A novel mixed valance vanadium phosphate Na 3.6 H 1.4 P 2V 5O 18 ·11H 2O was synthesized by a hydrothermal method and its structure was characterized by X ray diffraction, infrared spectroscopy...A novel mixed valance vanadium phosphate Na 3.6 H 1.4 P 2V 5O 18 ·11H 2O was synthesized by a hydrothermal method and its structure was characterized by X ray diffraction, infrared spectroscopy, differential thermal analysis, and thermogravimetric analysis. Na 3.6 H 1.4 P 2V 5O 18 ·11H 2O crystallizes in the cubic system with the cell parameter a =1.601(8) nm. The ratio of V( Ⅳ)/ V(Ⅴ) in the compound is 3.55.展开更多
In this paper, the growth characteristics of Acidithiobacillus ferrooxidans （At.f） and Acidithiobacillus thiooxidans （At. f） in mixed culture has been studied, explored mixed bacteria phosphate solubilization effe...In this paper, the growth characteristics of Acidithiobacillus ferrooxidans （At.f） and Acidithiobacillus thiooxidans （At. f） in mixed culture has been studied, explored mixed bacteria phosphate solubilization effect, from a kind of low-grade phosphate rock. The results show that mixed bacteria has strong ability to produce acid, and have stronger oxidation activity to energy source -Fe^2＋. Mixed bacteria can significantly increase the rate of phosphate solubilization from phosphate rock in low concentration pulp. It goes against mixed bacteria reproduction when pulp concentration increased, makes phosphate solubilization rate decreased.展开更多
BACKGROUND Hyperphosphatemia(HP)is a common complication in an advanced stage of chronic kidney disease(CKD)and is associated with cardiovascular issues,metabolic bone abnormalities and worsening of secondary hyperpar...BACKGROUND Hyperphosphatemia(HP)is a common complication in an advanced stage of chronic kidney disease(CKD)and is associated with cardiovascular issues,metabolic bone abnormalities and worsening of secondary hyperparathyroidism.Most patients on dialysis require phosphate binders to control HP.Sucroferric oxyhydroxide(SO)(Dynulta^(TM))is a calcium-free,polynuclear iron(III)based oral phosphate binder,for the treatment of HP.In this phase IV,open-label,singlearm,multi-center,12-week,SOLO CKD study evaluated efficacy and safety of Dynulta^(TM)in Indian CKD patients undergoing hemodialysis.AIM To investigate the efficacy,safety and tolerability of SO Chewable Tablet(Dynulta^(TM))in patients with CKD on hemodialysis.METHODS Hyperphosphatemic patients on hemodialysis and fulfilling eligibility criteria were included in the study for at least 12 weeks and received SO 1500 mg chewable tablet per day.The key endpoint was change in mean serum phosphorus levels after 12 weeks.Data were analysed using analysis of variance,Paired test,Wilcoxon test,and post-hoc comparisons,with P<0.05 considered statistically significant,using Graph Pad software.RESULTS A total of 114 patients were enrolled and 94 patients completed the study.The mean±SD serum phosphorous level was reduced from 7.62 mg/dL±2.02 mg/dL at baseline to 5.13 mg/dL±1.88 mg/dL after 12 weeks of treatment.At each follow-up visit,the reduction in mean serum phosphorous levels was statistically significant(P value<0.05)compared to baseline,confirming the efficacy of SO.A total of 33.33%of patients experienced adverse events(AEs).The most frequently reported AEs were pyrexia,nasopharyngitis and headache,which were considered unlikely to be related to the study drug treatment.No serious AEs was reported during the study period and no patients discontinued treatment due to AEs.CONCLUSION This first real-world study in Indian CKD patients on hemodialysis shows SO as a safe,and effective monotherapy for HP,though its small sample size limits generalizability.展开更多
Zinc tris Thiourea Sulphate (ZTS) is a semi organic non-linear optical crystal. The ZTS and phosphate mixed (in different mol %) ZTS crystals have been grown from aqueous solution using the slow evaporation method. Si...Zinc tris Thiourea Sulphate (ZTS) is a semi organic non-linear optical crystal. The ZTS and phosphate mixed (in different mol %) ZTS crystals have been grown from aqueous solution using the slow evaporation method. Single crystal XRD were carried out for ZTS and phosphate mixed ZTS crystals to determine cell parameters. FTIR analysis identified modes of vibrations of different molecular groups and confirms the presence of phosphate ion. The UV-Vis-NIR spectrum shows that the material has wide optical transparency in the entire visible region. The second harmonic generation (SHG) was confirmed by Kurtz powder method. It is found that 10 mol % of phosphate mixed ZTS crystal has better SHG efficiency than pure ZTS crystal. The Vicker microhardness test was carried out on the grown crystals and Vicker’s Hardness Number was found increase with increase in phosphate mixing.展开更多
This study focuses on identifying the factors under which mixed microbial seeds assist bio-chemical denitrification when Scrap Iron Filings(SIF)are used as electron donors and adsorbents in low C/N ratio waters.Batch ...This study focuses on identifying the factors under which mixed microbial seeds assist bio-chemical denitrification when Scrap Iron Filings(SIF)are used as electron donors and adsorbents in low C/N ratio waters.Batch studies were conducted in abiotic and biotic reactors containing fresh and aged SIF under different dissolved oxygen concentrations with NO_(3)^(-)−N and/or PO_(4)^(3−)influent(s)and their nitrate/phosphate removal and by-product formations were studied.Batch reactors were seeded with a homogenized mixed microbial inoculum procured from natural sludges which were enriched over 6 months under denitrifying conditions in the presence of SIF.Results indicated that when influent containing 40 mg/L of NO_(3)^(-)−N was treated with 5 g SIF,79.9%nitrate reduction was observed in 8 days abiotically and 100%removal was accomplished in 20 days when the reactor was seeded.Both abiotic and seeded reactors removed more than 92%PO_(4)^(3−)under high DO conditions in 12 days.Abiotic and biochemical removal of NO_(3)^(-)−N and abiotic removal of PO_(4)^(3−)were higher under independent NO_(3)^(-)−N/PO_(4)^(3−)loading,while 99%PO_(4)^(3−)was removed biochemically under combined NO_(3)^(-)−N and PO_(4)^(3−)loading.This study furthers the understandings of nitrate and phosphate removal in Zero Valent Iron(ZVI)assisted mixed microbial systems to encourage the application of SIF-supported bio-chemical processes in the simultaneous removals of these pollutants.展开更多
Three kinds of high-alumina repairing mixes for medium-frequency induction furnace were prepared by ramming method with sodium silicate, phosphoric acid and aluminium dihydrogen phosphate as binder, respectively. Phys...Three kinds of high-alumina repairing mixes for medium-frequency induction furnace were prepared by ramming method with sodium silicate, phosphoric acid and aluminium dihydrogen phosphate as binder, respectively. Physical properties of the specimens heat treated at different temperatures were tested and compared. The results show that the specimen bonded by sodium silicate behaves much higher strength after fired at 1 600 ℃ compared with the specimen, bonded by phosphoric acid or aluminium dihydrogen phosphate. Due to more liquid phase formation the properties of specimen bonded by sodium silicate are poor with a low strength and a large volume shrinkage at high temperatures. Meanwhile. the speeimen bonded by phosphoric acid and aluminium dihydrogen phosphate, respectively, show relatively high strengths and slight volume expansions at high temperatures because of in-situ mullite formation.展开更多
A new mixed metal phosphate of Cs2Ga4P8O(27), which also can be written as Cs2Ga4(P2O7)2(P4O(13)), was synthesized by high temperature solid state syntheses and structurally characterized by X-ray single-crystal diffr...A new mixed metal phosphate of Cs2Ga4P8O(27), which also can be written as Cs2Ga4(P2O7)2(P4O(13)), was synthesized by high temperature solid state syntheses and structurally characterized by X-ray single-crystal diffraction for the first time. The title compound crystallizes in monoclinic system with space group P21/c(No.14), and features a 3D framework which can be considered as alternating layers of {Ga2(P4O(13))}n and {Ga2(P2O7)2}n^(2n-) parallel to the bc plane further connected by Ga-O-P linkages, where Cs^+ cations are located in the free space between two adjacent layers to charge the valence. The Ga^(3+) cations in the compound contain two kinds of coordination models(4 and 6). Furthermore, the title compound coexists of two phospho-ric anionic groups which are non-condensed horseshoe-shaped(P4O(13)) and two(P2O7) with different symmetries. The density functional theory calculations indicate that Cs2Ga4P8O(27) is a direct band gap insulator with flat valence and dispersive conduction bands and a band gap of 4.13 eV.展开更多
Exploration of ultraviolet phosphates with balanced overall performance is of great significance and difficulty.Herein,the first barium bismuth zincophosphate,Ba_(2)Bi_(2)[Zn(PO_(4))_(4)],was rationally obtained by io...Exploration of ultraviolet phosphates with balanced overall performance is of great significance and difficulty.Herein,the first barium bismuth zincophosphate,Ba_(2)Bi_(2)[Zn(PO_(4))_(4)],was rationally obtained by ion mixing and anionic condensation,while single crystals of Ba_(2)Bi_(2)[Zn(PO_(4))_(4)]were synthesized by a high temperature molten salt method.In the strucutre of Ba_(2)Bi_(2)[Zn(PO_(4))_(4)],unprecedented_(∞)[Zn(PO_(4))_(4)]^(10−)chains,which were made up through the condensation of infrequent[Zn(PO_(4))_(5)]^(13−)groups,were ionically bridged by massive Ba^(2+)and Bi^(3+).Having benefitted from its unique one-dimensional anionic frame and the ultilization of mutiple ions,Ba_(2)Bi_(2)[Zn(PO_(4))_(4)]was characterized by a balanced overall performance over birefrigence,band gap and physicochemical stability.Especially,Ba_(2)Bi_(2)[Zn(PO_(4))_(4)]was verified as a congruently melting crystal with a high melting point of about 965℃,being conducive to practical applications.展开更多
In this work,for the first time,it is demonstrated that during the insertion/extraction of Na ions,the structural evolution at the Na_(4)site at a voltage range of 3-4 V is a key factor for the capacity decay of Na_(4...In this work,for the first time,it is demonstrated that during the insertion/extraction of Na ions,the structural evolution at the Na_(4)site at a voltage range of 3-4 V is a key factor for the capacity decay of Na_(4)Fe_(3)(PO_(4))_(2)P_(2)O_(7)(NFPP).Herein,a strategy of introducing columnar potassium ions at the Na_(4)site is proposed to address the aforementioned challenge.As a cathode material for sodium-ion batteries,the K_(0.12)Na_(3.88)Fe_(3)(PO_(4))_(2)P_(2)O_(7)/C(K-NFPP)composite enhances the reversibility of Na_(4)extraction.Specifically,the K-NFPP exhibits an initial discharge capacity of 107.8 mAh g^(-1)at a high current density of 5 C,with a capacity retention of 91.4% after 2000 cycles,outperforming the pristine NFPP material(81.1 m Ah g^(-1)and 67.1%).At 5 C,the K-NFPP also retains 81.5% of the reversible capacity at 0.1 C,whereas the NFPP only retains 68.3%.Moreover,the K-NFPP-based full-cell delivers an initial capacity of 110.1 m Ah g^(-1)at 1 C,with a capacity retention of 90% after 100 cycles.It is found that in comparison to K-doping of the Na1,Na2,and Na3 sites,K-doping at the Na4 site effectively optimizes the band gap and stabilizes the crystal structure,thereby reducing lattice changes of FeO_(6)evolution during Na^(+)insertion/extraction.As a result,the introduction of columnar potassium ions significantly enhances the capacity contribution of the Na_(4)site,optimizes reaction kinetics,and effectively mitigates the capacity decay of NFPP cathodes.It is believed that this study offers a new entry point for the application of NFPP in high-voltage sodium storage.展开更多
文摘A novel mixed valance vanadium phosphate Na 3.6 H 1.4 P 2V 5O 18 ·11H 2O was synthesized by a hydrothermal method and its structure was characterized by X ray diffraction, infrared spectroscopy, differential thermal analysis, and thermogravimetric analysis. Na 3.6 H 1.4 P 2V 5O 18 ·11H 2O crystallizes in the cubic system with the cell parameter a =1.601(8) nm. The ratio of V( Ⅳ)/ V(Ⅴ) in the compound is 3.55.
文摘In this paper, the growth characteristics of Acidithiobacillus ferrooxidans （At.f） and Acidithiobacillus thiooxidans （At. f） in mixed culture has been studied, explored mixed bacteria phosphate solubilization effect, from a kind of low-grade phosphate rock. The results show that mixed bacteria has strong ability to produce acid, and have stronger oxidation activity to energy source -Fe^2＋. Mixed bacteria can significantly increase the rate of phosphate solubilization from phosphate rock in low concentration pulp. It goes against mixed bacteria reproduction when pulp concentration increased, makes phosphate solubilization rate decreased.
文摘BACKGROUND Hyperphosphatemia(HP)is a common complication in an advanced stage of chronic kidney disease(CKD)and is associated with cardiovascular issues,metabolic bone abnormalities and worsening of secondary hyperparathyroidism.Most patients on dialysis require phosphate binders to control HP.Sucroferric oxyhydroxide(SO)(Dynulta^(TM))is a calcium-free,polynuclear iron(III)based oral phosphate binder,for the treatment of HP.In this phase IV,open-label,singlearm,multi-center,12-week,SOLO CKD study evaluated efficacy and safety of Dynulta^(TM)in Indian CKD patients undergoing hemodialysis.AIM To investigate the efficacy,safety and tolerability of SO Chewable Tablet(Dynulta^(TM))in patients with CKD on hemodialysis.METHODS Hyperphosphatemic patients on hemodialysis and fulfilling eligibility criteria were included in the study for at least 12 weeks and received SO 1500 mg chewable tablet per day.The key endpoint was change in mean serum phosphorus levels after 12 weeks.Data were analysed using analysis of variance,Paired test,Wilcoxon test,and post-hoc comparisons,with P<0.05 considered statistically significant,using Graph Pad software.RESULTS A total of 114 patients were enrolled and 94 patients completed the study.The mean±SD serum phosphorous level was reduced from 7.62 mg/dL±2.02 mg/dL at baseline to 5.13 mg/dL±1.88 mg/dL after 12 weeks of treatment.At each follow-up visit,the reduction in mean serum phosphorous levels was statistically significant(P value<0.05)compared to baseline,confirming the efficacy of SO.A total of 33.33%of patients experienced adverse events(AEs).The most frequently reported AEs were pyrexia,nasopharyngitis and headache,which were considered unlikely to be related to the study drug treatment.No serious AEs was reported during the study period and no patients discontinued treatment due to AEs.CONCLUSION This first real-world study in Indian CKD patients on hemodialysis shows SO as a safe,and effective monotherapy for HP,though its small sample size limits generalizability.
文摘Zinc tris Thiourea Sulphate (ZTS) is a semi organic non-linear optical crystal. The ZTS and phosphate mixed (in different mol %) ZTS crystals have been grown from aqueous solution using the slow evaporation method. Single crystal XRD were carried out for ZTS and phosphate mixed ZTS crystals to determine cell parameters. FTIR analysis identified modes of vibrations of different molecular groups and confirms the presence of phosphate ion. The UV-Vis-NIR spectrum shows that the material has wide optical transparency in the entire visible region. The second harmonic generation (SHG) was confirmed by Kurtz powder method. It is found that 10 mol % of phosphate mixed ZTS crystal has better SHG efficiency than pure ZTS crystal. The Vicker microhardness test was carried out on the grown crystals and Vicker’s Hardness Number was found increase with increase in phosphate mixing.
基金We are grateful for the project grants supported by the Major Science and Technology Programs for Water Pollution Control and Management of China(Nos.2012ZX07205-001 and 2017ZX7103-007).
文摘This study focuses on identifying the factors under which mixed microbial seeds assist bio-chemical denitrification when Scrap Iron Filings(SIF)are used as electron donors and adsorbents in low C/N ratio waters.Batch studies were conducted in abiotic and biotic reactors containing fresh and aged SIF under different dissolved oxygen concentrations with NO_(3)^(-)−N and/or PO_(4)^(3−)influent(s)and their nitrate/phosphate removal and by-product formations were studied.Batch reactors were seeded with a homogenized mixed microbial inoculum procured from natural sludges which were enriched over 6 months under denitrifying conditions in the presence of SIF.Results indicated that when influent containing 40 mg/L of NO_(3)^(-)−N was treated with 5 g SIF,79.9%nitrate reduction was observed in 8 days abiotically and 100%removal was accomplished in 20 days when the reactor was seeded.Both abiotic and seeded reactors removed more than 92%PO_(4)^(3−)under high DO conditions in 12 days.Abiotic and biochemical removal of NO_(3)^(-)−N and abiotic removal of PO_(4)^(3−)were higher under independent NO_(3)^(-)−N/PO_(4)^(3−)loading,while 99%PO_(4)^(3−)was removed biochemically under combined NO_(3)^(-)−N and PO_(4)^(3−)loading.This study furthers the understandings of nitrate and phosphate removal in Zero Valent Iron(ZVI)assisted mixed microbial systems to encourage the application of SIF-supported bio-chemical processes in the simultaneous removals of these pollutants.
文摘Three kinds of high-alumina repairing mixes for medium-frequency induction furnace were prepared by ramming method with sodium silicate, phosphoric acid and aluminium dihydrogen phosphate as binder, respectively. Physical properties of the specimens heat treated at different temperatures were tested and compared. The results show that the specimen bonded by sodium silicate behaves much higher strength after fired at 1 600 ℃ compared with the specimen, bonded by phosphoric acid or aluminium dihydrogen phosphate. Due to more liquid phase formation the properties of specimen bonded by sodium silicate are poor with a low strength and a large volume shrinkage at high temperatures. Meanwhile. the speeimen bonded by phosphoric acid and aluminium dihydrogen phosphate, respectively, show relatively high strengths and slight volume expansions at high temperatures because of in-situ mullite formation.
基金Supported by the National Natural Science Foundation of China(No.21101156)the State Key Laboratory of Structure Chemistry(No.20150016)+2 种基金Outstanding youth of colleges and universities of Department of Education,Fujian Province Natural Science Foundation for Youths(No.2016J05109)Fujian Education Department(No.JK2015056)the founding from Fujian Jiangxia University(JXZ2016002)。
文摘A new mixed metal phosphate of Cs2Ga4P8O(27), which also can be written as Cs2Ga4(P2O7)2(P4O(13)), was synthesized by high temperature solid state syntheses and structurally characterized by X-ray single-crystal diffraction for the first time. The title compound crystallizes in monoclinic system with space group P21/c(No.14), and features a 3D framework which can be considered as alternating layers of {Ga2(P4O(13))}n and {Ga2(P2O7)2}n^(2n-) parallel to the bc plane further connected by Ga-O-P linkages, where Cs^+ cations are located in the free space between two adjacent layers to charge the valence. The Ga^(3+) cations in the compound contain two kinds of coordination models(4 and 6). Furthermore, the title compound coexists of two phospho-ric anionic groups which are non-condensed horseshoe-shaped(P4O(13)) and two(P2O7) with different symmetries. The density functional theory calculations indicate that Cs2Ga4P8O(27) is a direct band gap insulator with flat valence and dispersive conduction bands and a band gap of 4.13 eV.
基金supported by the PhD research startup foundation of China West Normal University(No.412923).
文摘Exploration of ultraviolet phosphates with balanced overall performance is of great significance and difficulty.Herein,the first barium bismuth zincophosphate,Ba_(2)Bi_(2)[Zn(PO_(4))_(4)],was rationally obtained by ion mixing and anionic condensation,while single crystals of Ba_(2)Bi_(2)[Zn(PO_(4))_(4)]were synthesized by a high temperature molten salt method.In the strucutre of Ba_(2)Bi_(2)[Zn(PO_(4))_(4)],unprecedented_(∞)[Zn(PO_(4))_(4)]^(10−)chains,which were made up through the condensation of infrequent[Zn(PO_(4))_(5)]^(13−)groups,were ionically bridged by massive Ba^(2+)and Bi^(3+).Having benefitted from its unique one-dimensional anionic frame and the ultilization of mutiple ions,Ba_(2)Bi_(2)[Zn(PO_(4))_(4)]was characterized by a balanced overall performance over birefrigence,band gap and physicochemical stability.Especially,Ba_(2)Bi_(2)[Zn(PO_(4))_(4)]was verified as a congruently melting crystal with a high melting point of about 965℃,being conducive to practical applications.
基金financial support from the National Natural Science Foundation of China(52272237,22279101 and 22172117)the Natural Science Foundation of Shaanxi(2020JC-41 and 2024JC-YBQN-0141)+2 种基金the Scientific Research Program Funded by the Education Department of Shaanxi Provincial Government(22JP056)the S&T Program of Energy Shaanxi Laboratory(ESLB202402)the Foshan Science and Technology Innovation Team Project(1920001004098)。
文摘In this work,for the first time,it is demonstrated that during the insertion/extraction of Na ions,the structural evolution at the Na_(4)site at a voltage range of 3-4 V is a key factor for the capacity decay of Na_(4)Fe_(3)(PO_(4))_(2)P_(2)O_(7)(NFPP).Herein,a strategy of introducing columnar potassium ions at the Na_(4)site is proposed to address the aforementioned challenge.As a cathode material for sodium-ion batteries,the K_(0.12)Na_(3.88)Fe_(3)(PO_(4))_(2)P_(2)O_(7)/C(K-NFPP)composite enhances the reversibility of Na_(4)extraction.Specifically,the K-NFPP exhibits an initial discharge capacity of 107.8 mAh g^(-1)at a high current density of 5 C,with a capacity retention of 91.4% after 2000 cycles,outperforming the pristine NFPP material(81.1 m Ah g^(-1)and 67.1%).At 5 C,the K-NFPP also retains 81.5% of the reversible capacity at 0.1 C,whereas the NFPP only retains 68.3%.Moreover,the K-NFPP-based full-cell delivers an initial capacity of 110.1 m Ah g^(-1)at 1 C,with a capacity retention of 90% after 100 cycles.It is found that in comparison to K-doping of the Na1,Na2,and Na3 sites,K-doping at the Na4 site effectively optimizes the band gap and stabilizes the crystal structure,thereby reducing lattice changes of FeO_(6)evolution during Na^(+)insertion/extraction.As a result,the introduction of columnar potassium ions significantly enhances the capacity contribution of the Na_(4)site,optimizes reaction kinetics,and effectively mitigates the capacity decay of NFPP cathodes.It is believed that this study offers a new entry point for the application of NFPP in high-voltage sodium storage.
