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Cucurbitacin and Triterpenoid Glycosides from Hemsleya giganthy 被引量:10

Cucurbitacin and Triterpenoid Glycosides from Hemsleya giganthy
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摘要 From rhizomes of Hemsleya giganthy collected in Shichuan of China, 16 compounds were isolated. Among them, three compounds (8, 9, 15) are new natural products called Hemslecins G; Hemsgiganosides A and B; respectively. Their structures were elucidated as 7- hydroxy-23, 24-dihydro-cucurbitacin F-25-O-acetate (8); 3-O-(6-butyl ester-)-b-D-glu- curono- pyranosyl)-oleanolic acid-28-O-a-L-arabinopyranoside(9); 3-O-b-D-glucuropyranosyl oleanolic acid -28-O-b-D-gluco pyranosyl-(16)- b-D-glucopyranoside(15) by spectroscopic and chemical means. From rhizomes of Hemsleya giganthy collected in Shichuan of China, 16 compounds were isolated. Among them, three compounds (8, 9, 15) are new natural products called Hemslecins G; Hemsgiganosides A and B; respectively. Their structures were elucidated as 7- hydroxy-23, 24-dihydro-cucurbitacin F-25-O-acetate (8); 3-O-(6-butyl ester-)-b-D-glu- curono- pyranosyl)-oleanolic acid-28-O-a-L-arabinopyranoside(9); 3-O-b-D-glucuropyranosyl oleanolic acid -28-O-b-D-gluco pyranosyl-(16)- b-D-glucopyranoside(15) by spectroscopic and chemical means.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第5期475-478,共4页 中国化学快报(英文版)
基金 The authors are grateful to the financial support of the National Natural Science Foundation of China(Grant No.39970086) Natural Science Foundation of Yunnan(Grant No.98C089M) also thank the members of analytical group in Phytochemistry LaboratoTy,Kunming Institute of Botany for their measuring spectral data.
关键词 Hemsleya giganthy CUCURBITACEAE Hemslecins G Hemsgiganosides A B. H Hemsleya giganthy, Cucurbitaceae, Hemslecins G, Hemsgiganosides A, B. H
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