Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies i...Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies in industry today.High-nuclearity metal cluster-based MOFs with different functionalities are promising for this separation,but it is a complicated and difficult task to precisely control their structures.The strategy of pore-space partition(PSP)is a powerful way to construct this type MOFs,which has the characteristic of isostructural relationship,and can be resulted in a similar performance for them.Therefore,it is an interesting work to explore the effect of MOFs property by adjusting the size of PSP dividers.Herein,three tetranuclear Cu(Ⅱ)cluster-based MOFs(FJU-112/113/114)with dual functionalities has been successfully obtained by PSP strategy with various lengths of divider units.With the highest microporosity and unique functional site,FJU-114 realized a good improvement in the adsorption and separation performance of C_(2)H_(2)/CO_(2).The gas adsorption and lab-scale C_(2)H_(2)/CO_(2)breakthrough experiments demonstrated that FJU-114 exhibits the highest adsorption uptake of 77 cm^(3)/g for C_(2)H_(2),and shows the best separation factor of 4.2 among three MOFs.The GCMC simulation reveals that a stronger adsorption binding site of C_(2)H_(2)in FJU-114a located in the cage II near the unchanged tetranuclear copper node,combined with its high microporosity to achieve the effect of dual functionalities for the improvement performance of C_(2)H_(2)adsorption and separation.展开更多
Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hamper...Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hampered their practical use in water splitting.Herein,we develop a bond length adjustment strategy for optimizing naphthalene-based MOFs that synthesized by acid etching Co-naphthalenedicarboxylic acid-based MOFs(donated as AE-CoNDA)to serve as efficient catalyst for water splitting.AE-CoNDA exhibits a low overpotential of 260 mV to reach 10 mA cm^(−2)and a small Tafel slope of 62 mV dec^(−1)with excellent stability over 100 h.After integrated AE-CoNDA onto BiVO_(4),photocurrent density of 4.3 mA cm^(−2)is achieved at 1.23 V.Experimental investigations demonstrate that the stretched Co-O bond length was found to optimize the orbitals hybridization of Co 3d and O 2p,which accounts for the fast kinetics and high activity.Theoretical calculations reveal that the stretched Co-O bond length strengthens the adsorption of oxygen-contained intermediates at the Co active sites for highly efficient water splitting.展开更多
Short-term prediction of traffic flow is one of the most essential elements of all proactive traffic control systems.The aim of this paper is to provide a model based on neural networks(NNs)for multi-step-ahead traffi...Short-term prediction of traffic flow is one of the most essential elements of all proactive traffic control systems.The aim of this paper is to provide a model based on neural networks(NNs)for multi-step-ahead traffic prediction.NNs'dependency on parameter setting is the major challenge in using them as a predictor.Given the fact that the best combination of NN parameters results in the minimum error of predicted output,the main problem is NN optimization.So,it is viable to set the best combination of the parameters according to a specific traffic behavior.On the other hand,an automatic method—which is applicable in general cases—is strongly desired to set appropriate parameters for neural networks.This paper defines a self-adjusted NN using the non-dominated sorting genetic algorithm II(NSGA-II)as a multi-objective optimizer for short-term prediction.NSGA-II is used to optimize the number of neurons in the first and second layers of the NN,learning ratio and slope of the activation function.This model addresses the challenge of optimizing a multi-output NN in a self-adjusted way.Performance of the developed network is evaluated by application to both univariate and multivariate traffic flow data from an urban highway.Results are analyzed based on the performance measures,showing that the genetic algorithm tunes the NN as well without any manually pre-adjustment.The achieved prediction accuracy is calculated with multiple measures such as the root mean square error(RMSE),and the RMSE value is 10 and 12 in the best configuration of the proposed model for single and multi-step-ahead traffic flow prediction,respectively.展开更多
In this paper,the autocontrol of the simulation device of systematic circulatorysystem will be presented.The pressure and cardiac output of simulation system willbe adjusted to predeterminate value in physiological ar...In this paper,the autocontrol of the simulation device of systematic circulatorysystem will be presented.The pressure and cardiac output of simulation system willbe adjusted to predeterminate value in physiological area.This paper is based on fullyunderstanding of physical simulatory theories and device design of human cardiovas-cular system and the basic specific properties of simulation system.Non-linearityexsits in this system,and it is a multi-input and multi-output system.In the mean-time,simulative system has special property of time-lag and time-variant.The idea展开更多
Ⅰ.INTRODUCTION The Second World Ocean Assessment points out that climate change,unsustainable fishing,the introduction of invasive species,etc.,continue to pose a threat to the ocean,degrading the marine environment....Ⅰ.INTRODUCTION The Second World Ocean Assessment points out that climate change,unsustainable fishing,the introduction of invasive species,etc.,continue to pose a threat to the ocean,degrading the marine environment.Legal protection of the marine environment has been carried out from two aspects:the prevention of marine pollution and the conservation of marine biodiversity.1 One typical international instrument is the United Nations Convention on the Law of the Sea(UNCLOS)adopted in 1982,which established an overarching framework for the protection and preservation of marine environment in its partⅫ.展开更多
To enhance the cost-effectiveness of bulk hybrid AC-DC power systems and promote wind consumption,this paper proposes a two-stage risk-based robust reserve scheduling(RRRS)model.Different from traditional robust optim...To enhance the cost-effectiveness of bulk hybrid AC-DC power systems and promote wind consumption,this paper proposes a two-stage risk-based robust reserve scheduling(RRRS)model.Different from traditional robust optimization,the proposed model applies an adjustable uncertainty set rather than a fixed one.Thereby,the operational risk is optimized together with the dispatch schedules,with a reasonable admissible region of wind power obtained correspondingly.In addition,both the operational base point and adjustment capacity of tielines are optimized in the RRRS model,which enables reserve sharing among the connected areas to handle the significant wind uncertainties.Based on the alternating direction method of multipliers(ADMM),a fully distributed framework is presented to solve the RRRS model in a distributed way.A dynamic penalty factor adjustment strategy(DPA)is also developed and applied to enhance its convergence properties.Since only limited information needs to be exchanged during the solution process,the communication burden is reduced and regional information is protected.Case studies on the 2-area 12-bus system and 3-area 354-bus system illustrate the effectiveness of the proposed model and approach.展开更多
The development of space-air-ground integrated networks (SAGIN) requires sophisticated satellite Internet emulation tools that can handle complex, dynamic topologies and offer in-depth analysis. Existing emulation pla...The development of space-air-ground integrated networks (SAGIN) requires sophisticated satellite Internet emulation tools that can handle complex, dynamic topologies and offer in-depth analysis. Existing emulation platforms struggle with challenges like the need for detailed implementation across all network layers, real-time response, and scalability. This paper proposes a digital twin system based on microservices for satellite Internet emulation,namely Plotinus,which aims to solve these problems. Plotinus features a modular design, allowing for easy replacement of the physical layer to emulate different aerial vehicles and analyze channel interference. It also enables replacing of path computation methods to simplify testing and deploying algorithms. In particular, Plotinus allows for real-time emulation with live network traffic,enhancing practical network models. The evaluation result shows Plotinus’s effective emulation of dynamic satellite networks with real-world devices. Its adaptability for various communication models and algorithm testing highlights Plotinus’s role as a vital tool for developing and analyzing SAGIN systems, offering a cross-layer,real-time,and scalable digital twin system.展开更多
For decades, the search for potential signs of Martian life has attracted strong international interest and has led to significant planning and scientific implementation. Clearly, in order to detect potential life sig...For decades, the search for potential signs of Martian life has attracted strong international interest and has led to significant planning and scientific implementation. Clearly, in order to detect potential life signals beyond Earth, fundamental questions, such as how to define such terms as “life” and “biosignature”, have been given considerable attention. Due to the high costs of direct exploration of Mars, Mars-like regions on Earth have been invaluable targets for astrobiological research, places where scientists could practice the search for “biosignatures” and refine ways to detect them. This review summarizes scientific instrumental techniques that have resulted from this work. Instruments must necessarily be our “eyes” and “hands” as we attempt to identify and quantify biosignatures on Mars.Scientific devices that can be applied in astrobiology include mass spectrometers and electromagnetic-spectrum-based spectrometers,redox potential indicators, circular dichroism polarimeters, in situ nucleic acid sequencers, life isolation/cultivation systems, and imagers.These devices and how to interpret the data they collect have been tested in Mars-analog extreme environments on Earth to validate their practicality on Mars. To anticipate the challenges of instrumental detection of biosignatures through the full evolutionary history of Mars, Terrestrial Mars analogs are divided into four major categories according to their similarities to different Martian geological periods(the Early-Middle Noachian Period, the Late Noachian-Early Hesperian Period, the Late Hesperian-Early Amazonian Period, and the Middle-Late Amazonian Period). Future missions are suggested that would focus more intensively on Mars’ Southern Hemisphere, once landing issues there are solved by advances in spacecraft engineering, since exploration of these early terrains will permit investigations covering a wider continuum of the shifting habitability of Mars through its geological history. Finally, this paper reviews practical applications of the range of scientific instruments listed above, based on the four categories of Mars analogs here on Earth. We review the selection of instruments suitable for autonomous robotic rover tests in these Mars analogs. From considerations of engineering efficiency,a Mars rover ought to be equipped with as few instrument assemblies as possible. Therefore, once candidate landing regions on Mars are defined, portable suites of instruments should be smartly devised on the basis of the known geological, geochemical, geomorphological,and chronological characteristics of each Martian landing region. Of course, if Mars sample-return missions are successful, such samples will allow experiments in laboratories on Earth that can be far more comprehensive and affordable than is likely to be practicable on Mars.To exclude false positive and false negative conclusions in the search for extraterrestrial life, multiple diverse and complementary analytical techniques must be combined, replicated, and carefully interpreted. The question of whether signatures of life can be detected on Mars is of the greatest importance. Answering that question is extremely challenging but appears to have become manageable.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.21975044,21971038,21922810 and 22271046)the Fujian Provincial Department of Science and Technology(Nos.2023J01355,2023J011106 and 2022R1022001).
文摘Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies in industry today.High-nuclearity metal cluster-based MOFs with different functionalities are promising for this separation,but it is a complicated and difficult task to precisely control their structures.The strategy of pore-space partition(PSP)is a powerful way to construct this type MOFs,which has the characteristic of isostructural relationship,and can be resulted in a similar performance for them.Therefore,it is an interesting work to explore the effect of MOFs property by adjusting the size of PSP dividers.Herein,three tetranuclear Cu(Ⅱ)cluster-based MOFs(FJU-112/113/114)with dual functionalities has been successfully obtained by PSP strategy with various lengths of divider units.With the highest microporosity and unique functional site,FJU-114 realized a good improvement in the adsorption and separation performance of C_(2)H_(2)/CO_(2).The gas adsorption and lab-scale C_(2)H_(2)/CO_(2)breakthrough experiments demonstrated that FJU-114 exhibits the highest adsorption uptake of 77 cm^(3)/g for C_(2)H_(2),and shows the best separation factor of 4.2 among three MOFs.The GCMC simulation reveals that a stronger adsorption binding site of C_(2)H_(2)in FJU-114a located in the cage II near the unchanged tetranuclear copper node,combined with its high microporosity to achieve the effect of dual functionalities for the improvement performance of C_(2)H_(2)adsorption and separation.
基金supported by the National Key Research and Development Program of China (2022YFB4002100)the development project of Zhejiang Province's "Jianbing" and "Lingyan" (2023C01226)+4 种基金the National Natural Science Foundation of China (22278364, U22A20432, 22238008, 22211530045, and 22178308)the Fundamental Research Funds for the Central Universities (226-2022-00044 and 226-2022-00055)the Science Foundation of Donghai Laboratory (DH-2022ZY0009)the Startup Foundation for Hundred-Talent Program of Zhejiang UniversityScientific Research Fund of Zhejiang Provincial Education Department.
文摘Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hampered their practical use in water splitting.Herein,we develop a bond length adjustment strategy for optimizing naphthalene-based MOFs that synthesized by acid etching Co-naphthalenedicarboxylic acid-based MOFs(donated as AE-CoNDA)to serve as efficient catalyst for water splitting.AE-CoNDA exhibits a low overpotential of 260 mV to reach 10 mA cm^(−2)and a small Tafel slope of 62 mV dec^(−1)with excellent stability over 100 h.After integrated AE-CoNDA onto BiVO_(4),photocurrent density of 4.3 mA cm^(−2)is achieved at 1.23 V.Experimental investigations demonstrate that the stretched Co-O bond length was found to optimize the orbitals hybridization of Co 3d and O 2p,which accounts for the fast kinetics and high activity.Theoretical calculations reveal that the stretched Co-O bond length strengthens the adsorption of oxygen-contained intermediates at the Co active sites for highly efficient water splitting.
文摘Short-term prediction of traffic flow is one of the most essential elements of all proactive traffic control systems.The aim of this paper is to provide a model based on neural networks(NNs)for multi-step-ahead traffic prediction.NNs'dependency on parameter setting is the major challenge in using them as a predictor.Given the fact that the best combination of NN parameters results in the minimum error of predicted output,the main problem is NN optimization.So,it is viable to set the best combination of the parameters according to a specific traffic behavior.On the other hand,an automatic method—which is applicable in general cases—is strongly desired to set appropriate parameters for neural networks.This paper defines a self-adjusted NN using the non-dominated sorting genetic algorithm II(NSGA-II)as a multi-objective optimizer for short-term prediction.NSGA-II is used to optimize the number of neurons in the first and second layers of the NN,learning ratio and slope of the activation function.This model addresses the challenge of optimizing a multi-output NN in a self-adjusted way.Performance of the developed network is evaluated by application to both univariate and multivariate traffic flow data from an urban highway.Results are analyzed based on the performance measures,showing that the genetic algorithm tunes the NN as well without any manually pre-adjustment.The achieved prediction accuracy is calculated with multiple measures such as the root mean square error(RMSE),and the RMSE value is 10 and 12 in the best configuration of the proposed model for single and multi-step-ahead traffic flow prediction,respectively.
文摘In this paper,the autocontrol of the simulation device of systematic circulatorysystem will be presented.The pressure and cardiac output of simulation system willbe adjusted to predeterminate value in physiological area.This paper is based on fullyunderstanding of physical simulatory theories and device design of human cardiovas-cular system and the basic specific properties of simulation system.Non-linearityexsits in this system,and it is a multi-input and multi-output system.In the mean-time,simulative system has special property of time-lag and time-variant.The idea
文摘Ⅰ.INTRODUCTION The Second World Ocean Assessment points out that climate change,unsustainable fishing,the introduction of invasive species,etc.,continue to pose a threat to the ocean,degrading the marine environment.Legal protection of the marine environment has been carried out from two aspects:the prevention of marine pollution and the conservation of marine biodiversity.1 One typical international instrument is the United Nations Convention on the Law of the Sea(UNCLOS)adopted in 1982,which established an overarching framework for the protection and preservation of marine environment in its partⅫ.
基金supported by the National Key Research and Development Program of China (2016YFB0900100)the State Key Program of National Natural Science Foundation of China (51537010)the project of State Grid Corporation of China (52110418000T)。
文摘To enhance the cost-effectiveness of bulk hybrid AC-DC power systems and promote wind consumption,this paper proposes a two-stage risk-based robust reserve scheduling(RRRS)model.Different from traditional robust optimization,the proposed model applies an adjustable uncertainty set rather than a fixed one.Thereby,the operational risk is optimized together with the dispatch schedules,with a reasonable admissible region of wind power obtained correspondingly.In addition,both the operational base point and adjustment capacity of tielines are optimized in the RRRS model,which enables reserve sharing among the connected areas to handle the significant wind uncertainties.Based on the alternating direction method of multipliers(ADMM),a fully distributed framework is presented to solve the RRRS model in a distributed way.A dynamic penalty factor adjustment strategy(DPA)is also developed and applied to enhance its convergence properties.Since only limited information needs to be exchanged during the solution process,the communication burden is reduced and regional information is protected.Case studies on the 2-area 12-bus system and 3-area 354-bus system illustrate the effectiveness of the proposed model and approach.
基金supported in part by the National Natural Science Foundation of China under Grant 62341105.
文摘The development of space-air-ground integrated networks (SAGIN) requires sophisticated satellite Internet emulation tools that can handle complex, dynamic topologies and offer in-depth analysis. Existing emulation platforms struggle with challenges like the need for detailed implementation across all network layers, real-time response, and scalability. This paper proposes a digital twin system based on microservices for satellite Internet emulation,namely Plotinus,which aims to solve these problems. Plotinus features a modular design, allowing for easy replacement of the physical layer to emulate different aerial vehicles and analyze channel interference. It also enables replacing of path computation methods to simplify testing and deploying algorithms. In particular, Plotinus allows for real-time emulation with live network traffic,enhancing practical network models. The evaluation result shows Plotinus’s effective emulation of dynamic satellite networks with real-world devices. Its adaptability for various communication models and algorithm testing highlights Plotinus’s role as a vital tool for developing and analyzing SAGIN systems, offering a cross-layer,real-time,and scalable digital twin system.
基金supported by the National Natural Science Foundation of China (NSFC) Grant 41621004the Key Research Program of the Chinese Academy of Sciences (ZDBS-SSW-TLC001)+1 种基金the Strategic Priority Research Program of Chinese Academy of Sciences (XDB41010403)the Youth Innovation Promotion Association of the Chinese Academy of Sciences,the Key Research Programs of the Institute of Geology and Geophysics,Chinese Academy of Sciences (IGGCAS-201904 and IGGCAS-202102)
文摘For decades, the search for potential signs of Martian life has attracted strong international interest and has led to significant planning and scientific implementation. Clearly, in order to detect potential life signals beyond Earth, fundamental questions, such as how to define such terms as “life” and “biosignature”, have been given considerable attention. Due to the high costs of direct exploration of Mars, Mars-like regions on Earth have been invaluable targets for astrobiological research, places where scientists could practice the search for “biosignatures” and refine ways to detect them. This review summarizes scientific instrumental techniques that have resulted from this work. Instruments must necessarily be our “eyes” and “hands” as we attempt to identify and quantify biosignatures on Mars.Scientific devices that can be applied in astrobiology include mass spectrometers and electromagnetic-spectrum-based spectrometers,redox potential indicators, circular dichroism polarimeters, in situ nucleic acid sequencers, life isolation/cultivation systems, and imagers.These devices and how to interpret the data they collect have been tested in Mars-analog extreme environments on Earth to validate their practicality on Mars. To anticipate the challenges of instrumental detection of biosignatures through the full evolutionary history of Mars, Terrestrial Mars analogs are divided into four major categories according to their similarities to different Martian geological periods(the Early-Middle Noachian Period, the Late Noachian-Early Hesperian Period, the Late Hesperian-Early Amazonian Period, and the Middle-Late Amazonian Period). Future missions are suggested that would focus more intensively on Mars’ Southern Hemisphere, once landing issues there are solved by advances in spacecraft engineering, since exploration of these early terrains will permit investigations covering a wider continuum of the shifting habitability of Mars through its geological history. Finally, this paper reviews practical applications of the range of scientific instruments listed above, based on the four categories of Mars analogs here on Earth. We review the selection of instruments suitable for autonomous robotic rover tests in these Mars analogs. From considerations of engineering efficiency,a Mars rover ought to be equipped with as few instrument assemblies as possible. Therefore, once candidate landing regions on Mars are defined, portable suites of instruments should be smartly devised on the basis of the known geological, geochemical, geomorphological,and chronological characteristics of each Martian landing region. Of course, if Mars sample-return missions are successful, such samples will allow experiments in laboratories on Earth that can be far more comprehensive and affordable than is likely to be practicable on Mars.To exclude false positive and false negative conclusions in the search for extraterrestrial life, multiple diverse and complementary analytical techniques must be combined, replicated, and carefully interpreted. The question of whether signatures of life can be detected on Mars is of the greatest importance. Answering that question is extremely challenging but appears to have become manageable.
