Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electro...Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.展开更多
Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crac...Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crack,strengthened by steel wire wrapping.The effects of the thread tensile force of the steel winding in the form of single rings at the crack edges and the wires with different winding diameters and pitches were also studied.The results showed that the strengthening was preferably executed at a minimum value of the thread tensile force,which was 6.4%more effective than that at its maximum value.The analysis of the influence of the winding dia-meters showed that the equivalent stresses increased by 32%from the beginning of the crack growth until the wire broke.The increment in winding diameter decelerated the disclosure of the edge crack and reduced its length by 8.2%.The analysis of the influence of the winding pitch showed that decreasing the distance between the winding turns also led to a 33.6%reduction in the length of the straight crack and a 7.9%reduction in the maximum stres-ses on the strengthened pipeline cross-section.The analysis of the temperature effect on the pipeline material,within a range from-40℃to+50℃,resulted in a crack length change of up to 5.8%.As the temperature dropped,the crack length decreased.Within such a temperature range,the maximum stresses were observed along the cen-tral area of the crack,which were equal to 413 MPa at+50℃and 440 MPa at-40℃.The results also showed that the presence of the steel winding in the pipeline significantly reduced the length of crack propagation up to 8.4 times,depending on the temperature effect and design parameters of prestressing.This work integrated the existing methods for crack localization along steel gas pipelines.展开更多
In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to character...In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.展开更多
The pressure and temperature increase resulting from the impact of different threats onto target materials is analyzed with a unified laboratory-scale setup.This allows deriving qualitative information on the occurrin...The pressure and temperature increase resulting from the impact of different threats onto target materials is analyzed with a unified laboratory-scale setup.This allows deriving qualitative information on the occurring phenomenology as well as quantitative statements about the relative effects sizes as a function of target material and threat.The considered target materials are steel,aluminum,and magnesium.As threats,kinetic energy penetrator,explosively formed projectile,and shaped charge jet are used.For the investigated combinations,the measured overpressures vary by a factor of up to 5 for a variation of the material,by a factor of up to 7 for a variation of the threat,and by a factor larger than 15for a simultaneous variation of both.The obtained results as well as the experimental approach are relevant for the basic understanding of impact effects and risks due to material reactivity.The paper combines two main aims.Firstly,to provide a summary of own prior work in a coherent journal article and,secondly,to review and discuss these earlier results with a new perspective.展开更多
Diamond is a promising semiconductor material for future space exploration,owing to its unique atomic and electronic structures.However,diamond materials and related devices still suffer from irradiation damage under ...Diamond is a promising semiconductor material for future space exploration,owing to its unique atomic and electronic structures.However,diamond materials and related devices still suffer from irradiation damage under space irradiation involving high-energy irradiating particles.The study of the generation and evolution of point defects can help understand the irradiation damage mechanisms in diamond.This study systematically investigated the defect dynamics of diamond in 162 crystallographic directions uniformly selected on a spherical surface using molecular dynamics simulations,with primary knock-on atom(PKA)energies up to 20 keV,and temperatures ranging from 300 K to 1800 K.The results reveal that the displacement threshold energy of diamond changes periodically with crystallographic directions,which is related to the shape of potential energy surface along that direction.Additionally,the number of residual defects correlates positively with PKA energy.However,temperature has dual competing effects:while it enhances the probability of atomic displacement,it simultaneously suppresses the probability of defect formation by accelerating defect recombination.The calculation of sparse radial distribution function indicates that the defect distribution shows a certain degree of similarity in the short-range region across different PKA energies.As the PKA energy increases,defect clusters tend to become larger in size and more numerous in quantity.This study systematically investigates the anisotropy of displacement threshold energy and elucidates the relationship between various irradiation conditions and the final states of irradiation-induced defects.展开更多
The reduced-activation ferritic/martensitic(RAFM)steel CLF-1 has been designed as a candidate structural material for nuclear fusion energy reactors.For engineering mechanical design,the effects of temperature on the ...The reduced-activation ferritic/martensitic(RAFM)steel CLF-1 has been designed as a candidate structural material for nuclear fusion energy reactors.For engineering mechanical design,the effects of temperature on the strain distribution of CLF-1 steel during uniaxial tensile tests were explored within the temperature range from room temperature to 650°C using uniaxial tensile tests combined with in situ digital image correlation analysis.Strain-concentrated regions alternately distributed±45°along the tensile direction could be attributed to the shear stress having the maximum value at±45°along the tensile direction and the coordinated deformation of the microstructure.The total strain distribution changed from a normal distribution to a lognormal distribution with increasing deformation owing to the competition between the elastic and plastic strains at all test temperatures.Strain localization has a strong relationship with temperature at the same engineering strain because of the temperature effects on dynamic strain aging(DSA).The stronger the DSA effect,the stronger the strain localization.With increasing temperature,the stronger the strain localization at the same strain,the weaker the plasticity,that is,DSA-induced embrittlement,and the slower the strength decline,that is,DSA-induced hardening.展开更多
A series of laboratory pull-out tests was conducted to study the effects of temperature on the performance and behaviours of fully grouted rock bolt specimens cured within a specific temperature range,as well as for d...A series of laboratory pull-out tests was conducted to study the effects of temperature on the performance and behaviours of fully grouted rock bolt specimens cured within a specific temperature range,as well as for different durations.Each specimen consisted of a 20M rebar bolt at 1300 mm embedment length grouted inside a Schedule 80 steel pipe using Portland cement grout at a 0.4 water-to-cement ratio.Two temperatures(20℃and 45℃)were explored to investigate the effects of geothermally active temperature conditions on fully grouted rock bolts.Distributed fiber optic sensors were employed to provide continuous strain profiles along the entire embedment length to observe micro-mechanisms and monitor internal specimen temperature change during testing.The specimens cured at 45℃generally resulted in higher grout UCS(in certain cases 25%e50%higher)compared to those at 20℃;the ultimate capacity was not significantly impacted as the specimens'embedment length allowed full development of the rock bolt's capacity.The resulting strain profile trends showed generally higher strains experienced by the shorter(i.e.3-d)curing duration specimens under both curing temperatures compared to long-term curing.The 45℃specimens generally experienced lower strains and faster strain profile attenuation compared to specimens cured at 20℃.Understanding these effects and further analysis of FGRB specimen behaviours over time provide insights for mobilized and critical embedment lengths,capacity development,and support system stabilization.This paper highlights the results of this study and aims to bridge selected gaps in existing literature with a view to aid practitioners.展开更多
Climate change is significantly influenced by both clouds and Earth’s surface temperature(EST).While numerous studies have investigated clouds and EST separately,the extent of clouds’impact on EST remains unclear.Ba...Climate change is significantly influenced by both clouds and Earth’s surface temperature(EST).While numerous studies have investigated clouds and EST separately,the extent of clouds’impact on EST remains unclear.Based on the inspiration and limitation of cloud radiative effect(CRE),this study provides a pioneering attempt to propose a novel indicator,cloud radiative effect on surface temperature(CREST),aiming to quantify how clouds affect EST globally while also analyzing the physical mechanism.Using reanalysis and remotely sensed data,a phased machine learning scheme in combination of surface energy balance theory is proposed to estimate EST under all-sky and hypothetical clear-sky conditions in stages,thereby estimating the newly defined CREST by subtracting the hypothetical clear-sky EST from the all-sky EST.The inter-annual experiments reveal the significant spatial heterogeneity in CREST across land,ocean,and ice/snow regions.As a global offset of the heterogeneity,clouds exhibit a net warming effect on global surface temperature on an annual scale(e.g.,0.26 K in 1981),despite their ability to block sunlight.However,the net warming effect has gradually weakened to nearly zero over the past four decades(e.g.,only 0.06 K in 2021),and it’s even possible to transform into a cooling effect,which might be good news for mitigating the global warming.展开更多
The tensile behavior of(Fe_(50)Mn_(30)Co_(10)Cr_(10))_(100-x)Si_(x)(x=0(Si0),2(Si2))metastable HEAs prepared by selective laser melting was studied at cryogenic temperatures.The results demonstrate that the addition o...The tensile behavior of(Fe_(50)Mn_(30)Co_(10)Cr_(10))_(100-x)Si_(x)(x=0(Si0),2(Si2))metastable HEAs prepared by selective laser melting was studied at cryogenic temperatures.The results demonstrate that the addition of Si leads to lattice distortion and a decrease in stacking fault energy,especially at 77 K,which significantly promotes transformation-induced plasticity(TRIP)in Si2 HEAs.The yield strength,tensile strength,and ductility of Si2 HEAs are 505.2 MPa,1364.1 MPa,and 19%,which are 43%,53% and 58% higher than those of Si0 alloy,respectively.TRIP is the main deformation mode,in addition to dislocation slip,and plays a key role in strengthening.The reinforced and continuously sustained TRIP maintains a dynamic strain distribution during deformation.Ultrahigh strain hardening greatly enhances the strength and ductility.展开更多
In order to predict the long-term rutting of asphalt pavement, the effective temperature for pavement rutting is calculated using the numerical simulation method. The transient temperature field of asphalt pavement wa...In order to predict the long-term rutting of asphalt pavement, the effective temperature for pavement rutting is calculated using the numerical simulation method. The transient temperature field of asphalt pavement was simulated based on actual meteorological data of Nanjing. 24-hour rutting development under a transient temperature field was calculated in each month. The rutting depth accumulated under the static temperature field was also estimated and the relationship between constant temperature parameters was analyzed. Then the effective temperature for pavement rutting was determined based on the rutting equivalence principle. The results show that the monthly effective temperature is above 40 t in July and August, while in June and September it ranges from 30 to 40 Rutting development can be ignored when the monthly effective temperature is less than 30 t. The yearly effective temperature for rutting in Nanjing is around 38. 5 t. The long-term rutting prediction model based on the effective temperature can reflect the influences of meteorological factors and traffic time distribution.展开更多
A silicon temperature sensor with a conventional resistor structure is fabricated on thin-film silicon-on-insulator (SOI) substrate.The sensor has very promising characteristics.The maximum operating temperature ca...A silicon temperature sensor with a conventional resistor structure is fabricated on thin-film silicon-on-insulator (SOI) substrate.The sensor has very promising characteristics.The maximum operating temperature can reach 550℃ even at a low current of 0.1mA.Experimental results support that the minority-carrier exclusion effect can be strong in the conventional resistor structure when the silicon film is sufficiently thin,thus significantly raising the maximum operating temperature.Moreover,since the structure of the device on thin-film SOI wafer is not crucial in controlling the maximum operating temperature,device layout can be varied according to the requirements of applications.展开更多
Hydrogen evolution reaction （HER） at polycrystalline silver electrode in 0.1 mol/L HClO4 solution is investigated by cyclic voltammetry in the temperature range of 278-333 K. We found that at electrode potential φa...Hydrogen evolution reaction （HER） at polycrystalline silver electrode in 0.1 mol/L HClO4 solution is investigated by cyclic voltammetry in the temperature range of 278-333 K. We found that at electrode potential φa,app decreases with φ, while pre-exponential factor A remains nearly unchanged,which conforms well the prediction from Butler-Volmer equation. In contrast, with φ nega-tive shifts from the onset potential for HER to the potential of zero charge （PZC≈-0.4 V）, both Ea,app and A for HER increase （e.g., Ea,app increases from 24 kJ/mol to 32 kJ/mol）. The increase in Ea,app and A with negative shift in φ from -0.25 V to PZC is explained by the increases of both internal energy change and entropy change from reactants to the transition states, which is correlated with the change in the hydrogen bond network during HER. The positive entropy effects overcompensate the adverse effect from the increase in the activation energy, which leads to a net increase in HER current with the activation energy negative shift from the onset potential of HER to PZC. It is pointed out that entropy change may contribute greatly to the kinetics for electrode reaction which involves the transfer of electron and proton, such as HER.展开更多
[Objective] The aim was to analyse the variation characteristics of temperature in Anqing City and urban heat island effect.[Method] Based on the observation data of temperature from Anqing Station,other surrounding m...[Objective] The aim was to analyse the variation characteristics of temperature in Anqing City and urban heat island effect.[Method] Based on the observation data of temperature from Anqing Station,other surrounding meteorological stations and local automatic meteorological stations in suburbs,the annual variation of temperature and regional consistency was analysed,then the abrupt change of annual average temperature was tested by Mann-Kendall test,finally the influences of urban heat island effect on temperature variation in Anqing Station were studied.[Result] Affected by station migration and urban construction,the annual average temperature increased significantly in Anqing Station from 1977 to 2009,and the rising was more prominent after the middle of the 1990s.Mann-Kendall test showed that the change of temperature in Anqing Station was obviously abrupt around 1993;because of the development of urbanization,average temperature in Anqing Station was 0.8 ℃ higher than that in suburbs,and the minimum temperature rose more remarkably.In addition,urban heat island effect was the strongest in spring,followed by summer and autumn,while it was the weakest in winter.[Conclusion] The effects of urbanization development on the temperature in Anqing City were understood through this research.展开更多
Nitrogen loss without organic removal in biofilter was observed and its possible reason was explained. A lower hydraulic loading could improve aerobic denitrification rate. Aerobic denitrification was seriously affect...Nitrogen loss without organic removal in biofilter was observed and its possible reason was explained. A lower hydraulic loading could improve aerobic denitrification rate. Aerobic denitrification was seriously affected by low temperature(below 10℃). However, nitrification rate remained high when the temperature dropped from 15℃ to 5℃. It seemed the autotrophic biofilm in BAF could alleviate the adverse effect of low temperature.展开更多
The armyworm Mythimna roseilinea（Walker） is a major pest of grain crops in South China. So far little is known about its basic biology and ecology, making prediction of population dynamics difficult. This study exam...The armyworm Mythimna roseilinea（Walker） is a major pest of grain crops in South China. So far little is known about its basic biology and ecology, making prediction of population dynamics difficult. This study examined the relationships of individual development and population growth with temperature based on an age-stage, two-sex life table of M. roseilinea reared on maize in the laboratory at 18, 21, 24, 27 and 30℃. The highest values of net reproductive rate（R_0） and fecundity were observed at 21 and 24℃, respectively. Both the intrinsic rate of increase（r） and finite rate of increase（λ） increased significantly and mean generation time（T） decreased significantly with increasing temperature. M. roseilinea was able to develop, survive and lay eggs at all temperature regimes tested. Development rates of the egg, larval, pupal, as well as the whole pre-oviposition stages had a positive linear relationship with temperature. The calculated development threshold temperatures of egg, larval, pupal, pre-oviposition and total pre-oviposition stages were 13.29, 8.39, 14.35, 7.42, and 12.24℃, respectively, and their effective accumulated temperatures were 63.59, 445.00, 211.11, 89.02, and 698.95 degree-days, respectively. These results provide insight into temperature-based phenology and population ecology of this insect pest and will allow population prediction and management available in the field.展开更多
The investigation on Curie temperature and magnetocaloric effect of the FeCrMoCBYNi bulk metallic glass(BMG) with different crystallized phases was carried out by XRD,TEM and PPMS. The experimental results show that t...The investigation on Curie temperature and magnetocaloric effect of the FeCrMoCBYNi bulk metallic glass(BMG) with different crystallized phases was carried out by XRD,TEM and PPMS. The experimental results show that the Curie temperature(T_c) of Fe_(45)Cr_(15)Mo_(14)C_(15)B_6 Y_2 Ni_3 BMG with different annealing condition reaches a highest value of 95 K. The value of magnetic entropy change △S_M(T) of Sample 3 reaches a maxima of 0.48 J/(kg·K) at Tc temperature, which result from the interaction among the precipitated phases of(Fe,Cr)_(23)(C,B)_6, Fe_3 Mo_3 C and residual amorphous phase. Based on the experiment results, it can be obtained that the Curie temperature, magnetocaloric effect can reach their optimal value at low temperature, when the content of amorphous phase and precipitated phases type run up to certain value. The magnetic properties of Sample 1 with full amorphous phase and Sample 4 with full crystalline phase will both decrease.展开更多
The temperature dependence of hydrogen evolution reaction （HER） at a quasi-single crystalline gold electrode in both 0.1 mol/L HCl04 and 0.1 mol/L KOH solutions was investigated by cyclic voltammetry. HER current di...The temperature dependence of hydrogen evolution reaction （HER） at a quasi-single crystalline gold electrode in both 0.1 mol/L HCl04 and 0.1 mol/L KOH solutions was investigated by cyclic voltammetry. HER current displays a clear increase with reaction overpotential （η） and temperature from 278-333 K. In 0.1 mol/L HClO4 the Tafel slopes are found to increases slightly with temperature from 118 mV/dec to 146 mV/dec, while in 0.1 mol/L KOH it is ca. 153±15 mV/dec without clear temperature-dependent trend. The apparent activation energy （Ea） for HER at equilibrium potential is ca. 48 and 34 kJ/mol in 0.1 mol/L HC104 and 0.1 mol/L KOH, respectively. In acid solution, Ea decreases with increase in η, from Ea-37 kJ/mol （η=0.2 V） to 30 kJ/mol （η=0.35 V）. In contrast, in 0.1 mol/L KOH, Ea does not show obvious change with U. The pre-exponential factor （A） in 0.1 mol/L HC104 is ca. 1 order higher than that in 0.1 mol/L KOH. Toward more negative potential, in 0.1 mol/L HC104 A changes little with potential, while in 0.1 mol/L KOH it displays a monotonic increase with U. The change trends of the potential-dependent kinetic parameters for HER at Au electrode in 0.1 mol/L HClO4 and that in 0.1 mol/L KOH are discussed.展开更多
Many studies have indicated that structural strain will be significantly influenced by temperature variations,and a good understanding of the effect of temperature on structural strain is essential.A structural health...Many studies have indicated that structural strain will be significantly influenced by temperature variations,and a good understanding of the effect of temperature on structural strain is essential.A structural health monitoring system has been installed in a typical Tibetan timber building to measure the structural strains and ambient temperature since 2012.This paper presents the correlation between temperature and strain data from the monitored structure.A method combining singular spectrum analysis and polynomial regression is proposed for modeling the temperature induced strains in the structure.Singular spectrum analysis is applied to smooth the temperature data,and the correlation between the resulting temperature time series and the measured strains is obtained by polynomial regression.Parameters of the singular spectrum analysis and the regression model are selected to have the least regression error.Results show that the proposed method has both good reproduction and prediction capabilities for temperature induced strains,and that the method is accurate and effective for eliminating the effect of temperature from the measured strain.A standardized Novelty Index based on the residual strain is also used for the condition assessment of the structure.展开更多
The effects of Mn and Cr contents on bainitic transformation kinetics,microstructures and mechanical properties of high-carbon low alloy steels after austempered at 230,300 and 350 ℃ were determined by dilatometry,op...The effects of Mn and Cr contents on bainitic transformation kinetics,microstructures and mechanical properties of high-carbon low alloy steels after austempered at 230,300 and 350 ℃ were determined by dilatometry,optical microscopy,scanning electron microscopy,X-ray diffraction and tensile tests. The results showed that Mn and Cr can extend bainitic incubation period and completion time,and with the increase of Mn and Cr content,the bainitic ferrite plate thickness decreased and the volume fraction of retained austenite increased. TRIP（ transformation induced plasticity） effect was observed during tensile testing which improved the overall mechanical property. The increase of Mn concentration can improve the strength to a certain extent,but reduce the ductility. The increase of Cr concentration can improve the ductility of bainitic steels which transformed at a low temperature. The low temperature bainitic steel austempered at 230 ℃ exhibited excellent mechanical properties with ultimate tensile strength of（ 2146 ± 11） MPa and total elongation of（ 12. 95 ± 0. 15） %.展开更多
基金supported by the National Natural Science Foundation of China(No.62464010)Spring City Plan-Special Program for Young Talents(K202005007)+2 种基金Yunnan Talents Support Plan for Young Talents(XDYC-QNRC-2022-0482)Yunnan Local Colleges Applied Basic Research Projects(202101BA070001-138)Frontier Research Team of Kunming University 2023.
文摘Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.
基金funded by the Science Committee of the Ministry of Science and Higher Education of the Republic of Kazakhstan(Grant No.AP19680589).
文摘Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crack,strengthened by steel wire wrapping.The effects of the thread tensile force of the steel winding in the form of single rings at the crack edges and the wires with different winding diameters and pitches were also studied.The results showed that the strengthening was preferably executed at a minimum value of the thread tensile force,which was 6.4%more effective than that at its maximum value.The analysis of the influence of the winding dia-meters showed that the equivalent stresses increased by 32%from the beginning of the crack growth until the wire broke.The increment in winding diameter decelerated the disclosure of the edge crack and reduced its length by 8.2%.The analysis of the influence of the winding pitch showed that decreasing the distance between the winding turns also led to a 33.6%reduction in the length of the straight crack and a 7.9%reduction in the maximum stres-ses on the strengthened pipeline cross-section.The analysis of the temperature effect on the pipeline material,within a range from-40℃to+50℃,resulted in a crack length change of up to 5.8%.As the temperature dropped,the crack length decreased.Within such a temperature range,the maximum stresses were observed along the cen-tral area of the crack,which were equal to 413 MPa at+50℃and 440 MPa at-40℃.The results also showed that the presence of the steel winding in the pipeline significantly reduced the length of crack propagation up to 8.4 times,depending on the temperature effect and design parameters of prestressing.This work integrated the existing methods for crack localization along steel gas pipelines.
基金Project(51378510) supported by the National Natural Science Foundation of China。
文摘In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.
文摘The pressure and temperature increase resulting from the impact of different threats onto target materials is analyzed with a unified laboratory-scale setup.This allows deriving qualitative information on the occurring phenomenology as well as quantitative statements about the relative effects sizes as a function of target material and threat.The considered target materials are steel,aluminum,and magnesium.As threats,kinetic energy penetrator,explosively formed projectile,and shaped charge jet are used.For the investigated combinations,the measured overpressures vary by a factor of up to 5 for a variation of the material,by a factor of up to 7 for a variation of the threat,and by a factor larger than 15for a simultaneous variation of both.The obtained results as well as the experimental approach are relevant for the basic understanding of impact effects and risks due to material reactivity.The paper combines two main aims.Firstly,to provide a summary of own prior work in a coherent journal article and,secondly,to review and discuss these earlier results with a new perspective.
基金supported by the Science and Technology Innovation Program of Hunan Province,China(Grant No.2021RC4026)the National Natural Science Foundation of China(Grant Nos.12204538,12104507,and 92365203)Hunan Provincial Science Fund for Distinguished Young Scholars(Grant No.2022JJ10060).
文摘Diamond is a promising semiconductor material for future space exploration,owing to its unique atomic and electronic structures.However,diamond materials and related devices still suffer from irradiation damage under space irradiation involving high-energy irradiating particles.The study of the generation and evolution of point defects can help understand the irradiation damage mechanisms in diamond.This study systematically investigated the defect dynamics of diamond in 162 crystallographic directions uniformly selected on a spherical surface using molecular dynamics simulations,with primary knock-on atom(PKA)energies up to 20 keV,and temperatures ranging from 300 K to 1800 K.The results reveal that the displacement threshold energy of diamond changes periodically with crystallographic directions,which is related to the shape of potential energy surface along that direction.Additionally,the number of residual defects correlates positively with PKA energy.However,temperature has dual competing effects:while it enhances the probability of atomic displacement,it simultaneously suppresses the probability of defect formation by accelerating defect recombination.The calculation of sparse radial distribution function indicates that the defect distribution shows a certain degree of similarity in the short-range region across different PKA energies.As the PKA energy increases,defect clusters tend to become larger in size and more numerous in quantity.This study systematically investigates the anisotropy of displacement threshold energy and elucidates the relationship between various irradiation conditions and the final states of irradiation-induced defects.
基金supported by the National Natural Science Foundation of China(Nos.12175231 and 11805131)Anhui Natural Science Foundation of China(No.2108085J05)the Collaborative Innovation Program of Hefei Science Center,CAS(No.2022HSC-CIP009)。
文摘The reduced-activation ferritic/martensitic(RAFM)steel CLF-1 has been designed as a candidate structural material for nuclear fusion energy reactors.For engineering mechanical design,the effects of temperature on the strain distribution of CLF-1 steel during uniaxial tensile tests were explored within the temperature range from room temperature to 650°C using uniaxial tensile tests combined with in situ digital image correlation analysis.Strain-concentrated regions alternately distributed±45°along the tensile direction could be attributed to the shear stress having the maximum value at±45°along the tensile direction and the coordinated deformation of the microstructure.The total strain distribution changed from a normal distribution to a lognormal distribution with increasing deformation owing to the competition between the elastic and plastic strains at all test temperatures.Strain localization has a strong relationship with temperature at the same engineering strain because of the temperature effects on dynamic strain aging(DSA).The stronger the DSA effect,the stronger the strain localization.With increasing temperature,the stronger the strain localization at the same strain,the weaker the plasticity,that is,DSA-induced embrittlement,and the slower the strength decline,that is,DSA-induced hardening.
基金funded by the Canadian Department of National Defence(DND),the RMC Green Team Military GeoWorks Lab,and the National Sciences and Engineering Research Council(NSERC)of Canada.
文摘A series of laboratory pull-out tests was conducted to study the effects of temperature on the performance and behaviours of fully grouted rock bolt specimens cured within a specific temperature range,as well as for different durations.Each specimen consisted of a 20M rebar bolt at 1300 mm embedment length grouted inside a Schedule 80 steel pipe using Portland cement grout at a 0.4 water-to-cement ratio.Two temperatures(20℃and 45℃)were explored to investigate the effects of geothermally active temperature conditions on fully grouted rock bolts.Distributed fiber optic sensors were employed to provide continuous strain profiles along the entire embedment length to observe micro-mechanisms and monitor internal specimen temperature change during testing.The specimens cured at 45℃generally resulted in higher grout UCS(in certain cases 25%e50%higher)compared to those at 20℃;the ultimate capacity was not significantly impacted as the specimens'embedment length allowed full development of the rock bolt's capacity.The resulting strain profile trends showed generally higher strains experienced by the shorter(i.e.3-d)curing duration specimens under both curing temperatures compared to long-term curing.The 45℃specimens generally experienced lower strains and faster strain profile attenuation compared to specimens cured at 20℃.Understanding these effects and further analysis of FGRB specimen behaviours over time provide insights for mobilized and critical embedment lengths,capacity development,and support system stabilization.This paper highlights the results of this study and aims to bridge selected gaps in existing literature with a view to aid practitioners.
基金carried out under the co-funding of the National Natural Science Foundation of China(NSFC)project(Grant No.42022008)Zhuhai basic and applied research project(Grant No.ZH22017003200009PWC)the Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(Grant No.311022003).
文摘Climate change is significantly influenced by both clouds and Earth’s surface temperature(EST).While numerous studies have investigated clouds and EST separately,the extent of clouds’impact on EST remains unclear.Based on the inspiration and limitation of cloud radiative effect(CRE),this study provides a pioneering attempt to propose a novel indicator,cloud radiative effect on surface temperature(CREST),aiming to quantify how clouds affect EST globally while also analyzing the physical mechanism.Using reanalysis and remotely sensed data,a phased machine learning scheme in combination of surface energy balance theory is proposed to estimate EST under all-sky and hypothetical clear-sky conditions in stages,thereby estimating the newly defined CREST by subtracting the hypothetical clear-sky EST from the all-sky EST.The inter-annual experiments reveal the significant spatial heterogeneity in CREST across land,ocean,and ice/snow regions.As a global offset of the heterogeneity,clouds exhibit a net warming effect on global surface temperature on an annual scale(e.g.,0.26 K in 1981),despite their ability to block sunlight.However,the net warming effect has gradually weakened to nearly zero over the past four decades(e.g.,only 0.06 K in 2021),and it’s even possible to transform into a cooling effect,which might be good news for mitigating the global warming.
基金supported by Program for Innovative Research Team in Science and Technology in Fujian Province University,Chinathe Natural Science Foundation of Fujian Province,China(Nos.2023J011013,2020J01898)。
文摘The tensile behavior of(Fe_(50)Mn_(30)Co_(10)Cr_(10))_(100-x)Si_(x)(x=0(Si0),2(Si2))metastable HEAs prepared by selective laser melting was studied at cryogenic temperatures.The results demonstrate that the addition of Si leads to lattice distortion and a decrease in stacking fault energy,especially at 77 K,which significantly promotes transformation-induced plasticity(TRIP)in Si2 HEAs.The yield strength,tensile strength,and ductility of Si2 HEAs are 505.2 MPa,1364.1 MPa,and 19%,which are 43%,53% and 58% higher than those of Si0 alloy,respectively.TRIP is the main deformation mode,in addition to dislocation slip,and plays a key role in strengthening.The reinforced and continuously sustained TRIP maintains a dynamic strain distribution during deformation.Ultrahigh strain hardening greatly enhances the strength and ductility.
基金The National Natural Science Foundation of China(No.51378121)the Fok Ying Tung Education Foundation(No.141076)the Scientific Innovation Research of College Graduates in Jiangsu Province(No.KYLX_0164)
文摘In order to predict the long-term rutting of asphalt pavement, the effective temperature for pavement rutting is calculated using the numerical simulation method. The transient temperature field of asphalt pavement was simulated based on actual meteorological data of Nanjing. 24-hour rutting development under a transient temperature field was calculated in each month. The rutting depth accumulated under the static temperature field was also estimated and the relationship between constant temperature parameters was analyzed. Then the effective temperature for pavement rutting was determined based on the rutting equivalence principle. The results show that the monthly effective temperature is above 40 t in July and August, while in June and September it ranges from 30 to 40 Rutting development can be ignored when the monthly effective temperature is less than 30 t. The yearly effective temperature for rutting in Nanjing is around 38. 5 t. The long-term rutting prediction model based on the effective temperature can reflect the influences of meteorological factors and traffic time distribution.
文摘A silicon temperature sensor with a conventional resistor structure is fabricated on thin-film silicon-on-insulator (SOI) substrate.The sensor has very promising characteristics.The maximum operating temperature can reach 550℃ even at a low current of 0.1mA.Experimental results support that the minority-carrier exclusion effect can be strong in the conventional resistor structure when the silicon film is sufficiently thin,thus significantly raising the maximum operating temperature.Moreover,since the structure of the device on thin-film SOI wafer is not crucial in controlling the maximum operating temperature,device layout can be varied according to the requirements of applications.
基金ACKNOWLEDGMENTS This work was supported by the One Hundred Talents＇ Program of the Chinese Academy of Science, the National Natural Science Foundation of China （No.21073176）, and the National Basic Research Program of China National Science and Technology （No.2010CB923302）.
文摘Hydrogen evolution reaction （HER） at polycrystalline silver electrode in 0.1 mol/L HClO4 solution is investigated by cyclic voltammetry in the temperature range of 278-333 K. We found that at electrode potential φa,app decreases with φ, while pre-exponential factor A remains nearly unchanged,which conforms well the prediction from Butler-Volmer equation. In contrast, with φ nega-tive shifts from the onset potential for HER to the potential of zero charge （PZC≈-0.4 V）, both Ea,app and A for HER increase （e.g., Ea,app increases from 24 kJ/mol to 32 kJ/mol）. The increase in Ea,app and A with negative shift in φ from -0.25 V to PZC is explained by the increases of both internal energy change and entropy change from reactants to the transition states, which is correlated with the change in the hydrogen bond network during HER. The positive entropy effects overcompensate the adverse effect from the increase in the activation energy, which leads to a net increase in HER current with the activation energy negative shift from the onset potential of HER to PZC. It is pointed out that entropy change may contribute greatly to the kinetics for electrode reaction which involves the transfer of electron and proton, such as HER.
文摘[Objective] The aim was to analyse the variation characteristics of temperature in Anqing City and urban heat island effect.[Method] Based on the observation data of temperature from Anqing Station,other surrounding meteorological stations and local automatic meteorological stations in suburbs,the annual variation of temperature and regional consistency was analysed,then the abrupt change of annual average temperature was tested by Mann-Kendall test,finally the influences of urban heat island effect on temperature variation in Anqing Station were studied.[Result] Affected by station migration and urban construction,the annual average temperature increased significantly in Anqing Station from 1977 to 2009,and the rising was more prominent after the middle of the 1990s.Mann-Kendall test showed that the change of temperature in Anqing Station was obviously abrupt around 1993;because of the development of urbanization,average temperature in Anqing Station was 0.8 ℃ higher than that in suburbs,and the minimum temperature rose more remarkably.In addition,urban heat island effect was the strongest in spring,followed by summer and autumn,while it was the weakest in winter.[Conclusion] The effects of urbanization development on the temperature in Anqing City were understood through this research.
文摘Nitrogen loss without organic removal in biofilter was observed and its possible reason was explained. A lower hydraulic loading could improve aerobic denitrification rate. Aerobic denitrification was seriously affected by low temperature(below 10℃). However, nitrification rate remained high when the temperature dropped from 15℃ to 5℃. It seemed the autotrophic biofilm in BAF could alleviate the adverse effect of low temperature.
基金funded by the Special Fund for Agro-scientific Research in the Public Interest of China (201403031)the China Agriculture Research System (CARS-22)+2 种基金the National Key Research and Development Program of China (2017YFD0201802, 2017YFD0201701)he National Natural Science Foundation of China (31672019, 31371947)the Beijing Natural Science Foundation, China (6172030)
文摘The armyworm Mythimna roseilinea（Walker） is a major pest of grain crops in South China. So far little is known about its basic biology and ecology, making prediction of population dynamics difficult. This study examined the relationships of individual development and population growth with temperature based on an age-stage, two-sex life table of M. roseilinea reared on maize in the laboratory at 18, 21, 24, 27 and 30℃. The highest values of net reproductive rate（R_0） and fecundity were observed at 21 and 24℃, respectively. Both the intrinsic rate of increase（r） and finite rate of increase（λ） increased significantly and mean generation time（T） decreased significantly with increasing temperature. M. roseilinea was able to develop, survive and lay eggs at all temperature regimes tested. Development rates of the egg, larval, pupal, as well as the whole pre-oviposition stages had a positive linear relationship with temperature. The calculated development threshold temperatures of egg, larval, pupal, pre-oviposition and total pre-oviposition stages were 13.29, 8.39, 14.35, 7.42, and 12.24℃, respectively, and their effective accumulated temperatures were 63.59, 445.00, 211.11, 89.02, and 698.95 degree-days, respectively. These results provide insight into temperature-based phenology and population ecology of this insect pest and will allow population prediction and management available in the field.
基金supported by the National Natural Science Foundation of China(51741105)
文摘The investigation on Curie temperature and magnetocaloric effect of the FeCrMoCBYNi bulk metallic glass(BMG) with different crystallized phases was carried out by XRD,TEM and PPMS. The experimental results show that the Curie temperature(T_c) of Fe_(45)Cr_(15)Mo_(14)C_(15)B_6 Y_2 Ni_3 BMG with different annealing condition reaches a highest value of 95 K. The value of magnetic entropy change △S_M(T) of Sample 3 reaches a maxima of 0.48 J/(kg·K) at Tc temperature, which result from the interaction among the precipitated phases of(Fe,Cr)_(23)(C,B)_6, Fe_3 Mo_3 C and residual amorphous phase. Based on the experiment results, it can be obtained that the Curie temperature, magnetocaloric effect can reach their optimal value at low temperature, when the content of amorphous phase and precipitated phases type run up to certain value. The magnetic properties of Sample 1 with full amorphous phase and Sample 4 with full crystalline phase will both decrease.
基金V, ACKNOWLEDGMENTS This work was supported by one Hundred Talents＇ Program of the Chinese Academy of Science, the National Natural Science Foundation of China （No.21073176）, and 973 Program from the Ministry of Science and Technology of China （No.2010CB923302）.
文摘The temperature dependence of hydrogen evolution reaction （HER） at a quasi-single crystalline gold electrode in both 0.1 mol/L HCl04 and 0.1 mol/L KOH solutions was investigated by cyclic voltammetry. HER current displays a clear increase with reaction overpotential （η） and temperature from 278-333 K. In 0.1 mol/L HClO4 the Tafel slopes are found to increases slightly with temperature from 118 mV/dec to 146 mV/dec, while in 0.1 mol/L KOH it is ca. 153±15 mV/dec without clear temperature-dependent trend. The apparent activation energy （Ea） for HER at equilibrium potential is ca. 48 and 34 kJ/mol in 0.1 mol/L HC104 and 0.1 mol/L KOH, respectively. In acid solution, Ea decreases with increase in η, from Ea-37 kJ/mol （η=0.2 V） to 30 kJ/mol （η=0.35 V）. In contrast, in 0.1 mol/L KOH, Ea does not show obvious change with U. The pre-exponential factor （A） in 0.1 mol/L HC104 is ca. 1 order higher than that in 0.1 mol/L KOH. Toward more negative potential, in 0.1 mol/L HC104 A changes little with potential, while in 0.1 mol/L KOH it displays a monotonic increase with U. The change trends of the potential-dependent kinetic parameters for HER at Au electrode in 0.1 mol/L HClO4 and that in 0.1 mol/L KOH are discussed.
基金National Natural Science Foundation of China for Excellent Young Scholars under Grant No.51422801National Natural Science Foundation of China under Key Program 51338001Beijing Natural Science Foundation of China under Key Program:8151003
文摘Many studies have indicated that structural strain will be significantly influenced by temperature variations,and a good understanding of the effect of temperature on structural strain is essential.A structural health monitoring system has been installed in a typical Tibetan timber building to measure the structural strains and ambient temperature since 2012.This paper presents the correlation between temperature and strain data from the monitored structure.A method combining singular spectrum analysis and polynomial regression is proposed for modeling the temperature induced strains in the structure.Singular spectrum analysis is applied to smooth the temperature data,and the correlation between the resulting temperature time series and the measured strains is obtained by polynomial regression.Parameters of the singular spectrum analysis and the regression model are selected to have the least regression error.Results show that the proposed method has both good reproduction and prediction capabilities for temperature induced strains,and that the method is accurate and effective for eliminating the effect of temperature from the measured strain.A standardized Novelty Index based on the residual strain is also used for the condition assessment of the structure.
基金supported by the National Natural Science Foundation of China(Grant No.51271035 and U1560107)The financial support of the State Key Laboratory of Development and Application Technology of Automotive Steels
文摘The effects of Mn and Cr contents on bainitic transformation kinetics,microstructures and mechanical properties of high-carbon low alloy steels after austempered at 230,300 and 350 ℃ were determined by dilatometry,optical microscopy,scanning electron microscopy,X-ray diffraction and tensile tests. The results showed that Mn and Cr can extend bainitic incubation period and completion time,and with the increase of Mn and Cr content,the bainitic ferrite plate thickness decreased and the volume fraction of retained austenite increased. TRIP（ transformation induced plasticity） effect was observed during tensile testing which improved the overall mechanical property. The increase of Mn concentration can improve the strength to a certain extent,but reduce the ductility. The increase of Cr concentration can improve the ductility of bainitic steels which transformed at a low temperature. The low temperature bainitic steel austempered at 230 ℃ exhibited excellent mechanical properties with ultimate tensile strength of（ 2146 ± 11） MPa and total elongation of（ 12. 95 ± 0. 15） %.
