A photocatalyst of nanometer TiO2/conjugated polymer complex was successfully synthesized and characterized by spectroscopic methods and photocatalytic experiments. The complex photocatalyst could be activated by abso...A photocatalyst of nanometer TiO2/conjugated polymer complex was successfully synthesized and characterized by spectroscopic methods and photocatalytic experiments. The complex photocatalyst could be activated by absorbing both ultraviolet and visible light （λ = 190-800 nm）. Methylene blue （MB） could be degraded more efficiently on the complex photocatalyst than on the TiO2 under natural light. The conjugated polymer played a promoting role in the photocatalytic degradation of MB. The calcination temperature had an important effect in degradation of dye and could be summarized as 260℃ 〉 300 ℃ 〉 340 ℃ 〉 220 ℃ 〉 180 ℃.展开更多
Functionalized organozinc reagents can easily under 1, 4-addition reaction withunsaturated esters in the presence of catalytic amount of Ni (acac)_2 and tertiary ammes under verymild conditions to give the products in...Functionalized organozinc reagents can easily under 1, 4-addition reaction withunsaturated esters in the presence of catalytic amount of Ni (acac)_2 and tertiary ammes under verymild conditions to give the products in excellent yields.展开更多
Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinear optical property, with susceptibility chi((3)) of 2.4x10(-14) esu (10(-4) mol/L in 1:1 dimethyl sulfoxide/CHCl3 mixed solution) and ...Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinear optical property, with susceptibility chi((3)) of 2.4x10(-14) esu (10(-4) mol/L in 1:1 dimethyl sulfoxide/CHCl3 mixed solution) and second-order hyperpolarizability gamma of 5.18x10(-32) esu via heterodyned ultrafast optical Kerr effect measurement. It existed mainly as 1:1 complex oligomers and polymers as characterized by mass spectroscopy and elemental analysis etc.展开更多
In this paper, Method of Kobayashi Potential is used to determine the scattering behavior of a strip which is placed at the air-complex conjugate medium interface. And discussion is presented that how the complex conj...In this paper, Method of Kobayashi Potential is used to determine the scattering behavior of a strip which is placed at the air-complex conjugate medium interface. And discussion is presented that how the complex conjugate medium mod-ify the scattering properties of the strip. A comparison is also given with that if we replace the conjugate medium with standard dielectric medium. E-polarized electromagnetic plane wave is supposed to be obliquely incident upon the ge-ometry. Scattered fields in both the half spaces are supposed in terms of unknown weighting functions. Discontinuous properties of Weber-Schafheitlin integral and orthogonal properties of Jacobi’s polynomials are used to determine these unknown weighting functions. Far scattered fields have been calculated using Saddle Point Method and computed for different parameters of interest.展开更多
metol-free Robson -type macrocycle was synthesized for first time by proton-templation and from that the metal complexes were prepared.By X-ray study the structure of Ni(Ⅱ)-complex was characterized.
(η^-C_H_5)_2CeCl_5Mg_2(tmed)_2 was used as a catalyst to polymerize isoprene,Terminal ends of polyisoprene were identified as -CH_2-CH=CH_,which indicates that the insertion reaction of the monomer occurred between ...(η^-C_H_5)_2CeCl_5Mg_2(tmed)_2 was used as a catalyst to polymerize isoprene,Terminal ends of polyisoprene were identified as -CH_2-CH=CH_,which indicates that the insertion reaction of the monomer occurred between η^-allyl and cerium ion and gives a direct evidence for the η^-allyl mechanism of conjugated diene polymerzation with rare earth coordination catalysts.展开更多
Gradient-based iterative algorithm is suggested for solving a coupled complex conjugate and transpose matrix equations. Using the hierarchical identification principle and the real representation of a complex matrix, ...Gradient-based iterative algorithm is suggested for solving a coupled complex conjugate and transpose matrix equations. Using the hierarchical identification principle and the real representation of a complex matrix, a convergence proof is offered. The necessary and sufficient conditions for the optimal convergence factor are determined. A numerical example is offered to validate the efficacy of the suggested algorithm.展开更多
The signal synchronization transmission of a spatiotemporal chaos network is investigated. The structure of the coupling function between connected nodes of the complex network and the value range of the linear term c...The signal synchronization transmission of a spatiotemporal chaos network is investigated. The structure of the coupling function between connected nodes of the complex network and the value range of the linear term coefficient of the separated configuration in state equation of the node are obtained through constructing an appropriate Lyapunov function. Each node of the complex network is a laser spatiotemporal chaos model in which the phase-conjugate wave and the unilateral coupled map lattice are taken as a local function and a spatially extended system, respectively. The simulation results show the effectiveness of the signal synchronization transmission principle of the network.展开更多
Conjugated Schiff base macrocycles containing 1,3,3-oxadiazole were prepared by [2 + 2] cyclic condensation of phenylenediamine with 2,5-bis(m-formyl-phenyl)-1,3,4-oxadiazole. These macrocycles with iodine or TCNQ pro...Conjugated Schiff base macrocycles containing 1,3,3-oxadiazole were prepared by [2 + 2] cyclic condensation of phenylenediamine with 2,5-bis(m-formyl-phenyl)-1,3,4-oxadiazole. These macrocycles with iodine or TCNQ produced stable charge-transfer complexes. The formation of complexes were identified by UV-Vis and FT-IR spectra.展开更多
Fluorescence switch plays a vital role in bioelectronics and bioimaging.Herein,we presented a new kind of facile electrostatic complex nanoparticles(ECNs)for fluorescence switching in cells and marking of individual c...Fluorescence switch plays a vital role in bioelectronics and bioimaging.Herein,we presented a new kind of facile electrostatic complex nanoparticles(ECNs)for fluorescence switching in cells and marking of individual cell.The ECNs were prepared by mixing positively charged poly(6-(2-(thiophen-3-yl)ethoxy)hexyl trimethylammonium bromide)(PT)and negatively charged diarylethene sodium salt(DAECOONa).DAE-COONa is a photoswitchable molecule which can be transformed between the ring-closed fo rm and ring-open form under the irradiation of UV or visible light.The closed-form of DAE-COONa can efficie ntly quench the fluorescence of PT through intermolecular energy transfer,while the open form of DAE-COONa does not influence the emission of PT.Thus,the fluorescence of ECNs can be modulated by light irradiation,and the ECNs with good fluorescence switching performance have been employed for fluorescence imaging and individual cell lighting up process successfully.We demonstrate that the electrostatic complex strategy provides a facile method to construct fluorescence switch fo r selective cell marking and imaging applications.展开更多
Et3N(Mn^Ⅱ-triethylamine)complex conjugated with binuclear Mn^Ⅲ-hydroxide,Mn2(OH)3Cl and similar manganese complex with Et2NH(diethylamine)self-assembled in aqueous solutions have been investigated by simultaneous AF...Et3N(Mn^Ⅱ-triethylamine)complex conjugated with binuclear Mn^Ⅲ-hydroxide,Mn2(OH)3Cl and similar manganese complex with Et2NH(diethylamine)self-assembled in aqueous solutions have been investigated by simultaneous AFM(atomic force microscopy)and SNOM(scanning near-field optical microscopy)in thin layers prepared on mica and PET(polyethylene terephthalate)The size of the particles after crystallization of the precipitated former conjugate was controlled with XRD(X-ray diffraction).It is found that the conjugate self-assembling produces the smallest grains with the diameter of 65±7.5 nm measured at contact with the support.This particle size matches the crystallite size of 44.2 nm found by XRD for the conjugate taking into account the particles deformation under the contact with the support.The self-assembly of the smallest particles in solution has produced non-transparent for light core observed on mica with the size varied between 300 to 400 nm.The latter occurs due to hydrophobic interactions since no core of the former conjugate has been found on hydrophobic PET surface.No submicroscopic core is also found in the case of similar conjugate with Mn^Ⅱ-Et2NH complex on PET film and mica both.展开更多
A novel imidazole derivative with functional group and π-conjugated system, 1- [trans-4-（4-diethylaminostyryl）phenyl]imidazole （abbreviated as L）, and its Con complex （COCl2L4）2 （Co2C168H184N24Cl4, Mr = 2799....A novel imidazole derivative with functional group and π-conjugated system, 1- [trans-4-（4-diethylaminostyryl）phenyl]imidazole （abbreviated as L）, and its Con complex （COCl2L4）2 （Co2C168H184N24Cl4, Mr = 2799.05 ） have been synthesized and the crystal structure of the latter was determined by X-ray diffraction. The crystal is of triclinic, space group PI with a = 8.823（3）, b = 18.799（7）, c =23.065（9） A, α = 77.349（6）, β = 83.128（7）, ）, γ= 80.942（3）°, V = 3671.5（12） A^3, Z = 1, Dc = 1.266 g/cm^3,/z = 0.361 mm^-1 F（000） = 1482, the final R = 0.0587 and wR = 0.1284 for 6562 observed reflections with I 〉 2σ（I）. In the molecular structure of （COCl2L4）2, there are two crystallographically unique units. The Co^Ⅱ atoms are six-coordinated by four N atoms from four imidazole ligands （L） and two Cl atoms to form a distorted octahedral geometry. The optical properties of complex （COCl2L4）2 have been experimentally studied.展开更多
文摘A photocatalyst of nanometer TiO2/conjugated polymer complex was successfully synthesized and characterized by spectroscopic methods and photocatalytic experiments. The complex photocatalyst could be activated by absorbing both ultraviolet and visible light （λ = 190-800 nm）. Methylene blue （MB） could be degraded more efficiently on the complex photocatalyst than on the TiO2 under natural light. The conjugated polymer played a promoting role in the photocatalytic degradation of MB. The calcination temperature had an important effect in degradation of dye and could be summarized as 260℃ 〉 300 ℃ 〉 340 ℃ 〉 220 ℃ 〉 180 ℃.
文摘Functionalized organozinc reagents can easily under 1, 4-addition reaction withunsaturated esters in the presence of catalytic amount of Ni (acac)_2 and tertiary ammes under verymild conditions to give the products in excellent yields.
文摘Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinear optical property, with susceptibility chi((3)) of 2.4x10(-14) esu (10(-4) mol/L in 1:1 dimethyl sulfoxide/CHCl3 mixed solution) and second-order hyperpolarizability gamma of 5.18x10(-32) esu via heterodyned ultrafast optical Kerr effect measurement. It existed mainly as 1:1 complex oligomers and polymers as characterized by mass spectroscopy and elemental analysis etc.
文摘In this paper, Method of Kobayashi Potential is used to determine the scattering behavior of a strip which is placed at the air-complex conjugate medium interface. And discussion is presented that how the complex conjugate medium mod-ify the scattering properties of the strip. A comparison is also given with that if we replace the conjugate medium with standard dielectric medium. E-polarized electromagnetic plane wave is supposed to be obliquely incident upon the ge-ometry. Scattered fields in both the half spaces are supposed in terms of unknown weighting functions. Discontinuous properties of Weber-Schafheitlin integral and orthogonal properties of Jacobi’s polynomials are used to determine these unknown weighting functions. Far scattered fields have been calculated using Saddle Point Method and computed for different parameters of interest.
文摘metol-free Robson -type macrocycle was synthesized for first time by proton-templation and from that the metal complexes were prepared.By X-ray study the structure of Ni(Ⅱ)-complex was characterized.
文摘(η^-C_H_5)_2CeCl_5Mg_2(tmed)_2 was used as a catalyst to polymerize isoprene,Terminal ends of polyisoprene were identified as -CH_2-CH=CH_,which indicates that the insertion reaction of the monomer occurred between η^-allyl and cerium ion and gives a direct evidence for the η^-allyl mechanism of conjugated diene polymerzation with rare earth coordination catalysts.
文摘Gradient-based iterative algorithm is suggested for solving a coupled complex conjugate and transpose matrix equations. Using the hierarchical identification principle and the real representation of a complex matrix, a convergence proof is offered. The necessary and sufficient conditions for the optimal convergence factor are determined. A numerical example is offered to validate the efficacy of the suggested algorithm.
基金Project supported by the Natural Science Foundation of Liaoning Province,China (Grant No. 20082147)
文摘The signal synchronization transmission of a spatiotemporal chaos network is investigated. The structure of the coupling function between connected nodes of the complex network and the value range of the linear term coefficient of the separated configuration in state equation of the node are obtained through constructing an appropriate Lyapunov function. Each node of the complex network is a laser spatiotemporal chaos model in which the phase-conjugate wave and the unilateral coupled map lattice are taken as a local function and a spatially extended system, respectively. The simulation results show the effectiveness of the signal synchronization transmission principle of the network.
文摘Conjugated Schiff base macrocycles containing 1,3,3-oxadiazole were prepared by [2 + 2] cyclic condensation of phenylenediamine with 2,5-bis(m-formyl-phenyl)-1,3,4-oxadiazole. These macrocycles with iodine or TCNQ produced stable charge-transfer complexes. The formation of complexes were identified by UV-Vis and FT-IR spectra.
基金supported by the National Natural Science Foundation of China(Nos.91527306,21661132006)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA16020804)the Youth Innovation Promotion Association CAS(No.2016029)。
文摘Fluorescence switch plays a vital role in bioelectronics and bioimaging.Herein,we presented a new kind of facile electrostatic complex nanoparticles(ECNs)for fluorescence switching in cells and marking of individual cell.The ECNs were prepared by mixing positively charged poly(6-(2-(thiophen-3-yl)ethoxy)hexyl trimethylammonium bromide)(PT)and negatively charged diarylethene sodium salt(DAECOONa).DAE-COONa is a photoswitchable molecule which can be transformed between the ring-closed fo rm and ring-open form under the irradiation of UV or visible light.The closed-form of DAE-COONa can efficie ntly quench the fluorescence of PT through intermolecular energy transfer,while the open form of DAE-COONa does not influence the emission of PT.Thus,the fluorescence of ECNs can be modulated by light irradiation,and the ECNs with good fluorescence switching performance have been employed for fluorescence imaging and individual cell lighting up process successfully.We demonstrate that the electrostatic complex strategy provides a facile method to construct fluorescence switch fo r selective cell marking and imaging applications.
文摘Et3N(Mn^Ⅱ-triethylamine)complex conjugated with binuclear Mn^Ⅲ-hydroxide,Mn2(OH)3Cl and similar manganese complex with Et2NH(diethylamine)self-assembled in aqueous solutions have been investigated by simultaneous AFM(atomic force microscopy)and SNOM(scanning near-field optical microscopy)in thin layers prepared on mica and PET(polyethylene terephthalate)The size of the particles after crystallization of the precipitated former conjugate was controlled with XRD(X-ray diffraction).It is found that the conjugate self-assembling produces the smallest grains with the diameter of 65±7.5 nm measured at contact with the support.This particle size matches the crystallite size of 44.2 nm found by XRD for the conjugate taking into account the particles deformation under the contact with the support.The self-assembly of the smallest particles in solution has produced non-transparent for light core observed on mica with the size varied between 300 to 400 nm.The latter occurs due to hydrophobic interactions since no core of the former conjugate has been found on hydrophobic PET surface.No submicroscopic core is also found in the case of similar conjugate with Mn^Ⅱ-Et2NH complex on PET film and mica both.
基金This work was supported by the National Natural Science Foundation of China (50532030, 50335050, and 50325311) and Education Committee of Anhui Province (2006KJ158B)
文摘A novel imidazole derivative with functional group and π-conjugated system, 1- [trans-4-（4-diethylaminostyryl）phenyl]imidazole （abbreviated as L）, and its Con complex （COCl2L4）2 （Co2C168H184N24Cl4, Mr = 2799.05 ） have been synthesized and the crystal structure of the latter was determined by X-ray diffraction. The crystal is of triclinic, space group PI with a = 8.823（3）, b = 18.799（7）, c =23.065（9） A, α = 77.349（6）, β = 83.128（7）, ）, γ= 80.942（3）°, V = 3671.5（12） A^3, Z = 1, Dc = 1.266 g/cm^3,/z = 0.361 mm^-1 F（000） = 1482, the final R = 0.0587 and wR = 0.1284 for 6562 observed reflections with I 〉 2σ（I）. In the molecular structure of （COCl2L4）2, there are two crystallographically unique units. The Co^Ⅱ atoms are six-coordinated by four N atoms from four imidazole ligands （L） and two Cl atoms to form a distorted octahedral geometry. The optical properties of complex （COCl2L4）2 have been experimentally studied.
