widely used in industrial wastewater treatment due to the advantage of cost-effectiveness,availability of the adsorbent and ease of operation.However,the low adsorption capacity of the reported adsorbents is still a challenge for wastewater treatment with highefficiency.Here,we developed a super adsorbent(SUA-1),which was a kind of porous carbon nanofibers derived from a composite of PAN-based electrospinning and ZIF-8(PAN/ZIF-8)via simple heat treatment process.The asprepared SUA showed an ultra-high adsorption capacity for adsorbing methyl blue(MB)at nearly three times its own weight,as high as 2998.18 mg/g.A series tests demonstrated that the pore-making effect of ZIF-8 during heat treatment process endowed high BET surface area and generated ZnO components as chemical adsorption center.Under the synergistic effect of bonding and non-bonding forces including ionic bond,electrostatic interaction,andπ-πinteraction,the adsorption capacity has been greatly improved.In view of promising efficiency,this work provides guidance and insights for the preparation of highly efficient adsorbents based on electrospinning derived porous carbon nanofibers.
文摘Electrospinning technology has emerged as a promising method for fabricating flexible lithium-ion batter-ies(FLIBs)due to its ability to create materials with desir-able properties for energy storage applications.FLIBs,which are foldable and have high energy densities,are be-coming increasingly important as power sources for wear-able devices,flexible electronics,and mobile energy applica-tions.Carbon materials,especially carbon nanofibers,are pivotal in improving the performance of FLIBs by increas-ing electrical conductivity,chemical stability,and surface area,as well as reducing costs.These materials also play a significant role in establishing conducting networks and im-proving structural integrity,which are essential for extend-ing the cycle life and enhancing the safety of the batteries.This review considers the role of electrospinning in the fabrication of critical FLIB components,with a particular emphasis on the integration of carbon materials.It explores strategies to optimize FLIB performance by fine-tuning the electrospinning para-meters,such as electric field strength,spinning rate,solution concentration,and carbonization process.Precise control over fiber properties is crucial for enhancing battery reliability and stability during folding and bending.It also highlights the latest research findings in carbon-based electrode materials,high-performance electrolytes,and separator structures,discussing the practical challenges and opportunities these materials present.It underscores the significant impact of carbon materials on the evolution of FLIBs and their potential to shape future energy storage technologies.
基金supported by the Italian Ministry of University(MIUR)call PRIN 2017 with the project“PANACEA:A technology Platform for the sustainable recovery and advanced use of NAnostructured CEllulose from Agro-food residues”(grant No.2017LEPH3M).
文摘The increasing consciousness about the depletion of natural resources and the sustainability agenda are the major driving forces to try to reuse and recycle organic materials such as agri-food and industrial wastes.In this context,keratin fibers,as a waste from the tannery industry,represent a great opportunity for the development of green functional materials.In this paper,keratin fibers were surface functionalized using the Layer-by-Layer(LbL)deposition technique and then freeze-dried in order to obtain a lightweight,fire-resistant,and sustainable material.The LbL coating,made with chitosan and carboxymethylated cellulose nanofibers,is fundamental in enabling the formation of a self-sustained structure after freeze-drying.The prepared porous fiber networks(density 100 kg m^(-3))display a keratin fiber content greater than 95 wt%and can easily self-extinguish the flame during a flammability test in a vertical configuration.In addition,during forced combustion tests(50 kW m^(-2))the samples exhibited a reduction of 37% in heat release rate and a reduction of 75%in smoke production if compared with a commercial polyurethane foam.The results obtained represent an excellent opportunity for the development of fire-safe sustainable materials based on fiber wastes.
文摘Electrospinning has gained significant importance across various fields,including biomedicine,filtration,and packaging due to the control it provides over the properties of the resulting materials,such as fiber diameter and membrane thickness.Chitosan is a biopolymer that can be utilized with both natural and synthetic copolymers,owing to its therapeutic potential,biocompatibility,and biodegradability.However,producing electrospun chitosan is challenging due to its high solution viscosity,which often results in the formation of beads instead of uniform fibers.To address this issue,the spinnability of chitosan is significantly enhanced,and the production of continuous nanofibers is facilitated by combining it with polymers such as polyethylene oxide(PEO)in suitable ratios.These chitosan–PEO nanofibers are primarily used in biomedical applications,including wound healing,drug delivery systems,and tissue engineering scaffolds.Additionally,they have shown promise in water treatment,filtration membranes,and packaging.Among all the nanofiber mats,chitosan/PEO-AC had the smallest fiber diameter(83±12.5 nm),chitosan/PEO_45S5 had the highest tensile strength(1611±678 MPa).This comprehensive review highlights recent advancements,ongoing challenges,and future directions in the electrospinning of chitosan-based fibers assisted by PEO.
基金financially supported by the Natural Science Foundation of Chongqing,China(No.cstc2021jcyj-msxmX0943)the Chongqing Talent Plan for Young Top-Notch Talents(No.CQYC2021059217)the Foundation of Science and Technology Department of Sichuan Province(No.2022YFH0019).
文摘Layer-by-layer(LBL)assembly shows great potential in fabrication of flexible conductive cotton fabrics(FCCF)with carbon nanotubes(CNT)as conductive components but is limited because complicated chemical modification of CNT is usually required.Herein,we reported a facile and eco-friendly LBL approach to fabricating FCCF by dipping in chitosan(CS)aqueous solution and poly(sodium 4-styrenesulfonate)(PSS)wrapped CNT aqueous dispersion alternately.The FCCF with electrical conductivity higher than 30 S/m was achieved when 4 layers of CNT were coated on the cotton fabric(CF).The obtained FCCF possessed outstanding mechanical stability with electrical resistivity almost unchanged after exposure to 500 times mechanical abrasion and 500 circles of tape peeling.The FCCF showed excellent strain sensing performance with high sensitivity(with a gauge factor up to 35.1)and a fast response time(70 ms).It can be used as a strain sensor to accurately detect various human deformations such as finger bending and joint movements.The FCCF could be used as a temperature sensor in that it exhibited stable and reproducible negative temperature sensing behavior in the temperature range of 30-100℃.
基金supported by the Natural Science Foundation of Shandong Province(No.ZR2022QE076)the National Natural Science Foundation of China(No.52202092)。
文摘The over-exploitation of fossil fuel energy has brought about serious environmental problems.It would be of great significance to construct efficient energy conversion and storage system to maximize utilize renewable energy,which contributes to reducing environmental hazards.For the past few years,in terms of electrocatalysis and energy storage,carbon fiber materials show great advantages due to its outstanding electrical conductivity,good flexibility and mechanical property.As a simple and low-cost technique,electrospinning can be employed to prepare various nanofibers.It is noted that the functional fiber materials with different special structure and composition can be obtained for energy conversion and storage by combining electrospinning with other post-processing.In this paper,the structural design,controllable synthesis and multifunctional applications of electrospinning-derived functional carbon-based materials(EFCMs)is reviewed.Firstly,we briefly introduce the history,basic principle and typical equipment of electrospinning.Then we discuss the strategies for preparing EFCMs with different structures and composition in detail.In addition,we show recently the application of advanced EFCMs in energy conversion and storage,such as nitrogen species reduction reaction,CO_(2) reduction reaction,oxygen reduction reaction,water-splitting,supercapacitors and ion batteries.In the end,we propose some perspectives on the future development direction of EFCMs.
基金Projects(42076039,42106042)supported by the National Natural Science Foundation of ChinaProject(202165004)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(JC12022106)supported by 2022 Innovation Project for Young Scientific and Technological Talents in Basic Science Research,China。
文摘In this paper,1-butyl-3-methylimidazole tetrafluoroborate([BMIM]BF4)is used as corrosion inhibitor.Polyacrylonitrile(PAN)is used to load the corrosion inhibitor.PAN/[BMIM]BF4 hybrid nanofibers are successfullysynthesized by electrospinning technology.The alkyd varnish is coated on the fiber membrane to prepare a compositecoating,and then a series of tests are carried out on the self-healing and anticorrosive performance of the compositecoating.It is observed by scanning electron microscope that the fiber morphology is stable and there is no bead-likestructure.The composition of the composite fiber is analyzed by Fourier infrared spectroscopy,and it is confirmed thatthe hybrid nanofiber was successfully prepared.3D laser confocal scanning microscope was used to observe thecorrosion morphology and profile of the carbon steel.The composite coating shows good self-healing performance.[BMIM]BF4 can form a protective film on the surface of the bare carbon steel substrate through physical adsorption orchemical adsorption in an alkaline environment.Electrochemical impedance spectroscopy was tested and analyzed.It isfound that the maximum corrosion inhibition efficiency of the coating is 88.5%in 3.5 wt.%alkaline NaCl solution.Compared with the blank coating without nanofibers,the composite fiber varnish composite coating exhibits good selfhealingand anti-corrosion properties.
基金National Undergraduate Training Program for Innovation and Entrepreneurship of China (Grant No.202210288027).
文摘The abuse of plastic food packaging has brought about severe white pollution issues around the world.Developing green and sustainable biomass packaging is an effective way to solve this problem.Hence,a chitosan/sodium alginate-based multilayer film is fabricated via a layer-by-layer(LBL)self-assembly method.With the help of superior interaction between the layers,the multilayer film possesses excellent mechanical properties(with a tensile strength of 50 MPa).Besides,the film displays outstanding water retention property(blocking moisture of 97.56%)and ultraviolet blocking property.Anthocyanin is introduced into the film to detect the food quality since it is one natural plant polyphenol that is sensitive to the pH changes ranging from 1 to 13 in food when spoilage occurs.It is noted that the film is also bacteriostatic which is desired for food packaging.This study describes a simple technique for the development of advanced multifunctional and fully biodegradable food packaging film and it is a sustainable alternative to plastic packaging.
文摘Owing to the significant increase in air pollutants and the spread of infectious diseases,it seems that the use of face masks will become an essential item in human societies.Therefore,there is a need to conduct more research to develop novel types of respirators utilizing upto-date science such as nanotechnology.In this study,we fabricated a nanocomposite fibrous filter containing modified graphene oxide(GO)and zinc oxide(ZnO)nanoparticles.This layer was used as an active filter for absorbing and removing air pollutants,such as suspended submicron particles(below 2.5 microns)and CO_(2),NO_(2),and SO_(2)gases.The synthesized nanostructures and fibrous filters were characterized by different analysis(FTIR,XRD,TGA,and FESEM),and the performance of the filters was surveyed by tests such as pressure drop,CO_(2),NO_(2),SO_(2)gas rejection,and particulate removal.The results showed that the stabilization of the modified GO and ZnO nanostructures on the fibrous filter improved the effectiveness of this filter as a mask for removing toxic particles and gases,and the filter containing nanoparticles had the best performance.
基金National Natural Science Foundation of China (52103061)Young Elite Scientist Sponsorship Program by China Association for Science and Technology (YESS20220298)+2 种基金Tianjin Enterprise Science and Technology Commissioner Project (23YDTPJC00400)China Postdoctoral Science Foundation (2021T140419, 2022M711959)State Key Laboratory of Membrane and Membrane Separation, Tiangong University。
文摘Flexible wearable batteries are widely used in smartwatches, foldable phones, and fitness trackers due to their thinness and small size. Zinc-based batteries have the advantages of low cost, high safety, and ecofriendliness, which are considered to be the best alternative to flexible lithium-ion batteries(LIBs).Therefore, wearable flexible zinc-ion batteries(FZIBs) have attracted considerable interest as a promising energy storage device. Electrospun nanofibers(ESNFs) have great potential for application in wearable FZIBs due to their low density, high porosity, large specific surface area, and flexibility. Moreover, electrospinning technology can achieve the versatility of nanofibers through structural design and incorporation of other multifunctional materials. This paper reviews a wide range of applications of electrospinning in FZIBs, mainly in terms of cathode, anode, separator, polymer electrolyte, and all-inone flexible batteries. Firstly, the electrospinning device, principles, and influencing parameters are briefly described, showing its positive impact on FZIBs. Subsequently, the energy storage principles and electrode configurations of FZIBs are described, and some of the common problems of the batteries are illustrated, including zinc anode dendrite growth, corrosion, cathode structure collapse, and poor electrical conductivity. This is followed by a comprehensive overview of research progress on the individual components of FZIBs(cathode, anode, separator, and polymer electrolyte) from the perspective of electrostatically spun fiber materials and an in-depth study of all-in-one flexible batteries. Finally, the challenges and future development of FZIBs are individually concluded and look forward. We hope that this work will provide new ideas and avenues for the development of advanced energy technologies and smart wearable systems.
基金supported by the National Natural Science Foundation of China(12104249,11804313 and 11847135)the Youth Innovation Team Project of Shandong Provincial Education Department(2021KJ013,2020KJN015)by State Key Laboratory of Bio-Fibers and Eco-Textiles(Qingdao University)(GZRC202011&ZKT46)。
文摘In recent years,nanogenerators(NGs)have attracted wide attention in the energy field,among which triboelectric nanogenerators(TENGs)have shown superior performance.Multiple reports of electrospinning(ES)-based TENGs have been reported,but there is a lack of deep analysis of the designing method from microstructure,limiting the creative of new ES-based TENGs.Most TENGs use polymer materials to achieve corresponding design,which requires structural design of polymer materials.The existing polymer molding design methods include macroscopic molding methods,such as injection,compression,extrusion,calendering,etc.,combined with liquid-solid changes such as soluting and melting;it also includes micro-nano molding technology,such as melt-blown method,coagulation bath method,ES method,and nanoimprint method.In fact,ES technology has good controllability of thickness dimension and rich means of nanoscale structure regulation.At present,these characteristics have not been reviewed.Therefore,in this paper,we combine recent reports with some microstructure regulation functions of ES to establish a more general TENGs design method.Based on the rich microstructure research results in the field of ES,much more new types of TENGs can be designed in the future.
基金supported by the National Natural Science Foundation of China(Nos.52474290,52274261,52074109,52304284)the Open Subjects of Henan Provincial Key Laboratory of Coal Green Conversion(No.CGCF202201)+1 种基金the Key Scientific and Technological Project of Henan Province(No.242102240008)the Key Scientific Research Projects of Colleges and Universities in Henan Province(No.24A440003).
文摘A series of flexible and self-standing coal-derived carbon fibers(CCFs)were fabricated through electro-spinning coupled with carbonization using bituminous coal and polyacrylonitrile(PAN)as the carbon precursors.These CCFs were utilized as free-standing lithium-ion battery(LIB)anodes.Optimizing car-bonization temperature reveals that the CCFs exhibit a one-dimensional solid linear structure with a uni-form distribution of graphite-like microcrystals.These fibers possess a dense structure and smooth surface,with averaging diameter from approximately 125.0 to 210.0 nm at carbonization temperatures ranging from 600 to 900℃.During electrospinning and carbonization,the aromatic rings enriched in bituminous coal crosslink with PAN chains,forming a robust three-dimensional(3D)framework.This 3D microstructure significantly enhances the flexibility and tensile strength of CCFs,while increasing the graphite-like sp^(2)microcrystalline carbon content,thus improving electrical conductivity.The CCFs carbonized at 700℃demonstrate an optimal balance of sp^(3)amorphous and sp^(2)graphite-like carbons.The average diameter of CCFs-700 is 177 nm and the specific surface area(SSA)is 7.2 m^(2)g^(-1).Additionally,the fibers contain oxygen-containing functional groups,as well as nitrogen-containing func-tional groups,including pyridinic nitrogen and pyrrolic nitrogen.Owing to its characteristics,the CCFs-700 showcases remarkable electrochemical performance,delivering a high reversible capacity of 631.4 mAh g^(-1).CCFs-700 also exhibit outstanding cycle stability,which retains approximately all of their first capacity(400.1 mAh g^(-1))after 120 cycles.This research offers an economical yet scalable approach for producing flexible and self-supporting anodes for LIBs that do not require current collectors,binders and conductive additives,thereby simplifying the electrode fabrication process.
基金supported by the National Natural Science Foundation of China(No.32371398)the Sichuan International Science and Technology Innovation Cooperation Project,China(No.2023YFH0064)+1 种基金the National Key Research and Development Program of China(No.2016YFA0201700)the Fundamental Research Funds for the Central Universities,China。
文摘The combined use of guided tissue/bone regeneration(GTR/GBR)membranes and bone filling grafts represents a classical therapy for guiding the regeneration and functional reconstruction of oral soft and hard tissues.Nevertheless,due to its displacement and poor mechanical support,bone meal is not suitable for implantation in the case of insufficient cortical bone support and large dimensional defects.The combination of GTR/GBR membrane with a three-dimensional(3D)porous scaffold may offer a resolution for the repair and functional reconstruction of large soft and hard tissue defects.In this study,a novel integrated gradient biodegradable porous scaffold was prepared by bonding a poly(lactic-co-glycolic acid)(PLGA)/fish collagen(FC)electrospun membrane(PFC)to a 3D-printed PLGA/nano-hydroxyapatite(HA)(PHA)scaffold.The consistency of the composition(PLGA)ensured strong interfacial bonding between the upper fibrous membrane and the lower 3D scaffold.In vitro cell experiments showed that the PFC membrane(upper layer)effectively prevented the unwanted migration of L929 cells.Further in vivo investigations with an oral soft and hard tissue defect model in beagles revealed that the integrated scaffold effectively guided the regeneration of defective oral tissues.These results suggest that the designed integrated scaffold has great potential for guiding the regeneration and reconstruction of large oral soft and hard tissues.
基金support from the National Natural Science Foundation of China(Nos.52075246 and U2341264)the Natural Science Foundation of Jiangsu Province(Nos.BK20211568 and BZ2023045)+2 种基金National Science and Technology Major Project of China(No.J2019-Ⅲ-0010-0054)Fundamental Research Funds for the Central Universities(No.NE2022005)Liaoning Provincial Key Laboratory of Aircraft Ice Protection(No.XFX20220301).
文摘The excellent performance of laser-induced removal has been widely recognized,yet the limitation of its applications has been gradually approached for complex multilayer coatings in practical situations.Therefore,it is necessary to clarify the laser-induced removal mechanisms of different material layers,which may contribute to guiding precise and controllable layer-by-layer removal and subsequent repair.Herein,the laser-induced layer-by-layer removal of FeCo-based multilayer wave-absorbing coatings was designed and verified.The macro/micro morphologies and elemental analysis indicated that the removal of the topcoat and wave-absorbing layer was dominated by thermal ablation.Interestingly,experiments and simulations demonstrated that a shift in the removal mechanism,i.e.,from the ablation mechanism to the stripping mechanism,occurred when the laser irradiated the primer.It is mainly attributed to the competing contributions of temperature rise and thermal stress to the removal effect.Subsequent macrodynamic behavior captured by a high-speed camera also validated the combination of both re-moval mechanisms.Additionally,the evolution of the crystalline phase and element valence state was revealed.Further laser-induced breakdown spectroscopy revealed the microscopic material motions dur-ing the layer-by-layer removal,including molecular bond breaking induced by multiphoton absorption,atomic ionization,excitation and compounding of electrons and ions,crystal lattice deformation caused by electron-phonon coupling,etc.Based on the above analysis,the thermo-mechanical action mechanisms and microscopic motion models of laser-induced layer-by-layer removal for FeCo-based multilayer wave-absorbing coatings were established,which is expected to be an ideal method for breaking through the limitation of laser-induced removal’s applications.
基金Key Research and Development Program of Shaanxi Province,Grant/Award Number:2022GY-301National Key Research and Development Program of China,Grant/Award Numbers:2022YFB3807100,2022YFB3807102+3 种基金China Postdoctoral Science Foundation,Grant/Award Number:2020M683467Royal Society International Exchanges 2021 Cost Share(NSFC)scheme,Grant/Award Number:IECNSFC211074National Natural Science Foundation of China,Grant/Award Numbers:52073046,52103106,52172097Zhejiang Provincial Natural Science Foundation of China,Grant/Award Number:LGF21E020001.
文摘Lithium-gas batteries(LGBs)have garnered significant attention due to their impressive high-energy densities and unique gas conversion capability.Nevertheless,the practical application of LGBs faces substantial challenges,including sluggish gas conversion kinetics inducing in low-rate performance and high overpotential,along with limited electrochemical reversibility leading to poor cycle life.The imperative task is to develop gas electrodes with remarkable catalytic activity,abundant active sites,and exceptional electrochemical stability.Electrospinning,a versatile and well-established technique for fabricating fibrous nanomaterials,has been extensively explored in LGB applications.In this work,we emphasize the critical structure-property for ideal gas electrodes and summarize the advancement of employing electrospun nanofibers(NFs)for performance enhancement in LGBs.Beyond elucidating the fundamental principles of LGBs and the electrospinning technique,we focus on the systematic design of electrospun NF-based gas electrodes regarding optimal structural fabrication,catalyst handling and activation,and catalytic site optimization,as well as considerations for large-scale implementation.The demonstrated principles and regulations for electrode design are expected to inspire broad applications in catalyst-based energy applications.
基金Project(22408404)supported by the National Natural Science Foundation of China。
文摘The development of high-performance non-fullerene acceptors with extended exciton diffusion lengths has positioned the sequential layer-by-layer(LBL)solution processing technique as a promising approach for fabricating high-performance and large-area organic solar cells(OSCs).This method allows for the independent dissolution and deposition of donor and acceptor materials,enabling precise morphology control.In this review,we provide a comprehensive overview of the LBL processing technique,focusing on the morphology of the active layer.The swelling intercalation phase-separation(SIPS)model is introduced as the mainstream theory of morphology evolution,with a detailed discussion on vertical phase separation.We summarize recent strategies for morphology optimization.Additionally,we review the progress in LBL-based large-area device and module fabrication,as well as green processing approaches.Finally,we highlight current challenges and future prospects,paving the way for the commercialization of LBL-processed OSCs.
基金Project(2014TDJH104)supported by Shandong University of Science and Technology(SDUST)Research FundChina+3 种基金Project(2013RCJJ006)supported by Scientific Research Foundation of Shandong University of Science and Technology for Recruited TalentsChinaProject(BS2013CL009)supported by Scientific Research Foundation of Shandong for Outstanding Young ScientistChina
文摘To enhance the corrosion resistance of magnesium（Mg） alloy and to impart its surface with antibacterial functionality for inhibiting biofilm formation and biocorrosion, Mg（OH）2 films were fabricated on AZ31 magnesium alloy substrates by an in-situ hydrothermal method and well-defined multilayer coatings, consisting of gentamicin sulfate（GS） and poly（sodium 4-styrene sulfonate）（PSS）, were prepared via layer-by-layer（Lb L） assembly. The morphologies, chemical compositions and corrosion resistance of the obtained（PSS/GS）n/Mg sample were investigated using scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, electrochemical methods and immersion tests. Finally, the bactericidal activity of（PSS/GS）n/Mg samples against Staphylococcus aureus was assessed by the zone of inhibition methods and plate-counting method. The so-synthesized composite coating on the Mg alloy substrates exhibits good corrosion resistance and antibacterial performance, which make them attractive as coatings for medical implanted devices.
基金The National Natural Science Foundation of China(No.51475281,51375292)the National Natural Science Foundation for Young Scholar of China(No.51105239)
文摘A new type of vascular stent is designed for treating stenotic vessels. Aiming at overcoming the shortcomings of existing equipment and technology for preparing a bioabsorbable vascular stent （BVS）, a new method which combines 3D bio-printing and electrospinning to prepare the composite bioabsorbable vascular stent （CBVS） is proposed. The inner layer of the CBVS can be obtained through 3D bio- printing using poly-p-dioxanone （PPDO）. The thin nanofiber film that serves as the outer layer can be built through electrospinning using mixtures of chitosan-PVA （poly （vinyl alcohol））. Tests of mechanical properties show that the stent prepared through 3D bio-printing combined with electrospinning is better than that prepared through 3D bio- printing alone. Cells cultivated on the CBVS adhere and proliferate better due to the natural, biological chitosan in the outer layer. The proposed complex process and method can provide a good basis for preparing a controllable drug-carrying vascular stent. Overall, the CBVS can be a good candidate for treating stenotic vessels.
基金supported by the National Natural Science Foundation of China(2137312021471022)+5 种基金the Development of Science and Technology Plan of Jilin ProvinceChina(2010154920130102001JC)Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT13022)of Chinathe Program of Jilin Provincial Education Department(20131302013146)~~
文摘Vanadium pentoxide（V2O5）/molybdenum trioxide（MoO 3） composites with different molar ratios of vanadium（V） to molybdenum（Mo） were synthesized via a simple electrospinning technique. The photocatalytic activity of the composites were evaluated by their ability to photodegrade methylene blue and dimethyl phthalate（DMP） under visible-light irradiation. Compared with pure V2O5 and MoO 3,the V2O5/MoO 3 composites showed enhanced visible-light photocatalytic activity because of a V 3d impurity energy level and the formation of heterostructures at the interface between V2O5 and MoO 3. The optimal molar ratio of V to Mo in the V2O5/MoO 3 composites was found to be around 1/2. Furthermore,high-performance liquid chromatographic monitoring revealed that phthalic acid was the main intermediate in the photocatalytic degradation process of DMP.
