摘要
酞菁过渡金属大环配合物已广泛应用于能量转化与储存等相关的电化学反应过程,包括催化氧还原反应(ORR)和析氧反应(OER)等,其良好的催化氧反应双功能性能引起了广泛关注。本文主要综述了金属酞菁类催化剂的制备方法及当前研究进展,综述了影响金属酞菁类催化剂性能的因素,如:金属酞菁的结构、载体、中心金属离子及双金属离子的协同效应和边缘修饰基团的影响等。分析了全共轭结构对其热稳定性和催化性能提升的影响;聚合金属酞菁配合物和三维石墨烯的π-π相互作用有利于提高催化活性和耐久性;两种金属之间的协同效应和边缘修饰的供电子基团可以提升催化性能。
Phthalocyanine transition metal macrocyclic complexes have been widely applied in electrochemical reaction processes related to energy conversion and storage,including catalytic oxygen reduction reaction(ORR)and oxygen evolution reactions(OER),etc.Their excellent bifunctional performance in catalytic oxygen reactions has attracted extensive attention.This article mainly reviews the preparation methods and current research progress of metal phthalocyanine-based catalysts,as well as the factors influencing the performance of metal phthalocyanine-based catalysts,such as the structure of metal phthalocyanine,the support,the synergistic effect of central metal ions and bimetallic ions,and the influence of edge modification groups,etc.The influence of the fully conjugated structure on its thermal stability and the improvement of catalytic performance was analyzed;The π-π interaction between polymeric metal phthalocyanine complexes and three-dimensional graphene is conducive to improving catalytic activity and durability.The synergistic effect between the two metals and the edge-modified electron-donating groups can enhance catalytic performance.
作者
庄延琼
孙迎港
孙鹏
李忠芳
Yanqiong Zhuang;Yinggang Sun;Peng Sun;Zhongfang Li(School of Chemistry and Chemical Engineering,Shandong University of Technology,Zibo 255086,China)
出处
《化学进展》
北大核心
2025年第9期1290-1300,共11页
Progress in Chemistry
基金
国家自然科学基金项目(No.22172093,21776167)
山东省自然科学基金项目(No.ZR2023MB061)资助。
