Luan River is the main water source in Beijing-Tianjin-Hebei region,northern China,where the groundwater system is vulnerable and pollution issue is serious.It is significant for regional groundwater resources protect...Luan River is the main water source in Beijing-Tianjin-Hebei region,northern China,where the groundwater system is vulnerable and pollution issue is serious.It is significant for regional groundwater resources protection to identify the hydrogeochemistry evolution and affecting factors along flow direction occurred in the upper reaches,especially the surface water-groundwater(SWGW)conversion relationship.In this study,recharge,conversion and geochemistry evolution of SW and GW were elucidated based on physical-hydrochemical indicators and stable isotopes in 36 GW samples and 20 SW samples,which were collected in July 2019 and July 2020.The factor analysis was further utilized to determine the main factors responsible for regional hydrogeochemical evolution.Results indicate that GW recharged SW in plateau area,and SW and GW recharged each other in typical Alpine valley area.The hydrochemical types are HCO3-Ca·Mg and HCO3-Ca,and the hydrochemical evolution is dominated by weathering of silicate and carbonate minerals.The cation exchange adsorption has minor impact on groundwater hydrochemistry.The rise of SO42-and NO3-contents in groundwater is related to industrial and agricultural activities.The main controlling factors of SW hydrochemical components included recharge from groundwater,industrial and mining activities,explaining 90.04%of data variance.However,water-rock interaction,agricultural and domestic sewage are responsible for GW quality,accounting for 83.38%.展开更多
Understanding the role of cations within the catalysts in the interfacial water behavior at the electrolyte/catalyst interface is of pivotal importance for designing advanced catalysts toward hydrogen evolution reacti...Understanding the role of cations within the catalysts in the interfacial water behavior at the electrolyte/catalyst interface is of pivotal importance for designing advanced catalysts toward hydrogen evolution reaction(HER),which remains obscure and requires deep probing.Herein,we demonstrate the first investigation of interfacial water behavior on the surface of a series of sodium tungsten bronzes(Na_(x)WO_(3),0_(x)WO_(3)/electrolyte interface.Our integrated studies indicate that the Na ions significantly enrich the electronic state of WO_(6)octahedrons in Na_(x)WO_(3),which leads to the regulated electronic and atomic structures,endowing Na_(x)WO_(3)with disordered interfacial water network containing more isolated H_(3)O^(+)and subsequently moderate H^(*)adsorption to speed the Volmer step at the Na_(x)WO_(3)surface,thus boosting the HER.Consequently,the intrinsic HER activities achieved on those Na_(x)WO_(3)are tens of times higher than those on WO_(3).Particularly,it is found that Na concentration x=0.69 endows Na_(x)WO_(3)with the highest intrinsic HER activity,and the resultant Na_(0.69)WO_(3)with a unique porous octahedral structure exhibits a low overpotential of only 64 mV at current density of 10 mA cm^(-2)in acidic electrolyte.This study provides the first insight into the cation-dependent interfacial water behavior induced by the cations within the catalyst and establishes the interfacial water-activity relationship of HER,thus allowing for the design of a more advanced catalyst with efficient interfacial structu res towa rds HER.展开更多
A thorough understanding of the oxygen evolution reaction(OER)in Mo-based materials is crucial for the advancement of water-splitting technologies.However,the identification of the active phase in Mo-based systems rem...A thorough understanding of the oxygen evolution reaction(OER)in Mo-based materials is crucial for the advancement of water-splitting technologies.However,the identification of the active phase in Mo-based systems remains a subject of debate,largely due to the dissolution of molybdenum oxides in alkaline electrolytes.In this review,we provide a comprehensive overview of recent advances in the application of Mo-based materials for OER in alkaline media,with an emphasis on their diverse roles in catalysis.Various design strategies employed to optimize Mo-based materials are discussed,focusing on how these approaches influence their physicochemical properties and the specific effects of different design perspectives on their OER performance.Additionally,the structure-performance relationship underlying these materials is explored,offering insights into how structural modifications impact catalytic efficiency.Lastly,key challenges for Mo-based materials in OER applications are provided,and future research directions for further improving the efficacy of sustainable water-splitting technologies in alkaline environments are proposed.展开更多
A comprehensive understanding of the dynamic processes at the catalyst/electrolyte interfaces is crucial for the development of advanced electrocatalysts for the oxygen evolution reaction(OER).However,the chemical pro...A comprehensive understanding of the dynamic processes at the catalyst/electrolyte interfaces is crucial for the development of advanced electrocatalysts for the oxygen evolution reaction(OER).However,the chemical processes related to surface corrosion and catalyst degradation have not been well understood so far.In this study,we employ LiCoO_(2) as a model catalyst and observe distinct OER activities and surface stabilities in different alkaline solutions.Operando X-ray diffraction(XRD)and online mass spectroscopy(OMS)measurements prove the selective intercalation of alkali cations into the layered structure of LiCoO_(2) during OER.It is proposed that the dynamic cation intercalations facilitate the chemical oxidation process between highly oxidative Co species and adsorbed water molecules,triggering the so-called electrochemical-chemical reaction mechanism(EC-mechanism).The results of this study emphasize the influence of cations on OER and provide insights into new strategies for achieving both high activity and stability in high-performance OER catalysts.展开更多
（The effect of liquid diffusion coefficients on the microstructure evolution during solidification of primary （Al） phase in Al356.1 alloy was investigated by means of the phase-field simulation using two sets of di...（The effect of liquid diffusion coefficients on the microstructure evolution during solidification of primary （Al） phase in Al356.1 alloy was investigated by means of the phase-field simulation using two sets of diffusion coefficients in liquid phase, while fixing other thermophysical and numerical parameters. The first set is only with impurity coefficients of liquid phase in Arrhenius formula representing only the temperature dependence. While the second set is with the well-established atomic mobility database representing both temperature and concentration dependence. For the second set of liquid diffusion coefficients, the effect of non-diagonal diffusion coefficients on the microstructure evolution in Al356.1 alloy during solidification was also analyzed. The differences were observed in the morphology, tip velocity and composition profile ahead of the tip of the dendrite due to the three cases of liquid diffusivities. The simulation results indicate that accurate databases of mobilities in the liquid phase are highly needed for the quantitative simulation of microstructural evolution during solidification.展开更多
During the process of landslide, its dynamic mechanism is important to understand and predict these kinds of natural hazard. In this paper, a new method, based on concepts of complex networks, has been proposed to inv...During the process of landslide, its dynamic mechanism is important to understand and predict these kinds of natural hazard. In this paper, a new method, based on concepts of complex networks, has been proposed to investigate the evolution of contact networks in mesoscale during the sliding process of slope. A slope model was established using the discrete element method (DEM), and influences of inter-particle frictional coefficients with four different values on?dynamic landslides were studied. Both macroscopic analysis on slope?landslide?and mesoanalysis on structure evolution of contact networks, including the?average degree, clustering coefficient?and N-cycle, were done during the process?of landslide. The analysis results demonstrate that: 1) with increasing inter-particle?frictional coefficients, the displacement of slope decreases and the stable angle of slope post-failure increases, which is smaller than the peak internal frictional angle;2) the average degree decreases with the increase of inter-particle frictional coefficient. When the displacement at the toe of the slope is smaller,?the average degree there changes more greatly with increasing inter-particle?frictional coefficient;3) during the initial stage of landslide, the clustering coefficient?reduces sharply, which may leads to easily slide of slope. As the landslide?going?on, however, the clustering coefficient?increases denoting increasing stability?with?increasing inter-particle frictional coefficients. When the inter-particle?frictional coefficient is smaller than 0.3, its variation can affect the clustering coefficient?and stable inclination of slope post-failure greatly;and 4) the number of?3-cycle increases, but 4-cycle and 5-cycle decrease with increasing inter-particle frictional coefficients.展开更多
One of the important geotechnical parameters required for designing of the civil engineering structure is the compressibility of the soil.In this study,the main purpose is to develop a novel hybrid Machine Learning(ML...One of the important geotechnical parameters required for designing of the civil engineering structure is the compressibility of the soil.In this study,the main purpose is to develop a novel hybrid Machine Learning(ML)model(ANFIS-DE),which used Differential Evolution(DE)algorithm to optimize the predictive capability of Adaptive-Network-based Fuzzy Inference System(ANFIS),for estimating soil Compression coefficient(Cc)from other geotechnical parameters namelyWater Content,Void Ratio,SpecificGravity,Liquid Limit,Plastic Limit,Clay content and Depth of Soil Samples.Validation of the predictive capability of the novel model was carried out using statistical indices:Root Mean Square Error(RMSE),Mean Absolute Error(MAE),and Correlation Coefficient(R).In addition,two popular ML models namely Reduced Error Pruning Trees(REPTree)and Decision Stump(Dstump)were used for comparison.Results showed that the performance of the novel model ANFIS-DE is the best(R=0.825,MAE=0.064 and RMSE=0.094)in comparison to other models such as REPTree(R=0.7802,MAE=0.068 and RMSE=0.0988)andDstump(R=0.7325,MAE=0.0785 and RMSE=0.1036).Therefore,the ANFIS-DE model can be used as a promising tool for the correct and quick estimation of the soil Cc,which can be employed in the design and construction of civil engineering structures.展开更多
The oxygen evolution reaction(OER)is the essential module in energy conversion and storage devices such as electrolyzer,rechargeable metal–air batteries and regenerative fuel cells.The adsorption energy scaling relat...The oxygen evolution reaction(OER)is the essential module in energy conversion and storage devices such as electrolyzer,rechargeable metal–air batteries and regenerative fuel cells.The adsorption energy scaling relations between the reaction intermediates,however,impose a large intrinsic overpotential and sluggish reaction kinetics on OER catalysts.Developing advanced electrocatalysts with high activity and stability based on non-noble metal materials is still a grand challenge.Central to the rational design of novel and high-efficiency catalysts is the development and understanding of quantitative structure–activity relationships,which correlate the catalytic activities with structural and electronic descriptors.This paper comprehensively reviews the benchmark descriptors for OER electrolysis,aiming to give an in-depth understanding on the origins of the electrocatalytic activity of the OER and further contribute to building the theory of electrocatalysis.Meanwhile,the cutting-edge research frontiers for proposing new OER paradigms and crucial strategies to circumvent the scaling relationship are also summarized.Challenges,opportunities and perspectives are discussed,intending to shed some light on the rational design concepts and advance the development of more efficient catalysts for enhancing OER performance.展开更多
The interaction between thermomechanical parameters and microstructure evolution is so intense that it must be considered during the finite element method （FEM） simulation of the hot plastic working process, for mat...The interaction between thermomechanical parameters and microstructure evolution is so intense that it must be considered during the finite element method （FEM） simulation of the hot plastic working process, for materials that are difficult to deform. Taking the microstructure evolution into account, a novel type of constitutive relationship has been put forward for the IN718 alloy. The microstructure evolution model was first established for the dominant microstructure evolution processes. Then the microstructure evolution models and the method to determine the local flow stress of the corresponding microstructure for current thermomechanical parameters and deformation history were presented. Once the local flow stresses of different structures and their volume contributions were defined, the apparent flow stress of the material could be determined as the weighted sum of the local flow stresses and volume contributions. To validate the proposed method, a thermoviscoplastics and microstructure evolution coupled analysis for a forging process of a critical IN718 disk forging was performed. The predicting results were in close agreement with the experimental data.展开更多
The initial micro-cracks affect the evolution characteristics of macroscopic deformation and failure of rock but are often ignored in theoretical calculation,numerical simulation,and mechanical experiments.In this stu...The initial micro-cracks affect the evolution characteristics of macroscopic deformation and failure of rock but are often ignored in theoretical calculation,numerical simulation,and mechanical experiments.In this study,we propose a quantitative analysis model to investigate the effects of initial micro-cracks on the evolution of marble deformation and failure.The relationship between the micro-crack propagation and the marble failure characteristics was comprehensively studied by combining theoretical analysis with a micro-computed tomography(micro-CT)scanning technique.We found that with the increase of confining pressure,the matrix elastic modulus of the marble first increased and then tended to be stable,while the micro-cracks increased exponentially.The sensitivity ranges of the marble sample matrix elastic modulus and micro-cracks to confining pressure were 0–30 MPa and 30–50 MPa,respectively.The porosity and Poisson’s ratio decreased exponentially.The increasing proportion of internal micro-cracks led to an increase in the sample non-uniformity.The samples presented mainly shear failure under triaxial compression,and the failure angle decreased linearly with the increase of confining pressure.The convergence direction of cracks decreased gradually.This quantitative analysis model could accurately portray the relationship between the overall macroscopic deformation and the deviatoric stress of the samples at the compaction and the linear elastic stages,thus deepening the understanding of the stress–strain behavior of rocks.展开更多
Accurate measurement of the evolution of rock joint void geometry is essential for comprehending the distribution characteristics of asperities responsible for shear and seepage behaviors.However,existing techniques o...Accurate measurement of the evolution of rock joint void geometry is essential for comprehending the distribution characteristics of asperities responsible for shear and seepage behaviors.However,existing techniques often require specialized equipment and skilled operators,posing practical challenges.In this study,a cost-effective photogrammetric approach is proposed.Particularly,local coordinate systems are established to facilitate the alignment and precise quantification of the relative position between two halves of a rock joint.Push/pull tests are conducted on rock joints with varying roughness levels to induce different contact states.A high-precision laser scanner serves as a benchmark for evaluating the photogrammetry method.Despite certain deviations exist,the measured evolution of void geometry is generally consistent with the qualitative findings of previous studies.The photogrammetric measurements yield comparable accuracy to laser scanning,with maximum errors of 13.2%for aperture and 14.4%for void volume.Most joint matching coefficient(JMC)measurement errors are below 20%.Larger measurement errors occur primarily in highly mismatched rock joints with JMC values below 0.2,but even in cases where measurement errors exceed 80%,the maximum JMC error is only 0.0434.Thus,the proposed photogrammetric approach holds promise for widespread application in void geometry measurements in rock joints.展开更多
Due to the diversity of work requirements and environment,the number of degrees of freedom(DOFs)and the complexity of structure of industrial robots are constantly increasing.It is difficult to establish the accurate ...Due to the diversity of work requirements and environment,the number of degrees of freedom(DOFs)and the complexity of structure of industrial robots are constantly increasing.It is difficult to establish the accurate dynamical model of industrial robots,which greatly hinders the realization of a stable,fast and accurate trajectory tracking control.Therefore,the general expression of the constraint relation in the explicit dynamic equation of the multi-DOF industrial robot is derived on the basis of solving the Jacobian matrix and Hessian matrix by using the kinematic influence coefficients method.Moreover,an explicit dynamic equation with general constraint relation expression is established based on the Udwadia-Kalaba theory.The problem of increasing the time of establishing constraint relationship when the multi-DOF industrial robots complete complex task constraints is solved.With the SCARA robot as the research object,the simulation results show that the proposed method can provide a new idea for industrial robot system modeling with complex constraints.展开更多
To comprehensively understand the law of urban-rural relationship and propose scientific measures of urban-rural coordinated development in Northeast China,this study uses the coupling coordination degree model and ge...To comprehensively understand the law of urban-rural relationship and propose scientific measures of urban-rural coordinated development in Northeast China,this study uses the coupling coordination degree model and geographically and temporally weighted regression(GTWR)model to analyze the spatial-temporal patterns and the corresponding driving mechanisms of its urban-rural coordination since 1990.The results are as follows.First,the urban-rural coupling coordination degree in Northeast China was very low and improved slowly,but its stages of evolution is a good interpretation of the strategic arrangements of China's urbanization.Second,the urban-rural coupling coordination degree in Northeast China had spatial differences and was characterized by central polarization,converging on urban agglomeration,which was high in the south and low in the north.Moreover,the gap between the north and south weakened.Third,the spatial-temporal evolution of the urban-rural coordination relationship in Northeast China was influenced by pulling from the central cities,pushing from rural transformation,and government regulations.The influence intensity of the three mechanisms was weak,but the pulling from the central cities was stronger than that of the other two mechanisms.Furthermore,the spatial difference between the three mechanisms determines the spatial pattern and its evolution of the urban-rural coordination relationship in Northeast China.Fourth,to promote the development of urban-rural coordination in Northeast China,it is essential to advance urban-rural economic correlation,enhance the government^role in regulating and guiding,and adopt different policies for each region in Northeast China.展开更多
South of Hangzhou Bay, Zhejiang Province, exhibits an embayed muddy coastline, with the muddy beaches of embayments extending continuously seaward.The source of sediments on this coast presents an interesting problem ...South of Hangzhou Bay, Zhejiang Province, exhibits an embayed muddy coastline, with the muddy beaches of embayments extending continuously seaward.The source of sediments on this coast presents an interesting problem to marine geologists and geomorphologists .The total annual load of sediments from the rivers of Zhejiang is only 12×106t.These materials affect only the area near the river mouths. The paper showed that the sediment along the coast of Zhejiang mainly comes from the Changjiang Estuary through analysing the time and space variations of suspended sediment, the features of sediment and the sedimentary transport.The Changjiang River is the largest river system in China, its sediment to the sea amounting to 468×106t. The sediment during summer transports mainly eastward, and is affected by the water body with high temperature, salinity and transparency; the winter season is the period with high sediment concentration. The sediment of the Changjiang Estuary transports together with the longshore current of the East China Sea southward, the southern boundary can reach the sea region approximately 500 km from the Shacheng Harbour. The accretion rate seaward has been about 10 - 30 m since the 16th century. The sediment movement combined the longitudinal with the lateral, so that the muddy flats progress continuously seaward under the construction of the seashore profile .展开更多
The iterative formulas of inbreeding and relationship coefficients were put forward by using numerator elationship. It is suitable for any none - generation - overlap pedigree. The inbreeding and relationship coeffi- ...The iterative formulas of inbreeding and relationship coefficients were put forward by using numerator elationship. It is suitable for any none - generation - overlap pedigree. The inbreeding and relationship coeffi- ient of offsprings can be calculated by those of parents. The deducing process of numerator relationship is simple and clear comparing with path analysis. An example shows the usage of these formulas.展开更多
It is not reasonable to estimate the average relationship degree in statistics by using the mean of relationship coefficients between the individuals in a animal population.According to different usage of relationship...It is not reasonable to estimate the average relationship degree in statistics by using the mean of relationship coefficients between the individuals in a animal population.According to different usage of relationship coefficient,the estimation method of average relationship coefficient in animal population was disscussed by using Z transformation or CSC transformation,respectively,when relationship coefficient shows relationship degree or probability.展开更多
In this paper, the authors numerically analyzed the analytical relationships between angstrom coefficients and optical properties of aerosols to the existing data extracted from OPAC at the spectral length of 0.25 μm...In this paper, the authors numerically analyzed the analytical relationships between angstrom coefficients and optical properties of aerosols to the existing data extracted from OPAC at the spectral length of 0.25 μm to 2.5 μm at eight relative humidity for desert, urban, marine clean and continental clean aerosols. That is apart from their relationships with the wavelength that was determined, in this paper their relation with respect to aerosols’ type and RHs are determined. The properties extracted are scattering, absorption, and extinction coefficients and single scattering albedo. The results showed that the extinction and single scattering albedo are correct for all the aerosols but single scattering co-albedo is satisfied for only sahara and continental clean.展开更多
Objective:To study evolutionary relationship of the 5'untranslated regions(5'UTRs) in low passage dengue3 viruses(DEN3) isolated from hospitalized children with different clinical manifestations in Bangkok dur...Objective:To study evolutionary relationship of the 5'untranslated regions(5'UTRs) in low passage dengue3 viruses(DEN3) isolated from hospitalized children with different clinical manifestations in Bangkok during 24 year-evolution(1977-2000) comparing to the DEN3prototype(H87).Methods:The 5'UTRs of these Thai DEN3 and the H87 prototype were amplified by RT-PCR and sequenced.Their multiple sequence alignments were done by Codon Code Aligner v 4.0.4 software and their RNA secondary structures were predicted by MFOLD software.Replication of five Thai DEN3 candidates comparing to the 1187 prototype were done in human(HepG2) and the mosquito(C6/36) cell lines.Results:Among these Thai DEN3,the completely identical sequences of their first 89 nucleotides,their high-order secondary structure of 5'UTRs and three SNPs including the predominant C90 T,and two minor SNPs including A109 G and A112 G were found.The C90 T of Thai DEN3.Bangkok isolates was shown predominantly before 1977.Five Thai DEN3 candidates with the predominant C90 T were shown to replicate in human(HepG2) and the mosquito(C6/36) cell lines better than the H87 prototype.However,their highly conserved sequences as well as SNPs of the 5'UTR did not appear to correlate with their disease severity in human.Conclusions:Our findings highlighted evolutionary relationship of the completely identical 89 nucleotide sequence,the high-order secondary structure and the predominant C90 T of the 5'UTR of these Thai DEN3 during 24 year-evolution further suggesting to be their genetic markers and magic targets for future research on antiviral therapy as well as vaccine approaches of Thai DEN3.展开更多
In order to reveal the complex network characteristics and evolution principle of China aviation network, the relationship between the node degree and the nearest neighbor average degree and its evolution trace of Chi...In order to reveal the complex network characteristics and evolution principle of China aviation network, the relationship between the node degree and the nearest neighbor average degree and its evolution trace of China aviation network in 1988, 1994, 2001, 2008 and 2015 were studied. According to the theory and method of complex network, the network system was constructed with the city where the airport was located as the network node and the airline as the edge of the network. According to the statistical data, the node nearest neighbor average degree of China aviation network in 1988, 1994, 2001, 2008 and 2015 was calculated. Through regression analysis, it was found that the node degree had a negative exponential relationship with the nearest neighbor average degree, and the two parameters of the negative exponential relationship had linear evolution trace.展开更多
Mitotic metaphase chromosomes of 34 species of Drosophila melanogaster species group were examined. Certain new karyotypes were described for the first time, and their evolutionary and interspecific genetic relationsh...Mitotic metaphase chromosomes of 34 species of Drosophila melanogaster species group were examined. Certain new karyotypes were described for the first time, and their evolutionary and interspecific genetic relationships among 8 subgroups of D. melanogaster species group were analyzed systematically. The results were as follows. The basic karyotype of elegans subgroup was type A. The karyotypes of eugracilis subgroup, melanogaster subgroup, and ficusphila subgroup were all type C. The karyotypes of takahashii subgroup and suzukii subgroup were both type C and type D. The montium subgroup had six kinds of karyotypes types B, C, C＇, D, D＇, and E. The ananassae subgroup had three kinds of karyotypes： types F, G, and H. Thus, the melanogaster species group was classified into five pedigrees based on the diversity of these karyotypes： 1） elegans; 2） eugracilis-melanogasterficusphila; 3） takkahashii-suzukii; 4） montium; 5） ananassae. The above-mentioned results in karyotypic evolution were consistent with those of DNA sequence analysis reported by Yang except for the elegans subgroup and this subgroup was considered as the ancestral subgroup. Karyotype analysis of the same drosophila from different isofemale lines indicated that the same Drosophila from different places showed karyotypic variation which might be due to different geographical environment and evolutionary degree or interaction between the two factors.展开更多
基金funded by the Ecological Civilization Demonstration Area Comprehensive Geological Survey Project“Hydrogeological Survey of Chengde Area”(No.DD20200522)the National Natural Science Foundation of China(Nos.41521001 and 42177078)the“111”Program of China(No.B18049).
文摘Luan River is the main water source in Beijing-Tianjin-Hebei region,northern China,where the groundwater system is vulnerable and pollution issue is serious.It is significant for regional groundwater resources protection to identify the hydrogeochemistry evolution and affecting factors along flow direction occurred in the upper reaches,especially the surface water-groundwater(SWGW)conversion relationship.In this study,recharge,conversion and geochemistry evolution of SW and GW were elucidated based on physical-hydrochemical indicators and stable isotopes in 36 GW samples and 20 SW samples,which were collected in July 2019 and July 2020.The factor analysis was further utilized to determine the main factors responsible for regional hydrogeochemical evolution.Results indicate that GW recharged SW in plateau area,and SW and GW recharged each other in typical Alpine valley area.The hydrochemical types are HCO3-Ca·Mg and HCO3-Ca,and the hydrochemical evolution is dominated by weathering of silicate and carbonate minerals.The cation exchange adsorption has minor impact on groundwater hydrochemistry.The rise of SO42-and NO3-contents in groundwater is related to industrial and agricultural activities.The main controlling factors of SW hydrochemical components included recharge from groundwater,industrial and mining activities,explaining 90.04%of data variance.However,water-rock interaction,agricultural and domestic sewage are responsible for GW quality,accounting for 83.38%.
基金financially supported by the National Natural Science Foundation of China(22279069,22179067,22478211 and 22372017)the Major Fundamental Research Program of Natural Science Foundation of Shandong Province(ZR2022ZD10)。
文摘Understanding the role of cations within the catalysts in the interfacial water behavior at the electrolyte/catalyst interface is of pivotal importance for designing advanced catalysts toward hydrogen evolution reaction(HER),which remains obscure and requires deep probing.Herein,we demonstrate the first investigation of interfacial water behavior on the surface of a series of sodium tungsten bronzes(Na_(x)WO_(3),0_(x)WO_(3)/electrolyte interface.Our integrated studies indicate that the Na ions significantly enrich the electronic state of WO_(6)octahedrons in Na_(x)WO_(3),which leads to the regulated electronic and atomic structures,endowing Na_(x)WO_(3)with disordered interfacial water network containing more isolated H_(3)O^(+)and subsequently moderate H^(*)adsorption to speed the Volmer step at the Na_(x)WO_(3)surface,thus boosting the HER.Consequently,the intrinsic HER activities achieved on those Na_(x)WO_(3)are tens of times higher than those on WO_(3).Particularly,it is found that Na concentration x=0.69 endows Na_(x)WO_(3)with the highest intrinsic HER activity,and the resultant Na_(0.69)WO_(3)with a unique porous octahedral structure exhibits a low overpotential of only 64 mV at current density of 10 mA cm^(-2)in acidic electrolyte.This study provides the first insight into the cation-dependent interfacial water behavior induced by the cations within the catalyst and establishes the interfacial water-activity relationship of HER,thus allowing for the design of a more advanced catalyst with efficient interfacial structu res towa rds HER.
基金financially supported by the National Natural Science Foundation of China(52162036 and 22378342)the Key Project of Nature Science Foundation of Xinjiang(2021D01D08)+1 种基金the Major Projects of Xinjiang(2022A01005-4 and 2021A01001-1)the Key Research and Development Project of Xinjiang(2023B01025-1)。
文摘A thorough understanding of the oxygen evolution reaction(OER)in Mo-based materials is crucial for the advancement of water-splitting technologies.However,the identification of the active phase in Mo-based systems remains a subject of debate,largely due to the dissolution of molybdenum oxides in alkaline electrolytes.In this review,we provide a comprehensive overview of recent advances in the application of Mo-based materials for OER in alkaline media,with an emphasis on their diverse roles in catalysis.Various design strategies employed to optimize Mo-based materials are discussed,focusing on how these approaches influence their physicochemical properties and the specific effects of different design perspectives on their OER performance.Additionally,the structure-performance relationship underlying these materials is explored,offering insights into how structural modifications impact catalytic efficiency.Lastly,key challenges for Mo-based materials in OER applications are provided,and future research directions for further improving the efficacy of sustainable water-splitting technologies in alkaline environments are proposed.
基金financially supported by the Shenzhen Science and Technology Innovation Program(Grant No.JCYJ20220530150011024)。
文摘A comprehensive understanding of the dynamic processes at the catalyst/electrolyte interfaces is crucial for the development of advanced electrocatalysts for the oxygen evolution reaction(OER).However,the chemical processes related to surface corrosion and catalyst degradation have not been well understood so far.In this study,we employ LiCoO_(2) as a model catalyst and observe distinct OER activities and surface stabilities in different alkaline solutions.Operando X-ray diffraction(XRD)and online mass spectroscopy(OMS)measurements prove the selective intercalation of alkali cations into the layered structure of LiCoO_(2) during OER.It is proposed that the dynamic cation intercalations facilitate the chemical oxidation process between highly oxidative Co species and adsorbed water molecules,triggering the so-called electrochemical-chemical reaction mechanism(EC-mechanism).The results of this study emphasize the influence of cations on OER and provide insights into new strategies for achieving both high activity and stability in high-performance OER catalysts.
基金Projects (51021063,51301208) supported by the National Natural Science Foundation of ChinaProject (GZ755) supported by Sino-German Center for Promotion of Science+1 种基金Project (2011CB610401) supported by the National Basic Research Program of ChinaProject supported by Shenghua Scholar Program of Central South University,China
文摘（The effect of liquid diffusion coefficients on the microstructure evolution during solidification of primary （Al） phase in Al356.1 alloy was investigated by means of the phase-field simulation using two sets of diffusion coefficients in liquid phase, while fixing other thermophysical and numerical parameters. The first set is only with impurity coefficients of liquid phase in Arrhenius formula representing only the temperature dependence. While the second set is with the well-established atomic mobility database representing both temperature and concentration dependence. For the second set of liquid diffusion coefficients, the effect of non-diagonal diffusion coefficients on the microstructure evolution in Al356.1 alloy during solidification was also analyzed. The differences were observed in the morphology, tip velocity and composition profile ahead of the tip of the dendrite due to the three cases of liquid diffusivities. The simulation results indicate that accurate databases of mobilities in the liquid phase are highly needed for the quantitative simulation of microstructural evolution during solidification.
文摘During the process of landslide, its dynamic mechanism is important to understand and predict these kinds of natural hazard. In this paper, a new method, based on concepts of complex networks, has been proposed to investigate the evolution of contact networks in mesoscale during the sliding process of slope. A slope model was established using the discrete element method (DEM), and influences of inter-particle frictional coefficients with four different values on?dynamic landslides were studied. Both macroscopic analysis on slope?landslide?and mesoanalysis on structure evolution of contact networks, including the?average degree, clustering coefficient?and N-cycle, were done during the process?of landslide. The analysis results demonstrate that: 1) with increasing inter-particle?frictional coefficients, the displacement of slope decreases and the stable angle of slope post-failure increases, which is smaller than the peak internal frictional angle;2) the average degree decreases with the increase of inter-particle frictional coefficient. When the displacement at the toe of the slope is smaller,?the average degree there changes more greatly with increasing inter-particle?frictional coefficient;3) during the initial stage of landslide, the clustering coefficient?reduces sharply, which may leads to easily slide of slope. As the landslide?going?on, however, the clustering coefficient?increases denoting increasing stability?with?increasing inter-particle frictional coefficients. When the inter-particle?frictional coefficient is smaller than 0.3, its variation can affect the clustering coefficient?and stable inclination of slope post-failure greatly;and 4) the number of?3-cycle increases, but 4-cycle and 5-cycle decrease with increasing inter-particle frictional coefficients.
基金Ministry of Education and Training of Vietnam,Grant No.B2020-GHA-03the University of Transport and Communications,Hanoi,Vietnam.
文摘One of the important geotechnical parameters required for designing of the civil engineering structure is the compressibility of the soil.In this study,the main purpose is to develop a novel hybrid Machine Learning(ML)model(ANFIS-DE),which used Differential Evolution(DE)algorithm to optimize the predictive capability of Adaptive-Network-based Fuzzy Inference System(ANFIS),for estimating soil Compression coefficient(Cc)from other geotechnical parameters namelyWater Content,Void Ratio,SpecificGravity,Liquid Limit,Plastic Limit,Clay content and Depth of Soil Samples.Validation of the predictive capability of the novel model was carried out using statistical indices:Root Mean Square Error(RMSE),Mean Absolute Error(MAE),and Correlation Coefficient(R).In addition,two popular ML models namely Reduced Error Pruning Trees(REPTree)and Decision Stump(Dstump)were used for comparison.Results showed that the performance of the novel model ANFIS-DE is the best(R=0.825,MAE=0.064 and RMSE=0.094)in comparison to other models such as REPTree(R=0.7802,MAE=0.068 and RMSE=0.0988)andDstump(R=0.7325,MAE=0.0785 and RMSE=0.1036).Therefore,the ANFIS-DE model can be used as a promising tool for the correct and quick estimation of the soil Cc,which can be employed in the design and construction of civil engineering structures.
基金support from the U.S.Department of the Army and U.S.Army Future Commandsupport from the U.S.Army Research Laboratory Senior Research Fellowship Program。
文摘The oxygen evolution reaction(OER)is the essential module in energy conversion and storage devices such as electrolyzer,rechargeable metal–air batteries and regenerative fuel cells.The adsorption energy scaling relations between the reaction intermediates,however,impose a large intrinsic overpotential and sluggish reaction kinetics on OER catalysts.Developing advanced electrocatalysts with high activity and stability based on non-noble metal materials is still a grand challenge.Central to the rational design of novel and high-efficiency catalysts is the development and understanding of quantitative structure–activity relationships,which correlate the catalytic activities with structural and electronic descriptors.This paper comprehensively reviews the benchmark descriptors for OER electrolysis,aiming to give an in-depth understanding on the origins of the electrocatalytic activity of the OER and further contribute to building the theory of electrocatalysis.Meanwhile,the cutting-edge research frontiers for proposing new OER paradigms and crucial strategies to circumvent the scaling relationship are also summarized.Challenges,opportunities and perspectives are discussed,intending to shed some light on the rational design concepts and advance the development of more efficient catalysts for enhancing OER performance.
基金supported by the National Natural Science Foundation of China （No.59875071）.
文摘The interaction between thermomechanical parameters and microstructure evolution is so intense that it must be considered during the finite element method （FEM） simulation of the hot plastic working process, for materials that are difficult to deform. Taking the microstructure evolution into account, a novel type of constitutive relationship has been put forward for the IN718 alloy. The microstructure evolution model was first established for the dominant microstructure evolution processes. Then the microstructure evolution models and the method to determine the local flow stress of the corresponding microstructure for current thermomechanical parameters and deformation history were presented. Once the local flow stresses of different structures and their volume contributions were defined, the apparent flow stress of the material could be determined as the weighted sum of the local flow stresses and volume contributions. To validate the proposed method, a thermoviscoplastics and microstructure evolution coupled analysis for a forging process of a critical IN718 disk forging was performed. The predicting results were in close agreement with the experimental data.
基金supported by the National Natural Science Foundation of China(Nos.12272119 and U1965101).
文摘The initial micro-cracks affect the evolution characteristics of macroscopic deformation and failure of rock but are often ignored in theoretical calculation,numerical simulation,and mechanical experiments.In this study,we propose a quantitative analysis model to investigate the effects of initial micro-cracks on the evolution of marble deformation and failure.The relationship between the micro-crack propagation and the marble failure characteristics was comprehensively studied by combining theoretical analysis with a micro-computed tomography(micro-CT)scanning technique.We found that with the increase of confining pressure,the matrix elastic modulus of the marble first increased and then tended to be stable,while the micro-cracks increased exponentially.The sensitivity ranges of the marble sample matrix elastic modulus and micro-cracks to confining pressure were 0–30 MPa and 30–50 MPa,respectively.The porosity and Poisson’s ratio decreased exponentially.The increasing proportion of internal micro-cracks led to an increase in the sample non-uniformity.The samples presented mainly shear failure under triaxial compression,and the failure angle decreased linearly with the increase of confining pressure.The convergence direction of cracks decreased gradually.This quantitative analysis model could accurately portray the relationship between the overall macroscopic deformation and the deviatoric stress of the samples at the compaction and the linear elastic stages,thus deepening the understanding of the stress–strain behavior of rocks.
基金supported by the National Natural Science Foundation of China (Nos.42207175 and 42177117)the Ningbo Natural Science Foundation (No.2022J115)。
文摘Accurate measurement of the evolution of rock joint void geometry is essential for comprehending the distribution characteristics of asperities responsible for shear and seepage behaviors.However,existing techniques often require specialized equipment and skilled operators,posing practical challenges.In this study,a cost-effective photogrammetric approach is proposed.Particularly,local coordinate systems are established to facilitate the alignment and precise quantification of the relative position between two halves of a rock joint.Push/pull tests are conducted on rock joints with varying roughness levels to induce different contact states.A high-precision laser scanner serves as a benchmark for evaluating the photogrammetry method.Despite certain deviations exist,the measured evolution of void geometry is generally consistent with the qualitative findings of previous studies.The photogrammetric measurements yield comparable accuracy to laser scanning,with maximum errors of 13.2%for aperture and 14.4%for void volume.Most joint matching coefficient(JMC)measurement errors are below 20%.Larger measurement errors occur primarily in highly mismatched rock joints with JMC values below 0.2,but even in cases where measurement errors exceed 80%,the maximum JMC error is only 0.0434.Thus,the proposed photogrammetric approach holds promise for widespread application in void geometry measurements in rock joints.
基金the Beijing Municipal Scienceand Technology Project (No.KM202111417006)the Academic Research Projects of Beijing Union University (Nos.ZK10202305 and ZK80202004)the Beijing Municipal Science and Technology Project (No.KM202111417005)。
文摘Due to the diversity of work requirements and environment,the number of degrees of freedom(DOFs)and the complexity of structure of industrial robots are constantly increasing.It is difficult to establish the accurate dynamical model of industrial robots,which greatly hinders the realization of a stable,fast and accurate trajectory tracking control.Therefore,the general expression of the constraint relation in the explicit dynamic equation of the multi-DOF industrial robot is derived on the basis of solving the Jacobian matrix and Hessian matrix by using the kinematic influence coefficients method.Moreover,an explicit dynamic equation with general constraint relation expression is established based on the Udwadia-Kalaba theory.The problem of increasing the time of establishing constraint relationship when the multi-DOF industrial robots complete complex task constraints is solved.With the SCARA robot as the research object,the simulation results show that the proposed method can provide a new idea for industrial robot system modeling with complex constraints.
基金Under the auspices of National Natural Science Foundation of China(No.41401182,41501173)Youth Fund for Humanities and Social Sciences of the Ministry of Education of China(No.19YJC630177)+2 种基金Natural Science Foundation of Heilongjiang Province(No.LH2019D008)University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province(No.UNPYSCT-2018194)Talent Introduction Project of Southwest University(No.SWU019020)。
文摘To comprehensively understand the law of urban-rural relationship and propose scientific measures of urban-rural coordinated development in Northeast China,this study uses the coupling coordination degree model and geographically and temporally weighted regression(GTWR)model to analyze the spatial-temporal patterns and the corresponding driving mechanisms of its urban-rural coordination since 1990.The results are as follows.First,the urban-rural coupling coordination degree in Northeast China was very low and improved slowly,but its stages of evolution is a good interpretation of the strategic arrangements of China's urbanization.Second,the urban-rural coupling coordination degree in Northeast China had spatial differences and was characterized by central polarization,converging on urban agglomeration,which was high in the south and low in the north.Moreover,the gap between the north and south weakened.Third,the spatial-temporal evolution of the urban-rural coordination relationship in Northeast China was influenced by pulling from the central cities,pushing from rural transformation,and government regulations.The influence intensity of the three mechanisms was weak,but the pulling from the central cities was stronger than that of the other two mechanisms.Furthermore,the spatial difference between the three mechanisms determines the spatial pattern and its evolution of the urban-rural coordination relationship in Northeast China.Fourth,to promote the development of urban-rural coordination in Northeast China,it is essential to advance urban-rural economic correlation,enhance the government^role in regulating and guiding,and adopt different policies for each region in Northeast China.
文摘South of Hangzhou Bay, Zhejiang Province, exhibits an embayed muddy coastline, with the muddy beaches of embayments extending continuously seaward.The source of sediments on this coast presents an interesting problem to marine geologists and geomorphologists .The total annual load of sediments from the rivers of Zhejiang is only 12×106t.These materials affect only the area near the river mouths. The paper showed that the sediment along the coast of Zhejiang mainly comes from the Changjiang Estuary through analysing the time and space variations of suspended sediment, the features of sediment and the sedimentary transport.The Changjiang River is the largest river system in China, its sediment to the sea amounting to 468×106t. The sediment during summer transports mainly eastward, and is affected by the water body with high temperature, salinity and transparency; the winter season is the period with high sediment concentration. The sediment of the Changjiang Estuary transports together with the longshore current of the East China Sea southward, the southern boundary can reach the sea region approximately 500 km from the Shacheng Harbour. The accretion rate seaward has been about 10 - 30 m since the 16th century. The sediment movement combined the longitudinal with the lateral, so that the muddy flats progress continuously seaward under the construction of the seashore profile .
文摘The iterative formulas of inbreeding and relationship coefficients were put forward by using numerator elationship. It is suitable for any none - generation - overlap pedigree. The inbreeding and relationship coeffi- ient of offsprings can be calculated by those of parents. The deducing process of numerator relationship is simple and clear comparing with path analysis. An example shows the usage of these formulas.
基金Foundation item :Financed by the Heilongjiang province natural science fund.(1997- 0 3)
文摘It is not reasonable to estimate the average relationship degree in statistics by using the mean of relationship coefficients between the individuals in a animal population.According to different usage of relationship coefficient,the estimation method of average relationship coefficient in animal population was disscussed by using Z transformation or CSC transformation,respectively,when relationship coefficient shows relationship degree or probability.
文摘In this paper, the authors numerically analyzed the analytical relationships between angstrom coefficients and optical properties of aerosols to the existing data extracted from OPAC at the spectral length of 0.25 μm to 2.5 μm at eight relative humidity for desert, urban, marine clean and continental clean aerosols. That is apart from their relationships with the wavelength that was determined, in this paper their relation with respect to aerosols’ type and RHs are determined. The properties extracted are scattering, absorption, and extinction coefficients and single scattering albedo. The results showed that the extinction and single scattering albedo are correct for all the aerosols but single scattering co-albedo is satisfied for only sahara and continental clean.
基金supported by two research grants of Associate Professor Dr.W.Attatippaholkun:Grant No.493-5600-G-00-3461,Program in Science and Technology Cooperation,Human Capacity Development,Bureau for Global Programs,Field Support and Research,US Agency for International Development,Washington,DCThe Royal Golden Jubilee-Ph.D Program,Thailand Research Fund,Thailand
文摘Objective:To study evolutionary relationship of the 5'untranslated regions(5'UTRs) in low passage dengue3 viruses(DEN3) isolated from hospitalized children with different clinical manifestations in Bangkok during 24 year-evolution(1977-2000) comparing to the DEN3prototype(H87).Methods:The 5'UTRs of these Thai DEN3 and the H87 prototype were amplified by RT-PCR and sequenced.Their multiple sequence alignments were done by Codon Code Aligner v 4.0.4 software and their RNA secondary structures were predicted by MFOLD software.Replication of five Thai DEN3 candidates comparing to the 1187 prototype were done in human(HepG2) and the mosquito(C6/36) cell lines.Results:Among these Thai DEN3,the completely identical sequences of their first 89 nucleotides,their high-order secondary structure of 5'UTRs and three SNPs including the predominant C90 T,and two minor SNPs including A109 G and A112 G were found.The C90 T of Thai DEN3.Bangkok isolates was shown predominantly before 1977.Five Thai DEN3 candidates with the predominant C90 T were shown to replicate in human(HepG2) and the mosquito(C6/36) cell lines better than the H87 prototype.However,their highly conserved sequences as well as SNPs of the 5'UTR did not appear to correlate with their disease severity in human.Conclusions:Our findings highlighted evolutionary relationship of the completely identical 89 nucleotide sequence,the high-order secondary structure and the predominant C90 T of the 5'UTR of these Thai DEN3 during 24 year-evolution further suggesting to be their genetic markers and magic targets for future research on antiviral therapy as well as vaccine approaches of Thai DEN3.
文摘In order to reveal the complex network characteristics and evolution principle of China aviation network, the relationship between the node degree and the nearest neighbor average degree and its evolution trace of China aviation network in 1988, 1994, 2001, 2008 and 2015 were studied. According to the theory and method of complex network, the network system was constructed with the city where the airport was located as the network node and the airline as the edge of the network. According to the statistical data, the node nearest neighbor average degree of China aviation network in 1988, 1994, 2001, 2008 and 2015 was calculated. Through regression analysis, it was found that the node degree had a negative exponential relationship with the nearest neighbor average degree, and the two parameters of the negative exponential relationship had linear evolution trace.
基金This work was supported by National Natural Sciences Foundation of China (No. 39930100) International Collaborative Project of Hubei Provincial Department of Education (No. G200610001).
文摘Mitotic metaphase chromosomes of 34 species of Drosophila melanogaster species group were examined. Certain new karyotypes were described for the first time, and their evolutionary and interspecific genetic relationships among 8 subgroups of D. melanogaster species group were analyzed systematically. The results were as follows. The basic karyotype of elegans subgroup was type A. The karyotypes of eugracilis subgroup, melanogaster subgroup, and ficusphila subgroup were all type C. The karyotypes of takahashii subgroup and suzukii subgroup were both type C and type D. The montium subgroup had six kinds of karyotypes types B, C, C＇, D, D＇, and E. The ananassae subgroup had three kinds of karyotypes： types F, G, and H. Thus, the melanogaster species group was classified into five pedigrees based on the diversity of these karyotypes： 1） elegans; 2） eugracilis-melanogasterficusphila; 3） takkahashii-suzukii; 4） montium; 5） ananassae. The above-mentioned results in karyotypic evolution were consistent with those of DNA sequence analysis reported by Yang except for the elegans subgroup and this subgroup was considered as the ancestral subgroup. Karyotype analysis of the same drosophila from different isofemale lines indicated that the same Drosophila from different places showed karyotypic variation which might be due to different geographical environment and evolutionary degree or interaction between the two factors.
