From rhizomes of Hemsleya giganthy collected in Shichuan of China, 16 compounds were isolated. Among them, three compounds (8, 9, 15) are new natural products called Hemslecins G; Hemsgiganosides A and B; respectivel...From rhizomes of Hemsleya giganthy collected in Shichuan of China, 16 compounds were isolated. Among them, three compounds (8, 9, 15) are new natural products called Hemslecins G; Hemsgiganosides A and B; respectively. Their structures were elucidated as 7- hydroxy-23, 24-dihydro-cucurbitacin F-25-O-acetate (8); 3-O-(6-butyl ester-)-b-D-glu- curono- pyranosyl)-oleanolic acid-28-O-a-L-arabinopyranoside(9); 3-O-b-D-glucuropyranosyl oleanolic acid -28-O-b-D-gluco pyranosyl-(16)- b-D-glucopyranoside(15) by spectroscopic and chemical means.展开更多
Three new cucurbitacins were isolated from the BuOH extract of the rhizomes of Hemsleya lijiangensis. Their structures were elucidated as 23, 24 -dihydro cucurbitacin F-16, 25-diacetate(1), 23, 24-dihydro cucurbitaci...Three new cucurbitacins were isolated from the BuOH extract of the rhizomes of Hemsleya lijiangensis. Their structures were elucidated as 23, 24 -dihydro cucurbitacin F-16, 25-diacetate(1), 23, 24-dihydro cucurbitacin F-16, 25-diacetate-2-O-β-D glucopyranoside (2), 23, 24-dihydro-cucurbitacin F-16-acetate(3), respectively; by spectral analyses.展开更多
基金The authors are grateful to the financial support of the National Natural Science Foundation of China(Grant No.39970086)Natural Science Foundation of Yunnan(Grant No.98C089M)also thank the members of analytical group in Phytochemistry LaboratoTy,Kunming Institute of Botany for their measuring spectral data.
文摘From rhizomes of Hemsleya giganthy collected in Shichuan of China, 16 compounds were isolated. Among them, three compounds (8, 9, 15) are new natural products called Hemslecins G; Hemsgiganosides A and B; respectively. Their structures were elucidated as 7- hydroxy-23, 24-dihydro-cucurbitacin F-25-O-acetate (8); 3-O-(6-butyl ester-)-b-D-glu- curono- pyranosyl)-oleanolic acid-28-O-a-L-arabinopyranoside(9); 3-O-b-D-glucuropyranosyl oleanolic acid -28-O-b-D-gluco pyranosyl-(16)- b-D-glucopyranoside(15) by spectroscopic and chemical means.
基金The authors are grateful to the financial support of the National Natural Sciences Foundation of China (Grant No.39970086) and the Natural Science Foundation of Yunnan (Grant No.98C089M) also thank the members of analytical group in Phytochemistry Labo
文摘Three new cucurbitacins were isolated from the BuOH extract of the rhizomes of Hemsleya lijiangensis. Their structures were elucidated as 23, 24 -dihydro cucurbitacin F-16, 25-diacetate(1), 23, 24-dihydro cucurbitacin F-16, 25-diacetate-2-O-β-D glucopyranoside (2), 23, 24-dihydro-cucurbitacin F-16-acetate(3), respectively; by spectral analyses.
