Copper is widely used as conductive components in transmission lines,facing severe corrosion risks.The current passing through copper conductors will significantly affect its corrosion process,yet there is a lack of d...Copper is widely used as conductive components in transmission lines,facing severe corrosion risks.The current passing through copper conductors will significantly affect its corrosion process,yet there is a lack of detailed study on the corrosion mechanism under this specific condition.Thus,this study inves-tigated the effect of direct current current-carrying(DC C-C)conditions on the atmospheric corrosion behavior of copper conductors under thin electrolyte layer(TEL)through electrochemical measurements and corrosion exposure experiments.Results revealed that the presence of DC C-C significantly hastened the corrosion process of copper conductors in the TEL,leading to distinct corrosion patterns at the input and output ends.Furthermore,both the extent of corrosion acceleration and the unevenness of corrosion were positively correlation with the DC C-C level.The above phenomenon was attributed to the special motion of charged particles and paramagnetic substances in TEL under the self-generated magnetic field.展开更多
On the basis of expounding the corrosion mechanism of the stator hollow copper conductor in the water-cooling generator, methods of preventing corrosion of the stator hollow copper conductor in the wa-ter-cooling gene...On the basis of expounding the corrosion mechanism of the stator hollow copper conductor in the water-cooling generator, methods of preventing corrosion of the stator hollow copper conductor in the wa-ter-cooling generator through adjusting water quality of its cooling water have been proposed. For internal water cooling systems which are airtight, the corrosion of the hollow copper conductor can be prevented through keeping foreign oxygen and carbon dioxide from entering the system, and the amount of oxygen in the internal water can be lowered by blowing high purity nitrogen. For systems not airtight, the corrosion of the hollow copper conductor can be inhibited through lowering the amount of oxygen to some extent by sealing and increasing pH value by processing part of cooling water with bypass small flow sodium-type mix-bed.展开更多
Copper sulfide Cu2S is a p-type semiconducting compound that has attracted great attentions in the thermoelectric （TE） community most recently. Considering the intrinsic ultralow lattice thermal conductivity, the en...Copper sulfide Cu2S is a p-type semiconducting compound that has attracted great attentions in the thermoelectric （TE） community most recently. Considering the intrinsic ultralow lattice thermal conductivity, the enhancement of TE performance in CuzS should be achieved through improving its electrical transport properties. To achieve this goal, lithium element was doped into CuzS in this study. A series of Cu2_xLixS samples with different Li contents （x = 0, 0.005, 0.010, 0.050, and 0.100） was synthesized by the melting-annealing method. When x 〈 0.05, the Cuz_xLixS samples are stable and pure phases, having the same monoclinic structure with the pristine Cu2S at room temperature. The electrical conductivities in the Cu2_xLixS samples are greatly improved with the Li-doping content increasing due to the enhanced carrier concentrations. Meanwhile, doping Li into CuzS increases the ionic activation energy and lessens the influence of mobile Cu ions on the heat-carrying phonons. Thus, the thermal conductivities of the Li-doped Cu2S samples increase. A maximal figure of merit （zT） of 0.84 at 900 K is obtained in Cul.99Lio.018, about 133% improvement as compared with that in Cu2S matrix.展开更多
The slight-alkalization of generator internal cooling water(GICW)is widely used to inhibit the corrosion of hollow copper conductor and thereby ensure the safe operation of the generator.CO_(2) inleakage is increasing...The slight-alkalization of generator internal cooling water(GICW)is widely used to inhibit the corrosion of hollow copper conductor and thereby ensure the safe operation of the generator.CO_(2) inleakage is increasingly identified as a potential security risk for GICW system.In this paper,the influence of CO_(2) inleakage on the slight-alkalization of GICW was theoretically discussed.Based on the equilibriums of the CO_(2)-NaOH-H_(2)O system,CO_(2) inleakage saturation was derived to quantify the amount of the dissolved CO_(2) in GICW.This parameter can be directly calculated with the measured conductivity and the[Na+]of GICW.The influence of CO_(2) inleakage on the slight-alkalization conditioning of GICW and the measurement of its water quality parameters were then analyzed.The more severe the inleakage,the narrower the water quality operation ranges of GICW,resulting in the more difficult the slight-alkalization conditioning of GICW.The temperature calibrations of the conductivity and the pH value of GICW show nonlinear correlations with the amount of CO_(2) inleakage and the NaOH dosage.This study provides insights into the influence of CO_(2) inleakage on the slight-alkalization of GICW,which can serve as the theoretical basis for the actual slight-alkalization when CO_(2) inleakage occurs.展开更多
基金supported by the National Natu-ral Science Foundation of China(Nos.52171074 and 52471084)the Young Elite Scientists Sponsorship Program by CAST(No.YESS20220137)the Science and Technology Commission of Shanghai Municipality(No.19DZ2271100).
文摘Copper is widely used as conductive components in transmission lines,facing severe corrosion risks.The current passing through copper conductors will significantly affect its corrosion process,yet there is a lack of detailed study on the corrosion mechanism under this specific condition.Thus,this study inves-tigated the effect of direct current current-carrying(DC C-C)conditions on the atmospheric corrosion behavior of copper conductors under thin electrolyte layer(TEL)through electrochemical measurements and corrosion exposure experiments.Results revealed that the presence of DC C-C significantly hastened the corrosion process of copper conductors in the TEL,leading to distinct corrosion patterns at the input and output ends.Furthermore,both the extent of corrosion acceleration and the unevenness of corrosion were positively correlation with the DC C-C level.The above phenomenon was attributed to the special motion of charged particles and paramagnetic substances in TEL under the self-generated magnetic field.
文摘On the basis of expounding the corrosion mechanism of the stator hollow copper conductor in the water-cooling generator, methods of preventing corrosion of the stator hollow copper conductor in the wa-ter-cooling generator through adjusting water quality of its cooling water have been proposed. For internal water cooling systems which are airtight, the corrosion of the hollow copper conductor can be prevented through keeping foreign oxygen and carbon dioxide from entering the system, and the amount of oxygen in the internal water can be lowered by blowing high purity nitrogen. For systems not airtight, the corrosion of the hollow copper conductor can be inhibited through lowering the amount of oxygen to some extent by sealing and increasing pH value by processing part of cooling water with bypass small flow sodium-type mix-bed.
基金financially supported by the National Natural Science Foundation of China (Nos. 51472262 and 51625205)the Key Research Program of Chinese Academy of Sciences (No.KFZD-SW-421)the Shanghai Government (No. 15JC1400301)
文摘Copper sulfide Cu2S is a p-type semiconducting compound that has attracted great attentions in the thermoelectric （TE） community most recently. Considering the intrinsic ultralow lattice thermal conductivity, the enhancement of TE performance in CuzS should be achieved through improving its electrical transport properties. To achieve this goal, lithium element was doped into CuzS in this study. A series of Cu2_xLixS samples with different Li contents （x = 0, 0.005, 0.010, 0.050, and 0.100） was synthesized by the melting-annealing method. When x 〈 0.05, the Cuz_xLixS samples are stable and pure phases, having the same monoclinic structure with the pristine Cu2S at room temperature. The electrical conductivities in the Cu2_xLixS samples are greatly improved with the Li-doping content increasing due to the enhanced carrier concentrations. Meanwhile, doping Li into CuzS increases the ionic activation energy and lessens the influence of mobile Cu ions on the heat-carrying phonons. Thus, the thermal conductivities of the Li-doped Cu2S samples increase. A maximal figure of merit （zT） of 0.84 at 900 K is obtained in Cul.99Lio.018, about 133% improvement as compared with that in Cu2S matrix.
文摘The slight-alkalization of generator internal cooling water(GICW)is widely used to inhibit the corrosion of hollow copper conductor and thereby ensure the safe operation of the generator.CO_(2) inleakage is increasingly identified as a potential security risk for GICW system.In this paper,the influence of CO_(2) inleakage on the slight-alkalization of GICW was theoretically discussed.Based on the equilibriums of the CO_(2)-NaOH-H_(2)O system,CO_(2) inleakage saturation was derived to quantify the amount of the dissolved CO_(2) in GICW.This parameter can be directly calculated with the measured conductivity and the[Na+]of GICW.The influence of CO_(2) inleakage on the slight-alkalization conditioning of GICW and the measurement of its water quality parameters were then analyzed.The more severe the inleakage,the narrower the water quality operation ranges of GICW,resulting in the more difficult the slight-alkalization conditioning of GICW.The temperature calibrations of the conductivity and the pH value of GICW show nonlinear correlations with the amount of CO_(2) inleakage and the NaOH dosage.This study provides insights into the influence of CO_(2) inleakage on the slight-alkalization of GICW,which can serve as the theoretical basis for the actual slight-alkalization when CO_(2) inleakage occurs.
